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FTIR characterization of copper ethanolamine - wood interaction
1999 - IRG/WP 99-20154
The interaction of copper ethanolamine (Cu-EA) and wood components was studied by using Fourier transform infrared spectroscopy (FTIR). In Cu-EA treated wood, significant reduction was noticed on the band attributed to carbonyl vibration from carboxylic groups at 1735±5 cm-1 and an increase in band intensity was obtained from carbonyl in carboxylate at 1595±5 cm-1. The same observation was made ...
Jun Zhang, D P Kamdem


Microdistribution of water-borne preservatives in blue gum treated by full-cell process
1990 - IRG/WP 3617
The present work deals with the study of the microdistribution of copper, chrome and arsenic elements in Eucalyptus globulus Labill. sapwood, treated with a CCA water-borne preservative by full-cell process, with the help of scanning electron microscopy together with energy dispersion X-ray analysis technique. The work shows that the retention of CCA elements is high in vessels and vasicentric par...
D De Sousa Castro Reimão, J M Palacios


Multiple-Phase Pressure (MPP) Process: One-stage CCA treatment and accelerated fixation process. 4. MPP compared with other processes for achieving acceptable treatment of radiata pine heartwood
1998 - IRG/WP 98-40115
Although radiata pine sapwood is very amenable to preservative treatment, it is often difficult to achieve the required standard for heartwood treatment. A preliminary investigation showed that to achieve the NZ Timber Preservation Council minimum penetration requirements for radiata pine heartwood using the Multiple-Phase Pressure (MPP) Process, a hydraulic pressure of at least 1250 kPa for 20 m...
K Nasheri, J A Drysdale, G Durbin, M E Hedley


Field test of wood preservatives with Nasutitermes rippertii RAMBUR in Cuba
1996 - IRG/WP 96-10181
A field test of wood preservatives was carried out with Nasutitermes rippertii RAMBUR in the vicinity of the Material Testing Centre „Alexander von Humboldt" in Santiago de las Vegas/ Havana (Cuba) for 12 and 24 months. Test specimens of Pinus sylvestris L., Picea abies (L.) Karst. and Fagus sylvatica L. with dimensions of 25 x 25 x 490 mm³ were arranged vertically or horizontally in a circle o...
W Unger


Changes of EPR spectra of wood, impregnated with copper based preservatives, during exposure to Antrodia vaillantii
2000 - IRG/WP 00-10355
Spruce wood (Picea abies) samples were impregnated with two different aqueous solutions: copper(II) octanoate with ethanolamine or copper(II) sulfate (cCu = 1,0 x 10-2 mol/l). Impregnated and unimpregnated test pieces were exposed to wood rotting fungus Antrodia vaillantii. Some strains of this fungus are known as copper tolerant. After four weeks of exposure to A. vaillantii, we could not detect ...
M Humar, M Petric, F Pohleven, M Šentjurc


Evaluation of a laboratory soft rot test on basis of weight loss and residual strength
1989 - IRG/WP 2336
Based on the principles of different previously reported experimental procedures dealing with laboratory soft rot testing, a study was conducted on treated poplar and beech. Preservatives used were CCA, CCF, AAC, Azaconazole and TCMTB. Treated samples were exposed for three months in a vermiculite substrate to Chaetomium globosum. Evaluation was based on absolute mass loss, percentage weight loss ...
W Verbeke, J Van Acker, M Stevens


Treatment groups and remedies for CCA treated hardwood and softwood poles
1999 - IRG/WP 99-40142
Different hardwood and softwood species from Bangladesh and Bhutan was investigated regarding density, green fiber stress, natural durability of heartwood and CCA treated sapwood, CCA treatability grades, sapwood thickness, and kiln-drying properties for long term use as electric poles. These properties along with the past service records for nineteen years, separated ten heardwood and five softwo...
A K Lahiry


Technologies for the Management of Wood Waste Containing Metals-Based Preservatives
2005 - IRG/WP 05-50224-16
Disposal of the metals from preservative treated wood can occur through two general strategies: “removal and confinement” or “dilution”. The acceptability of each of these two choices is typically dictated through the disposal regulations of a particular region. A considerable amount of research has been conducted to develop new and innovative “removal and confinement” technologies...
H M Solo-Gabriele, T G Townsend


