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Thermal decomposition behavior of CCA-treated wood for safe disposal and the safe recovery of heavy metals through pyrolysis
2006 - IRG/WP 06-50238
If we could estimate the chemical changes in heavy metals by temperature in chromated copper arsenate (CCA)-treated wood during pyrolysis, it is expected that we could solve the environmental problems of heavy metals, which may occur during pyrolysis, and therefore, the thermal decomposition behavior of effective elements of CCA-treated wood was examined to find a safe disposal method. First, CCA-...
Dong Won Son, Dong-heub Lee, Sun-hae Cheon, Myung Jae Lee


A Prediction of Arsenic Groundwater Concentrations Influenced by Construction and Demolition Debris Landfills in Florida Containing CCA-Treated Wood
2006 - IRG/WP 06-50242
Groundwater fate and transport models can provide an indication of the potential impacts of arsenic from the infiltration of leachate from unlined C&D debris landfills containing CCA-treated wood. A solute transport model, Migration of Organic/Inorganic Chemicals (MYGRT), was chosen to predict groundwater contaminant concentrations at specified locations from a hypothetical source (C&D lan...
J Jambeck, T Townsend, H Solo-Gabriele


Wood decay fungi from New Zealand ‘leaky’ buildings: PCR identification and laboratory decay tests of wood preservative-treated Pinus radiata (Part 1)
2007 - IRG/WP 07-10620
Fungi colonising Pinus radiata D. Don framing timber of ‘leaky’ New Zealand buildings were isolated to produce pure cultures. Mycelia from these cultures on agar media were collected to extract DNA. To identify the fungi to the species level, polymerase chain reaction (PCR) with primer pairs ITS1-F and ITS4 were performed followed by sequencing of the internal transcribed spacer (ITS) region. ...
D Stahlhut, R L Farrell, R Wakeling, M Hedley


Detecting fungal DNA in treated and non-treated wood
2007 - IRG/WP 07-10621
Isolating fungi from wood has long involved culturing on selective media followed by identification using various keys. This process can be cumbersome, costly, and, most importantly, not always capable of detecting all of the fungi present. The recent development of molecular methods for isolation and identification of fungi has created tremendous opportunities for expanding our knowledge of the...
C Freitag, M Freitag, J Morrell


Assaying Pentachlorophenol-treated Wood Using XRF
2007 - IRG/WP 07-20362
A study was conducted to evaluate the effect of oil type on the performance of test posts treated with oil-penta and exposed in DeQueen, AR for forty years in ground contact. The original assays for the poles were done by lime ignition, a practice used sparingly today in treating plants or by independent inspectors, in part due to the complicated analysis procedure and chances for error. XRF ins...
H M Barnes, C R McIntyre, D W Bullock , M H Freeman, G B Lindsey


Quantitative Determination of Cyproconazole in Wood treated with Tanalith CY
2007 - IRG/WP 07-20369
The HPLC method has been widely applied to quantitative determination of cyproconazole in preservative solutions. However, HPLC assay has not been successfully employed to determine cyproconazole content in treated wood. Some extractives from treated wood hinder cyproconazole determination because they have a similar retention time to that of cyproconazole on an HPLC chromatogram. In addition, ...
I Momohara, T Miyauchi, M Mori


Corrosion of metal fasteners in contact with copper preservative treated wood
2007 - IRG/WP 07-20370
The corrosion rates of metal fasteners in contact with alkaline copper quat (ACQ) treated wood with or without commercially available water repellent was compared to that of cedar. In this experiment, fasteners were sandwiched between two pieces of treated wood and exposed to a humid environment at a slightly elevated temperature. The use of a “sandwich” design allowed periodic examination of ...
BaekYong Choi, J N R Ruddick


Use of Moisture Meters with Treated Wood
2007 - IRG/WP 07-40382
Drying wood treated with waterborne preservatives after treatment to near outdoor EMC conditions improves its physical performance characteristics. This is primarily due to the reduced checking, splitting and warping which can occur when wet wood, particularly if restrained from shrinking by being nailed or otherwise fastened, shrinks in use. Monitoring of the drying process, rate, and end point...
W B Smith, Hwan Myeong Yeo, C Stark, B Morey, C Tascioglu, P Schneider, D Herdman, M Freeman


