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Water repellency and dimensional stabilIty of wodd treated with waterborne resin acids/TOR
2007 - IRG/WP 07-40364
Wood used in above ground applications such as decking undergoes undesired dimensional changes leading to the lumber warping, cupping, splitting, etc. This is a major concern to consumers but it can be reduced by treating lumber with a water repellent. The ability of resin acids, hydrophobic compounds naturally present in southern yellow pines, was examined as a possible water repellent. A wate...
T P Schultz, D D Nicholas, J Shi


The efficacy of commercial silicones against blue stain and mould fungi in wood
2008 - IRG/WP 08-30471
Scots pine (Pinus sylvestris L.) wood samples were vacuum pressure impregnated with quatsilicone micro emulsion (<40 nm particle size), aminosilicone macro emulsion (110 nm) and silicone macro emulsion with alkyl modified side groups (740 nm) and the resulting material properties were studied. Quatsilicone micro emulsion resulted in maximum bulking (4.8%) and anti-swelling efficiency (21.8%) in...
S C Ghosh, C Mai, H Militz


Leaching performance, decay and termite resistance of wood treated with boron compounds incorporated with phenol-formaldehyde resin
2009 - IRG/WP 09-30503
A resol-type phenol-formaldehyde (PF) resin was synthesized and designed to penetrate wood incorporated with boron compounds in order to immobilize boron in wood. The leaching performance, decay and termite resistance of treated wood was investigated. Three kinds of boron compounds, that is, boric acid (BA), borax (BX) and disodium octaborate tetrahydrate (DOT), were selected to mix with PF and tw...
Liping Yu, Jinzhen Cao


Vinyl Benzoate Photostabilizes Wood Whereas Vinyl Cinnamate and Vinyl 4-T-butylbenzoate are Less Effective
2009 - IRG/WP 09-40452
Thin wood veneers were esterified to different weight gains with three different aromatic vinyl esters, vinyl benzoate, vinyl cinnamate and vinyl 4-T-butylbenzoate and the photostability of the modified wood was examined. There was a linear relationship between the level of esterification of wood with vinyl benzoate and the photostability of the modified veneers exposed to natural weathering. Viny...
M Jebrane, G Sèbe, I Cullis P Evans


Properties of strand board bonded with ammonium pentaborate (APB) modified phenol formaldehyde resin
2009 - IRG/WP 09-40455
Ammonium pentaborate (APB) is combined with phenol formaldehyde (PF) resin in this study to develop a high-performance wood-based composite. The effect of APB and its combination with polyethylene glycol (PEG) on the physical, mechanical properties as well as formaldehyde emission of strand board were tested and compared with disodium octaborate tetrahydrateand (DOT) and zinc borate (ZB). The resu...
Wei Gao, Jinzhen Cao


Eco-Friendly Composites from Bagasse and Soy-based Resin
2009 - IRG/WP 09-40462
In this study, bagasse and soy-based resin were used for producing composite materials. The objective of this study was evaluation of some physical and mechanical properties of boards made of various ratios (100:0, 60:40, 40:60 and 0:100) of bagasse to wood fiber mixtures (wt: wt) with addition of Soy/PF resin at three levels (4, 8 and 10%) and 1.5% wax. All properties were tested according to AST...
G Rassam, B Jamnani


Treatment of Scots pine wood with oil in water and water in oil emulsion systems: Effects on boron leaching and water absorption
2010 - IRG/WP 10-30535
The aim of this study was to investigate the water absorption and water repellent efficiency of oils and oil water emulsions [oil-in-water (O/W) and water-in-oil (W/O)] and possibilities of reducing the amount of boron leaching from treated wood. Scots pine wood samples treated with waste or sunflower oil and water formulations contained 3%BA. The level of water absorption and water repellent effi...
E D Tomak, Ü C Yildiz, A Can


Effect of 4 Preservatives on Physical, Mechanical and Mold-Resistant Properties of Bamboo Oriented Strand Boards
2010 - IRG/WP 10-40483
This study investigated the effects of 4 preservative systems on physical, mechanical and mold-resistant properties of bamboo oriented strand board (OSB) panels bonded with urea formaldehyde resin. Preservative A (Zinc Borate), B (IPBC), C (AAC+Borate) and D (carbendazim + prochloraz) were incorporated with strands during blending at three loading levels. The results showed that the mechanical and...
Juwan Jin, Daochun Qin, Wanshu Wei, Kuan Fan


