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Immunolabelling studies on the detection of enzymes during the degradation of wood by Phanerochaete chrysosporium
1988 - IRG/WP 1364
The degradation of lignin in native lignocellulosic substrates by white rot fungi is poorly understood. Biochemical studies have shown the involvement of a number extracellular ligninolytic enzymes released by white rot fungi which are capable of the oxidative conversion of DHP's (lignin model compounds) in vitro, but to date conclusive evidence for occurrence of these enzymes in wood und...
G F Daniel, T Nilsson, B Pettersson


Paintability and gluability of wood treated with arsenic-free and chromium free preservative treatments
2006 - IRG/WP 06-40342
The objective of this project was to study, in comparison with traditional CCA treatment, the paintability and gluability of wood treated with arsenic-free and chromium-free preservative treatments. Four formulations, all certified CTB P+, were selected in accordance with their representativeness of the preservative product market: one CCA reference formulation and three chromium and arsenic free...
L Podgorski, G Legrand


Influence of ethanolamine on lignin depolymerization and copper leaching from treated Norway spruce and beech wood
2007 - IRG/WP 07-30423
Copper-ethanolamine based wood preservatives are replacing several classical copper-chromium based solutions, due to foreseen ban of chromium. Fixation of copper-ethanolamine based wood preservatives is not as good as fixation of copper-chromium ones. The main object of this manuscript was to prove, that ethanolamine is the prime reason for insufficient fixation of copper-ethanolamine formulations...
M Humar, B Bucar, M Zupancic, D Žlindra, F Pohleven


Anatomical, physical and chemical changes of Bamboo (Phyllostachys puberscence ) during weathering processes
2008 - IRG/WP 08-10650
Bamboo (Phyllostachys puberscence) culms with 1, 2, 3 year old were exposed to natural weathering condition in Gwangju, Korea for 12 months. Changes in color, surface topography, strength and chemical properties were investigated using various microscopic and instrumental techniques. After one year’s weathering, the color of bamboo became lighter but strengths of bamboo did not change significan...
Jong Sik Kim, Kwang Ho Lee, Mi Young Cha, Yoon Soo Kim


Oxidative stress and lignin peroxidase production in Phanerochaete chrysosporium
2008 - IRG/WP 08-10655
In Phanerochaete chrysosporium liquid cultures, the induction of lignin peroxidases is directly related to accumulation of reactive oxygen species at the mitochondrial level. In this study, we demonstrate that the expression of the mitochondrial thiol-related antioxidant system is not directly coupled to the LiPs expression. When the antioxidant systems are not able to cope with ROS accumulation, ...
M Morel, L Diss, C Fourrey, M Chalot, M Droux, J P Jacquot, E Gelhaye


The Comparison of Fixation and Leachability of Bark, Fruit and Leaf Tannin Extracts with Boron Minerals
2008 - IRG/WP 08-30473
Tannins extracted from several plants have natural durability properties. Due to these properties, some of the researchers have studied them for protecting wood. In this study, Scots pine (Pinus sylvestris) and beech (Fagus orientalis) wood samples were treated with bark, fruit, and leaf extracts as well as water-based wood preservative salts at various concentrations to increase fixation. The pen...
S Sen, C Tascioglu, K Tirak


Degradation of polychlorinated organic biocides by the wood decaying fungi
2008 - IRG/WP 08-50253
Organochlorine biocides such as lindane, pentachlorophenol sodium salt, and polychlorinated biphenyl 153 have been widely used as wood preservatives. Due to their low degradability by soil bacteria, treated waste wood products pose a serious threat to the environment. Consequently, there is an increased need for development of new strategies for their detoxification. In this work, the bioremediati...
I Vidic, L Zupancic-Kralj, K Sepcic, F Pohleven


Fungal Attack on Lignin and Cellulose: Elucidation of Brown- and White-Rot Mechanisms Comparing Biomimetic and In-Vivo Degradation Patterns
2010 - IRG/WP 10-10714
This paper examines research and hypotheses that have been developed over several years on wood degradation mechanisms. This information is combined with new data and analyses to explain why wood decay patterns caused by brown-rot fungi and specific types of white-rot fungi are different. New data, including work with both biomimetic studies on low molecular weight compounds, degradative enzymes, ...
V Arantes, B Goodell, A M F Milagres, Yuhui Qian, T Filley, J Jellison, S Kelley


