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Wood furfurylation process development. Part 2: Lowry impregnation trials
2007 - IRG/WP 07-40377
The objective was to evaluate whether Lowry-impregnation of Scots pine with FA100-mix, instead of the FA40-mix, would lead to similar or slightly higher WPGs and to investigate any potential changes in penetration pattern. The results indicate that the penetration was better, also penetrating the outer zone of the heartwood. Furthermore, it was possible to reduce the WPG-levels for pine down to 50...
M Westin, E Larnøy, S Lande


Protection of wood for above ground application through modification with a fatty acid modified N-methylol/paraffin formulation
2007 - IRG/WP 07-40378
Hydrophobic chemical modification can be regarded as an alternative approach to conventional wood preservation using biocides in order to protect wood in hazard class 3 according the European Standard EN 335-1. A formulation containing fatty acid modified N-methylol/paraffin and an aluminium salt catalyst was used to change the material properties of wood in order to protect wood from fungal dec...
Nguyen Hong Minh, H Militz, C Mai


Natural Weathering of Coated Oil Heat Treated Wood
2007 - IRG/WP 07-30440
Oil heat-treated (thermally modified) pine wood was coated with 9 different types of solvent- or water-borne exterior finishes. The systems with modified wood substrate as well as unpainted and painted non-modified controls were exposed to weathering (EN 927-3) on two locations with sub-alpine and alpine climate. The influence of natural ageing on surface systems was evaluated after one year of ex...
M Petric, B Kricej, M Pavlic, A Rapp


The effects of chemical modification on the biological properties of alder and spruce particleboards
2007 - IRG/WP 07-40363
This study is evaluated by measuring the weight loss, and the ability of white and brown-rot fungi to attack unmodified and modified particleboards manufactured using spruce (Picea orientalis (L.) Link.) and alder (Alnus glutinosa) chips. The chips were reacted with acetic, succinic, maleic and phthalic anhydride at constant temperature for 3 hours then, hot pressed at 150 °C by using phenol for...
Ü C Yildiz, E Dizman, S Yildiz, A Temiz, M Aslan, E D Gezer


Treatment of Green Logs infested by Exotic Pest: Case Study of the Emerald Ash Borer: Agrilus planipennis Fairmaire
2007 - IRG/WP 07-10628
Invasive alien insect species periodically infest forests in the United States causing the destruction of plant species and decimating populations, resulting in significant economic and ecological losses for areas involved. The Emerald Ash Borer (EAB) was first discovered on North American soil in the summer of 2002 near Detroit, Michigan and has since spread to several other Midwestern states and...
P Nzokou, S Tourtellot, D P Kamdem


A step towards a better understanding of fungal colonization of modified wood - QRT-PCR studies
2008 - IRG/WP 08-10653
The area of wood protection is in a period of change. New wood protection systems have been developed while their mode of action remains insufficiently understood. The development of molecular methods provides potential tools to investigate the interaction between modified wood and decay fungi. One small step to tackle some of the unsolved questions about the mode of action of modified wood is tak...
G Alfredsen, A Pilgård, A Hietala


Spruce and pine heartwood treatment by means of microwave radiation
2008 - IRG/WP 08-40411
An easier penetrability and a more even uptake of wood protection agents is aimed for the two most common wood species in Europe, namely Norway spruce (Picea abies) and Scots pine heartwood (Pinus sylvestris), particularly when there is a great difference in absorption behavior of sapwood and heartwood. Microwave conditioning can improve permeability, reduce density and heat conductivity and chang...
A Treu, H Rieche, H Militz


Spruce and pine heartwood treatment by means of microwave radiation
2008 - IRG/WP 08-40411
An easier penetrability and a more even uptake of wood protection agents is aimed for the two most common wood species in Europe, namely Norway spruce (Picea abies) and Scots pine heartwood (Pinus sylvestris), particularly when there is a great difference in absorption behavior of sapwood and heartwood. Microwave conditioning can improve permeability, reduce density and heat conductivity and chang...
A Treu, H Rieche, H Militz


Preliminary investigation of biological resistance, water absorption and swelling of thermally compressed pine wood panels
2008 - IRG/WP 08-40396
Wood can be modified by compressive, thermal and chemical treatments. Compression of wood under thermal conditions is resulted in densification of wood. This study evaluated decay and termite resistance of thermally compressed pine wood panels at either 5 or 7 MPa and at either 120 or 150?C for one hour. The process caused increases in density and decreases in thickness of the panels; however, lab...
Ö Ünsal, S N Kartal, Z Candan, R Arango, C A Clausen, F Green III