Differential retention and leaching of CCA (C) in sapwood and heartwood of Kenyan-grown blue gum (Eucalyptus saligna) and black wattle (Acacia mearnsii)
2005 - IRG/WP 05-30371
Retention and leaching of CCA(C) in small samples of sapwood and heartwood of Kenyan-grown blue gum (Eucalyptus saligna) and black wattle (Acacia mearnsii) were tested under laboratory conditions. Clear samples (100mm x 30mm x 40mm) were removed from the sapwood and heartwood of sampled defect-free and sound plantation trees of the two species. These were separately air-dried to 15% MC, end-seal...
R Venkatasamy


CCA-treated Wood Disposed in Landfills and Life-cycle Trade-Offs With Waste-to-Energy and MSW Landfill Disposal
2005 - IRG/WP 05-50231
CCA-treated wood as a solid waste is managed in various ways throughout the world. Although some wood is combusted for the production of energy in the U.S., more often than not, CCA-treated wood is disposed in landfills. In other countries, wood, often including CCA-treated wood, is combusted for the production of energy. This paper is presented in two parts. Part I evaluates the impact of CCA-tre...
J Jambeck, K Weitz, T G Townsend, H M Solo-Gabriele


A technique for measuring preservative loss or redistribution during leaching
1983 - IRG/WP 2199
Radiata pine sapwood stakes were treated with benzalkonium chloride (AAC) or copper-chrome-arsenate (CCA). After fixation and drying the outer 2 mm and 2-4 mm layers were removed from one radial longitudinal face. The planed face was coated with a waterproof coating and AAC-treated stakes were leached for 6, 12 or 18 weeks; 12 weeks for the CCA-treated stakes. After airdrying three 2 mm layers (0-...
J A Drysdale


Chemically modified tannin and tannin-copper complexes as preservatives for wood
2001 - IRG/WP 01-30271
The efficacy of Mimosa tannin, chemically modified tannin, and tannin-copper complexes as wood preservatives was studied. When the tannin-ammonia-CuCl2 solutions were impregnated into wood specimens in a one-step procedure, a large quantity of the tannin-copper complex was fixed in the specimens. Little of the complex was leached from specimens by a weathering treatment, and these specimens showed...
H Yamaguchi


Preservation of coppice wood for the fabrication of glued beams or panels
1987 - IRG/WP 3427
In this survey we will examine the specific problems concerning the conservation and the preservation of timber (issued from trunks of small diameter corresponding to products of clearings or coppices) destined for the fabrication of solid reconstituted elements. Thus for six metropolitan species of wood, we first characterized the biological deteriorations which occur after felling and their kine...
G R Y Déon, R Schwartz


The movement of iron into field test stakes
1987 - IRG/WP 2284
Failed and sacrificial stakes recovered from the Westham Island field test site were examined for their iron content. Varying amounts were recorded, which were greatest in the failed stakes. The possible role of the iron taken up by the below ground portion of the stakes, in accelerating the decay process and/or the preservative leaching is under investigation. The reaction of the iron with the ch...
J N R Ruddick, P I Morris


Performance of preservative-treated rubberwood (Hevea brasiliensis) in Goa and Kochi waters (west coast of India).
1997 - IRG/WP 97-20104
Performance of rubberwood (Hevea brasiliensis) against biodeterioration, when pressure-treated with Copper-Chrome-Arsenic (CCA) and Copper-Chrome-Boric (CCB) and exposed in Mandovi estuary (Goa) and in Kochi waters for a period of 32 months and 9 months respectively, has been discussed. The control panels were completely destroyed within a period of 4 to 6 months at both the localities. The resist...
L N Santhakumaran, M V Rao


Copper based wood preservative - A new approach using fixation with resin acids of rosin
2000 - IRG/WP 00-30249
Copper soaps with carboxylic acid groups of resin acids of rosin were shown to be potential long-term wood preservatives. The principle involved is the attachment of copper to the network formed by the inorganic part of the preservative (rosin) through the -COOH groups. The mechanisms of fixation have been studied, and it has been shown that this association could be obtained : (1) by forming the ...
C Roussel, J P Haluk, A Pizzi, M-F Thévenon


