IRG Documents Database and Compendium


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Environmental fate of copper-based wood preservatives in different soil substrates - Part 2: Study of the metal sorption and migration potential under simulated rainfall
1998 - IRG/WP 98-50101-21 b
In order to examine the potential environmental impact of spillages of the saltborne wood preservative CCA in treatment plants, four large scale experiments are set-up so as to follow the water transport and ion mobility in various field soils. A plastic container is filled with a sand, silt, clay and potting soil, made up at their respective bulk density and wetted to a given moisture content. U...
G M F Van Eetvelde, R Hartmann, J M Mwangi, H S Öztürk, M Stevens


Metal Migration from Douglas-fir Poles Treated with Ammoniacal Copper Zinc Arsenate According to Best Management Practices
2010 - IRG/WP 10-50272
The potential for migration of metal components from ammoniacal copper zinc arsenate treated (ACZA) poles was examined using pole sections treated using Best Management Practices. Copper and zinc levels were highest in runoff collected following the first rainfall events, then declined. Copper and zinc levels in runoff averaged 20 ppm and 5 pm respectively. The metal levels were then used to pr...
J J Morrell, C S Love, C Freitag


Effect of exposure site on metal migration from copper azole, alkaline copper quat or chromated copper arsenate treated southern pine decking
2015 - IRG/WP 15-50313
Metal migration from chromated copper arsenate, copper azole or alkaline copper quaternary compound treated southern pine lumber was assessed at sites in Mississippi and Oregon. Metal levels tended to be consistently higher in decks exposed in Mississippi. Rainfall characteristics did differ slightly at the two sites, but the levels did not appear to be of a magnitude that might affect metal mobi...
J J Morrell, H M Barnes


Quantifying metal migration from a deck constructed with copper-azole-treated lumber
2024 - IRG/WP 24-50391
Soluble copper or micronized copper wood preservatives are the most common available wood preservative systems for residential applications in the United States. Copper containing wood preservatives have been scrutinized for their potential negative impacts on the environment, across many jurisdictions. Concerns arise from the potential for preservatives to migrate out of treated wood upon water e...
G Presley, M Konkler


Modelling of PCP migration in the environment: Feeding the models with laboratory data
1993 - IRG/WP 93-50001-08
In 1989, Hydro-Québec began a study program on pentachlorophenol (PCP) to ensure safe use of the product at all stages. One of the aspects of the study is the creation of a predictive system for evaluating the behavior of PCP and oil migration from wood poles to the environment. This system comprises four mathematical models for predicting PCP and oil migration in and on the surface of the pole, ...
A Besner, P Tétreault, R Gilbert


Système informatisé d'aide à la décision pour la gestion de la migration du pentachlorophénol dans l'environnement
1993 - IRG/WP 93-50001-10
This paper describes a Decision Support System (DSS), concerning pentachlorophenol (PCP) migration in the environment. The principal objectives of the DSS are to assist managers in siting of PCP-treated poles in the Hydro-Québec system and the storage areas and in the treatment of customer complaints. Four mathematical models are incuded in the system: a model simulating migration inside and on t...
G Lefebvre, J-C Tessier


Migration of active ingredients from treated timber into fresh water
1991 - IRG/WP 3669
Spruce roundwoods and segments were treated with three different wood preservatives. Two of them containing copper and chromium the other one free of chromium. After fixation (3 weeks, 20°C) the specimens were leached by using artifical rain or by shaking the segments for one hour in contact with demineralized water. The water was analysed for the relevant elements of the preservative tested. Lea...
H Klipp, H Willeitner, K Brandt, A Müller-Grimm


Non-enzymatic Gloeophyllum trabeum decay mechanisms: Further study
2001 - IRG/WP 01-10395
Information will be presented on the mechanisms involved in, and potential application of, non-enzymatic wood decay by brown rot decay fungi. Specifically, the hypothesized role of low molecular weight phenolate derivatives will be discussed in relation to non-enzymatic degradation of wood. The mechanism of binding of iron by cellulose, and binding and reduction of iron by fungal derivatives and m...
B Goodell, J Jellison


