IRG Documents Database and Compendium


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The biocidal efficacy of sulphates against basidiomycetes
1999 - IRG/WP 99-30192
Copper sulphate is used for the preservation of wood since decades. However, if copper sulphate is not combined with a compound it can be leached up to 50% and more from the treated wood. Previous results for leached wood indicated that the loss of biological efficacy against soft rot corresponds to leaching of copper. For basidiomycetes, however, the effectiveness decreases much more rapidly. The...
H Leithoff, E Melcher


A review of the current status of the estimation of emissions from preserved wood and their use in the environmental risk assessment of wood preservatives under the Biocidal Products Directive
2005 - IRG/WP 05-50224-7
A review and update of the status of the issues concerning the estimation of emissions from preserved wood (e.g. amendments to the proposed ‘OECD Guidelines’), and the environmental risk assessment of wood preservatives under the Biocidal Products Directive (e.g. compartmental sizes, emissate ecotoxicity testing)....
E F Baines


Biocidal Products Directive 98/8/EC and PT 08
2005 - IRG/WP 05-50224-1
The ECB Biocides Work Area is responsible for the scientific and technical issues concerning the approval of active substances in biocidal products as laid down in Directive 98/8/EC concerning the placing of biocidal products on the market. The first part of the presentation will deal with the Review Programme, especially it's legal context, the status of submitted dossiers and the p...
K van der Jagt


Biocidal property of the phenolic fraction of ethanol extractives of Hopea parviflora heartwood
1993 - IRG/WP 93-30003
Natural resistance of some species of timber to fungal decay and insect damage (particularly termite) is ascribed toxic nature and quantity of certain chemical substances present in the cell wall of heartwood. These chemical substances generally known to be Phenolic and Polyphenolic compounds (Rao 1982). Earlier investigations on extractives were mainly in relation to resistance of timber to decay...
R V Krishnan, K S Theagarajan, H S Ananthapadmanabha, M Nagaraja Sharma, V V Prabhu, H C Nagaveni


Addition of boron compounds and octanoic acid for improvement of biocidal properties and copper fixation at copper-ethanolamine based wood preservatives
2006 - IRG/WP 06-30408
Copper-ethanolamine based wood preservatives became important active substance (formulation) for wood protection, novelty. As copper itself can not ensure sufficient protection against wood destroying organisms and fixation in wood we combine it with other biocides like ethanolamine, boron and octanoic acid. This investigates were performance on spruce wood impregnated with different combination o...
F Pohleven, M Humar


Thermal decomposition behavior of CCA-treated wood for safe disposal and the safe recovery of heavy metals through pyrolysis
2006 - IRG/WP 06-50238
If we could estimate the chemical changes in heavy metals by temperature in chromated copper arsenate (CCA)-treated wood during pyrolysis, it is expected that we could solve the environmental problems of heavy metals, which may occur during pyrolysis, and therefore, the thermal decomposition behavior of effective elements of CCA-treated wood was examined to find a safe disposal method. First, CCA-...
Dong Won Son, Dong-heub Lee, Sun-hae Cheon, Myung Jae Lee


Micro-Distribution of Metals in Wood Treated with a Nano-Copper Wood Preservative
2007 - IRG/WP 07-40360
The microdistribution of copper in southern pine treated with a newly-developed nano-copper wood preservative was examined to determine if it differed from that reported for wood treated with conventional copper-based wood preservatives. Field Emission Scanning Electron Microscopy (FE-SEM) in combination with x-ray microanalysis (EDX) revealed the presence of nano-sized copper and iron particles i...
H Matsunaga, M Kiguchi, P Evans


Effect of barriers on moisture content of treated and non-treated utility poles
2007 - IRG/WP 07-40369
The potential for non-biocidal barriers to slow moisture sorption was investigated using butt treated western redcedar poles immersed in either water or moist soil over a 2 year period. Moisture sorption was initially slowed by the barriers, but openings at the bottoms of the barriers eventually allowed moisture to migrate upward. Moisture levels in wrapped poles eventually reached those found in...
C S Love, J J Morrell


Refinement of emission values for preserved wood in the ‘Storage Scenario’, for use in the environmental risk assessment of Wood Preservatives under the Biocidal Products Directive
2007 - IRG/WP 07-50244
The evaluation of an active substance or a biocidal product under the Biocidal Products Directive (BPD) requires that an environmental risk assessment is carried out. The risk assessment for wood preservatives includes a scenario for the treated wood in storage after treatment, in which the predicted environmental concentration (PEC) in soil, surface water and groundwater is calculated, using emis...
E F Baines


