IRG Documents Database and Compendium


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Changes of copper and chromium content after leaching in wood impregnated with the CCB and CB preservatives
2000 - IRG/WP 00-50147
The objective of the study was impregnated with CCB and CB preservatives pine wood of moisture content varying from 12% to 55% subjected to leaching. Losses of copper and chromium were determined for individual layers of wood up to 3 cm from the girth. The results were compared to the total amount of metals determined in water extracts. The degree of leaching of metal ions from wood of 55% moistur...
B Mazela


Leaching tests on CCA-treated wood using inorganic salt solutions
1984 - IRG/WP 3310
Pinus radiata sapwood treated to approximately 10 kg/m³ with Tanalith NCA or Tanalith C-type CCA preservatives was ground to a fine powder and samples were then leached with solutions of calcium chloride, calcium nitrate, magnesium nitrate, or a mixture of potassium di-hydrogen orthophosphate and di-potassium hydrogen orthophosphate, at 0.03M-1.00M solution concentrations. Leached wood samples we...
D V Plackett


Borate diffusion from fused borate rods in douglas-fir transmission poles
1994 - IRG/WP 94-30042
Pressure-treated utility poles have given many years of excellent service, but their lifetime is often shortened by internal decay of the untreated heartwood center, particularly in refractory species, such as Douglas-fir. This paper reports the distribution of boron from fused borate rods installed in CCA-treated Douglas-fir transmission poles. The boric acid equivalent was roughly monitored by t...
T L Highley, W Finney, F Green III


Wood preservation in Canada - Regulation and Registration
2001 - IRG/WP 01-50166-02
The Canadian wood preservation industry is at a critical juncture now as a number of initiatives converge on the industry over the next few years. Issues facing the industry include: Re-evaluation of the conventional wood preservative chemicals - inorganic arsenicals, creosote and pentachlorophenol targeted for July 2001. Delayed registration of new actives as a result of re-evaluation activity an...
P A Cooper


Exclusion of anions from the wood cell wall
1991 - IRG/WP 3661
Anionic components of wood preservatives and fire retardants such, as arsenates and phosphates, equilibrate at much lower concentrations in the cell wall bound water than in the free solution in the cell lumens. A degree of anion exclusion is expected in wood, due to the Donnan membrane effect. Fixed anions in the wood cell wall, produced by pH-dependent dissociation of the weak acid groups in woo...
P A Cooper


Relating CCA fixation to leaching of CCA components from treated products
1995 - IRG/WP 95-50045
The relationship between chromium fixation in CCA-C treated wood, as determined by CrVI analysis of solution expressed from treated wood and the leaching of Cu, Cr, As and CrVI in a simulated rain test are evaluated for dimension lumber (2"x6") and pole sections. Leachate concentrations after 2 hour exposure to a misting spray (about 300 mm cumulative rainfall) decrease rapidly with increased degr...
P A Cooper, R MacVicar, Y T Ung


Wood cement composites using spent CCA treated wood
1999 - IRG/WP 99-50126
The feasibility of using spent or out-of-service CCA treated wood as a component of wood/cement composites was evaluated. Cold pressed wood particle cement boards were made using CCA treated particles from a red pine (Pinus resinosa Ait.) pole removed from service and from untreated red pine wood from a new pole. Boards were manufactured using a range of wood to cement ratios and water to cement r...
Chen Huang, P A Cooper


Kinetics and mechanism of fixation of Cu-Cr-As wood preservatives. Part 4: Conversion reactions during storage
1974 - IRG/WP 332
Precipitates simulating those produced in wood by preservative fixation reactions were prepared by the reduction of Boliden K 33 and Celcure AP solutions with hydrogen peroxide and hydrazine. The pH changes on aging at 20 and 50°C were studied and related to the chemistry of fixation previously described. Hydrolysis of copper arsenates may render arsenic acid temporarily water soluble pending pre...
S-E Dahlgren


