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A bioassay of remedially treated pole material
1987 - IRG/WP 3453
Stubs prepared from treated and untreated utility poles were installed in a test plot and pressure spade treated at the groundline with one of four preservative greases. At one and three year intervals, core samples were removed from the stubs and the improvement in the preservative efficacy due to the greases was assessed. The bioassay investigation showed that only bis(tributyltin) oxide (TBTO) ...
J N R Ruddick, L Parker


Removing Cu, Cr and As from CCA treated yellow pine by oleic acid
2003 - IRG/WP 03-50202
In this study, CCA treated yellow pine utility poles were cut into three different dimensions and 4 different pH levels (2, 2.5, 3.5 and 5) of Oleic acid was used. The leached wood samples were collected at the end of the 1, 3, 7 and 14 days to determine the remaining Cu, Cr and As concentrations. The concentrations of Cu, Cr and As were determined by X-RF. The effects of pH, dimension and duratio...
E D Gezer, Ü C Yildiz, S Yildiz, E Dizman, A Temiz


Uptake by grape plants of preservatives from pressure-treated posts not detected
1975 - IRG/WP 350
Leaf and stem tissue and fruit of grape plants (Vitis rotundifolia Michx. cv. Magnolia) were analyzed for copper, chromium, and arsenic, 1, 2, and 3 years after planting 3 inches from copper-chrome-arsenate or fluor-chrome-arsenate-dinitrophenol-treated southern pine posts. Quantities of copper in leaf and stem tissue and fruit of plants next to posts treated with copper-containing preservatives r...
M P Levi, D Huisingh, W B Nesbitt


Microbial ecology of treated Lap-joints exposed at Hilo, Hawaii for 24 months
1997 - IRG/WP 97-20107
This paper is a continuation of previous work reported in IRG/WP 96-20089 by Molnar et al. (1996) in which Lap-joints, made from Southern yellow pine and treated with ACQ, DDAC or propiconazole were sampled over 12 months exposure at Hilo, Hawaii. 18 and 24 month samplings have since taken place and are reported here. TnBTO treated Lap-joints made of scots pine which were exposed later as a standa...
S Molnar, D J Dickinson, R J Murphy


Speciation of leachates from CCA-treated wood
2005 - IRG/WP 05-50224-27
Different species of arsenic and chromium are characterized by different toxicities and different mobilities. The environmental impacts of CCA-treated wood would therefore be a function of the chemical forms of the metal releases. As a consequence a series of tasks were undertaken to evaluate arsenic and chromium species from CCA-treated wood. The intent of these tasks was to quantify the total...
H M Solo-Gabriele, T G Townsend, Yong Cai, B I Khan, Jin-Kun Song, J Jambeck, B Dubey, Yong-Chul Jang


Leaching of components from CCF treated timber in ground contact
1998 - IRG/WP 98-50108
In order to investigate the depletion of different CCF-salts during service small stakes (10*10*450mm³) were treated with five water-borne wood preservatives and after fixation brought into ground contact for several years. After failing some of the broken down stakes were used to determine the remaining concentration of relevant ions and their distribution in different segments of the stakes. A...
E Melcher


CCA removal from treated wood by chemical, mechanical and microbial processing
1998 - IRG/WP 98-50101-26
Most preservative-treated wood produced and consumed in the U.S. is treated with toxic inorganic compounds containing copper, chromium, and arsenic. Because chromated copper arsenate (CCA) is fixed to the wood, treated wood has not been considered toxic or hazardous and is currently landfilled. Increasing public concern about environmental contamination from treated wood combined with increasing q...
C A Clausen, R L Smith


Determination of thermal degradation of isothiazolone treated wood
1997 - IRG/WP 97-30154
Wood treated with 4,5-dichloro-2-n-octyl-4-isothiazolin-3-one was the subject of thermal degradation study. The study included burning isothiazolone treated wood under various temperatures with and without oxygen. The result showed that no harmful combustion products, such as polychlorinated dibenzo-p-dioxins, polychlorinated dibenzo-p-furans and polychlorinated biphenyls, were detected. These fin...
Bing Yu


