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Study of UV resistance and natural weathering of coatings on chemically modified wood
2013 - IRG/WP 13-40629
In this study, UV resistance and weathering performance of rubberwood (Hevea brasiliensis) and radiata pine (Pinus radiata) modified with benzoyl chloride and acetic anhydride was studied. Performance of polyurethane based wood coatings on modified wood was also evaluated. Unmodified and chemically modified specimens were exposed to accelerated and natural weathering. Modified and unmodified woo...
K K Pandey, K Srinivas


Characterization of wood modification prepared by in situ polymerization with pre-polymer and the mechanism of modification
2013 - IRG/WP 13-40633
Chemical modification of wood is a potential way to obtain high quality wood. In this study, the fast-growing poplar was impregnated with modifier using a pulse-dipping machine by in situ polymerization. Fungal decay analysis, mechanical properties and dimension stability of the natural and modified woods were investigated. The wood samples were also characterized by X-ray diffraction (XRD) Therma...
Qian Lang, Zeng Bi, Junwen Pu


Quantification of copper and chromium in field stakes after different exposure times: Remaining metal content and distribution
2013 - IRG/WP 13-50291
In order to determine the distribution of copper and chromium as well as their remaining concentration EN 252 specimens and thicker pine sapwood stakes (non standard format) were treated with a commercial CC salt in a vacuum pressure process. The stakes were installed in the test field of the Institute of Wood Research, Hamburg, in August 2010. In all cases three stakes were removed after 4, 8, 12...
T Liese, M Bahmani, E Melcher


The Chelator Mediated Fenton System in the Brown Rot Fungi: Details of the Mechanism, and Reasons Why it has Been Ineffective as a Biomimetic Treatment in some Biomass Applications – a Review
2014 - IRG/WP 14-10828
The chelator-mediated Fenton (CMF) reaction requires the action of two types of chelating compounds. The first chelator, oxalate, solubilizes and then sequesters iron, and the second chelator reduces iron. Iron reduction must be controlled near the fungal hyphae to prevent damaging Fenton chemistry from occurring in that location. Similarly, iron reduction must be promoted within the wood/plant ce...
B S Goodell, M Nakamura, J Jellison


Changes in mechanical and chemical properties of wood exposed outdoors
2014 - IRG/WP 14-20550
The aim of this study was to investigate differences in certain mechanical and chemical properties of three different wood species (common beach (Fagus sylvatica), Norway spruce (Picea abies), and copper-ethanolamine (CuE) impregnated Norway spruce (Picea abies)) that were exposed in use class 3 (CEN, 2006) for periods between 4 and 30 months. The results show, that changes in the investigated me...
N Thaler, C Brischke, D Žlindra, V Vek, M Humar


Scanning Transmission X-ray Microscopy as a tool for examining chemical changes in wood cell walls due to enzymatic activity
2014 - IRG/WP 14-20556
As development of techniques for examining enzymatic activity on solid, complex biological materials, is considered to be an important factor in further development of enzyme applications and for understanding the decay of plant materials, this study explores applicability of Scanning Transmission X-ray Microscope (STXM) for determining chemical changes in enzymatically treated samples at the cell...
D Jeremic, R Goacher, R Yan, C Karunakaran, E R Master


Resistance to Decay Fungi of Scots Pine Impregnated with Natural and Chemical Preservatives
2014 - IRG/WP 14-30650
In this study, heart-wood and sap-wood specimens of the Scots pine which is naturally grown in Turkey were treated with natural (valex) and some chemical preservatives such as CCA - C (Copper / Chrome / Arsenic), CBA - A (Copper / Boron / Azole). The wood protective efficacies of these preservatives were investigated by means of fungi decay test (EN 113). As a result of the study it was found t...
S Yildiz, U B Şimşek


VOC-free remedial treatment agent on organic solvent basis with surface cleaning by photocatalysis using titanium dioxide
2014 - IRG/WP 14-40651
Due to the EU Regulations according to the harmonisation of the European market of biocidal products and the EU Regulations regarding emissions of volatile organic compounds in residential properties a new VOC free yet organic solvent based remedial treatment agent is introduced including a potential method to clean up the wooden surface of remaining biocides after a remedial treatment using photo...
H Ahl, J Fromm, P Jüngel, E Melcher, M Pallaske


