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Performance of dip and pressure treated wood in termite ground proximity exposures in Hilo, HI, and Colombia
2008 - IRG/WP 08-30491
A number of preservative systems were evaluated for their ability to control termite attack when applied as both dip and pressure treatments. With dip treatments, better performance was observed with southern pine than spruce-pine-fir using the same solution strength treatment, probably as a result of the about 50% greater uptake with southern pine and associated deeper preservative penetration. B...
P Walcheski, A Zahora


Alkaline copper treated wood for use in residential decking
2008 - IRG/WP 08-30490
Alkaline copper quaternary ammonium compound (ACQ) treated decking was exposed in a field experiment and the mobile copper assessed based on that collected in the leachate. The amount of copper which leached was modeled after 4 years. The results showed that boards which leached most chemical initially provided the greatest loss over four years. The reduction in the mobility of copper with time wa...
J N R Ruddick


High Temperature Treated Wood
2008 - IRG/WP 08-40429
High temperature can modify internal structure and physic-chemical properties of wood by a controlled pyrolysis process. Such treatment, among other changes in properties, modifies the wood color in a way that resembles exotic species, increasing its market value. The main objective of this work is to determine the changes in wood properties caused by the effect of temperature and time, in order t...
C C Borges, A L Barbosa, R Faber de Campos, S T Targas


Corrosion of fastener and connector in contact with alkaline copper treated wood – it is a problem
2008 - IRG/WP 08-40437
For many decades, chromated copper arsenate (CCA) was the most common wood preservative used in North America for residential and industrial applications. Since December 31, 2003, the use of CCA for residential application was voluntarily terminated. One of the most widely accepted alternative wood preservatives in Western Canada is Alkaline Copper Quaternary Compound (ACQ). This paper will compar...
J N R Ruddick


Comparison of laboratory and natural exposure leaching of copper from wood treated with three wood preservatives
2008 - IRG/WP 08-50258
Standard and non-standard laboratory and field leaching tests were used to compare copper leaching from wood treated to above ground and ground contact specified retentions for three wood preservative systems, CCA-C, ACQ-D and a micronized copper formulation with quat DDAC as co-biocide. Copper leaching was highest for the ACQ formulation. Percent leaching was lowest for the micronized copper sy...
P A Cooper, Y T Ung


Evaluation of Water Repellency of Treated Wood Using Several Alternative Methods
2009 - IRG/WP 09-20419
In this study, the results of water repellency testing using a digital swellometer method for water-borne organic-preservative systems with water repellent additives are reported. The findings suggest that the traditional method of using matched untreated controls as a reference developed from historic solvent-based treatments for determination anti-swelling efficacy (ASE) may underestimate the a...
L Jin, A F Preston


Leaching performance, decay and termite resistance of wood treated with boron compounds incorporated with phenol-formaldehyde resin
2009 - IRG/WP 09-30503
A resol-type phenol-formaldehyde (PF) resin was synthesized and designed to penetrate wood incorporated with boron compounds in order to immobilize boron in wood. The leaching performance, decay and termite resistance of treated wood was investigated. Three kinds of boron compounds, that is, boric acid (BA), borax (BX) and disodium octaborate tetrahydrate (DOT), were selected to mix with PF and tw...
Liping Yu, Jinzhen Cao


Resistance to decay fungi of ammonium borate oleate treated wood
2009 - IRG/WP 09-30505
Ammonium borate oleate molecule (ABO) produced from reaction between boric acid, ammonia and oleic acid was tested as wood preservative treatment against brown and white rot fungi according to European standards. This compound was prepared according to a previous study which has proved existence of synthesis reaction and effectiveness against termites (Lyon et al. 2007b). Four solutions of ABO in ...
F Lyon, M-F Thevenon, A Pizzi, J Gril


Re-Distribution of Copper in the Cell Walls of Wood Treated with Micronized Copper Quat
2009 - IRG/WP 09-30506
Wood treated with copper-based preservatives to be used in ground contact may fail to inhibit soft rot fungi if penetration of copper into the cell wall is insufficient. Preservatives containing soluble copper are known to penetrate the cell wall; however, it is not known whether preservatives containing particulate copper will also migrate into the cell wall in sufficient quantities to control so...
R Stirling, J Drummond


