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Leaching amount of wood preservatives from treated wood in different size during outdoor exposure for 6 months
2000 - IRG/WP 00-50160
Eighteen impregnated specimens with CCA, ACQ, and BAAC preservatives were subjected to a outdoor leaching test. Test specimens, 10 x 10 x 25 cm3, 5 x 10 x 25 cm3, 2 x 10 x 25 cm3 in size, were cut from Japanese cedar (Cryptomeria japonica). Both of end surfaces were sealed with a silicone sealer in the half number of specimens. Total leaching amounts of copper from the open-end ACQ specimens of 10...
K Yamamoto, S Motegi, A Inai


Effects of cyproconazole and copper sulphate on the length of the hyphal growth unit (HGU) of the white-rot fungus Coriolus versicolor
2003 - IRG/WP 03-10473
Wood decay basidiomycetes have been shown to produce appreciable quantities of extracellular mucilaginous materials (ECMM). The relationship between ECMM and total biomass production has been investigated in the white-rot fungus Coriolus versicolor (CTB 863 A). Differences in the amount of ECMM produced by the fungus proportionally to the total biomass, were observed under a range of physiological...
D Vesentini, D J Dickinson, R J Murphy


Chromium in wood preservation: Health and environmental aspects
1978 - IRG/WP 3120
The majority of water-borne salts in current use contain hexavalent chromium, usually as dichromate or chromium trioxide. In about 1913 it was suggested that chromates, phosphates or borates could be added to the sodium fluoride and dinitrophenol mixtures then in use in order to inhibit corrosion. Dichromates were found to be most suitable and the resulting mixture known as Thriolith and later Tri...
T R G Cox, B A Richardson


Laboratory termite testing of copper boron tebuconazole
2000 - IRG/WP 00-20192
The American Wood Preservers' Association laboratory choice and no choice termite test (AWPA E1-97) was performed on a formulation of copper azole, which is comprised of copper, boric acid, and tebuconazole. The formulation tested has a ratio of copper:boric acid:tebuconazole of 25:25:1. So as to examine the impact of leaching, the southern yellow pine wafers were treated with and without...
R F Fox, E A Pasek, J Patel


Difference of CCA efficacy among coniferous wood species
1990 - IRG/WP 3601
Wood blocks of Cryptomeria japonica, Tsuga heterophylla, and Pinus radiata successively extracted with n-hexane, ether, and methanol were treated with various concentrations of CCA type 3, which were subjected to the decay by Tyromyces palustris. The weight loss were different among species and kinds of extraction. Cryptomeria japonica treated with CCA had higher fungal resistance than Tsuga heter...
K Yamamoto, M Inoue


Screening of the efficacy of tall oils against wood decaying fungi
2004 - IRG/WP 04-30354
Tall oil is a by-product in pulping of resinous wood by the sulphate process. Tall oil contains a complex mixture of wood extractives. Some of these extractives act as natural protection against wood decaying fungi while other serve as nutrition for the fungi. This report describes a screening of the efficacy of four refined tall oils with different chemical composition on wood decaying fungi. ...
G Alfredsen, P O Flæte, A Temiz, M Eikenes, H Militz


Assessing the leachability of chlorothalonil and methylene bis thiocyanate from antisapstain treated radiata pine
1998 - IRG/WP 98-30176
Rain wash-off and leaching of antisapstain fungicides from wood may cause pollution of waterways and may also lead to a decrease in the efficacy of a formulation against fungal degrade as chemicals deplete from the timber surface. In the current study, the leachability of chlorothalonil (CTL) and methylene bis thiocyanate (MBT), the active ingredients of a commercial antisapstain formulation, was...
B Kreber, T L Woods


Field evaluation of CCA movement in sap-displaced copper chrome arsenic treated softwood poles
1989 - IRG/WP 3539
Commercial sap-displaced UK grown Scots and Corsican pine, and Sitka and Norway spruce poles were exposed in a field site at Dundee, Scotland and radial distribution profiles of CCA monitored prior to implantation and after subsequent field exposure. Results show that groundline levels of all preservative elements were higher after 1 and 2 years field exposure compared with those recorded prior to...
S D Hainey, G M Smith, A Bruce, P D Evans, B King, H J Staines


Performance of preservative-treated wood not in ground contact
1975 - IRG/WP 254
Experimental sash units of Pinus strobus L. and Pinus resinosa Ait. wood were removed from a test fence at Ottawa, Canada after outdoor exposure of over 20 years. The units were superficially treated, prior to painting, with preservatives containing either copper naphthenate, pentachlorophenol or a combination of zinc naphthenate and pentachlorophenol. Results indicated that all treatments were ef...
J K Shields, J Krzyzewski


Laboratory evaluation of the termiticidal effectiveness of TanalithÒ 3485
1995 - IRG/WP 95-10109
The termiticidal effectiveness of the copper azole TANALITH 3485 was evaluated with the benchmark preservative TANALITH C in a laboratory bioassay using two species of subterranean termites, Mastotermes darwiniensis Froggatt and Coptotermes acinaciformis (Froggatt). Retentions of TANALITH 3485 tested were 0.15, 0.24, 0.285 and 0.40% m/m Cu and for TANALITH C 0.025, 0.05, 0.08 and 0.095% m/m Cu. Un...
J W Creffield, J A Drysdale, N Chew, N-K Nguyen


