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Chemical analysis for TBTN in LOSP-treated wood and preservative fluids
1994 - IRG/WP 94-20027
Tributyltin napthenate (TBTN) is being substituted for tributyltin oxide (TBTO) in LOSP preservative formulations because its lower reactivity/better stability allows co-formulation with synthetic pyrethroids. Better stability may reduce molecular degradation both in-service and during analysis. It was considered necessary to check whether TBTO analysis methods were suitable for use on TBTN treate...
D P Wraight, M J Kennedy


Analysis of degradation observed on ancient wooden objects buried underground
2001 - IRG/WP 01-10403
Ancient wooden objects were sometimes excavated from the moat of mounded tombs in Japan. Such wooden objects were in the shape of a sunshade, bird, shield, pole, yugi(a bag that holds arrows) among others. Archaeologists discussed the usage of such shaped objects, but no one could clearly explain their use. Some objects were observed using an ordinary microscope. Deterioration by bacteria was foun...
H Sakai


In-ground evaluation of a copper azole wood preservative (Tanalithâ E) at a tropical Australian test site
1996 - IRG/WP 96-30100
A field trial to determine the in-ground termite and decay resistance of Pinus radiata D. Don impregnated with a copper azole formulation, TANALITHâ E, has been established at a tropical site in the Northern Territory of Australia. Four retentions of TANALITHâ E, containing 1.54, 2.08, 2.92 and 4.30 kg/m³ of Cu, are being evaluated. For comparison, Pinus radiata specimens treated to two retenti...
J W Creffield, J A Drysdale, N Chew


Leaching of CCA preservative from treated timber in marine environment
2001 - IRG/WP 01-30254
Knowledge on the amount of preservatives leaching out of treated wood is essential to optimise the chemical loading in various species of timber required for different end uses. In order to gain more insight into this aspect, the residual CCA content in 40 treated timber panels belonging to 14 species removed on destruction by marine organisms from a series of durability tests conducted in Kochi w...
M V Rao, V Kuppusamy, K S Rao, L N Santhakumaran


Changes to New Zealand Timber Treatment Specifications
2004 - IRG/WP 04-20288
Changes have been made to the New Zealand timber treatment specifications in response to frequent incidences of decay in framing timber and doubts about the long-term performance of tributyltin formulations when used in exposed situations. Changes have been made to Hazard Class H1 to allow a level of treatment to provide short to medium decay resistance to framing which would protect it, should l...
M E Hedley


Alternative technologies for wood wastes recycling - Part B: Biotreatment of PCP- and creosote-treated wood
1998 - IRG/WP 98-50101-18 b
Alternative technologies have been investigated to detoxify treated wood. Two classes of organic compounds are studied. Creosote-treated wood are classified in France as dangerous wood wastes. A conventional incineration could be provided for these wood wastes but the cost of this elimination could be very high (> 2000 FFR/ton). For these reasons, we have tested two kinds of new processes as al...
S Legay, P Marchal, G Labat


Wood preservative development: Have we learnt anything, and where will it take us?
1994 - IRG/WP 94-30054
This paper addresses the disparate approaches to the development and approval of wood preservatives used in a number of regions, and the implications of the test requirements, or lack thereof, on the likely performance of the subsequent treated wood in service. The test methodologies and performance criteria used in various regions will have long term consequences for the future of the wood preser...
A F Preston


Ultrastructure of degraded, CCA-treated Pinus radiata wood from a marine pile
1990 - IRG/WP 1461
During an inspection of marine piles, 12 years after installation, severe degradation was noted on one of them in the vicinity of a corroded eye-bolt. The wood was dark brown in colour and tended to crumble easily. Wood fragments were examined by light microscopy and scanning and transmission electron microscopy and were also analysed for carbohydrates and lignin. Light microscopy showed numerous ...
A P Singh, M E Hedley


Determination of total fluoride in preservative-treated wood by ion selective electrode, without steam distillation
1996 - IRG/WP 96-20086
An analytical method was developed to determine total fluoride in wood treated with aqueous fluoride or borate-fluoride formulations. Ground wood was mixed with 60% sodium hydroxide solution and oven-dried overnight before furnacing at 600°C. The cool fused product was dissolved in warm water before adding a powerful complexant/buffer solution containing sulphosalicylic acid and EDTA. Fluoride wa...
M J Kennedy


