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Study of UV resistance and natural weathering of coatings on chemically modified wood
2013 - IRG/WP 13-40629
In this study, UV resistance and weathering performance of rubberwood (Hevea brasiliensis) and radiata pine (Pinus radiata) modified with benzoyl chloride and acetic anhydride was studied. Performance of polyurethane based wood coatings on modified wood was also evaluated. Unmodified and chemically modified specimens were exposed to accelerated and natural weathering. Modified and unmodified woo...
K K Pandey, K Srinivas


Field performance of wood impregnated with siloxanes using supercritical carbon dioxide
2013 - IRG/WP 13-40632
This paper presents preliminary results from a 13-month field test containing pine sapwood samples (Pinus sylvestris) impregnated with a mixture of siloxane and organic biocides using supercritical carbon dioxide as carrier. Samples were exposed above ground at a Danish field test site using matched non-treated sapwood controls for every treated sample. All samples were painted before exposure. Pi...
A Kjellow, F Imsgard, J Fernandes, R Wagner, J Delis


Characterization of wood modification prepared by in situ polymerization with pre-polymer and the mechanism of modification
2013 - IRG/WP 13-40633
Chemical modification of wood is a potential way to obtain high quality wood. In this study, the fast-growing poplar was impregnated with modifier using a pulse-dipping machine by in situ polymerization. Fungal decay analysis, mechanical properties and dimension stability of the natural and modified woods were investigated. The wood samples were also characterized by X-ray diffraction (XRD) Therma...
Qian Lang, Zeng Bi, Junwen Pu


Combined effects of thermal modification and ACQ-D impregnation on properties of southern yellow pine wood
2013 - IRG/WP 13-40637
In this study, samples of southern yellow pine sapwood were first thermally modified and then treated by the alkaline copper quat-type D (ACQ-D) wood preservative. Two heating temperature (180℃ and 220℃) and two concentrations of ACQ-D solution (0.9% and 1.35%) were used in the experiments. The combined effects of thermal modification and ACQ-D on leaching performance, mechanical prope...
Wang Wang, Yuan Zhu, Jinzhen Cao


Effect of bio-resin from cashew nut shell liquid (CNSL) on decay resistance properties of wood
2013 - IRG/WP 13-40649
This study assesses the decay resistance properties of bio-resin modified wood against decay fungi of the Basidiomycota according to the EN 113 protocol. A bio-resin system was developed by ozonolysis process from cashew nut shell liquid (CNSL), a naturally occurring mixture of phenolics. Small wood blocks from sapwood of Scots pine (Pinus sylvestris), Obeche (Triplochiton scleroxylon) and Gmelina...
M Ashaduzzaman, M D Hale, V Tverezovskiy, G A Ormondroyd


Quantification of copper and chromium in field stakes after different exposure times: Remaining metal content and distribution
2013 - IRG/WP 13-50291
In order to determine the distribution of copper and chromium as well as their remaining concentration EN 252 specimens and thicker pine sapwood stakes (non standard format) were treated with a commercial CC salt in a vacuum pressure process. The stakes were installed in the test field of the Institute of Wood Research, Hamburg, in August 2010. In all cases three stakes were removed after 4, 8, 12...
T Liese, M Bahmani, E Melcher


The Chelator Mediated Fenton System in the Brown Rot Fungi: Details of the Mechanism, and Reasons Why it has Been Ineffective as a Biomimetic Treatment in some Biomass Applications – a Review
2014 - IRG/WP 14-10828
The chelator-mediated Fenton (CMF) reaction requires the action of two types of chelating compounds. The first chelator, oxalate, solubilizes and then sequesters iron, and the second chelator reduces iron. Iron reduction must be controlled near the fungal hyphae to prevent damaging Fenton chemistry from occurring in that location. Similarly, iron reduction must be promoted within the wood/plant ce...
B S Goodell, M Nakamura, J Jellison


Changes in mechanical and chemical properties of wood exposed outdoors
2014 - IRG/WP 14-20550
The aim of this study was to investigate differences in certain mechanical and chemical properties of three different wood species (common beach (Fagus sylvatica), Norway spruce (Picea abies), and copper-ethanolamine (CuE) impregnated Norway spruce (Picea abies)) that were exposed in use class 3 (CEN, 2006) for periods between 4 and 30 months. The results show, that changes in the investigated me...
N Thaler, C Brischke, D Žlindra, V Vek, M Humar