Influence of ethanolamine on lignin depolymerization and copper leaching from treated Norway spruce and beech wood
2007 - IRG/WP 07-30423
Copper-ethanolamine based wood preservatives are replacing several classical copper-chromium based solutions, due to foreseen ban of chromium. Fixation of copper-ethanolamine based wood preservatives is not as good as fixation of copper-chromium ones. The main object of this manuscript was to prove, that ethanolamine is the prime reason for insufficient fixation of copper-ethanolamine formulations...
M Humar, B Bucar, M Zupancic, D Žlindra, F Pohleven


Tropical In-Ground Durability of CCB-treated Keruing and other Structural Sarawak Timbers after 8 – 10 Years Exposure
2007 - IRG/WP 07-30439
The heartwood of 12 mainly low-durability native timber species of Sarawak [4 Dipterocarpus (Keruing) species, Anisoptera grossivenia (Mersawa kunyit), Canarium apertum (Seladah), Dacryodes incurvata (Seladah laut), Dryobalanops oblongifolia (Kapur kelansau), Mesua macrantha (Mergasing), Podocarpus micropedunculatus (Kayu cina), Shorea compressa (Engkabang langgai), and Pterospermum javanicum (Ba...
A H H Wong, Ling Wang Choon


Natural Weathering of Coated Oil Heat Treated Wood
2007 - IRG/WP 07-30440
Oil heat-treated (thermally modified) pine wood was coated with 9 different types of solvent- or water-borne exterior finishes. The systems with modified wood substrate as well as unpainted and painted non-modified controls were exposed to weathering (EN 927-3) on two locations with sub-alpine and alpine climate. The influence of natural ageing on surface systems was evaluated after one year of ex...
M Petric, B Kricej, M Pavlic, A Rapp


Mold resistance of heat-treated wood
2007 - IRG/WP 07-40358
The resistance of heat-treated sugi sapwood against three mold fungi was evaluated. Wood specimens were first subjected to heat treatments at 180 and 220ºC for 2 and 4 hours. Mold growth on the surface of the specimens was measured 1, 2, 4 and 6 weeks after the inoculation with the fungi in laboratory conditions. Laboratory decay tests were performed using two brown and white-rot fungi along with...
S N Kartal


Micro-Distribution of Metals in Wood Treated with a Nano-Copper Wood Preservative
2007 - IRG/WP 07-40360
The microdistribution of copper in southern pine treated with a newly-developed nano-copper wood preservative was examined to determine if it differed from that reported for wood treated with conventional copper-based wood preservatives. Field Emission Scanning Electron Microscopy (FE-SEM) in combination with x-ray microanalysis (EDX) revealed the presence of nano-sized copper and iron particles i...
H Matsunaga, M Kiguchi, P Evans


Fire, flame resistance and thermal properties of oil thermally-treated wood
2007 - IRG/WP 07-40361
Oil thermal treatment, first developed by German scientists, is a promising technology for improving the durability and dimensional stability of wood for outdoor above-ground residential uses such as siding and shingles. The present authors’ previous research showed that 220ºC is an optimal treatment temperature, with 2 hours’ treatment producing wood with significantly improved moisture and ...
Jieying Wang, P Cooper


Effects of sodium hypochlorite on compression strength and copper retention of spruce wood treated with copper azole and alkaline copper quat
2007 - IRG/WP 07-40362
This work investigates the effects of sodium hypochlorite on compression strength values and copper retention ratios of refractory spruce wood (Picea oriental L.) treated with the waterborne preservative Copper Azole, (CBA-A, Tanalith-E 3492) and alkaline copper quat (ACQ-2200). Before the copper azole and alkaline copper quat treatment, the samples were immersed in 500 ml of sodium hypochlorite s...
S Yildiz, E Dizman, A Temiz, Ü C Yildiz


The effect of additives on copper losses from alkaline copper treated wood
2007 - IRG/WP 07-50246
The replacement of chromated copper arsenate (CCA) by alkaline copper compounds has heightened awareness of the potential impact of copper losses on aquatic organisms. While there remains a healthy debate concerning the actual risk of copper leaching from wood preservatives into aquatic ecosystems, it is clear that reducing these losses will be necessary to avoid continued regulatory actions aga...
J Mitsuhashi, J J Morrell, L Jin, A F Preston


