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Evaluation of Commercially Available Polyurethane Resin to Develop Non-biocidal Wood Preservation Treatments
2016 - IRG/WP 16-40751
Evaluation of commercially available polyurethane (PU1 and PU2 and polyisocyanate (PNCO) to develop non-biocidal wood preservation treatments have been conducted. A simple method by vacuum impregnation of these resins into beech wood (Fagus sylvatica L) and pine wood (Pinus sylvestris L.) samples followed by varied curing process at ambient temperature, 103oC, and 200oC have been performed. Based ...
M Mubarok, Y Sudo Hadi, J Suryana, I W Darmawan, F Simon, S Dumarcay, C Gérardin, P Gérardin


Marine Borer Resistance of Acetylated and Furfurylated Wood – Results from up to 16 years of Field Exposure
2016 - IRG/WP 16-40756
Furfurylated and acetylated Scots pine sapwood has been tested since 1999 in a marine field with high marine borer activity. In 2004, two test groups with acetylated southern yellow pine (product later known as Perennial Wood™) were put out and over the whole test period differently furfurylated wood (later marketed as Kebony®) test groups have been started. Furthermore, some combinations of mo...
M Westin, P Larsson Brelid, T Nilsson, A O Rapp, J P Dickerson, S Lande, S Cragg


Improvement of wood properties by impregnation with liquefied spruce bark based resins
2016 - IRG/WP 16-40761
In this paper, biobased phenolic thermosetting resins are designed to be used as wood stabilization treatment. The originality of the study stands in substituting part of phenol by spruce (picea abies) bark: this is achieved by a liquefaction process in phenol in the presence of sulfuric acid as catalyst. Next, thermosetting resins are synthetized from liquefied bark by condensation on formaldehy...
X Duret, E Fredon, E Masson, P Gérardin


Accelerated weathering and fungal resistance of wood modified with isopropenyl acetate
2016 - IRG/WP 16-40764
Chemical modification of Rubberwood (Heveabrasiliensis Müll.Arg) with isopropenyl acetate (IPA) in presence of anhydrous aluminum chloride and iodine as catalysts was carried out. Modified wood surfaces were exposed to UV light source in an accelerated weathering tester to evaluate UV resistance. Anti-swelling efficiency (ASE) and fungal resistance of modified wood were also evaluated. Modified w...
G B Nagarajappa, K K Pandey


Lignin-Based Adhesive for Engineered Wood Products
2016 - IRG/WP 16-50319
Lignin as a naturally occurring polyphenolic compound has an excellent potential to replace petroleum-based phenol in formulation of phenol-formaldehyde adhesive that are used in manufacturing of engineered wood products. However, there are three major obstacles in application of polymeric lignin as phenol replacement: 1) low reactivity toward phenol, 2) high molecular weight, and 3) high polydisp...
I Kalami, M Arefmanesh, E Master, M Nejad


Weathering protection of European hardwoods through double modification
2017 - IRG/WP 17-30715
Beech and poplar were thermally modified, treated with melamine resin and both treatments were combined. The weathering performance (cracks and general appearance) of modified beech and poplar was assessed in natural weathering and correlated to material properties such as work in bending (WB) and Brinell hardness. In addition, the equilibrium moisture content after exposure of 12 months and subse...
G Behr, A Gellerich, S Bollmus, H Militz


Dimensional Stability of Melamine Formaldehyde-Treated Southern Pine
2017 - IRG/WP 17-40774
The objective of this preliminary study was to evaluate the influence of different levels of melamine formaldehyde (MF) and curing cycle on the dimensional properties of southern pine. Thirty samples for each combination of treatment and curing regimen plus untreated controls and controls subjected to the same curing regimen were tested. Shrinkage/swelling coefficients showed that up to 60% ASE c...
H M Barnes, L S Sites, T S F A França, M G Sanders, F J N França


Susceptibility to filamentous fungi of plywood for furniture coated with waterborne acrylic lacquers
2017 - IRG/WP 17-40778
Filamentous fungi (mould), thanks to their little trophic requirements belong to organisms which grow exceptionally easy and fast in favorable hygrothermal conditions and attack both organic and inorganic materials even with only trace amounts of organic substances on the surface. The fungi often cause spoilage of foodstuffs, worsen the aesthetic of wood-based elements, and pose a threat to the en...
A Fojutowski, M Nowaczyk-Organista, P Hochmańska