A hypothesis on a second non-biocidal property of wood extractives, in addition to toxicity, that affects termite behavior and mortality
2008 - IRG/WP 08-10638
While it is has long been recognized that heartwood extractives affect termite behavior, the exact cause and relationship between total extractives, extractive types, and termite resistance remains unclear. Generally, researchers have proposed that the extractives are toxic and/or repel termites. We propose, based on the well known fact that many extractives have excellent antioxidant properties...
T P Schultz, K Ragon, D D Nicholas


The role of chromium in wood preservatives under BPD - a review and the current situation in Europe
2008 - IRG/WP 08-30468
Already during the IRG-meeting in Trømso a paper was presented to give an overview regarding the situation on chromium (JÜNGEL et al. 2006). Already in that year there was an increased attempt to achieve a science-based correct and harmonised solution in Europe regarding the chromium-question by the European Commission. Nevertheless the competent authorities (CAs) and the industry were similarly...
P Jüngel, S Hellkamp


Wood preservative obtained by recycling – preliminary selection of leaching inhibitor
2008 - IRG/WP 08-50252
Based on recycling of used household batteries, a process was developed to enable the recovery of major manufacturing components, leading to a solution of zinc (32 g.l-1) and manganese (15 g.l-1) salts, free of heavy metals. The potential use of the above solution as wood preservative was demonstrated by means of assays both of fungicidal activity -using white and brown rot fungi- and of insectici...
C Ibáñez, C Mantero, G Cecchetto, M Rabinovich, M Cerdeiras


Rapid Microwave-Assisted Acid Extraction of Metals from Chromated Copper Arsenate (CCA)-Treated Southern Pine Wood
2009 - IRG/WP 09-50262
The effects of acid concentration, reaction time, and temperature in a microwave reactor on recovery of CCA-treated wood were evaluated. Extraction of copper, chromium, and arsenic metals from chromated copper arsenate (CCA)-treated southern pine wood samples with three different acids (i.e., acetic acid, oxalic acid, and phosphoric acid) was investigated using in microwave reactor. Oxalic acid wa...
Bin Yu, Chung Y Hse, T F Shupe


Fungal Attack on Lignin and Cellulose: Elucidation of Brown- and White-Rot Mechanisms Comparing Biomimetic and In-Vivo Degradation Patterns
2010 - IRG/WP 10-10714
This paper examines research and hypotheses that have been developed over several years on wood degradation mechanisms. This information is combined with new data and analyses to explain why wood decay patterns caused by brown-rot fungi and specific types of white-rot fungi are different. New data, including work with both biomimetic studies on low molecular weight compounds, degradative enzymes, ...
V Arantes, B Goodell, A M F Milagres, Yuhui Qian, T Filley, J Jellison, S Kelley


Effect of Heavy Metals on the Expression of Manganese Dependent Peroxidases of Phanerochaete chrysosporium
2010 - IRG/WP 10-10722
This work is part of an ongoing investigation that studies the application of a solution rich in Zn and Mn, obtained from a recycling process, as a preservative for wood. The effects of Zn2+ and Mn2+ on the enzyme-expression level of manganese-dependent peroxidase (MnP) from Phanerochaete chrysosporium was studied by real-time PCR. The glyceraldehyde 3-phosphate dehydrogenase gene (gpd) was used a...
C Ibáñez, M Rabinovich, M Barraco, G Gecchetto, M Cerdeiras


Toward an assessment of copper bioavailability in treated wood
2010 - IRG/WP 10-20445
Many modern wood preservative systems rely on copper (Cu). Some oxalate-producing fungi detoxify Cu by immobilizing it in crystals, and this may decrease its physiological availability (bioavailability). Cu bioavailability may also decrease during wood treatment. Cu retention in wood, however, is typically measured as a weight-to-volume concentration without an estimate of its bioavailability and ...
J S Schilling, J J Inda


The assessment of biological and mechanical properties of wood treated with ionic liquids – N,N-dimethylamine and 1-decylimidazole derivatives
2012 - IRG/WP 12-40582
This paper presents the results of tests of the effectiveness of action of new imidazolium and bis-ammonium ionic liquids against Basidiomycotina and Ascomycotina wood-destroying fungi. All the investigated ionic liquids showed high fungicidal action against Coniophora puteana. In order to characterize the influence of ionic liquids on mechanical wood properties, the compression strength along the...
W Przybylska