Evaluating the Process of ACQ-Treated Woods with TGAand CEM Analysis
2007 - IRG/WP 07-20374
To provide an understanding of the fundamental thermal behaviour and the disposal-end products of ACQ-treated woods, this study is comprised of two categories of examination. The first is related to the use of TGA under different thermal decomposition conditions (nitrogen or air, and 5 or 40 oC/min), and the use of EDX to examine certain residual elements of the char. The second applies the CEM ...
Han Chien Lin, Tsang-Chyi Shiah, Jung Ting Tsai


Durability of some alternatives to preservative-treated wood. Progress report 2: Results from field tests after 5 years’exposure
2007 - IRG/WP 07-30442
A number of alternatives to preservative-treated wood have been tested according to EN 252 (stake test) and a specially designed ground-proximity field test, the latter in Sweden as well as in Hawaii, USA. Seven untreated wood species and four alternative wood treatments labelled as environmentally friendly (acetylation, linseed oil, heat treatment, vinyl polymer) were included in the study. Four ...
M-L Edlund, J Jermer


Primary Study on Compressed Preservative-treated Wood (CPW) for Outdoor Applications
2008 - IRG/WP 08-40412
In this study, the compressed wood samples pre-treated with hot water bath or water spraying were immersed in the ammoniacal copper quat –type D (ACQ-D) preservative solution to get compressed preservative-treated wood (CPW). The liquid absorption and the recovery rate of compression deformation of the compressed wood was determined, as well as the surface hardness, the distribution of density a...
Jinzhen Cao, Jia Mao


Termite resistance of DMDHEU-treated wood
2008 - IRG/WP 08-40401
Chemical wood modification with dimethyloldihydroxy-ethyleneurea (DMDHEU) or its derivatives are applicable to both solid lumber and wood-based composites. Advantages of DMDHEU-based modification are an increase of dimensional stability and high durability against white, brown and soft rot fungi. At higher chemical loadings, the hardness of the wood is considerably increased. Due to the durabil...
H Militz, S Schaffert, B C Peters, C J Fitzgerald


Effects of acetic acid and nitric acid pre-treatment on copper content of spruce wood treated with CBA-A and CCA
2008 - IRG/WP 08-40406
This work investigates the effects of nitric acid and acetic acid on compression strength values and copper retention contents of refractory spruce wood (Picea oriental L.) treated with the waterborne preservative Copper azole, (CBA-A, Tanalith-E 3492) and copper / chrom / arsenic (CCA). Before the CBA-A and CCA treatment, the samples were immersed in 500 ml of nitric and acetic acid solutions for...
S Yildiz, E Dizman, Ü C Yildiz


Effect of steam on fixation of Cu-amine preservative treated wood
2008 - IRG/WP 08-50251
The rates of copper fixation in copper amine preservative treated wood were investigated with different fixation conditions (20° with drying and 50° without drying) and post-steaming. We also measured the degree of leaching for other biocide components (azoles, quatz, and Cu-HDO). Treatments conditioned at 20° with drying required 50 days or more to fix in woods. While copper was stabilized i...
Sung-Mo Kang, In-Yong Hwang, Suk-Kuwon Kim


Thermochemical Remediation of Preservative-Treated Wood
2008 - IRG/WP 08-50254
Remediation methods continue to be developed and refined for CCA-treated wood in order to divert this material from landfills and create secondary products from the wood fiber. A two-step thermochemical remediation method was developed to assess the efficiency of metal removal from CCA-treated spruce flakes. Nearly all the metals (As, Cr, and Cu) were thermochemically extracted from chromated copp...
R Sabo, C A Clausen, J E Winandy


Leachability of Arsenic, Chromium and Copper from Weathered Treated Wood
2008 - IRG/WP 08-50255
The objective of this study was to quantify the loss of arsenic, chromium and copper from weathered treated wood under normal field conditions as most residential structures currently in service in the U.S. have been constructed at least 3 years ago. For comparison, leaching from different retention levels of weathered CCA treated wood (low, medium and high) is compared to leaching from new ACQ tr...
A R Hasan, Ligang Hu, H M Solo-Gabriele, Yong Cai, L A Fieber


Laboratory Studies on Copper Availability in Wood Treated with Soluble Amine Copper and Micronized Copper Systems
2008 - IRG/WP 08-30489
A laboratory method has been employed to investigate the level of soluble copper in wood treated with various copper-based preservative systems, such as micronized copper (particulate copper) and amine copper solutions. This report describes the methodology and preliminary results on determination of the soluble copper in the treating solutions and the treated wood by these systems, as well as th...
L Jin, P Walcheski, A Preston


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