Resistance against basidiomycetes of 1,3-dimethylol-4,5-dihydroxy ethylene urea (DMDHEU)-modified plywood of Pinus sylvestris
2008 - IRG/WP 08-40398
Plywood produced with rotary-cut veneers of Pinus sylvestris impregnated with a solution of 1.3 M 1.3-dimethylol-4.5-dihydroxyethyleneurea (DMDHEU) and glued with a phenolic resin (Prefere 4976 DYNEA) were inoculated with Coniophora puteana, Coriolus versicolor and Pleurotus ostreatus, following the European standard ENV 12038. The specimens were leached following European standard EN 84. The re...
A Dieste, A Pfeffer, S Bollmus, H Militz


Termite resistance of DMDHEU-treated wood
2008 - IRG/WP 08-40401
Chemical wood modification with dimethyloldihydroxy-ethyleneurea (DMDHEU) or its derivatives are applicable to both solid lumber and wood-based composites. Advantages of DMDHEU-based modification are an increase of dimensional stability and high durability against white, brown and soft rot fungi. At higher chemical loadings, the hardness of the wood is considerably increased. Due to the durabil...
H Militz, S Schaffert, B C Peters, C J Fitzgerald


COST Action E37. Sustainability Through New Technologies For Enhanced Wood Durability -
2008 - IRG/WP 08-40417
The main overall objective of the Action was to concentrate on the contribution of wood durability to sustainability through the development of systems for quality assurance and performance classification of modified wood and wood products as alternatives to wood treated with traditional preservatives. By this means it seeked to improve and consequently to increase the cost-effective use of compon...
R-D Peek, J Van Acker


Bi-oleothermal treatment of wood at atmospheric pressure: resistance to fungi and insects, resistance to weathering and reaction to fire results
2008 - IRG/WP 08-40418
Bi-oleothermal process is a simple treatment which has been developped by CIRAD in cooperation with FCBA. It allows a deep impregnation of wood with hydrophobic products using cheap facilities. The process includes two steps at atmospheric pressure. The first one is a dipping of wood samples in a hot oil bath (between 110 °C and 200°C) which creates an overpressure inside the wood. The second on...
L Podgorski, I Le Bayon, I Paulmier, J-D Lanvin, V Georges, D Grenier, H Baillères, J-M Méot


Chemical modification of Scots Pine Sawdust by mixed anhydrides
2008 - IRG/WP 08-40439
By making react mixtures containing acetic-fatty anhydrides on Scots pine sawdust (SPS) without any solvent or catalyst; we synthesized mixed acetic-fatty esters of SPS. Such mixtures were synthesized by reaction between a carboxylic acid and acetic anhydride. These mixtures were obtained after reaction of acetic anhydride and a fatty acid that yields at equilibrium a mixture of five compounds: ac...
J Peydecastaing, E Borredon, S El Kasmi


Effect of different ASAs (alkenyl succinic anhydrides) on the treatment of biological protection of wood in use class 4
2008 - IRG/WP 08-40440
The alkenyl suscinic anhydrides (ASAs) used in this work are adducts resulting from the maleinization reaction of fatty acid alkyl esters. Various products with different alkyl groups were synthesized from rapeseed (Brassica napus) oil esters, rich in oleic acid. The liquids obtained showed a viscosity similar to that of vegetable oils and a brown color. When applied into wood, a thermal treatment...
C Vaca-Garcia, O Pignolet


Effectiveness of sol-gel treatments coupled with copper and boron against subterranean termites
2009 - IRG/WP 09-30493
Wood modification by sol-gel treatments shows many positive features, like antimicrobial properties. Wood was also successfully modified with alkoxysilanes enhancing its resistance against soil micro-organisms. Silver, copper, zinc compounds, boric acid or organic biocides such as alkylammonium compounds may be added to the sol-gel to enhance its biocidal properties. Nevertheless, if some of these...
E Feci, L Nunes, S Palanti, S Duarte, G Predieri, F Vignali


Biological Treatment to Improve Wood Product Quality and Durability - Fifteen Years of Effort and Experience at FPInnovations-Forintek Division
2009 - IRG/WP 09-40444
Wood plays an important role in the world economy. However, wood is subject to attack from wood-degrading fungi and insects and durability and quality of wood products are becoming increasing concerns for consumers. Development of effective and low environmental impact technologies to improve wood product quality and durability will be required to address these concerns. The application of a bio...
Dian-Qing Yang