Creosote movement from treated wood immersed in fresh water: Initial PAH migration
2003 - IRG/WP 03-50201
Creosote has a long history of successful use as a wood preservative, but polycyclic aromatic hydrocarbons (PAHs) in this preservative have raised environmental concerns, particularly when creosote-treated wood is used in aquatic environments. A number of models have been developed to predict the risk of creosote use in aquatic environments, but one limitation of these models is a lack of data o...
Sung-Mo Kang, J J Morrell, J Simonsen, S T Lebow


Role of Global Cooperation in Wood Protection for Conserving Forest Resources
2007 - IRG/WP 07-50249
The current uses of treated wood are discussed along with the emerging concerns for continued use of these products. The issues of new chemicals, treatments for wood based composites, migration of chemicals from treated wood, and the disposal of these products at the end of their useful life are all outlined. The potential for the IRG to serve as the focus for research discussion as well as coll...
J J Morrell, G Deroubaix


Protection of Ochroma pyramidale from fungal decay with N,N-napthaloylhyroxylamine
1998 - IRG/WP 98-30182
Fungal decay of wood in service results in billions of dollars (U.S.) in losses annually. Recent environmental restrictions, both U.S. and international, are limiting and eliminating the use of broad-spectrum, heavy metal biocides for wood preservation. Restrictions result primarily from problems with disposal. New wood preservatives need to be developed and tested which specifically target key el...
F Green III, T L Highley


Fungal degradation of wood treated with metal-based preservatives. Part 2: Redox states of chromium
1996 - IRG/WP 96-10164
Concerns have arisen about the leaching of heavy metals from wood treated with metal-based preservatives, such as chromated copper arsenate (CCA). Of particular concern is the toxic redox state of chromium and arsenic in aging and decayed CCA-treated wood. Generally, hexavalent chromium is more toxic than trivalent chromium and trivalent arsenic is more toxic than pentavalent arsenic. The desired ...
B Illman, S Bajt, T L Highley


Effect of leaching temperature and water acidity on the loss of metal elements from CCA treated timber in aquatic conditions. Part 2: Semi-industrial investigation
1995 - IRG/WP 95-50040-13
In continuation of previous leaching research on the quantification and modelling of metal elements released from CCA treated timber, a series of experiments has been carried out dealing with the influence of temperature and pH of the relative aquatic environment. The leaching method used is the Dutch prestandard for building materials, a long term static leaching test simulating practical bank-sh...
G M F Van Eetvelde, W J Homan, H Militz, M Stevens


Metal carboxylates for wood pest control
1996 - IRG/WP 96-30109
Metal carboxylates have been used as wood preservatives for more than fifty years. Predominantly salts of naphtenic acids have been commercially applied so far. They have water repellent as well as fungicidal and insecticidal properties. In the last years, metal carboxylates of saturated fatty acids were introduced. Fatty acids with 7-10 carbon atoms already have fungicidal activity by themselves....
F Pohleven, M Petric


Migration of Metals from Douglas-fir Lumber Treated with ACZA or Pentachlorophenol Using Best Management Practices: Preliminary Tests
2005 - IRG/WP 05-50224-4
The potential for migration of preservative components from ammoniacal copper zinc arsenate (ACZA) and pentachlorophenol treated Douglas-fir lumber in non-soil contact exposure was assessed in a simulated rainfall device. Metal levels from ACZA treated wood were elevated for the first 30 minutes of rainfall and then declined sharply. Repeated cycles of rainfall led to declines in initial metal l...
J J Morrell, Hua Chen, J Simonsen


Removal of heavy metals from treated wood using biological methods
2005 - IRG/WP 05-50226
Heavy metals were removed from wood treated with copper based preservatives using brown-rot fungus Fomitopsis palustris. The amount of effective elements removed by treatment methods was examined. The relationship between oxalic acid concentration and the amount of heavy metals removed from each treated wood was also investigated. The relationship between fungus weight and removal rate was also in...
Dong-won Son, Dong-heub Lee