Influence of Exposure Direction on Leaching of a Biocide from Painted Wood Surfaces
2014 - IRG/WP 14-50303
The objective of this project was to investigate the influence different exposure directions – North, East, South and West on the cumulative quantity of a biocide leached from painted wood surfaces due to rainfall and the consequences for the risk assessment. The study included a solvent-borne primer without biocides and a topcoat protected with a biocidal active substance. Both products were a...
M Klamer


Practical extraction of metals from CCA-treated wood
2014 - IRG/WP 14-50305
The extraction effects of acid concentration, reaction time and temperature in a microwave reactor on recovery of chromated copper arsenate (CCA)-treated wood were evaluated. Extraction of copper, chromium, and arsenic metals from CCA-treated southern pine wood samples with three different wood particle sizes (i.e., (1) 0.5 cm3, (2) 0.5x05x1.0 cm, and (3) 0.5x0.5x1.5 cm) was investigated using a m...
Bin Yu, Chung Y Hse, T F Shupe


Biocidal Products Regulation – Structure and Impact for Product Authorization and Testing in EU
2014 - IRG/WP 14-50308
Since September 2013 the Biocidal Products Regulations (BPR) has been in force in Europe. BPR replaces the Biocidal Products Directive (EC/98/8) and in some respect marks a turning point in the European legislation concerning registration of all types of biocides. BPR introduces some changes both for suppliers of active substances and for companies that produce and place biocide containing wood p...
M Klamer


Functional silicones used as a potential tool for the development of non-biocidal wood treatments
2015 - IRG/WP 15-30665
The increase of wood resistance against biological agents for outdoor use is conventionally performed by deep impregnation with preservatives. However, some of the traditional wood preservatives, used for decades for wood protection and regarded as the most effective, are currently subjected to severe restrictions because of their toxicity. In fact, new preservation technologies are constantly ent...
F Lhumeau, C Delaite, F Marchal, F Pochon, M Kutnik


Enhancing wood properties through bio-based and non-biocidal co-polyesters
2016 - IRG/WP 16-40740
The commonly used wood preservation treatments are nowadays facing huge environmental issues, as well as increasing public concern. As regards those concerns, legislation tends to regulate the use of biocidal preservation chemicals. Thus, it does appear crucial to provide alternatives to the use of biocides to allow different outdoor uses of wood such as for, posts, decking, and cladding or even ...
C L’Hostis, M-F Thévenon, E Fredon, P Gérardin


Evaluation of Commercially Available Polyurethane Resin to Develop Non-biocidal Wood Preservation Treatments
2016 - IRG/WP 16-40751
Evaluation of commercially available polyurethane (PU1 and PU2 and polyisocyanate (PNCO) to develop non-biocidal wood preservation treatments have been conducted. A simple method by vacuum impregnation of these resins into beech wood (Fagus sylvatica L) and pine wood (Pinus sylvestris L.) samples followed by varied curing process at ambient temperature, 103oC, and 200oC have been performed. Based ...
M Mubarok, Y Sudo Hadi, J Suryana, I W Darmawan, F Simon, S Dumarcay, C Gérardin, P Gérardin


Ensuring Quality of Treated Wood – Regulations, Certifications and Associative Background in the Field of Wood Protection in Europe
2017 - IRG/WP 17-20626
Beside legal requirements, buyers and end-users of wood preservatives and/or of treated wood and wood-based materials may require additional warranties regarding the quality and the performance of the products available on the market. These greatly enhance the confidence of end-users and the chance for a product of being marketed with a quality label. Additionally, quality control systems and trai...
M Kutnik, M Klamer, E Melcher


Guidance on the European Biocidal Products Regulation Concerning Efficacy of Wood Preservatives
2017 - IRG/WP 17-20627
In Europe wood preservatives belong to Product Type 8 (PT8) of the Biocidal Products Regulation (BPR, EU n. 528/2012), which regulates the authorisation of biocidal active substances and products in the European market. The applicant, who aims to obtain authorization to place a product onto the European market, needs to submit data to substantiate the label claims for the intended uses. Label cla...
I Stephan, M Kutnik, E Conti, M Klamer, L Nunes, J Van Acker, R Plarre


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