Influence addition of boron compounds to adhesives on the bonding quality and fungicidal properties of glued wood
2010 - IRG/WP 10-40497
Wood is one of the most important construction materials. However, users of wood face two issues: limited dimensions and insufficient durability. These issues have been overcome with the development of bonding and wood preservation. The preservation of glued wood is elucidated in this paper. Through the addition of boric acid to adhesives, we tried to improve the fungicidal properties of glued woo...
M Humar, B Lesar, A Ugovsek, M Kariz, P Kralj, M Šernek


Lignin blocking effects on weathering process of wood plastic composites
2010 - IRG/WP 10-40529
The weathering of wood–plastic composites (WPC) causes discoloration which affects their aesthetic aspects. It has been proved that these discolorations are due to lignin degradation. Effects of blocking the susceptible structure of lignin assessed by chemical treatment such as acetylation and methylation are reported in this study. Surface chemical change of wood plastic composite (WPC) formula...
P Darabi, A Naghi karimi, S Ahmade Mirshokraie, M-F Thévenon


Tannin resin-boron for outdoor wood protection and fire retardancy
2011 - IRG/WP 11-30567
Boron in the form of boric acid is well known for its efficacy against wood destroying organisms, as well as for its high leachability from treated wood when in outside exposure. Moreover, due to the European directive 2008/58/EC, boric acid is only authorized at low levels. In order to keep considering boric acid as an interesting active ingredient for wood protection, the issue is now to fix it ...
M-F Thévenon, G Tondi, N Leménager, S Wieland, A Pizzi


Micromorphological and chemical characteristics of waterlogged archaeological bamboos excavated from the Yellow Sea
2012 - IRG/WP 12-10785
Bamboos have widely used as documentation material in Far Eastern countries such China, Korea and Japan. In particular, bamboo slips as documentation material were extensively used even after the wide spread of paper in those countries. A large number of bamboo slips have been excavated from the shipwreck since 2009 in Korea. Understanding the cause of deterioration of ancient bamboos is crucial f...
Mi Young Cha, Yoon Soo Kim


Tannin resin-boron associations: Leaching and biological resistance
2012 - IRG/WP 12-30587
The easy leaching of boron in wood preservation formulations has allowed to use this fungicide only for short term applications. The recently discovered adduct with flavonoids allows boron to resist longer periods of time within wood and consequently extend its life. Two different leaching treatments were compared and the fungal and termite decay was examined. The biological tests have shown extre...
G Tondi, S Wieland, N Lemenager, A Petutschnigg, A Pizzi, M-F Thevenon


Study of the use of organosolv lignin as bio-preservative of wood
2012 - IRG/WP 12-30603
The service life of wood depends on the species, use and environmental conditions of exposure. The treatment of wood protects it against degradation by xylophagous agents, enhancing the durability of material up to 10 times, and reducing the deforestation around 12.5%. In this way, the use of treatments is necessary because increases the service life of material and protect against xylophagous age...
P S B dos Santos, A Garcia, P H G de Cademartori, D A Gatto, J Labidi


Curing kinetics of nano cupric oxide (CuO) modified PF resin as wood adhesive: Effect of surfactant
2013 - IRG/WP 13-40620
The effect of nano cupric oxide (CuO) in combination with surfactants on the curing kinetics of phenol formaldehyde (PF) resin, as well as the bonding strength of plywood prepared using the modified resin were investigated in this study using dynamic and isothermal differential scanning calorimetry (DSC). The result showed that the incorporation of nano CuO along with alkane surfactant made in the...
Wei Gao, Guanben Du


Scanning Transmission X-ray Microscopy as a tool for examining chemical changes in wood cell walls due to enzymatic activity
2014 - IRG/WP 14-20556
As development of techniques for examining enzymatic activity on solid, complex biological materials, is considered to be an important factor in further development of enzyme applications and for understanding the decay of plant materials, this study explores applicability of Scanning Transmission X-ray Microscope (STXM) for determining chemical changes in enzymatically treated samples at the cell...
D Jeremic, R Goacher, R Yan, C Karunakaran, E R Master


Resistance of fungal derived pigments to ultraviolet light exposure
2014 - IRG/WP 14-30642
The potential for using fungal derived pigments as surface treatments for limiting photodegradation of wood was investigated. Extracts from Chlorociboria aeruginosa and Scytalidium cuboideum were compared with a traditional aniline dye and chromic acid treatment. Hybrid poplar sapwood samples treated with these solutions were exposed to 86.4 kj/m2 of UV radiation and assessed for lignin degradatio...
H G Beck, S Freitas, G Weber, S C Robinson, J J Morrell


