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Multiscale modification on water resistance and dimensional stability of Populus cathayana by alkali lignin combined with heat treatment
2018 - IRG/WP 18-40826
The aim of this study was to enhance the water resistance and dimensional stability of fast growing wood by alkali lignin combined with heat treatment. Poplar (Populus cathayana) samples were first impregnated with alkali lignin solution and then subjected to heat treatment at 140, 160, and 180°C respectively for 2h. Properties of leachability, moisture adsorption and water absorption, contact an...
H Zhou, J Li, E Ma


Reactivity of alkoxysilanes with cellulose and lignin in presence of catalysts
2018 - IRG/WP 18-40831
The origin of research was another step in development of a new conservation method for wood cultural heritage. Wood silanisation seemed to be an alternative method to waterlogged wood PEG treatment. The superior aim from the practical point of view was to increase dimensional stability and reduce the hygroscopicity of archaeological wood. The aim of the study was to identify interactions between ...
J Siuda, W Perdoch, B Mazela, M Zborowska


Properties and potential use of Irvingia gabonensis and Irvingia wombolu kernel extracts as natural wood adhesives: Towards formaldehyde free wood composite products
2018 - IRG/WP 18-40832
Irvingia species are widely distributed in central and West Africa as well as parts of Asia and are earmarked for domestication due to the multitude of potential products that can be obtained from them. With renewed interest in renewable sources, the current study establishes the feasibility of utilizing extracts from Irvingia gabonensis and Irvingia wombolu kernels as wood adhesives. Proximate an...
A O Alawode, S O Amiandamhen, M Meincken, L Tyhoda


Non-stochiometric oxidation and ROS generation promoted by guaiacol lignin structures and lignocelluose surfaces may be a component of brown rot fungal degradation mechanisms
2019 - IRG/WP 19-10937
Model guaiacol compounds representing lignin monomers, as well as DHP-lignin and wood flour of controlled particle size were used to assess iron reduction at the pH of the natural wood cell wall. All compounds functioned as electron donors for ferric iron, with the lignin monomers demonstrating capacity for non-stochiometric reduction of iron with multiple moles of ferric ion reduced per mole of l...
Y Tamarua, M Yoshidaa, L D Eltisb, B Goodell


Biosourced hybrid phenolic resins as coatings for the protection of wood and wood composites
2019 - IRG/WP 19-30745
Biosourced phenolic resins, based on the phenol-formaldheyde (PF) type, were prepared for their application as coating for wood and wood composites protection, especially against fire. The resins were synthesized by combining an organic polymeric matrix with another inorganic phase. The organic phase was prepared substituting phenol by natural phenolic compounds such as lignin and tannins. The ino...
P L de Hoyos-Martínez, R Herrera, J Labid, F Charrier El Bouhtoury


FTIR analysis of wood blocks decayed by brown-rot fungi
2020 - IRG/WP 20-10959
Calibration curves of the relative lignin contents in Cryptomeria japonica decayed by brown-rot fungi were developed with Infrared Spectroscopy and Klason technique. First, wood decay test was conducted using brown-rot fungi (Fomitopsis palusris, F. pinicola, Wolfiporia cocos, Gloeophyllum trabeum, and Neolentinus suffrutescens) and white-rot fungus (Trametes versicolor) was used as a comparison. ...
R Kondo, Y Horikawa, R Kose, M Yoshida


The iron reduction by chemical components of wood blocks decayed by wood rotting fungi
2021 - IRG/WP 21-10979
Brown-rot fungi, a group of wood rotting fungi, is well known to be one of major microorganisms that cause the deterioration of wooden buildings in Japan and have been considered to use chelator-mediated Fenton (CMF) reaction in concert with hydrolytic and redox enzymes for degradation of wood cell wall. CMF can be described as a non-enzymatic degradation system that utilizes hydroxyl radicals pro...
R R Kondo, Y Horikawa, K Ando, B Goodell, M Yoshida


Environmentally Friendly Wood Modification based on Tannin-Furfuryl alcohol - Effect on stabilisation, mechanical properties and decay durability
2022 - IRG/WP 22-40929
Furfurylation is a well-known wood modification technology. This paper studied the effect of tannin addition on the wood furfurylation. Three kinds of dicarboxylic acids, adipic acid, succinic acid, and tartaric acid, as well as glyoxal as a comparing agent, were used to catalyse the polymerisation of furanic or tannin-furanic solutions during wood modification. Impregnation of furanic or tannin-f...
M Mubarok, E Azadeh, F O Akong, S Dumarçay, A Pizzi, C Charbonnier-Gérardin, P Gérardin


