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Accelerated diffusion treatment of sawn Sitka spruce grown in the UK
1986 - IRG/WP 3395
The treatment of 'green' sapwood and heartwood of Sitka spruce by diffusion methods was investigated. Steam/dip treatment processes gave increased solution uptakes and depths of penetration of copper in comparison with a simple dip treatment. Further investigation is required to reduce diffusion gradients with copper based formulations and to improve the penetration of '...
R J Murphy, D J Dickinson


International collaborative laboratory comparison of two wood preservatives against subterranean termites: Second update
1995 - IRG/WP 95-10117
As was agreed by members at the termite workshop at the 24th annual meeting of IRG in Orlando, USA, in May 1993 to initiate an international subterranean termite laboratory bioassay to compare the various preferred termite protocols used by IRG termitologists was initiated. The author was nominated to co-ordinate this comparative laboratory evaluation of two wood preservatives (CCA and Cu-naphthen...
J R J French


The Copper Tolerance of Mycelium vs. Spores for Two Brown Rot Fungi
2002 - IRG/WP 02-10422
The copper tolerance of two brown rot fungi, Gloeophyllum sepiarium and Oligoporus placentus, has been tested using both mycelia and basidiospores as inoculum sources. Mycelial growth of O. placentus on agar medium was shown to be much more tolerant to copper (as copper sulfate) than that of G. sepiarium. However, there was no difference in copper tolerance of basidiospores between the two specie...
S Choi, J N R Ruddick, P I Morris


Dimensional stabilization and decay resistance of wood treated with brown-rotted lignin and copper sulfate
1990 - IRG/WP 3608
The objective of this study was to evaluate the potential usefulness of brown-rotted lignin (BRL) as a dimensional stabilization and copper complexing agent for wood treatment. For dimensional stabilization, aqueous solutions of the lignin extract were combined with either copper sulfate, glyoxal or other additives. Anti-shrink efficiency (ASE) values as high as 42% were obtained with wood treated...
L Jin, D D Nicholas, T Schultz


Creosote losses due to ageing methods prior to laboratory efficacy testing
2002 - IRG/WP 02-20256
Laboratory efficacy testing of creosote is affected by the impact of volatile components on the fungal growth. European test methods for assessing efficacy against Basidiomycetes and soft rot fungi is based on two standard methods, EN 113 and ENV 807 respectively. Combined with both fungal tests two pre-treatment methods are commonly used, namely EN 84 (leaching) and EN 73 (evaporation). Within th...
J Van Acker, K Ghekiere, M Stevens


Influence of hydrophobic agents on the leachability of boron
1995 - IRG/WP 95-30064
Besides its low mammalian toxicity and a broad range of activity towards both fungi and insects, boron shows a high diffusibility, encouraging it to treat wood species of low permeability. However, its difussibility is at the same time responsible for a high risk of leaching, known since long. Nevertheless quantitative data about this process are only rarely available. Therefore, the leaching of b...
A Peylo, H Willeitner


Accelerated termicidal performance data for new water-based copper linoleate formulations
1996 - IRG/WP 96-30104
An organic solvent based copper linoleate (Culin) has proved itself as an effective wood preservative in long term field trials in South Africa over a period of 30 years. Whilst the organic solvent based product offers good wood preservative performance, primary industrial interest has been in an emulsified version of the product. The objective of this study was to evaluate the influence of two di...
D Conradie, P Turner


Mechanistic aspects of the reactions of copper complexes with lignin in the presence of hydrogen peroxide and lipid hydroperoxide model compounds as proposed for white rot fungi
2001 - IRG/WP 01-10399
The structural principles and the oxidative reactions of the catalytic system consisting of copper, hydroperoxides, and copper coordination compounds that contain aromatic nitrogen atoms are similar to those of catalytic centers of oxidative enzymes involved in delignification reactions of white rot fungi. The system is capable of selectively degrading lignin and its low molecular weight would all...
K Fackler, P Lamaipis, E Srebotnik, M Humar, C Tavzes, F Pohleven, M Sentjurc, T Watanabe, K Messner


