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Effect of leaching temperature and water acidity on the loss of metal elements from CCA treated timber in aquatic applications. Part 1: Laboratory scale investigation
1995 - IRG/WP 95-50046
In order to investigate the applicability of current prestandard leaching test methods, a series of experiments has been performed on CCA impregnated wood dealing with the influence of pH, temperature and agitation of the surrounding water. The leaching method used in this first part of the investigation is the European prestandard drafted by CEN/TC38/WG11, a short term dynamic leaching test under...
G M F Van Eetvelde, R J Orsler, G E Holland, M Stevens


Termite resistance of treated wood in an above-ground field test
1986 - IRG/WP 1300
This paper provides an update on the results from an above ground field test evaluating the effectiveness of wood preservatives against subterranean termites. Results for the one and two year inspections of treated southern pine sapwood exposed in Hawaii to Coptotermes formosanus are presented. Chromated copper arsenate is providing excellent protection as is the pyrethroid deltamethrin. Borate an...
A F Preston, P A McKaig, P J Walcheski


Examination of preservative-treated Pinus sylvestris using electron paramagnetic resonance
1992 - IRG/WP 92-3710
EPR is currently being used to help elucidate the nature and extent of the chemical reactions occurring between wood and copper based timber preservatives. In the work reported here treated Scots pine samples were examined at room temperature and in the frozen state. Plots of the electronic parameters A|| vs. g|| were found to be a useful index of the electronic properties of the various formulati...
A S Hughes, R J Murphy, J F Gibson, A J Cornfield


Interaction of copper-amine complexes with wood: Influence of copper source, amine ligands and amine to copper molar ratio on copper retention and leaching
1999 - IRG/WP 99-30203
The absorption and leachability of copper in copper amine (Cu-EA) treated wood are influenced by the formulation and the composition of copper amine treating solutions. The sources of copper used, Cu(OH)2, CuCO3, CuSO4 and Cu(NO3)2, in the copper amine complex formulation affect the leachability of copper. Data show that copper amine from CuSO4 and Cu(NO3)2 treated wood has less copper loss during...
Jun Zhang, D P Kamdem


Penetration and absorption of water-borne preservatives in conifers from the Western United States: A preliminary report
1988 - IRG/WP 3475
The treatment of most softwoods from the western United States with waterborne chemicals poses a major challenge. Although many of these species are commercially treated with waterbornes, there is considerable debate about their treatability. At present, there is little or no information on the treatability of western wood species with waterborne chemicals. The lack of accurate treatability inform...
S Kumar, J J Morrell


The microbial ecology of treated birch stakes in a soil-bed
1983 - IRG/WP 1209
The microbial ecology of small birch stakes exposed in soil beds in two Fungus Cellars was investigated. Patterns of fungal colonisation and decay initiation are described in untreated birch and copper fluosilicate-treated stakes. Results are based on fungal isolation onto selective media and direct light microscopical observations of decay features. In untreated stakes there was a rapid build-up ...
C P Clubbe


Influence of water soluble extractives on CCA fixation and leaching performance of red maple and red oak
1997 - IRG/WP 97-30133
We have observed several peculiarities in relation to CCA fixation in red maple and red oak woods such as high variability in fixation rates and leaching performance in maple and precipitate formation in solutions expressed from CCA treated red oak wood blocks at different stages of fixation. We have postulated that the extractives could be the factor of influence, as this has already been reporte...
T Stevanovic-Janezic, P A Cooper, Y T Ung


Depletion of preservatives from treated wood: Results from laboratory, fungus cellar and field test
1993 - IRG/WP 93-50001-07
This paper compares results of preservative component losses using a range of test procedures with several different water-borne preservatives. The data shows that laboratory leaching tests are in some cases comparable to, but in other cases significantly underestimate preservative component losses when compared with field or fungus cellar depletion tests. The results also suggest that preservativ...
L Jin, A F Preston


Leaching of Copper from ACQ treated wood exposed above ground
2004 - IRG/WP 04-50219
The leaching of chemicals of ACQ Type C treated wood exposed above ground for 16 months was studied. Commercially treated Hem-fir boards (Tsuga heterophylla Raf. and Amabilis fir Forb) of 37.5 mm by 87.5 mm were used. The amounts of chemical leached monthly by the rainfall were determined and the leachate was collected and analyzed. Also, the environmental factors influencing the leaching were ...
P A Chung, J N R Ruddick