Sorption properties of wood impregnated with aqueous solution of boric acid and montan wax emulsion
2010 - IRG/WP 10-40492
Non-biocidal techniques for wood protection become more and more important, nowadays. One of the possible treatments is use of water repellents. In the present research influence of, one of the possible water repellent, the montan wax emulsion, on the moisturizing and the sorption characteristic of impregnated wood was investigated. To achieve a better protection against wood decay fungi, montan w...
B Lesar, M Humar


Effect of P/F ratio, PF concentration and treating method on boron leaching from wood treated with PF modified boron compounds
2011 - IRG/WP 11-30559
In order to immobilize boron in wood, three kinds of resol-type phenol-formaldehyde (PF) resin with different P/F ratios were synthesized in laboratory and incorporated with three types of boron compounds to treat wood. The used boron compounds included boric acid (BA), borax (BX) and disodium octaborate tetrahydrate (DOT). The leaching test of boron from wood blocks was performed according to the...
Liping Yu, Jinzhen Cao


Tannin resin-boron for outdoor wood protection and fire retardancy
2011 - IRG/WP 11-30567
Boron in the form of boric acid is well known for its efficacy against wood destroying organisms, as well as for its high leachability from treated wood when in outside exposure. Moreover, due to the European directive 2008/58/EC, boric acid is only authorized at low levels. In order to keep considering boric acid as an interesting active ingredient for wood protection, the issue is now to fix it ...
M-F Thévenon, G Tondi, N Leménager, S Wieland, A Pizzi


Use of X-Ray Micro-Computed Tomography to Visualize Copper in Preservative Treated Wood
2012 - IRG/WP 12-20488
This study tests the hypothesis that X-ray micro-computed tomography will be able to visualize the distribution of copper in wood treated with a micronized wood preservative containing copper carbonate. A small wood block measuring 12 x 12 x 19 mm was cut from a 2.4 m x 51 mm x 51 mm southern pine batten that had been treated with a micronized wood preservative. Tomograms of the wood block were ob...
P D Evans, A Limaye, H Averdunk, M Turner, T J Senden, M A Knackstedt


Tannin resin-boron associations: Leaching and biological resistance
2012 - IRG/WP 12-30587
The easy leaching of boron in wood preservation formulations has allowed to use this fungicide only for short term applications. The recently discovered adduct with flavonoids allows boron to resist longer periods of time within wood and consequently extend its life. Two different leaching treatments were compared and the fungal and termite decay was examined. The biological tests have shown extre...
G Tondi, S Wieland, N Lemenager, A Petutschnigg, A Pizzi, M-F Thevenon


Termite resistance of wood impregnated with phenol-formaldehyde (PF) modified boron compounds
2012 - IRG/WP 12-30604
In order to investigate the effect of phenol-formaldehyde (PF) modified boron compounds on termite resistance of two main plantation-grown wood species, namely, Masson pine (Pinus massoniana Lamb.) and Chinese fir (Cunninghamia lanceolata (Lamb.) Hook.), laboratory termite tests and field tests were carried out according to AWPA standard E1-97 and AWPC protocols/2007. Different concentrations of b...
Jinzhen CAO, Liping YU, Xuexiang HE


Preparation of Copper Rosinate Emulsion and Its Resistance against Wood Decay Fungi
2013 - IRG/WP 13-30619
A leaching-resistant water-borne copper preservative was prepared by means of the following three steps: (1) Gum rosin was saponified with potassium hydroxide. (2) The soap reacted with copper sulfate to form copper rosinate. (3) The copper rosinate was emulsified with a mixture of Tween 20 and Span 80. Poplar (Populus ussuriensis) wood was impregnated with 0.5%, 1.0%, 1.5%, or 2.0% of the copper ...
Mingxin Zhang, Shujun Li, Qian Wang, Bo Li, Qiong Wu


Curing kinetics of nano cupric oxide (CuO) modified PF resin as wood adhesive: Effect of surfactant
2013 - IRG/WP 13-40620
The effect of nano cupric oxide (CuO) in combination with surfactants on the curing kinetics of phenol formaldehyde (PF) resin, as well as the bonding strength of plywood prepared using the modified resin were investigated in this study using dynamic and isothermal differential scanning calorimetry (DSC). The result showed that the incorporation of nano CuO along with alkane surfactant made in the...
Wei Gao, Guanben Du


Visualization of Copper in the Voids and Cell Walls of Treated Wood using X-Ray Micro-Computed Tomography
2013 - IRG/WP 13-40640
This study extends our observations of the distribution of copper in treated wood. A small wood block was cut from a southern pine batten that had been treated with a particulate-copper preservative and similar sized block was cut from a batten that had been treated with a copper-amine preservative. Both blocks were imaged using X-ray micro-computed tomography. We obtained tomograms of each treate...
P D Evans, A Limaye, H Averdunk, M Turner, T J Senden