Photo-discoloration and Degradation of Wood and its Stabilisation by Modification with Benzoyl Chloride
2004 - IRG/WP 04-40274
Photo degradation of Pinus roxburghii (chir pine) and Hevea brasiliensis (rubber wood) was studied under artificial accelerated weathering conditions in a Xenon test chamber. The irradiated samples were analyzed for color changes and chemical changes. Analysis of colour changes in wood surfaces by UV-Vis. irradiation was carried out using a colour measuring (CIELAB) system and chemical changes ...
K K Pandey


Ammoniacal wood preservative for use in non-pressure treatment of spruce and aspen poplar. Part 1
1984 - IRG/WP 3273
End-matched lumber of Picea glauca (Moench)Voss (white spruce) and Populus tremuloides Michx. (aspen poplar) timbers was treated by a thermal diffusion process in open tank treating vessels using an ammoniacal copper-arsenate wood preservative. The process proved technically feasible with respect to controlling the vapourization of ammonia from open tanks during treatment at high temperatures. Tre...
C D Ralph, J K Shields


Kinetic of the wood degradation produced by wood decay fung
1993 - IRG/WP 93-20016
The degradation degree of a wooden structure has a direct influence on its loss of mechanical strength. It's necessary to deepen in non destructive techniques which permit to extrapolate the results obtained in laboratory to structural timber used in the building's construction. This work studies the relationship existing between the pulse velocity of ultrasonic waves and the wei...
M T De Troya, A M Navarrete, A Sanchez, V Bucur


Fixation of chromated copper arsenate (CCA) wood preservative in Australian hardwoods: A comparison of three Eucalyptus species
1996 - IRG/WP 96-30107
New environmental guidelines for the management of CCA treatment plants were released in Australia in 1995. This has stimulated interest in techniques for controlling or accelerating the fixation of CCA in freshly treated timber products. The ability to understand, then effectively control and/or accelerate fixation of CCA in treated timber products can be an economic, technical and environmental ...
J Holmes


Degradation of the gelatinous-layer in aspen and rubber wood by the blue stain fungus Lasiodiplodia theobromae
1996 - IRG/WP 96-10168
Studies on the degradative ability of the blue stain fungus Lasiodiplodia theobromae Pat. have shown several strains to cause significant weight losses (i.e. ca 20%) in the temperate and tropical wood species, aspen (Populus tremula) and rubber wood (Hevea brasiliensis). In addition to the consumption of soluble carbohydrates and extractives, major changes in the ultrastructure of fibre cell walls...
O Encinas, G F Daniel


Study of the degradation of retified wood through ultrasonic and gravimetric techniques
1994 - IRG/WP 94-40030
One of the non-polluting processes that increase the natural durability of wood is a thermal treatment in an atmosphere poor in oxygen, producing what is normally denominated "retified wood". In this study the validity of a non-destructive technique (ultrasound) in order to determine the biodegradation suffered by wood across time has been studied. For this reason, the behavior of a wood species (...
D T De Troya, A M Navarrete


Albumin borate: A new non-toxic, wide-spectrum, long-term wood preservative
1998 - IRG/WP 98-30167
Boron, widely recognized for its broad range of activity towards both fungi and insects and for its low mammalian toxicity, can not provide long term protection to treated timber due to its high leachability. Boron, in the form of boric acid, can be partially fixed to timber by the formation of an association with egg albumin, which is insolubilized by heat-induced coagulation. Chemical investiga...
M-F Thévenon, A Pizzi, J-P Haluk


Soil-bed studies. Part 2: The efficacy of wood preservative
1983 - IRG/WP 2205
Various methods of decay assessment were investigated. Three stages or phases of decay were identified which could be used to describe the efficacy of a preservative system or virulence of a soil-bed testing medium. These included the lag, decay, and senescent phase. Premature senescence could arise if wood samples became waterlogged. It was concluded that time to failure was unsuitable as a metho...
P Vinden, J F Levy, D J Dickinson