LCA examination of preservative treated timber products and alternatives; initial results
1995 - IRG/WP 95-50040-04
Co-operative development of an LCA methodology suitable for application to preservative treated products has been carried out, based on scoping assessments of two products, CCA treated fenceposts and creosote treated distribution poles. The general results of these scoping exercices are described, based on the CCA case study. These include the identification of critical stages in the life-cycle on...
W Hillier, R J Murphy, D J Dickinson, J N B Bell


The present status of wooden catamarans of the Indian Coast
1997 - IRG/WP 97-10231
Catamarans (a.k.a. kattumarams) are the most widely used fishing craft in India, and hundreds of thousands of poor, traditional fishermen depend on these vessels for their livelihood that are almost made entirely of wood. In recent years, acute shortages and phenomenal increases in prices of timber species used in catamaran fabrication have been reported, causing great hardship to the user communi...
K S Rao


Factors affecting decay rates in a fungus cellar
1985 - IRG/WP 2242
Birch and pine stakes treated with chromated copper arsenate and didecyldimethylammonium chloride were incubated in two soils in a "Fungus Cellar" test. At three month intervals, sets of stakes were inspected and assigned visual ratings or removed from the soil beds for weight loss determination. Preliminary results after nine months exposure have shown differences in the decay rates between birch...
P A McKaig


Effectiveness of wood preservatives and treatments against marine borers in Philippine waters
1976 - IRG/WP 416
A 5-year exposure test was conducted on the effectiveness of wood preservatives and treatments against marine borers in Philippine waters. Air-dried heartwood samples of apitong (Dipterocarpus grandiflorus) 76.2 x 88.9 x 609.6 mm³ (3 x 3.5 x 24 in³) in size were pressure treated with coal tar creosote and two types of CCA (copper/chrome/arsenic) and CuCZA (copperized chromated zinc arsenate) wat...
F R Siriban, M G Laxamana, P G Mata


IRG/COIPM INTERNATIONAL MARINE TEST - To determine the effect of timber substrate on the efectiveness of different preservatives in sea-water: Coding scheme
1976 - IRG/WP 420
It was agreed in Wildhaus on 15 May 1976 that preparations for the test detailed in Document No: IRG/WP/414 should commence immediately, but that initially only two water-borne preservatives should be used - a copper/chrome/arsenic (CCA) and a copper/chrome/boron (CCB) formulation respectively. PRL, England (R Cockcroft) would be responsible for supplying only the reference species treated with th...
Anonymous


Effects of biocides on the extracellular mucilaginous material (ECMM) produced by two wood rotting basidiomycetes
2003 - IRG/WP 03-10469
Growth and production of extracellular mucilaginous material (ECMM) by the brown-rot fungus Gloeophyllum trabeum (FPRL 108 N) and the white-rot fungus Coriolus versicolor (CTB 863 A) was assessed in liquid culture, supplemented with the biocides CuSO4 and cyproconazole. The production of biomass in G. trabeum was significantly influenced by the concentration of CuSO4 in the medium. When CuSO4 was...
D Vesentini, D J Dickinson, R J Murphy


Leaching Characteristics of Alder Wood Treated with Copper Based Wood Preservatives
2005 - IRG/WP 05-50225
In this study, it was designed for determining leaching characteristics of CCA and alternatives wood preservatives. Alder wood blocks were treated with CCA (1 % and 2 %), ACQ-1900 (2 % and 3 %), ACQ-2200 (1 % and 2 %), Tanalith E 3491 (2 % and 2.8 %), Wolmanit CX-8 (% 1 and 2 %). Leaching studies were conducted according to AWPA E11-97. Copper analyses of leachate were determined Atomic absorption...
A Temiz, Ü C Yildiz, E D Gezer, S Yildiz, E Dizman


A bioassay of remedially treated pole material
1987 - IRG/WP 3453
Stubs prepared from treated and untreated utility poles were installed in a test plot and pressure spade treated at the groundline with one of four preservative greases. At one and three year intervals, core samples were removed from the stubs and the improvement in the preservative efficacy due to the greases was assessed. The bioassay investigation showed that only bis(tributyltin) oxide (TBTO) ...
J N R Ruddick, L Parker