Effect of bio-resin from cashew nut shell liquid (CNSL) on decay resistance properties of wood
2013 - IRG/WP 13-40649
This study assesses the decay resistance properties of bio-resin modified wood against decay fungi of the Basidiomycota according to the EN 113 protocol. A bio-resin system was developed by ozonolysis process from cashew nut shell liquid (CNSL), a naturally occurring mixture of phenolics. Small wood blocks from sapwood of Scots pine (Pinus sylvestris), Obeche (Triplochiton scleroxylon) and Gmelina...
M Ashaduzzaman, M D Hale, V Tverezovskiy, G A Ormondroyd


Bio-based thermoset resins for bonding and eco-friendly preservation in the wood industry
2013 - IRG/WP 13-40650
Yellow dextrins and tannins were used in wood adhesives formulation to substitute resins based on formaldehyde. Several formulations were carried out in alkaline aqueous media by varying the weight fraction of two compounds from 10% to 30%. The cross-linking was performed using epichlorohydrin as a reticulant agent. Rheological behaviours and initial adhesion of three liquid formulations, before r...
C Motillon, A Allal, A Visse, F Charrier, B Charrier, A Baldé


Dynamic mechanical analysis (DMA) of nano cupric oxide (CuO) modified aqueous phenol formaldehyde (PF) resin
2014 - IRG/WP 14-40654
Phenol formaldehyde (PF) resins, modified by nano CuO incorporating alkane surfactant and polyvinyl alcohol (PVA) 17-99, were analyzed by dynamic mechanical analysis (DMA). The mechanical properties of its bonded plywood including tensile strength, modulus of rupture (MOR), modulus of elasticity (MOE) and shear strength under five test conditions were evaluated. Results indicated that the incorpor...
Wei Gao, Guanben Du


Performance of some wood modification treatments against marine borers
2014 - IRG/WP 14-40668
Since some years, new treatment technology to protect wood against wood destroying fungi is introduced. Limited knowledge on their resistance to water organisms is available. Therefore, the resistance of chemically modified wood was assessed in a field test according to the European Standard EN 275 over a period of 3 resp. 5 years at sites in the North Sea and the Baltic Sea. Scots pine (Pinus syl...
A Klüppel, C Mai, H Militz, S Cragg


Lignin Modification to Produce Sustainable Polyurethane Resin for Wood Coatings
2014 - IRG/WP 14-40682
The use of lignin as the most abundant aromatic natural polymer has been evaluated for use in the production of lignin-based polyurethane resin for coating applications. Coatings are made of resins (ca. 50%), which today are mainly derived from petroleum-based polymers. This study is focused on the development of an environmentally friendly method of modifying lignin to be used as source of natura...
M Nejad, M Arefmanesh, S Chandra, J Mostaghimi, E Master


Penetration of phenol formaldehyde (PF) resin into beech wood studied by light microscopy
2015 - IRG/WP 15-20558
In this study, we examined the distribution and penetration depth of phenol-formaldehyde (PF) resin into wood specimens by light microscopy (LM). Two PF resins from different producers, of concentrations 9, 18 and 27 wt % in water, were vacuum impregnated into European beech wood (Fagus sylvatica) blocks of 15x25x50 mm³. The presence of chemical agent in the wood was carried out by way of their i...
V Biziks, S Bicke, H Militz


Decay resistance of beech wood and plywood treated with different type of phenol-formaldehyde (PF) resins
2016 - IRG/WP 16-40717
In this study treatment of beech and poplar wood veneers with (PF) resin industrial scale and screening tests of nine different phenol-formaldehyde (PF) resins were made. Specifically, the effect of different phenol-formaldehyde (PF) resin types on the resistance of beech wood against brown- and white-rot fungi was evaluated. Criteria for selection of optimal (PF) resin were based on minimum WPG ...
V Biziks, S Bicke, H Militz


Modifying wood with paraffin wax emulsion impregnation and thermal modification: hydrophobization effect and mechanism of the combined treatment
2016 - IRG/WP 16-40726
The aim of this study was to enhance the water repellency of wood by a combined treatment of paraffin wax emulsion (PWE) impregnation and thermal modification. Two different treating procedures were used to modify the southern pine (pinus spp.). One is first PWE impregnation and then thermal modification, another is first thermal modification and then PWE impregnation. The treated samples were imm...
Wang Wang, Jinzhen Cao, Cong Chen


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