Novel bio-based tannin/furfurylic alcohol thermosets: application to wood preservation
2022 - IRG/WP 22-40959
This project is integrated within the overall context of sustainable development and targets the valorization the wood industry by-products such as polyphenolic extractives, and in particular tannins. The objective targets the use of the same polymer used for production of tannin-furanic foams, but here for wood preservation to avoid the utilization of biocides. The aims is to the design of copoly...
C Gérardin-Charbonnier, E Azadeh, A Pizzi, P Gerardin


Geopolymer as a fixation method for tannin-based wood preservatives
2023 - IRG/WP 23-30774
This study aims to test if a second step impregnation with a geopolymer solution can fix Colatan GT10, a commercial extract rich in tannins, to wood, reducing their leaching and improving their performance as wood preservatives. Scots pine sapwood specimens of 40×10×5 mm3 were impregnated with Colatan GT10 tannin mix, geopolymer, and as combined treatment Colatan GT10 with subsequent geopolymer ...
Y M López-Gómez, A Barbero-López, A Haapala


Recent studies into improved fire retardancy of wood undertaken at Luleå University of Technology
2023 - IRG/WP 23-30784
Modern construction is moving more towards engineered wood products, such as glulam and cross-laminated timber (CLT). This increase is driven by the aspiration to deliver high-rise buildings with enhanced environmental profiles and human well-being. This desire to use wood in construction is pushing the need for fire treatments capable of meeting a products service life. However, the use of wood ...
D Jones, C-F Lin, I Kim, E Garskaite, O Karlsson, D Sandberg


UV protection and dimensional stability of lignin-based wood treatments
2023 - IRG/WP 23-40979
New developments in the field of wood modification aim to enhance the intrinsic properties of natural timber. The limitation of wood should be preferably achieved with biobased ingredients and efficient, eco-friendly treatments possessing low environmental impact. Consequently, new solutions assuring expected properties and functionality over elongated service life and reducing the risk of product...
R Herrera,O Gordobil, F Poohphajai, A Sandak


Optimization of furfurylic alcohol/tannin ratio to improve the performance of biosourced thermoset resins for wood protection
2023 - IRG/WP 23-40994
This study concerns the chemical modification of wood with different ratios of tannin and furfuryl alcohol (FA) in the presence of maleic acid as catalyst. Tannins were used not only as cross-linking agents, but also as co-monomers to improve wood durability, while reducing the amount of FA used. Different aqueous formulations were prepared containing decreasing amount of FA (from 45.45% to 0%) an...
E Azadeh, A Pizzi, P Gérardin, C Gérardin-Charbonnier


Time-lapse evaluation of Aureobasidium pullulans growth on selected lignin derivatives and chitosan
2024 - IRG/WP 24-11032
Wood, often referred to as the “building material of the 21st century”, has gained recognition as an attractive alternative to several traditional building solutions. To enlarge the application of wood, several properties including biotic and abiotic degradation resistance need to be improved. Consequently, new solutions are available on the market that ensure expected properties and functiona...
Gubensek, F Poohphajai, A Tosic, K Butina Ogorelek, W Pajerski, A Cernosa, V Hribljan, A Sandak


Characterization of cell wall morphology and water-soluble extractives in Japanese larch decayed by white-pocket-rot fungi
2024 - IRG/WP 24-11034
Porodaedalea chrysoloma (Fr.) Fiasson & Niemelä is a basidiomycete that can cause white-rot decay in Japanese larch (Larix kaempferi) heartwood. P. chrysoloma is a white-rot fungus with a unique pattern that causes white-pocket-rot in the xylem of Japanese larch. However, the mechanism by which P. chrysoloma yields the pattern of white-pocket-rot in Japanese larch heartwood remains unclear. Thus,...
Y Mori, H Arai, T Ito, H Hashitani, K Yamashita, Y Ota, M Kiguchi


Influence of the substitution of phenol with lignin cleavage products in phenol-formaldehyde impregnation resins for wood modification on the fungal decay resistance and impregnation depth
2024 - IRG/WP 24-30805
The impregnation modification of wood with phenol-formaldehyde (PF) resins increases the woods dimensional stability and resistance against fungal decay. However, to decrease the usage of non-renewable resources, the substitution of phenol has been a topic of scientific interest. Lignin is a currently underutilized resource with a chemical structure that contains phenolic units. For adhesive appli...
J Karthäuser, L Tarentino, A Treu, H Militz, G Alfredsen


Developing thermal-energy storage systems based on Kraft lignin-glyoxal and organic phase-change material modified wood
2024 - IRG/WP 24-30810
This study investigated the use of modified wood as a thermal-energy storage material through the integration of paraffin-based phase-change materials (PCMs). The objective was to evaluate the influence of Kraft lignin-glyoxal prepolymer on the properties of wood modified with PCMs. The implementation of the modified wood involved preparing PCM emulsions, synthesizing lignin-glyoxal prepolymer, an...
C-F Lin, O Karlsson, D Jones, D Sandberg


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