Microwave conditioning of Pinus radiata D. Don for preservative treatment
2000 - IRG/WP 00-40182
This paper reviews the effect of pressure steam conditioning on the permeability and treatability of green radiata pine heartwood and the potential for substituting microwave conditioning for steaming. The penetration of liquids into radiata pine occurs mainly in the radial tissue. The permeability of green radiata pine improves following steam conditioning by blowing out the soft radial tissue. T...
P Vinden, G Torgovnikov, J Romero


Evaluation of chlorpyrifos as an insecticidal component of a wood preservative
1984 - IRG/WP 3301
After two years of laboratory and field testing, chlorpyrifos is showing excellent potential as an insecticidal treatment to wood. In laboratory termite tests, retentions as low as 1-2 parts-per-million or approximately 0.0008 kg/m³ (0.00005 lbs/ft³) are effective against the Coptotermes formosanus. Laboratory leaching tests have shown no significant effect on the concentration of the retained c...
K Rose, J Kozuma, P Sparrow


Assessment of dehydrogenase activity, fluoride content and total chromium content of soil profiles exposed to preservative treated wood within a model system
1993 - IRG/WP 93-10015
The development and prospective use of a closed model system to facilitate study of a number of indicators of environmental impact of wood preservatives laboratory conditions has been described (IRG/WP/2395-92). Chemical analysis of leachate samples collected from drained soil profiles containing creosoted pole sections remedially treated with a chromated fluoride preservative indicated small incr...
G M Smith, D C R Sinclair, A Bruce, H J Staines


The treatment of sawn whitewood with organic solvent wood preservative
1982 - IRG/WP 3192
The impregnation schedules approved in the UK for the treatment of sawn European whitewood (Picea abies) with organic solvent borne preservatives result in comparitively high loadings relative to the limited depth of penetration they achieve. Results are presented, which show how substantial reduction in the overall loading may be achieved without concomitant reduction in penetration. A model for ...
L D A Saunders


Evaluation of substituted isothiazolone as a potential new wood preservative
1984 - IRG/WP 3306
Laboratory decay tests were carried out with isothiazolone (4,5-dichloro-2-n-octyl-4-isothiazolone-3-one) treated wood. This compound was found to be extremely effective against three common wood decaying brown-rot fungi, exhibiting toxic threshold values in the range of 0.37 to 0.50 kg/m³. For the white-rot fungus, Coriolus versicolor, the toxic threshold values for treated pine and sweetgum wer...
D D Nicholas, A F Preston, D E Greenley, S V Parikh


Changed permeability and surface properties of hornbeam wood due to its degradation by erosive strain of Phanerochaete chrysosporium
2004 - IRG/WP 04-40290
Specimens of hornbeam wood were submitted to a medium-term degradations by erosive fungus Phanerochaete chrysosporium. Biodegradations of specimens resulted in their apparent structural alterations, changes in permeability and increased intensity of interactions with polar liquids. Modified physical properties of biodegraded wood may significantly influence its penetration with polar media and che...
R Solár, S Kurjatko, L Reinprecht, M Mamon, V Vacek


Effect of soil parameters on biocide depletion: laboratory and field studies of water- and emulsion-borne preservatives
2000 - IRG/WP 00-30234
Two field test sites with different soils were selected. Soil analysis showed that the soil at the two sites had considerable texture, base saturation, acidity, and cation exchange capacity differences. Five sets of field stakes were treated as follows: three with water-borne CCA to about 0.4 pcf (6.4 kgm-3) retention, one with 0.75% DDAC, and one with 0.75% DDAC:0.25% chlorothalonil. The last two...
T Schultz, D D Nicholas, D E Pettry, M G Kim


An evaluation of the potential of ion mobility spectrometry for detection of organic wood preservative components in solutions and treated wood
1994 - IRG/WP 94-20038
For the disposal of wood waste under ecological sound conditions information about its hazardous potential is required. Until now, no highly sensitive rapid analytical methods are available for the detection of wood preservatives under industrial process conditions. Preliminary experiments showed that Ion Mobility Spectrometry (IMS) could be a promising method for rapid detection of organic preser...
A Voss, J N R Ruddick, W J Homan, H Militz, H Willeitner


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