Effects of pre-harvest girdling on selected properties of red pine, red maple and Eastern larch
1999 - IRG/WP 99-40137
Trees of three species - tamarack (Larix laricina), soft maple (Acer rubrum) and red pine (Pinus resinosa) - were girdled immediately below the crown,one to two years before felling. The wood from these trees was compared with wood taken from un-girdled control trees felled at the same. Sapwood and heartwood, from the controls, and from above and below the girdle of treated trees, were examined fo...
A Taylor, P A Cooper


Removing Cu, Cr and As from CCA treated yellow pine by oleic acid
2003 - IRG/WP 03-50202
In this study, CCA treated yellow pine utility poles were cut into three different dimensions and 4 different pH levels (2, 2.5, 3.5 and 5) of Oleic acid was used. The leached wood samples were collected at the end of the 1, 3, 7 and 14 days to determine the remaining Cu, Cr and As concentrations. The concentrations of Cu, Cr and As were determined by X-RF. The effects of pH, dimension and duratio...
E D Gezer, Ü C Yildiz, S Yildiz, E Dizman, A Temiz


The future for chromium in wood preservation
1985 - IRG/WP 3332
Most water-borne preservatives contain CrVI compounds, originally to reduce corrosion although now also to improve toxicant fixation. Chromium contributes to preservation and this is recognised in, for example, New Zealand and USA where chromium contents are included in calculations of overall preservative activity of CCA formulations, but chromium may also have anti-stain and joinery (millwork) p...
B A Richardson, T R G Cox


Development of a commercial-scale CCA chemical sludge recycling system
1993 - IRG/WP 93-50001-19
The occurrence of fixation reactions in Copper Chromium Arsenate (CCA) treatment solutions is increased where the treatment of unseasoned and partially seasoned timbers in hot climates occurs. The by-products of the fixation reactions are predominantly insoluble chromium arsenate compounds, commonly referred to as CCA sludge. Historically, this material has been disposed of into toxic waste landfi...
A J B Butler


Speciation of leachates from CCA-treated wood
2005 - IRG/WP 05-50224-27
Different species of arsenic and chromium are characterized by different toxicities and different mobilities. The environmental impacts of CCA-treated wood would therefore be a function of the chemical forms of the metal releases. As a consequence a series of tasks were undertaken to evaluate arsenic and chromium species from CCA-treated wood. The intent of these tasks was to quantify the total...
H M Solo-Gabriele, T G Townsend, Yong Cai, B I Khan, Jin-Kun Song, J Jambeck, B Dubey, Yong-Chul Jang


A simple field apparatus for measuring relative gaff penetration and assessing the effect of additives for improving pole climbability
2000 - IRG/WP 00-20187
A simple apparatus for measuring and comparing the relative "hardness" of utility poles is described. This "slide-hammer" gaff penetration apparatus was designed as a field testing unit to measure the depth of gaff penetration into test poles after application of a uniform and reproducible force to the gaff. The apparatus is simple to use in both the laboratory and field. Data is provided for resu...
A R Zahora


Effect of humidity and temperature on fastener withdrawal resistance from CCA and ACZA treated Douglas-fir
2000 - IRG/WP 00-20209
The effects of preservative treatment on fastener withdrawal was investigated in Douglas-fir lumber conditioned to two moisture regimes. In general, conditioning samples to 19% moisture content produced more substantial changes in withdrawal resistance of galvanized fasteners than did conditioning to 12%. Treatment had little or no effect on withdrawal resistance of stainless steel fasteners. With...
Sung-Mo Kang, J J Morrell


Pentachlorophenol - The US and Canadian experience
1995 - IRG/WP 95-50040-26
Pentachlorophenol ("Penta") is a highly effective and economical wood preservative. The principal use in the United-States and Canada is pressure-treatment of wood; major applications are for railroad ties, pilings, posts, cross arms, and poles. Treatment of wood products with pentachlorophenol typically extends the functional life of wood by at least eight times. Because of the presence of certai...
J Wilkinson


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