The effects of pH on leaching of copper-chrome-arsenate (CCA) from pressure-treated Kenyan-grown Eucalyptus saligna and Acacia mearnsii: Initial findings.
2002 - IRG/WP 02-30298
The effects of pH on leaching of CCA from pressure-treated Kenyan-grown Eucalyptus saligna and Acacia mearnsii were tested under laboratory conditions. Small samples of the two species (100mm x 30mm x 40mm) were smooth sawn from 8-year old trees to represent equal amounts of both sapwood and heartwood, air-dried to 12% moisture content, end-sealed, and pressure-treated at a commercial treatment p...
R Venkatasamy


The extraction of boron from treated wood for quantitative analysis: A comparison of procedures
1992 - IRG/WP 92-2414
The extraction of boron preservative from treated rubberwood and scots pine samples was compared using methods based on refluxing and extraction in 1N NaOH or distilled water at 80°C. The extract solutions were analysed by Inductively Coupled Plasma spectroscopy (ICP/AES). A simple extraction procedure based on immersion of wood samples of approximate dimension 2 x 1 x 1 cm³ in distilled water a...
R J Murphy, D J Dickinson, P W McCormack, M K Lung


Effect of humidity and temperature on fastener withdrawal resistance from CCA and ACZA treated Douglas-fir
2000 - IRG/WP 00-20209
The effects of preservative treatment on fastener withdrawal was investigated in Douglas-fir lumber conditioned to two moisture regimes. In general, conditioning samples to 19% moisture content produced more substantial changes in withdrawal resistance of galvanized fasteners than did conditioning to 12%. Treatment had little or no effect on withdrawal resistance of stainless steel fasteners. With...
Sung-Mo Kang, J J Morrell


The effect of kerfing on check formation in treated white spruce (Picea glauca) poles
1981 - IRG/WP 3167
62 white spruce poles, 6 m in length, were cut from full size utility poles commercially pressure treated with preservative. 21 of the poles were treated with pentachlorophenol, while of the remainder, all of which were treated with ammoniacal copper arsenate, 22 were kerfed and 19 were unkerfed. The poles were installed in the Westham Island field test site, near Vancouver, and inspected annually...
J N R Ruddick


Long-Term Release of Arsenic, Chromium, and Copper from CCA-Treated Wood and Ash
2005 - IRG/WP 05-50227
In this study, laboratory long-term leaching studies were conducted to characterize the leaching behavior of arsenic, chromium, and copper from CCA-treated wood samples (block, chip, and sawdust) and CCA-wood ash and to determine the rate of release of the metals from the CCA wood products. The leaching solutions were periodically collected and analyzed for the concentrations of arsenic, chromium,...
Hyunmyung Yoon, Heeseok Kang, Yong-Chul Jang


Leaching tests on CCA-treated wood using inorganic salt solutions
1984 - IRG/WP 3310
Pinus radiata sapwood treated to approximately 10 kg/m³ with Tanalith NCA or Tanalith C-type CCA preservatives was ground to a fine powder and samples were then leached with solutions of calcium chloride, calcium nitrate, magnesium nitrate, or a mixture of potassium di-hydrogen orthophosphate and di-potassium hydrogen orthophosphate, at 0.03M-1.00M solution concentrations. Leached wood samples we...
D V Plackett


Analysis of the boron content of preservative treated oak and pitch pine heartwood before and after leaching
1992 - IRG/WP 92-3697
Studies to determine the effects, if any, of a variety of boron formulations on heartwood of English oak and American Pitch pine have been previously reported (King et al (1991)). Small wood blocks were treated, at 10°C or 45°C, with borax, polybor or Boracol 20 for periods of 1 month or 4 months then analysed or continuously leached with tap water for a period of 1 month. Reported results showe...
S McCutcheon, G M Smith, J W Palfreyman, B King


Relating CCA fixation to leaching of CCA components from treated products
1995 - IRG/WP 95-50045
The relationship between chromium fixation in CCA-C treated wood, as determined by CrVI analysis of solution expressed from treated wood and the leaching of Cu, Cr, As and CrVI in a simulated rain test are evaluated for dimension lumber (2"x6") and pole sections. Leachate concentrations after 2 hour exposure to a misting spray (about 300 mm cumulative rainfall) decrease rapidly with increased degr...
P A Cooper, R MacVicar, Y T Ung


Wood cement composites using spent CCA treated wood
1999 - IRG/WP 99-50126
The feasibility of using spent or out-of-service CCA treated wood as a component of wood/cement composites was evaluated. Cold pressed wood particle cement boards were made using CCA treated particles from a red pine (Pinus resinosa Ait.) pole removed from service and from untreated red pine wood from a new pole. Boards were manufactured using a range of wood to cement ratios and water to cement r...
Chen Huang, P A Cooper