Thermal behavior of zinc borate-treated wood
2009 - IRG/WP 09-30511
The objective of this study was to investigate the thermal behavior of zinc borate (ZnB)-treated solid wood by thermal analysis (TA). Thermogravimetry (TG) and differential thermogravimetry (DTG) curves obtained from TA showed that ZnB-treated wood specimens had higher char yields and lower maximum thermal decomposition temperature than untreated wood specimens. Reducing thermal decomposition temp...
E Terzi, H Sutcu, S N Kartal


Mold-resistance Effect of Bamboo Wood Treated with CCC-organic Complexes
2009 - IRG/WP 09-30514
Mold resistant effect of CCA, ACQ, CuAz, CCC and the compound of CCC and propiconazole were researched on bamboo wood of Phyllostachys pubescens were reported in this paper. Results showed that all of the test fungicides could protect bamboo wood better from Penicillam citrinum than from Trichoderma viride and Aspergillus niger. The complex of CCC and propiconazole had the best resisting effect on...
Sun Fangli, Yang Le, Chen Anliang, Bao Binfu, Li Qiao


Micronized Copper Preservative Systems: Observations on the Release of Cupric ion (Cu2+) from Treated Wood and Performance against Wood Decay Fungi
2009 - IRG/WP 09-30519
In an attempt to address the mechanism of action of micronized copper preservatives, a 20-week continuous water leaching study was conducted. The leaching results indicated that, once impregnated in wood, micronized copper preservatives continuously release cupric ion, and the levels of cupric ion released from micronized copper treated wood are higher than those released from CCA treated wood, a...
J Zhang, R Ziobro


Rapid Microwave-Assisted Acid Extraction of Metals from Chromated Copper Arsenate (CCA)-Treated Southern Pine Wood
2009 - IRG/WP 09-50262
The effects of acid concentration, reaction time, and temperature in a microwave reactor on recovery of CCA-treated wood were evaluated. Extraction of copper, chromium, and arsenic metals from chromated copper arsenate (CCA)-treated southern pine wood samples with three different acids (i.e., acetic acid, oxalic acid, and phosphoric acid) was investigated using in microwave reactor. Oxalic acid wa...
Bin Yu, Chung Y Hse, T F Shupe


Factors affecting sodium hypochlorite extraction of CCA preservative components from out of service treated wood for recycling
2009 - IRG/WP 09-50263
Significant amounts of chromated copper arsenate (CCA) treated wood products such as utility poles and residential constructions remain in service. There is an increasing public concern about environmental contamination from CCA treated wood when it is removed from service for reuse or recycling, placed in landfills or burned in commercial incinerators. In this paper, we investigate the effects of...
E D Gezer, P A Cooper


Wettability and bonding strength of wood thermally-treated with different combinations of soy oil and chemical additives
2009 - IRG/WP 09-40454
Thermal treatment is a method which has gained wider acceptability as an alternative to the chemical treatment in wood preservation. In order to maximize the benefits of this technique several options have been adopted including the use of soy oil in transferring the heat to the wood. Available information on thermal treatment in general and the oil method in particular show that there are still n...
L Awoyemi, P A Cooper, T Ung


Barefoot-heat-impact of oil-heat-treated wood: An important thermal property of decking boards
2009 - IRG/WP 09-40458
In this study the phenomenon of sensual heat impression was examined, when walking with bare feet on sun exposed wood based decking boards. A suitable method for measuring the heat flux from decking boards into an artificial foot was developed. The method and measuring device is described as well as results from measuring three different decking board materials: Oil-heat-treated spruce (OHT), untr...
A O Rapp, C R Welzbacher, C Brischke


Biological Performance of Boron-based Chemicals Treated Wood Composites
2009 - IRG/WP 09-40464
In this study, the biological performance of wood-based composites panels treated with boron containing chemicals against to a fungus was determined. Boric acid, borax, zinc borate and agricultural borate (Tarım-bor™), developed and patented by National Boron Research Institute, were mixed with wood chips or fibers and then particleboard, medium strand board and middle density fiberboar...
Ü C Yıldız, H Kalaycıoğlu, S Yıldız, A Temiz, E Tomak Dizman, A Çavdar Dönmez