Experimental variations in the distribution of CCA preservative in lignin and holocellulose as a function of treating conditions (temperature, concentration, pH, species, and time)
1984 - IRG/WP 3277
The exact distributions between lignin and holocellulose and retentions on wood of copper, chromium and arsenic as a function of various sets of conditions in a 3x3x4x2 factorial experiment in which combinations of three temperatures of treatment, three CCA solution concentrations, four pH's of the initial CCA solution and two timber species, namely Pinus radiata and Eucalyptus grandis, a...
A Pizzi, E Orovan, M Singmin, A Jansen, M C Vogel


Fixation and leaching characteristics of Douglas-fir treated with CCA-C
2004 - IRG/WP 04-50213
Fixation and leaching characteristics of CCA-treated Douglas-fir was evaluated using the expressate method and the AWPA E11-97 leaching procedure. CCA fixation, as monitored by the chromium reduction, was much faster in heartwood than in sapwood; however, copper and arsenic fixation in heartwood appeared to be incomplete regardless of the extension of fixation time. This poor fixation of copper a...
Gyu-Hyeok Kim, Yun-Sang Song, Dong-heub Lee


CCA type C depletion of Southern yellow pine utility poles
1995 - IRG/WP 95-50049
Depletion and redistribution of preservative components were evaluated on five CCA-C treated poles in service for over six years in Conley, Georgia. A statistical approach was taken in which retentions below ground were compared to retentions above ground due to a lack of initial data on individual poles. It was hypothesized that the below ground retentions should be lower than the corresponding a...
P D Osborne, R F Fox


Conforming to European standards on preservative treatment
1998 - IRG/WP 98-20150
New European standards require that specifications for the preservative treatment of timber are written in terms of the penetration and retention of preservative within the treated commodity that result from the treatment process. In order to check compliance with this type of specification, suitable methods of quantitative analysis must be available. This paper presents the results of a study by ...
E D Suttie, R J Orsler


Upgrading the fungal resistance of OSB
1999 - IRG/WP 99-40138
There is a perception that oriented strand board (OSB) is less resistant to fungl than plywood under conditions of moderate exposure to moisture. Douglas fir-faced plywood (DFP) has been suggested as a benchmark for acceptable durability under such conditions. This project was initiated to determine the minimum level of low-toxicity chemical treatment needed to upgrade the fungal resistance of OSB...
P I Morris, J E Clark, D Minchin, R Wellwood


Programme d'études sur le pentachlorophénol
1993 - IRG/WP 93-50001-09
In 1989, Hydro-Québec began a study program on pentachlorophenol (PCP), with a view to ensuring safe management of the product at all stages of its utilization. The topics under study include storage of treated poles, behavior of PCP in the environment, soil decontamination, water treatment, characterization and disposal of treated wood waste, and assessment of substitutes. This paper summarizes ...
G Beaulieu, A Bériault, R Chénier, L Houde


Influence of fungal exposure on the redistribution of copper in treated spruce wood
2002 - IRG/WP 02-10450
The redistribution of copper in treated wood after exposure to basidiomycete decay fungi is described. The micro-distribution of copper in copper(II) sulphate or copper(II) octanoate/ethanolamine treated Norway spruce wood before and after exposure to 3 different wood decay fungi was studied using transmission electron microscopy with X-ray microanalysis. The copper content of the mycelium and the...
M Humar, F Pohleven, R J Murphy, D J Dickinson, I Moris, M Zupancic, P Kalan, M Petric


The potential of high pressure pulsation processes to treat white spruce lumber with water-borne preservatives
1988 - IRG/WP 3471
Laboratory work using end sealed 4x8x46 cm³ white spruce samples has been done to explore the suitability of three variants of a 2.1 MPa pulsation process for the impregnation of white spruce with CCA. The results showed that the process improved significantly the penetration of the preservatives and reduced significantly cell collapse, when compared with the results of treatment using a 2.1 MPa ...
J P Hösli, J N R Ruddick


IRG/COIPM INTERNATIONAL MARINE TEST - to determine the effect of timber substrate on the effectiveness of water-borne salt preservatives in sea-water. Progress Report 17: Report of fifth inspection (4 years) in Italy
1983 - IRG/WP 4103
The wood samples of Alstonia scholaris, Fagus sylvatica, Pinus sylvestris were submerged in the sea at Follonica, Italy, in April 1977. Follonica, latitude 42°55' North and longitude 10°45' East, is situated on the Tyrrhenian coast. The recorded temperature varies from 13°C to 25°C, salinity 37-38% and pH about 8. The inspections were carried out after 6 months (10/1977), 12 ...
A Gambetta, E Orlandi