Scanning Transmission X-ray Microscopy as a tool for examining chemical changes in wood cell walls due to enzymatic activity
2014 - IRG/WP 14-20556
As development of techniques for examining enzymatic activity on solid, complex biological materials, is considered to be an important factor in further development of enzyme applications and for understanding the decay of plant materials, this study explores applicability of Scanning Transmission X-ray Microscope (STXM) for determining chemical changes in enzymatically treated samples at the cell...
D Jeremic, R Goacher, R Yan, C Karunakaran, E R Master


Visualization of gold/silver nanostars in wood by surface enhanced Raman spectroscopy
2014 - IRG/WP 14-30653
Nanotechnology is a fast growing up-to-date technology and ventures expeditiously in the wood preservative market. However, there is still a huge lack of understanding about the interaction and incorporation of nanoparticles (NSs) in wood. Surface-enhanced Raman scattering (SERS) offers unique advantages as an analytical tool with a high selectivity and sensitivity without matrix interference. Her...
C Geers, L Rodríguez-Lorenzo, M Placencia Peña, P Brodard, T Volkmer, B Rothen-Rutishauser, A Petri-Fink


VOC-free remedial treatment agent on organic solvent basis with surface cleaning by photocatalysis using titanium dioxide
2014 - IRG/WP 14-40651
Due to the EU Regulations according to the harmonisation of the European market of biocidal products and the EU Regulations regarding emissions of volatile organic compounds in residential properties a new VOC free yet organic solvent based remedial treatment agent is introduced including a potential method to clean up the wooden surface of remaining biocides after a remedial treatment using photo...
H Ahl, J Fromm, P Jüngel, E Melcher, M Pallaske


Full-scale impregnation of wood with siloxane using supercritical carbon dioxide
2014 - IRG/WP 14-40659
Full-scale impregnation of wood with siloxane was carried out using supercritical carbon dioxide as solvent. A batch of 3530 kg of Scots pine sapwood was impregnated to a retention of approximately 1.3% siloxane. The treatment also consisted of a simultaneous impregnation with organic biocides. The performance of the wood was evaluated in terms of capillary water uptake according to a modified EN ...
A Kjellow, F Imsgard, J Fernandes, R Wagner, J Delis


Improving dimensional stability of thermally treated wood by secondary modification – potential and limitations
2014 - IRG/WP 14-40664
The potential of treating thermally modified wood with melamine resin to improve the dimensional stabilization is tested in this research. Two different boards of poplar (Populus ssp.) were cut into two halves. One half of each board was thermally modified (T1 and T2) in a commercial process, the other half was used as untreated reference material. The material was thermally modified using the vac...
G Behr, K-C Mahnert, S Bollmus, H Militz


Development of new wood treatments combining boron impregnation and thermo modification - Effect on decay and termites durability
2014 - IRG/WP 14-40666
Environmental pressures appeared in most European countries during the last decade has lead to the development of more environmentally acceptable preservation methods. In this context, wood heat treatment has been one of the most investigated alternative methods during the last years. Treated at temperatures ranging between 180 and 220°C, wood components undergo more or less important chemical mo...
S Salman, A Pétrissans, M-F Thévenon, S Dumarçay, B Pollier, P Gérardin


Experiences with an industrial system for controlled thermal wood modification in pressurized unsaturated steam
2014 - IRG/WP 14-40678
Thermal wood modification in pressurized reactors has a long history, but these processes are to date industrially scarcely used, because of the relatively complicated process equipment, compared to the more common high-temperature processes in kilns at atmospheric pressure. However, based on our practical experience with the FirmoLin® process, supported by recent scientific findings, it is foun...
W Willems


Chemical composition of extractives of different wood compartments of Pinus merkusii and their potential implication in wood durability
2015 - IRG/WP 15-10841
Amounts and nature of extractives differ strongly according to the compartment of wood and to the nature of the wood species. Previous studies reported that knotwood of several European Pinus sp. contains extractives contents much higher than stemwood consisting mainly of lignans which may find valuable applications in cosmetic, nutraceutic or pharmaceutic sectors. Different explanations have been...
A Wijayanto, S Dumarçay, R Kartika Sari, W Syafii, P Gérardin, C Gérardin-Charbonnier