Experiences with an industrial system for controlled thermal wood modification in pressurized unsaturated steam
2014 - IRG/WP 14-40678
Thermal wood modification in pressurized reactors has a long history, but these processes are to date industrially scarcely used, because of the relatively complicated process equipment, compared to the more common high-temperature processes in kilns at atmospheric pressure. However, based on our practical experience with the FirmoLin® process, supported by recent scientific findings, it is foun...
W Willems


Durability of Fence Posts of Four Wood Species After 20 Years in Field Test
2015 - IRG/WP 15-30670
In the past years, wood consumption from native forests has drastically reduced the availability of wood. Fast-growing species such as Pinus and Eucalyptus suitably impregnated with chemicals may show a service life equal or higher than hardwood with high natural durability. The field tests have been an alternative widely used to evaluate the durability of wood and the efficiency of preservatives....
A Florian da Costa, A C Salgado de Freitas, E Meneses Oliveira


Optimising wood chemical modification with lactic acid oligomers by screening of processing conditions and chemical additives
2016 - IRG/WP 16-40741
Oligomer systems based on lactic acid (OLA), were impregnated in wood and polymerised in-situ by heat treatment to improve the properties of the treated wood especially regarding anti-swelling efficiency (ASE), hygroscopicity, water leaching resistance and durability. This article relates the optimisation of the heat treatment conditions and the consideration of selected chemicals for improvement ...
C Grosse, M-F Thévenon, M Noël, P Gérardin


Chemical, physical-mechanical characterization and durability of thermally modified beech and ash wood by thermo-vacuum process (Termovuoto)
2016 - IRG/WP 16-40758
The paper illustrates part of the results from the CIP Eco-innovation project “Thermo-vacuum: new process for new generation of thermally modified wood”. The project is part of the 7th Framework Programme for European Research and Technological Development, and thermo-vacuum modified wood is already on the European market. The project was selected by the European Commission, EASME Agency, as "...
M Jebrane, I Cuccui, O Allegretti, N Terziev


Development of a new method for wood hydrophobizing and fixation of copper compounds by chemical hardening of vegetable based modified oils
2016 - IRG/WP 16-40754
Wood products with ground and direct water contact, but without sufficient biological durability, have to be protected against biological degradation by fungi and other microorganisms. Due to European legislation (Biocidal Products Regulation 528/2012), the selection of possible chemical agents, which are still allowed to be used, is diminishing rapidly. The use of previously widely applied, very ...
C Swaboda, M Fischer, K Jacobs


Accelerated weathering and fungal resistance of wood modified with isopropenyl acetate
2016 - IRG/WP 16-40764
Chemical modification of Rubberwood (Heveabrasiliensis Müll.Arg) with isopropenyl acetate (IPA) in presence of anhydrous aluminum chloride and iodine as catalysts was carried out. Modified wood surfaces were exposed to UV light source in an accelerated weathering tester to evaluate UV resistance. Anti-swelling efficiency (ASE) and fungal resistance of modified wood were also evaluated. Modified w...
G B Nagarajappa, K K Pandey


Overview of the treated wood quality control program in the United States with the recent challenges and advances
2017 - IRG/WP 17-20616
In the past two decades, there have been significant and rapid changes in wood protection technologies for residential applications which have moved away from long established heavy duty metal oxide based products such as chromated copper arsenate (CCA). The successor generation of wood protection systems usually contain copper as the primary biocide, in combination with carbon-based co-biocides s...
L Jin


Dimensional Stability of Melamine Formaldehyde-Treated Southern Pine
2017 - IRG/WP 17-40774
The objective of this preliminary study was to evaluate the influence of different levels of melamine formaldehyde (MF) and curing cycle on the dimensional properties of southern pine. Thirty samples for each combination of treatment and curing regimen plus untreated controls and controls subjected to the same curing regimen were tested. Shrinkage/swelling coefficients showed that up to 60% ASE c...
H M Barnes, L S Sites, T S F A França, M G Sanders, F J N França


Accessibility of hydroxyl groups in anhydride modified wood as measured by deuterium exchange
2017 - IRG/WP 17-40784
Acetylated wood shows improved properties largely due to the reduced amount of water in the acetylated cell wall. However, the exact mechanism by which water is excluded in acetylated wood remains unclear. Acetylation reduces hydroxyl content by substitution of hydroxyl groups in wood polymers but may also hinder access to unmodified hydroxyls by physical bulking. This work assesses hydroxyl acces...
G Beck, S Strohbusch, E Larnøy, H Militz, C Hill