Effect of Particle Size on Wax Distribution in Paraffin Wax Emulsion Impregnated Wood
2017 - IRG/WP 17-40779
Paraffin wax emulsion impregnation has been a common eco-friendly approach for improving water repellency of wood. In this study, southern pine (Pinus spp.) and Scots pine (Pinus sylvesteris L.) samples were impregnated with paraffin wax emulsions of different solid contents and particle sizes, and then the time domain nuclear magnetic resonance (TD-NMR) was used to elucidate the influence of part...
Wang Wang, Jinzhen Cao, Yiheng Huang


Black-stain Resistant Acrylic Latexes for Wood Coatings Applications
2017 - IRG/WP 17-40786
Translucent coatings on wood in exterior applications often fail due to photodegradation and colonization by black-stain fungi and require frequent refinishing. This limits competitiveness with alternative materials. In this project, it was hypothesized that an effective dispersion of inorganic nanoparticles will provide a translucent coating with long-term resistance to black-stain fungi. Functio...
G Boivin, A M Ritcey, P I Morris, V Landry


Bacterial adhesion to selected wood finishes
2017 - IRG/WP 17-40793
A new generation of furniture, including antibacterial surfaces, should adjust to the changing needs of an ageing population. Respectively, determination of bacterial adhesion on wooden surfaces, finished with various wood finishes or coating is an important topic. The main aims of our work were of a preliminary character. We wanted to state if the existing methods for testing of bacterial adhesio...
M Petrič, D Kekec, J Žigon, K Godič Torkar, K Bohinc


A Synergistically Stabilized Oil-in-Water Paraffin Pickering Emulsion Used in Wood Treatment
2018 - IRG/WP 18-40840
Pickering emulsions (emulsions stabilized by solid particles) are attractive as they have strong similarities with traditional surfactant-stabilized emulsions. In this study, an oil-in-water (O/W) paraffin Pickering emulsion system with satisfying stability and small droplet size distribution was developed by hydrophilic silica particles and traditional surfactants as mixed emulsifiers. The drople...
J Jiang, J Cao


The Study of the Preparation of Overlaid MDF with the Flame Retardant Impregnated Paper
2018 - IRG/WP 18-40848
The preparation of overlaid medium density fiberboard (MDF) was studied. The flame retardant impregnated papers (FRIP) were overlaid on the surface of the MDF for the fire protection. The results showed that: 1) The production of the FRIP was based on the technology of melamine-impregnated paper, which required the viscosity of the impregnated resin lower than 20s. However, with the addition of th...
W Qu, M Wu, Y-Z Wu


Thermally modified timber treated with methacrylate
2018 - IRG/WP 18-40849
Thermally modified timber (TMT) from Scots pine sapwood similar to Thermo-D quality was impregnated with methacrylate resin by the hot-and-cold method and subsequently cured at elevated temperatures. The results showed that methacrylate resin could be used to reduce colouring of painted TMT wood during accelerated weathering probably by hindering the migration of extractives. The resin itself did ...
O Karlsson, O Myronycheva, DJones, D Elustondo, D Sandberg


Accumulation of copper in parenchyma cells in southern pine wood treated with micronized and amine-copper preservatives
2019 - IRG/WP 19-20657
Our previous research used X-ray micro-computed tomography to examine the micro-distribution of copper in southern pine wood treated with a micronized wood preservative (MCA) and an amine-copper preservative (ACQ). We found that copper in wood treated with MCA was mainly concentrated in fusiform rays (rays containing resin canals), and in vertical (axial) resin canals. A similar, although not iden...
D Feng, M L Turner, A Limaye, M A Knackstedt, P D Evans


Use of resin obtained from Italian guayule crops for wood preservation purposes: some preliminary results
2019 - IRG/WP 19-30736
The potential of guayule (Partenium argentatum Gray) as a source of anti-termite, anti-fungal and insect repellent products to be used in wood preservation, has been largely explored in the past. The fact that such products are obtained as byproducts in the process of natural rubber extraction from this plant, thus increasing the profit of the process, together with the ability of this crop to gr...
S Palanti, E Conti, M Russo, F Stefani, C Querci


Biosourced hybrid phenolic resins as coatings for the protection of wood and wood composites
2019 - IRG/WP 19-30745
Biosourced phenolic resins, based on the phenol-formaldheyde (PF) type, were prepared for their application as coating for wood and wood composites protection, especially against fire. The resins were synthesized by combining an organic polymeric matrix with another inorganic phase. The organic phase was prepared substituting phenol by natural phenolic compounds such as lignin and tannins. The ino...
P L de Hoyos-Martínez, R Herrera, J Labid, F Charrier El Bouhtoury