Ecotoxicological effects of exposed CCA preservative treated wood in environments
2001 - IRG/WP 01-50173
For the evaluation of environmental effect of CCA treated wood exposd in the field, the simulated soil pot system of the laboratory was used. The effective components of preservatives were leached and determined after artificially conditioning a soil pot of CCA treated wood with more than 500mm water, the average monthly precipitation. As the water passed through the soil, As, Cr and Cu in the soi...
Dong-heub Lee, Dong-won Son


Fixation and leaching characteristics of Douglas-fir treated with CCA-C
2004 - IRG/WP 04-50213
Fixation and leaching characteristics of CCA-treated Douglas-fir was evaluated using the expressate method and the AWPA E11-97 leaching procedure. CCA fixation, as monitored by the chromium reduction, was much faster in heartwood than in sapwood; however, copper and arsenic fixation in heartwood appeared to be incomplete regardless of the extension of fixation time. This poor fixation of copper a...
Gyu-Hyeok Kim, Yun-Sang Song, Dong-heub Lee


Programme d'études sur le pentachlorophénol
1993 - IRG/WP 93-50001-09
In 1989, Hydro-Québec began a study program on pentachlorophenol (PCP), with a view to ensuring safe management of the product at all stages of its utilization. The topics under study include storage of treated poles, behavior of PCP in the environment, soil decontamination, water treatment, characterization and disposal of treated wood waste, and assessment of substitutes. This paper summarizes ...
G Beaulieu, A Bériault, R Chénier, L Houde


Influence of fungal exposure on the redistribution of copper in treated spruce wood
2002 - IRG/WP 02-10450
The redistribution of copper in treated wood after exposure to basidiomycete decay fungi is described. The micro-distribution of copper in copper(II) sulphate or copper(II) octanoate/ethanolamine treated Norway spruce wood before and after exposure to 3 different wood decay fungi was studied using transmission electron microscopy with X-ray microanalysis. The copper content of the mycelium and the...
M Humar, F Pohleven, R J Murphy, D J Dickinson, I Moris, M Zupancic, P Kalan, M Petric


Information on a project about the conditions of admissibility of wood-protecting agents in connection with environmental protection in Poland
1974 - IRG/WP 57
Wood-protecting agents are compounds acting toxically on fungi and insects. If handled improperly or carelessly, they may exert an action harmful to health and safety of men. This action is concerning: a) workers employed at the production of wood-protecting agents; b) workers employed at the impregnation, or at the transport and handling of impregnated wood; c) inhabitants of buildings with impre...
J Wazny


Soft rot in heartwood of preservative-treated pole stubs of Eucalyptus cypellocarpa L. Johnson
1983 - IRG/WP 1204
Pole stubs of Eucalyptus cypellocarpa L. Johnson, treated in the sapwood with certain waterborne preservatives and exposed for 21 to 23 years in a dry tropical region were severely soft-rotted in the heartwood, as well as the sapwood. They broke with a brash fracture when stress tested (loaded as a cantilever) in the field. The severe soft rot in the heartwood was not detected by the knife test or...
J E Barnacle, G C Johnson, M A Tighe


Alternative methodology for the environmental impact assessment of treated wood: the wood emissions ecotoxicology
2000 - IRG/WP 00-50161
Preservative products and technologies are important for optimising the use of wood and wood products in our society. The regulations of their use under the european Biocidal Products Directive 98/8/EC will require an evaluation of the environmental impact of treated wood. The methodology currently used for this determination is the PEC/PNEC ratio. It consists of calculating PEC values (Predictive...
P Marchal, H W Wegen, J Van Acker, E Melcher, R-D Peek, W J Homan, D Aston, D Rudolph, E F Baines


Residual CCA levels in CCA treated poles removed from service
2000 - IRG/WP 00-50152
Fifty-two CCA treated poles removed from service after 1 - 50 years were sampled at different depths from their below ground and above ground zones and the preservative levels and mass balances related to the location in the pole and pole age. Generally CCA retentions were still well above the toxic threshold for decay in even the oldest poles. This confirms the good leach resistance of CCA and th...
P A Cooper, D Jeremic, J L Taylor


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