A spectroscopic investigation of copper ethylenediamine fixation in wood
1999 - IRG/WP 99-20160
The fixation reaction which take place between copper ethylenediamine (Cu-en) solution and wood were expolored using X-ray photoelectron spectroscopy (XPS) and Fourier Transformed Infrared Spectroscopy (FTIR). The FTIR spectra revealed that copper reacts with the carboxylic acid and phenolic groups in wood to form stable complexes. The copper ethylenediamine complexes formed in wood were identifie...
Xiao Jiang, J N R Ruddick


Termite resistance of treated wood in an above-ground field test
1985 - IRG/WP 2241
A field test method has been developed for evaluating the susceptibility of wood products to termites in protected situations above ground. In this method fungal attack on the wood products is minimal, though decay has been observed in conjunction with termite attack in some specimens. Preliminary results from exposure of replicate wood samples treated with preservatives in Florida to Reticuliterm...
A F Preston, P A McKaig, P J Walcheski


Determination of toxicity data for preservatives against Basidiomycetes by measuring the reduction in compression strength of wood
1988 - IRG/WP 2297
Blocks of Pinus radiata D. Don were treated to 12 retention levels with CCA and NaPCP. These were exposed for 12 weeks in agar jars to the dry rot (brown rot) Serpula lacrymans (Schum. ex Fr.) S.F. Gray. After mass loss determination, the same blocks were tested for reduction in compression strength parallel to the grain. Using both these parameters, together with interpolated 6 week strength loss...
J Wazny, J D Thornton


Protection of cellulose string with biocide/water repellent mixtures
1997 - IRG/WP 97-30148
Protecting cellulosic materials in soil contact poses a formidable challenge. Many soil inhabiting bacteria and fungi that cannot degrade wood can nevertheless rapidly depolymerize cellulose once its protective lignin matrix is removed. As a result, cellulose based materials are rarely used in direct contact with soil. One exception, however, is the use of cellulose string to support climbing vine...
A B Chang, J J Morrell


The resistance of timbers to impregnation with wood preservatives
1979 - IRG/WP 3137
It is anatomical structure which determines liquid flow rate within different timber species. This cannot be deduced from properties such as density or rate of growth, and can only be found by experiment. A standard test has been in use at the Princes Risborough Laboratory for many years, employing a pressure-impregnation treatment, and a large number of timbers have been studied. The test consist...
Anonymous


A comparison of analytical and visual techniques used for assessment of weathering properties of chromium and copper azole treated timber
1994 - IRG/WP 94-20023
The weathering properties of preservative treated timber were studied by measuring surface lignin loss and by microscopic examination after weathering, and results were related to qualitative assessments of visual appearance after weathering. Measurement of relative rates of delignification of untreated and preservative treated timber obtained by FTIR analysis, and weight loss determined on thin v...
J A Cornfield, M D C Hale, G Fettis


The fixation of copper in Pinus sylvestris using the sodium salts of two polyhydroxycarboxylic acids
1992 - IRG/WP 92-3706
As part of the research concerned with the development of fixed, copper based preservatives, the salts of polyhydroxycarboxyIic acids, have been used in copper sequestration studies and fixation trials in Pinus sylvestris splinters. Selected compounds have been shown to be effective sequestrants at low concentrations allowing alkaline solutions to be formulated. Leaching trials following a 48 hour...
M Bacon, J A Cornfield


Copper tolerance of various Antrodia vaillantii isolates
2001 - IRG/WP 01-10406
Copper based preservatives have been extensively used in the field of wood preservation. However, several brown-rot fungi to be tolerant to copper and consequently, efficacy of copper based wood preservatives may not be sufficient. Copper tolerance is especially by some fungi that are closely aligned to or included in genus Antrodia. The highest copper tolerance was found at some strains of wood r...
F Pohleven, A Malnaric, M Humar, C Tavzes


Recycling of CCA treated wood in the US
1998 - IRG/WP 98-50101-08
The production of CCA treated wood has increased dramatically in recent years. Previous estimates of the volume of treated wood to be removed were based on the assumed service life of the material, generally 20 to 25 years. This study based on a survey of contractors installing treated decks, determined that the actual service life of these decks is much shorter than their assumed functional servi...
J McQueen, J Stevens, D P Kamdem


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