Artificial weathering exposure as an alternative for standard ageing according to EN 84 (leaching) and EN 73 (evaporation)
2002 - IRG/WP 02-20254
In order to verify potential weaknesses of wood preservatives fungal tests are carried out after ageing of wood preservative treated test blocks. The European standard EN 599 as a framework for efficacy assessment of wood preservatives includes the use of two ageing methods prior to fungal testing, namely a leaching method (EN 84) and an evaporation method (EN 73). The European research project "F...
J Van Acker, M Grinda, D J Dickinson


Leaching from CCA-treated wood submerged in seawater: Effect of high loadings, and a comparison between laboratory and marine conditions
1996 - IRG/WP 96-50080
This study of leaching examined the following variables: CCA loading; marine versus laboratory exposure and length of submergence. Blocks of Pinus sylvestris were treated to a range of nominal retentions from 15 to 50 kg/m³. Each block was then divided into three cubes and all transverse faces were sealed. All cubes were allowed to fix at ambient temperature for a minimum of one week. One set of ...
R M Albuquerque, S M Cragg, J D Icely


Growth of the copper tolerant brown rot fungus Antrodia vaillantii on different substrates
1995 - IRG/WP 95-10121
In recent years the copper tolerant brown rot fungus Antrodia vaillantii caused severe damages on impregnated wood in ground contact. The pattern of decay gave the impression that impregnated wood was even more severely attacked than unimpregnated. To investigate this question more closely laboratory tests were carried out. In a "choice test" Antrodia vaillantii grew preferably towards CC-impregna...
H Leithoff, I Stephan, M-T Lenz, R-D Peek


Preservative treatment of rubber wood (Hevea brasiliensis) to increase its service life
2005 - IRG/WP 05-40320
Rubber wood (Hevea brasiliensis) possess excellent properties for interior designing, wood working and furniture making. But it is very much susceptible to sap stain and mould fungi which decreases the service life. For profitable uses , it is necessary to increase the service life of rubber wood. To protect the rubber wood from wood degrading agents, the sawn timber were treated with Borax – b...
K Akhter


Influence of surface coating on the leachability of boric acid and bifluorides from spruce wood
1995 - IRG/WP 95-50050
In the Netherlands, window joinery made from non-durable timber species (spruce) are widely protected with preservative rods. These rods contain non-fixing wood preservatives (e.g. bifluorides or boric acid). This reseach was performed to show the possible influence of a coating system to hinder the leaching of the active ingredients. The results of the leaching tests show, that bifluorides and ev...
W J Homan, H Militz


Influence of variable lignin content amongst hardwoods on soft-rot susceptibility and performance of CCA preservative
1982 - IRG/WP 1151
This paper presents the outline of an argument, based on both new and established data, which relates varying lignin content to variation of soft-rot susceptibility between hardwood species and of performance of CCA preservatives in controlling soft-rot. Although more data need to be generated to prove this relationship, sufficient evidence exists for the hypothesis to be given close attention, pa...
J A Butcher, T Nilsson


Utilization of coconut timber from north Sulawesi, Indonesia. Part 2: Treatability
1994 - IRG/WP 94-40025
Under tropical conditions coconut wood is quickly degraded by mold and blue stain fungi. Low density wood in ground contact is commonly decomposed by wood destroying fungi within a period of only a few months, higher density wood from the outer stem regions within 24 to 30 months (MOSTEIRO, CASIN, SERIBAN 1976; McQUIRE 1975). Moreover, according to McQUIRE (1975) green wood of lower density is hig...
R-D Peek


Decay and termite resistance of wood treated with boron-containing quaternary ammonia compound, didecyl dimethyl ammonium tetrafluoroborate (DBF) incorporated with acryl-silicon type resin
2004 - IRG/WP 04-30334
This study evaluates the decay and termite resistance of surface-treated wood with didecyl dimethyl ammonium tetrafluoroborate (DBF) incorporated with acryl-silicon type resin emulsion. DBF is a quaternary ammonia compound and contains boric tetrafluoride (BF4-) as a counter ion in its chemical structure. In the study, DBF was incorporated with an acryl-silicon type resin to increase water-resista...
S N Kartal, W J Hwang, K Shinoda, Y Imamura


Fixation of CCA preservatives in cocos-, oil- and rattan-palm
1986 - IRG/WP 3371
In previous tests with jubaea-palm almost no fixation of a CCA-preservative Type B could be achieved, consequently, further leaching tests were carried out with samples of 1 cocos-, 1 oil- and 2 rattan-palms from Malaysia. A good fixation of chromium and copper took place in cocos-palm after 4 weeks storage at 28°C. Nevertheless the fixation was slower than in pine-wood and demanded an elevated t...
H Willeitner, K Brandt