Enhanced uptake of wood modification agents in “bioincised” wood
2009 - IRG/WP 09-40445
The permeability of refractory wood species e.g. Picea abies and Abies alba is reduced resulting in a radial penetration of chemical solutions of only a few millimetres. Exploitation of these wood species is therefore not possible for many applications. A novel biotechnological method (European patent 05027812.6) based on the pre-treatment of wood with the white-rot fungus Physisporinus vitreus si...
F W M R Schwarze, M Schubert


Rapid Microwave-Assisted Acid Extraction of Metals from Chromated Copper Arsenate (CCA)-Treated Southern Pine Wood
2009 - IRG/WP 09-50262
The effects of acid concentration, reaction time, and temperature in a microwave reactor on recovery of CCA-treated wood were evaluated. Extraction of copper, chromium, and arsenic metals from chromated copper arsenate (CCA)-treated southern pine wood samples with three different acids (i.e., acetic acid, oxalic acid, and phosphoric acid) was investigated using in microwave reactor. Oxalic acid wa...
Bin Yu, Chung Y Hse, T F Shupe


Modification of Wood by a Water-Repellent Compound Used in the Textile Industry: Boron Release and Termite Resistance
2009 - IRG/WP 09-40447
In the study, wood specimens were treated with disodium octoborate tetrahydrate (DOT) and a commercial water and oil repellent compound, FORGUARD M®, a weak cationic emulsion containing dipropylene glycol monomethylether, water and solids in its formulation and used in the textile industry. There were two different processes for preservative treatments: double and single treatments. The leaching ...
S N Kartal, E Terzi, B Erilkun, Y Imamura


The resistance of thermo-oil modified wood against decay and mould fungi
2009 - IRG/WP 09-40448
Thermally modified wood in comparison to natural wood demonstrates some advantageous functional properties like decreased hygroscopicity, higher dimensional stability. It also has increased durability and improved resistance to fungal decay. However thermal modification of wood may lead to reduced strength properties what may limit the use of wood in mechanically beared constructions. The changes ...
A Fojutowski, A Kropacz, A Noskowiak


Termite resistance of some modified wood species
2009 - IRG/WP 09-40449
During the last few decades, researchers worldwide have investigated and developed new treatment techniques to improve intrinsic wood properties. Some of these techniques were introduced to the market recently and are gaining in importance.. Various wood properties of these new materials have been studied intensively. These include physical-mechanical properties (dimensional stability, moisture ...
H Militz, B C Peters, C J Fitzgerald


Weathering of Wood Modified with the N-Methylol Compound 1,3‑dimethylol-4,5-dihydroxyethyleneurea (DMDHEU)
2009 - IRG/WP 09-40467
Scots pine (Pinus sylvestris L.) sapwood boards were treated with a methylated 1,3‑dimethylol-4,5-dihydroxyethyleneurea (mDMDHEU) causing weight gains of approx. 25% and exposed to weathering for 18 months. Compared to untreated boards, treatment with mDMDHEU reduced surface discoloration mainly caused by staining fungi. Boards treated with mDMDHEU exhibited clearly lower moisture content th...
C Mai, Yanjun Xie, A Krause, K Urban, P D Evans, K Richter, H Militz


Wood properties influencing the penetration of Scots pine (Pinus sylvestris) sapwood with the wood modification agent furfuryl alcohol
2009 - IRG/WP 09-40470
The European standard EN 350-2 classifies Scots pine sapwood as class 1 (easy to treat). However large variations in sapwood penetration exist which affect a homogenous distribution of preservatives. Hence individual penetration schemes have to be developed and adjusted to the material most difficult to treat in order to provide adequate sapwood penetration. To ensure better economic process con...
K Zimmer, E Larnøy, G Koch


Material properties of furfurylated wood for window production
2009 - IRG/WP 09-40480
Wood modification with furfuryl alcohol is an extensively investigated process and already produced commercially. Furfurylated wood is in the focus of a European project on its use for the production of high performance windows. Different wood species were treated with furfuryl alcohol and tested on water uptake, dimensional changes, leaching in water, resistance to fungal degradation, and ecotoxi...
A Treu, A Pilgård, S Puttmann, A Krause


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