The effect of stack height on the performance of preservatives used for the prevention of sapstain on seasoning wood
1997 - IRG/WP 97-10192
The performance of three anti-sapstain preservatives was investigated under field conditions in south east England. The preservatives under test were: copper-8-quinolinolate (Mitrol PQ8) trimethylalkylammoniumchloride and sodium hexanoate (Sinesto B) and chlorothalonil (Tuff Brite). The preservatives were tested on Corsican Pine grown in south east England. The field trial was set up to investigat...
J R Williams, D J Dickinson, J F Webber


Residual CCA levels in CCA treated poles removed from service
2000 - IRG/WP 00-50152
Fifty-two CCA treated poles removed from service after 1 - 50 years were sampled at different depths from their below ground and above ground zones and the preservative levels and mass balances related to the location in the pole and pole age. Generally CCA retentions were still well above the toxic threshold for decay in even the oldest poles. This confirms the good leach resistance of CCA and th...
P A Cooper, D Jeremic, J L Taylor


Wood preservation in Uruguay
1987 - IRG/WP 3404
The purpose of this paper is a brief description of the current status of wood treatment in Uruguay. The forest resources of the country are summarized, the environment, their economic importance and future potential. The present wood treating facilities are described, together with the chemicals used and the standards generally accepted. Wood treated products used in the Uruguayan market are cite...
G Baillod


Leachability of active ingredients from some CCA treated and creosoted poles in service. A progress report after 10 years testing
1990 - IRG/WP 3627
CCA K33 TYPE B treated or creosoted poles, 10 pieces of each treatment type, have been monitored from the treatment plant to an electricity line, which was build up in Southern Finland in 1978. Preservative retention was determined by taking borings at four different levels: 1.5 m from the top end, 1 m above ground line, ground line and 0.5 m below ground. Determinations were made before setting u...
A J Nurmi


PXTS; A Metal Free Oligomer Wood Preserving System - A Summary of Data To Date
2004 - IRG/WP 04-30350
The world is continually looking for new wood preservative technology, especially to address environmental concerns. Recent changes in the USA have limited the use of arsenical containing formulations to industrial use through a negotiated voluntary cancellation of most residential label uses. PXTS (Polymeric Alkylphenol Polysulfide) offers a brand new technology that is an all organic system, lik...
M H Freeman, D D Nicholas, D Renz, R Buff


Effects of CCA treatment on settlement and growth of barnacles under field conditions
1998 - IRG/WP 98-50116
As part of a field experiment at seven European marine sites evaluating the effects of CCA treatments on non-target marine organisms, panels treated to nominal loadings of 12, 24 and 48 kg/m3 CCA were exposed at marine sites around the coast of Europe. Within two weeks of exposure, a heavy settlement of barnacles took place on the panels exposed intertidally in France. The intensity of settlement ...
S M Cragg, C Brown, R M Albuquerque, R A Eaton, P Goulletquer


Leaching from field test stakes. Results from two different methods of analysis
1993 - IRG/WP 93-50013
Field test stakes treated with Boliden K33 containing copper, chromium and arsenic exposed at three different fields in Sweden and rejected due to decay, have in two studies been analysed regarding leaching and remaining preservatives. The stakes have been exposed during 20 to 43 years. The density of the stakes and content of copper, chromium and arsenic have been determined in the top part of th...
F G Evans, M-L Edlund


Preservative treatment of round bamboos by a new technique - Some further studies. Part 1
1990 - IRG/WP 3607
In general, the easy susceptibility of bamboos to wood destroying agencies is a major constraint in its rational utilisation. This is more so in tropical countries like India where wood destroying agencies are quite active. In an earlier publication, it was reported that round bamboo specimens of Bambusa balcooa, having three nodes, could be satisfactorily treated by CCA by a new technique develop...
V R Sonti, B Chatterjee


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