Lignin Modification to Produce Sustainable Polyurethane Resin for Wood Coatings
2014 - IRG/WP 14-40682
The use of lignin as the most abundant aromatic natural polymer has been evaluated for use in the production of lignin-based polyurethane resin for coating applications. Coatings are made of resins (ca. 50%), which today are mainly derived from petroleum-based polymers. This study is focused on the development of an environmentally friendly method of modifying lignin to be used as source of natura...
M Nejad, M Arefmanesh, S Chandra, J Mostaghimi, E Master


A novel enzymatic treatment as a new approach for wood protection
2015 - IRG/WP 15-40701
Wood durability is a worldwide concern and most treatments tend to fail with regard to their efficacy along the time. Weather conditions lead to a loss of the treatment substances into the surrounding environment and, in consequence, generate also a public health concern. Recently, the employment of oxidative enzymes, such as laccases, has been proposed as a tool for lignocellulosics modificatio...
C Fernández-Costas, S Palanti, M Ángeles Sanromán, D Moldes


Weather degradation of thin wood samples
2016 - IRG/WP 16-20578
Untreated wooden surfaces degrade when exposed to varying doses of natural weathering. In this study, thin wood samples were studied for weathering effects with the aim of modeling the degradation utilizing Near-infrared hyperspectral imaging. Several sets of samples were exposed outdoors for time intervals from 0 to 21 days, and one set of samples was exposed to UV-radiation in a laboratory chamb...
I Burud, K A Smeland, K Hovde Liland, T K Thiis, J Sandak, A Sandak, L Ross Gobakken


Evaluation of advanced tannin-boron preservative in unsterile soil-bed tests
2016 - IRG/WP 16-30693
In Europe, boron compounds are facing restrictions, and due to their natural solubility into water, the only way to keep using them for wood protection is to fix them into the wood, at very low level (Obanda et al. 2008). In the meantime, the idea of protecting wood with natural preservatives has been back into favour (Lotz and Hollaway 1988, Nakayama et al. 2001, Singh and Singh 2012). Tannin a ...
Jinbo Hu, Yiqiang Wu, Shanshan Chang, Guangming Yuan, G Tondi, M-F Thévenon


New perspectives for wood protection: enzyme-based treatments
2016 - IRG/WP 16-40742
Wood protection research is continuously looking for more benign and effective treatments. One of the main concerns deals with the toxicity of the active compounds employed in the formulations of the preservatives, since they could become a health and environmental issue. Secondly, long-lasting treatments are preferred in order to increase the service life of the treated wood. Weathering condition...
C Fernández-Costas, S Palanti, M Á Sanromán, D Moldes


Contamination of recycled wood from selected recycling companies in Europe
2016 - IRG/WP 16-50322
Recycled wood is becoming more and more important material source for production of new materials and chemicals. For good quality of end products predominately clean recycled wood should be used. In present research, we have focus on concentrations of non-wooden materials in recycled wood and presence of inorganic pollutants: chlorine (Cl), chromium (Cr), copper (Cu), zinc (Zn), lead (Pb), iron (F...
B Lesar, M Humar, G Hora


Copolymers of tannin extracts as wood protection agents
2017 - IRG/WP 17-30709
Wouldn´t be a dream to preserve wood with the substances which the nature already synthesizes for protecting itself? The idea we would like to pursue is simple: Increase the concentration of these substances, the tannins, trying to fix them properly in wood. It appears easy but it is not. Sensibility against leaching, fungal decay and weathering were observed. In this paper new flavonoid co-polym...
G Tondi, L Sommerauer, A Oberle, A Petutschnigg, M-F Thevenon


Bio-preservative properties of technical lignins from South African pulp mills: An investigation towards a conceptualized development of natural compound-based wood preservatives
2018 - IRG/WP 18-30724
The depletion of naturally durable timber and the risk posed by some of the conventional wood preservatives to human health and the environment continue to drive research efforts towards developing new formulations that are benign. Furthermore, the global concept of environmental sustainability aims at optimal use of resources and to comprehensively include conversion of waste to value added produ...
A Alade, L Tyhoda, M Meincken


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