The use of new, aqueous chemical wood modifications to improve the durability of wood-plastic composites
2017 - IRG/WP 17-40787
The wood flour used in wood-plastic composites (WPCs) can biologically deteriorate and thus the overall mechanical performance of WPCs decrease when exposed to moisture and fungal decay. Protecting the wood flour by chemical modification can improve the durability of the wood in a nontoxic way so it is not harmful to the environment. WPCs were made with modified wood flour and then evaluated for m...
R E Ibach, C M Clemons, G C Chen


Influence of hygro-thermal treatment temperature and duration on dimensional stabilisation of wood modified with poly(butylene succinate)
2017 - IRG/WP 17-40813
To improve wood properties, especially dimensional stability, a treatment based on poly(butylene succinate) oligomers (OBS) was experimented. After impregnation in wood, a further hygro-thermal treatment (HTT) was carried out in a pressurized reactor at 100% relative humidity (RH) at differing temperatures for differing durations. The aim of HTT is to induce partial swelling of wood cell walls so ...
C Grosse, M Noël, L Rautkari, P Gérardin


A Green and Novel Technology for Recovering Copper and Wood from Treated Wood Waste – Part II: Optimization, copper metal recovery, and process design
2017 - IRG/WP 17-50326
The US consumes 70 million pounds of copper and produces 580 million cubic feet treated wood annually. The EPA disallows burning and reusing treated wood waste due to health/environmental concerns. Vast quantities of copper and wood are landfilled. Two safe and low cost extraction systems, citric acid and ammonium citrate, were identified in Part I of this study. In Part II of the study, effects o...
S Chen, R Patel


Corrosion verification experiment of the screw driven into CLT
2017 - IRG/WP 17-40816
Japan has abundant forest resources, but we depend on import for 70 percent of the consumed timber. Japan has the vision which promotes the timber self-sufficiency rate 30% to 50% by 2020. Therefore CLT attracts attention as a new timber material. Japan has a climate with high temperature and humidity, and wooden buildings are often treated with chemicals as a measure against biological deteriorat...
N Wada, H Ishiyama, S Yamamoto


Biocontrol of wood decay insects and nematodes as an alternative to traditional chemical treatments
2018 - IRG/WP 18-10914
The protection of wood has been defined until relatively recently, as the application of a chemical to increase its durability. On the other hand, society is becoming more and more demanding in terms of the use of products which have the minimum ecological impact. This has led many countries to reduce the list of biocidal products that can be used (European Biocides Regulation), therefore it is ne...
L Robertson, J F Galván, F Llinares, R Viñambres, M T de Troya


Understanding of the effect of ancestral and natural saltwater treatment on durability, fibers densification and chemical modification of palm wood
2018 - IRG/WP 18-10921
The palm-tree sector plays a very important role on both the socioeconomic and ecological levels, in Tunisia. There are three million trees in Tunisian palm plantations, ensuring a potential significant wood production, mainly in the craft and furniture industries. In the past, Date Palm wood (Phoenix dactylifera L.,) was also used as structural material. Its low natural durability and its low m...
M T Elaieb, A Namsi, M Tella, M-F Thévenon, K Chandelier


Natural resistance of Bambusa vulgaris to termite and powder-post beetle attack in laboratory and graveyard tests
2018 - IRG/WP 18-10925
Deterioration is the major setback to the utilisation of bamboo products. To enhance bamboo utilization, an understanding of the level of resistance to degradation is important. In this study, level at which Bambusa vulgaris will naturally resistant attack by subterranean termites and powder-post beetles were evaluated. B. vulgaris aged 2, 3 and 4 years were subjected to attack by subterranean ter...
N A Sadiku, S O Bada


FTIR-ATR monitoring of chemical changes of thermo-chemically modified beech wood degraded by brown-rot fungus
2018 - IRG/WP 18-40823
Wood chemical modification with lactic acid oligomers (OLA) has been reported to confer promising properties for wood outdoors applications. To better understand the lactic acid interaction with wood, chemical changes following biological degradation have been characterized with a battery of tests. Fourier transform infrared (FTIR) spectroscopy has been proved to be a valuable tool for studying fu...
C Grosse, M Noël, M-F Thevenon, P Gérardin


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