Functional silicones used as a potential tool for the development of non-biocidal wood treatments
2015 - IRG/WP 15-30665
The increase of wood resistance against biological agents for outdoor use is conventionally performed by deep impregnation with preservatives. However, some of the traditional wood preservatives, used for decades for wood protection and regarded as the most effective, are currently subjected to severe restrictions because of their toxicity. In fact, new preservation technologies are constantly ent...
F Lhumeau, C Delaite, F Marchal, F Pochon, M Kutnik


The effect of preservative treatment on mechanical strength and structural integrity of wood
2015 - IRG/WP 15-30667
The use of wood for demanding construction applications is increasing in Europe. Wooden constructions are frequently designed of susceptible conifer wood, which is endangered by wood decay fungi in wet applications. Therefore in many cases treating wood with preservatives is unavoidable to ensure the desired service life. However, chemical treatment of wood can result in changes of its mechanical ...
M Humar, D Kržišnik, C Brischke


Durability of Fence Posts of Four Wood Species After 20 Years in Field Test
2015 - IRG/WP 15-30670
In the past years, wood consumption from native forests has drastically reduced the availability of wood. Fast-growing species such as Pinus and Eucalyptus suitably impregnated with chemicals may show a service life equal or higher than hardwood with high natural durability. The field tests have been an alternative widely used to evaluate the durability of wood and the efficiency of preservatives....
A Florian da Costa, A C Salgado de Freitas, E Meneses Oliveira


Characterization of biofilm formation on wood treated with vegetable oils by color-based image interpretation method
2015 - IRG/WP 15-40697
The protection of wood in order to extend its service life is an important issue nowadays. As an alternative to traditional wood coatings biofilms can be used. It is a living protective coating for the wood surface against UV and bio-degradation that has the ability to recover from local damage, such as cracks. This paper presents preliminary results of biofilm formation from an 8-month’s fie...
K Filippovych, H Huinink, L van der Ven, O C G Adan


Release of Copper from Pressure Treated Wood
2016 - IRG/WP 16-20584
Micronized copper based wood preservatives including micronized copper quat (MCQ) and micronized copper azole (MCA) have been introduced commercially to the North American market since 2006 as alternatives to alkaline copper quat (ACQ) or soluble copper azole (CA) preservatives. Unlike ACQ or CA, MCQ and MCA use dispersed particulate copper particles rather than soluble ionic copper to make treat...
Jun Zhang, J Horton


Accelerated Weathering Performance of Impregnated Wood Samples Coated with Zinc by Means of Plasma-Assisted Particle Deposition
2016 - IRG/WP 16-30682
Many different methods are currently applied for wood protection against outdoor conditions. The most important of these is the process of impregnation with liquid substances. However, this kind of wood preservatives cannot provide a long-term protection of wooden surfaces. Weathering-resistant surfaces can be obtained by applying UV absorbing agents. In this study, the influence of zinc particles...
A Can, H Sivrikaya


The termite resistance of wood impregnated with nano-zinc oxide and nano-zinc borate dispersions
2016 - IRG/WP 16-30691
In this work, the effects of the impregnation with nano-ZnO and nano-ZnB dispersions on the termite resistance of European beech wood were investigated. Three different concentrations (namely 0.5%, 1% and 2%) of the above two materials were tested. Water leaching effect was also investigated. It was concluded that a severe effect in terms of termite workers mortality is induced by the use of both ...
C Lykidis, T de Troya, M Conde, J Galván, G Mantanis


Resistance of heat treated Ash wood under steam pressure: rot fungi, soil micro-organisms and termites
2016 - IRG/WP 16-40724
Thermal modification processes have been developed to increase the biological durability and dimensional stability of wood. The aim of this paper was to study the influence of ThermoWood® treatment intensity on wood decay resistance improvement against soil-inhabiting micro-organisms, brown/white rots and termite’s exposures. All of the tests were carried out in the laboratory with two differen...
K Candelier, S Hannouz, M-F Thévenon, D Guibal, P Gérardin, M Pétrissans, R Collet


How intraspecific radial variability of the European Oak’s may influence mild pyrolysis process and durability of the material
2016 - IRG/WP 16-40725
Last decades wood is promoted as building material. Unprotected wood exposed to outdoor conditions undergoes a variety of degradation induced essentially by fungi attacks. Heat treatment of wood by mild pyrolysis (180°C T 240°C under inert atmosphere) is a preservation process with a weak environmental impact, and therefore, is viewed as an interesting alternative to the chemical impregnation me...
J Hamada, A Pétrissans, F Mothe, M Pétrissans, P Gérardin


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