Leaching of Boron - more than 3 years of field exposure
1997 - IRG/WP 97-30143
The diffusibility of Boron in wood and thus the ability of its leaching is known since long. Nevertheless quantitative data on this process are only rarely available. To overcome this lack of information field exposure tests were started with beam-segments treated with pure boric acid and poles treated with CCB. In addition some of the beam-segments were surface-treated with a varnish to investiga...
A Peylo, H Willeitner


Soft rot fungi found in copper/chrome/arsenic treated hardwood power transmission poles in Queensland
1978 - IRG/WP 185
In Queensland the effective service life of copper/chrome/arsenic (CCA) treated hardwood telegraph and power transmission poles is being dramatically shortened due to attack by soft rot decay fungi. The Australian Wood Preservation and Pole Industries are funding research into this serious soft rot problem involving C.S.I.R.O. and the University of Queensland. The C.S.I.R.O. is actively engaged wi...
L E Leightley


Soft rot decay in CCA treated eucalypts in Queensland - A comment
1986 - IRG/WP 1301
A survey has been completed concerned with the distribution and severity of groundline soft rot decay in the CCA treated sapwood of eucalypt poles in Queensland. The survey encountered some 1000 poles of which 55% were slightly, 28% moderately and 17% severely decayed. Soft rot decay was more severe in urban than rural locations. Embedment of poles in concrete resulted in severe soft rot. No signi...
L E Leightley


Weathering of copper-amine treated wood
2000 - IRG/WP 00-40155
Copper ethanolamine (Cu-EA) treated southern pine (SP) were artificially weathered with a QUV Weathering Tester. The weathering regime was composed of a continuous UV-light irradiation for 2 hours followed by a water spray for 18 minutes for a total time of 1200 hours. The changes on the surface of the weathered samples were characterized by Fourier transform infrared spectroscopy (FTIR) analysis,...
J Zhang, D P Kamdem


Sediment toxicity study of marine piles treated with CCA-C
1995 - IRG/WP 95-50040-35
A study was undertaken to demonstrate the effects of 10-day exposure to sediments mixed with leachate from chromated copper arsenate Type-C (CCA-C) southern pine marine piles treated to a retention of 40 kg/m³ (2.5 pcf) and untreated southern pine piles on the benthic amphipod, Ampelisca abdita. The biological endpoint used to establish effects was organism survival. Leachate obtained during a 28...
W J Baldwin, E A Pasek, P D Osborne


A possible role of unique TCA cycles in wood-rotting basidiomycetes
2003 - IRG/WP 03-10461
The copper tolerant brown-rot fungus, Fomitopsis palustris, acquires metabolic energy by use of the constitutively-occurring Kornberg’s glyoxylate cycle coordinating with oxalate biosynthesis and glucose oxidation (Erman Munir et al. Proc. Natl. Acad. Sci. USA, (2001) 98, 11126-11130). Furthermore, this fungus does not have the normal TCA cycle, lacking 2-oxoglutarate dehydrogenase which is a ke...
E Munir, T Hattori, M Shimada


Remedial ground-line treatment of CCA poles in service. A progress report after 28 months' testing
1988 - IRG/WP 3481
Remedial treatments of CCA-treated poles in service with incipient soft rot were carried out with boron rods, boron/glycol solution, boric acid paste, copper/creosote paste and a commercial product (DFCK paste) respectively. The micro-flora before remedial treatment and 6 months after as well as the spread of chemicals in the poles were reported in Document No: IRG/WP/3388. In this progress report...
B Henningsson, H Friis-Hansen, A Käärik, M-L Edlund


Oxidation of wood components during CCA-C fixation
1993 - IRG/WP 93-30024
Pre-extracted radial sections of southern yellow pine sapwood were treated with CCA-C and analyzed by X-ray photoelectron spectroscopy (XPS). The ratio of C1 (carbon bonded to carbon and/or hydrogen) to C2 (carbon bonded to one oxygen) in XPS Cls spectra was taken as a measure of the progress of oxidation of wood components during CCA fixation. This ratio was 0.82 before CCA treatment and increase...
M Kaldas, P A Cooper


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