Improvement of wood decay and termite durability resulting from combined treatments based on borax/phenol-formaldehyde impregnation followed by thermal modification
2019 - IRG/WP 19-40871
This study determined the factors influencing the boron content after leaching of pine blocks impregnated with aqueous solution of phenol-formaldehyde (PF) resin with or without borax and subjected to heat treatment by response surface methodology. An experimental design permits to analyze the effects of heat treatment temperature (150, 185 and 220°C), curing time (5, 12, 5 and 20 hours), resin c...
S Salman, M-F Thevenon, A Petrissans, S Dumarcay, P Gerardin


Effect of pretreatment of wood surfaces with a copper monoethanolamine solution on the natural weathering performance of semitransparent stains
2019 - IRG/WP 19-40881
Semitransparent stains for wood products are favored for outdoor applications in Japan because these finishes do not hide the wood grain. However, the photoprotective effects of wood surfaces are low, therefor there is a need to improve the weathering performance. We examined the natural weathering performance of semitransparent stains on wood pretreated with a copper monoethanolamine solution (Cu...
S Isaji, H Shibui, Y Hirabayashi


Penetration pathway of oilborne preservative in heartwood of Japanese larch (Larix kaempferi)
2019 - IRG/WP 19-40886
The liquid permeability of Japanese larch (Larix kaempferi) wood is extremely low, especially in the heartwood. It is difficult to achieve the penetration of wood preservatives, which is specified by standards, with pressure treatment of waterborne preservatives. Recently, the protection treatment with an oilborne preservative called “deeper penetration treatment” is commercially available, wh...
H Shibui, T Miyauchi, T Shigeyama, M Ikeda, Y Sugai


Longterm Performance of Treated Timbers in Marine Exposures
2020 - IRG/WP 20-10969
The performance of preservative-treated or modified woods in marine exposures was evaluated at test sites in Newport, Oregon, USA and Brisbane, Queensland, Australia. All samples have exhibited excellent performance at the Newport, Oregon site, while attack was more aggressive at the sub-tropical Brisbane site. Acetylated wood as well as samples treated with 7.3% chromated copper arsenate (CCA-T...
M Konkler, A R Zahora, J Norton, J J Morrell


Monitoring uptake and penetration of pesticides during impregnation of pine (Pinus sylvestris) and spruce (Picea abies) wood with bio-based microemulsion gel formulations
2020 - IRG/WP 20-30756
Even in dry state wood is susceptible to biological degradation. Preservation against biological decay in exposed conditions is conventionally achieved by impregnating the wood with pesticides applied at professional and industrial levels. Impregnation of wood with preservatives is a complex process that involves wood macro- and microstructure, and the physical characteristics of woods. Here we fo...
D Messaoudi, K Ruel, J-P Joseleau


Performance of resin-treated solid wood and laminated veneer lumber (LVL) under marine conditions
2021 - IRG/WP 21-10973
Wood is a traditional building material in the marine environment, where it is exposed to extremely harsh conditions. Most of the indigenous softwood and hardwood species in Europe are not durable against attack by marine organisms. Recently, wood modification has been considered as an alternative to protect non-durable wood species under use class (UC) 5 (EN 335, 2013) conditions. The present stu...
L Emmerich, C Brischke, S Bicke, H Militz


Experience Experience from over 20 years of field trials of resin treated wood – Marine borer resistance of MMF and DMDHEU modified wood
2021 - IRG/WP 21-10976
In 1999 a field test of Scots pine treated with MMF (Methylated Melamine Formaldehyde) resin and acetylated Scots pine post treated with MMF resin was started. Six years later a commissioned full NWPC test for BASF of Belmadur® (DMDHEU resin treated wood) was started at the same site. The testing, according to European Standard EN 275, was done in a bay by Kristineberg Marine Research Station o...
M Westin, P Larsson Brelid, A O Rapp, J Habicht


Marine borer resistance of various wood materials in Japan
2021 - IRG/WP 21-10983
Wood resistance against marine borer was intensively studied in the 1940s in Japan, but the research activities on the subject diminished afterward, as the use of wooden marine structures and ships decreased. Today, however, use of wood as a construction material is officially promoted for its environmental benefits. The author started to immerse some wood materials in the seawater pool at PARI ...
M Yamada


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