Performance of Fasteners in Treated Wood: A Comparative Study
2009 - IRG/WP 09-40465
Fastener performance is an important property for treated wood. Published data on screw and nail performance for different preservative systems currently on the market are, however, limited. In this study, screw and nail withdrawal strength for southern pine wood treated with ACQ (above ground and ground contact), MCQ (above ground and ground contact), borate (disodium octaborate tetrahydrate – ...
Q Wu, T Shupe, J Curole, K Ragon, M Voitier, M Freeman, D Ring


Seasonal shifts of fungal community structure at the interface of treated or untreated wood and soil
2010 - IRG/WP 10-10721
Many wood species are degraded rapidly in soil by the fungal community. In order to preserve wood and structures in which it is used, chemical preservatives are used. Little is known about the interaction of treated wood and the surrounding soil fungal community. For this work, presented at IRG 41, wooden specimens (Pinus sylvestris sapwood, sizes 25 mm x 50 mm x 500 mm (longitudinal)) were treate...
M Noll, I Stephan


Toward an assessment of copper bioavailability in treated wood
2010 - IRG/WP 10-20445
Many modern wood preservative systems rely on copper (Cu). Some oxalate-producing fungi detoxify Cu by immobilizing it in crystals, and this may decrease its physiological availability (bioavailability). Cu bioavailability may also decrease during wood treatment. Cu retention in wood, however, is typically measured as a weight-to-volume concentration without an estimate of its bioavailability and ...
J S Schilling, J J Inda


Mould growth on wood-based materials – a comparative study
2010 - IRG/WP 10-20455
Ten different wood-based materials - preservative-treated wood, fire retardant-treated wood, modified wood, WPCs and untreated references of pine sapwood and spruce - were tested for mould growth according to SP method 2899 during 42 days at 90% RH and 22°C. Even though the results must be interpreted carefully, they indicate significant differences in mould resistance between the materials tes...
P Johansson, J Jermer


The use of thermal desorption and pyrolysis combined with a semiconductor VOC detector for the on-site detection of preservative-treated wood
2010 - IRG/WP 10-20456
The purpose of this study was twofold; to identify possible marker molecules released from preservative-treated wood upon heat treatment and then develop a prototype detector for this marker. Two methods for heating the samples were used: Pyrolysis combined with Gas-Chromatography with IR-detection and Thermal Desorption combined with Gas-Chromatography with mass detection. A first prototype detec...
I Svensson, A Gonzalez, L Irusta, Mª J Fernandez-Berridi, O Munné


Biological performance of wood treated with tar-oil recovered during slow pyrolysis of macadamia nut shells
2010 - IRG/WP 10-30523
This study evaluated decay and termite resistance of wood treated with tar oil obtained from a commercial pyrolysis process of macadamia nut shells. Vacuum-treated pine wood specimens were subjected to various brown and white rot fungi based on the soil-block test method specified by the American Wood Protection Association (AWPA) after leaching process. Treated specimens were also subjected to th...
S Nami Kartal, E Terzi, C Kose, J Hofmeyr, Y Imamura


A comparison of the chemistry of alkaline copper and micronized copper treated wood
2010 - IRG/WP 10-30528
This paper discusses the chemistry of the reaction of alkaline copper and micronized copper with wood. The objective of this study is to examine the copper species produced in wood during the fixation reaction using electron paramagnetic resonance (EPR) spectroscopy. The initial experiments (phases 1 to 2) were designed to confirm the effect of time of treatment and solution concentration on the s...
Wei Xue, P Kennepohl, J N R Ruddick


Mobility of Copper from MCQ in Shell-Treated Wood Exposed Above Ground
2010 - IRG/WP 10-30534
Most Canadian treated decking in service has been given just a thin shell of preservative treatment but it has still performed very well. This is because copper migrated into checks and prevented germination of basidiospores on the freshly exposed untreated wood. Unlike soluble copper systems, MCQ has its copper primarily in the form of small basic copper carbonate particles. For MCQ to be effecti...
R Stirling, P I Morris


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