Transmission poles with sub-standard retentions protected by Field Liners outperform standard poles in service
1997 - IRG/WP 97-40095
Eucalyptus cloeziana 12m transmission poles were treated with sub-standard creosote retentions of 80kg/m3 and Field Liners were fitted to the poles before they were placed in service at Umbumbulu, Kwazulu Natal. Poles treated with standard creosote retentions of 130kg/m3 but without Field Liners were also placed in service in the same area. Core samples were taken from both groups of poles after 1...
M R Behr, G D Shelver, A A W Baecker


Bioassays for rapid assessment of heavy metal toxicity in seawater
1998 - IRG/WP 98-50112
In evaluating the effect of CCA leachate on the establishment of fouling communities on wood exposed in the sea, three organisms were assessed as biological indicators of heavy metal toxicity. These were two macroalgae, Fucus serratus and Undaria pinnatifida. and the motile protist thraustochytrid, Schizochytrium aggregatum. The choice of these organisms for the tests carried out was based on the ...
C J Brown, R L Fletcher, R A Eaton


Optimum growth conditions for the metal-tolerant wood decay fungus, Meruliporia incrassata TFFH 294
1999 - IRG/WP 99-50142
There is a worldwide need for alternative methods for the treatment and disposal of CCA-treated waste wood. Illman and Highley (IRG/WP 96-10163) reported the isolation of a unique strain of Meruliporia incrassata (TFFH 294) with tolerance to CCA. The strain is capable of degrading CCA treated waste wood, giving a 40% weight loss in the ASTM soil block test. The strain is an ideal candidate for deg...
V W Yang, B Illman


Evaluation of the corrosivity of the treated wood - Laboratory vs field test methodologies
2000 - IRG/WP 00-20211
The corrosivity of treated wood to fasteners has been evaluated using laboratory test procedures, including AWPA Standard E12-94. The standard method was modified in order to allow detailed study of commercial metal fasteners in terms of sample types, installation configuration and exposure conditions. Parallel field tests were also performed. The experimental results generated from these tests su...
L Jin, A F Preston


Dimension of lysimeters and the evaluation of the migration of wood preservative components in soil
1996 - IRG/WP 96-50065
In the past, investigations concerning the migration behaviour of wood preservatives were made to a minor extent and no uniform methods of test exist. The migration behaviour of CFB was determined using 5 lysimeters of different dimension. The results of the migration and distribution of the anions in the soil showed considerable differences between both ions. Approximately the whole quantity of c...
E Melcher, R-D Peek


Preliminary modelling of methylisothiocyanate movement through Douglas fir transmission poles
1988 - IRG/WP 3466
Methylisothiocyanate is a volatile solid that is the active ingredient of several registered and experimental wood fumigants. Information on the sorption and diffusion of this chemical in Douglas-fir heartwood and sapwood was used to develop a two-dimensional model of fumigant movement within a single horizontal cross-section of a transmission pole. The model indicated that dry wood (14% MC) stron...
A R Zahora, P E Humphrey, J J Morrell


Equilibrium distribution of toxic elements in the burning of impregnated wood
2001 - IRG/WP 01-50172
The current work focuses on predicting the behavior of arsenic, chromium, and copper in the burning of impregnated wood. A theoretical method is used to study the chemistry of the system, with special interest directed towards the vaporization tendency of the potentially toxic elements. The core of the study is the global equilibrium analysis that simultaneously takes into consideration all chemic...
K Sandelin, R Backman


Metal Leaching from Pressure Treated Wood in Sanitary Landfill Leachate
2004 - IRG/WP 04-50220
Pressure treated wood products contain heavy metals to prevent biological decay. Scrap treated wood from construction activities and demolished structures containing treated wood are typically disposed in landfills. To examine the potential mobility of metals from pressure-treated wood disposed in landfills, wood samples were leached using leachate from lined landfills and the concentrations of ar...
B Dubey, T G Townsend, H M Solo-Gabriele


The degradation of wood by metal fastenings and fittings
1972 - IRG/WP 302
As well as the hazards of biological decay, timber used in boat building is subject to the effects of chemical decay associated with the corrosion of metallic fastenings. The title has been deliberately chosen to emphasize that in wooden construction the troubles are not just those of corrosion of the fastenings, but also the destructive secondary effects on the wood caused by the products of the ...
L C Pinion


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