Status of Work on OECD Test Guidelines for Emissions of Wood Preservatives to the Environment
2005 - IRG/WP 05-50224-3
In April, 2003, OECD published an ESD on wood preservatives that provides guidance on how to estimate emissions: 1) during the wood preservative application processes and storage of treated wood prior to shipment; and 2) from treated wood-in-service. The ad hoc Expert Group that developed the wood preservatives ESD identified the need to develop Test Guidelines to estimate the amount of biocides ...
W Jakob


Influence of acidification on decay processes of CCB treated wood
2004 - IRG/WP 04-10514
The phenomenon of copper tolerance by brown rot fungal strains has been known for a long period but the complete mechanism of copper tolerance by these fungi is not understood yet. Copper tolerance has previously been linked to oxalic acid excreted by copper tolerant brown rot fungal strains. This acid reacts with copper in the wood to form an insoluble and therefore less toxic copper oxalate. The...
M Humar, S A Amartey, M Šentjurc, F Pohleven


An environmental aspect relating to leachability of CCA from hardwood and softwood poles in Bangladesh
2001 - IRG/WP 01-50167
Leachability of CCA and the service performance of 8 softwood and 5 heartwood poles in service after 5 to 17 years in Bangladesh have been studied. The study included determination of retention of CCA-C in outer 6 mm zones at groundline (GL) and above groundline (AGL) along with the observation of decay and conditions of soils. The mean leaching of CCA-C derived from retention differential at GL a...
A K Lahiry


Water repellency of wood treated with alkylammonium compounds and chromated copper arsenate
2000 - IRG/WP 00-30231
The comparative water sorption properties of southern pine treated with CCA and several alkylammonium compounds was evaluated for freshly treated wood and for wood after exposure in a fungus cellar. It was found that CCA imparts considerable water repellency to wood which is reduced somewhat after exposure to wet soil. With the exception of a long chain (C20 -C22) compound, the alkylammonium compo...
D D Nicholas, A Kabir, A D Williams, A F Preston


Preservative treatment of wood by diffusion processes - Simulation of commercial treatment processes
1988 - IRG/WP 3498
Spruce (Picea abies), Scots pine (Pinus sylvestris) and birch (Betula pendula) were preservative treated by diffusion with mixtures of copper sulphate and arsenic pentoxide. The preservative was fixed after a suitable diffusion storage period by soaking in ammonia solution. A high standard of treatment could be achieved in spruce sapwood. This was attributed to its low wood density, and high wood ...
P Vinden


Performance of copper naphthenate-treated hardwoods
2001 - IRG/WP 01-30269
Copper naphthenate (CuNap) is a historically proven, commercially produced and industry utilized preservative for many wooden commodities including poles, fence posts, lumber, timber and wood shakes/shingles. Historically, most wood preservatives are tested using the sapwood of softwood species like pine (Pinus spp.) and or Douglas-fir (Pseudosuga menziesii) and even though the railroads of the wo...
H M Barnes, T L Amburgey, H M Freeman, J A Brient


Persistance of active ingredients in treated wood
1993 - IRG/WP 93-50001-20
Disposing of chemically protected waste wood implies the distinction between surface and pressure treatment. Considering that barked round-wood merely contains, after 7 months open storage, less than 30 g per ton of bark or 25 mg per ton of sapwood, depending on the type of insecticide, the bark or sapwood shavings may be incinerated normally, according to less severe legal prescriptions than for ...
E Graf, P Manser, S Rezzonico, B Zgraggen


Timber preservatives and corrosion
1983 - IRG/WP 3228
A survey of preservative treated timber commodities has illustrated problems that may be caused by corrosion. After treatment, timber should be compatible with commonly used fasteners. Whilst many corrosion methods have been used in the past, no standardized method is used by workers in timber preservation. The Queensland Department of Forestry is developing laboratory test methods for assessing c...
R I Davis


Five years leaching of Boron
1999 - IRG/WP 99-30195
The diffusibility of Boron in wood and thus its leaching behaviour in water contact is known since long. Nevertheless quantitative data on the long-term leaching behaviour are rare. Consequently, field exposure tests were started with beam-segments treated with pure boric acid and with poles treated with CCB. Detailed data of more than five years of field exposure are now available. Pure boron tre...
A Peylo, H Willeitner


Experiences with the OECD guideline proposals for the estimation of emissions from preservative-treated wood in the environment
2004 - IRG/WP 04-50209
The practicability of 2 CEN proposals for OECD guidelines on the estimation of emissions from preservative treated wood by laboratory methods for either wood held in storage after treatment and for wooden commodities that are not covered, and are not in contact with ground (guideline 1) or wooden commodities that are not covered and are in contact with ground, fresh water or seawater (guideline 2...
U Schoknecht, R Wegner, E Melcher


Environmental fate of copper-based wood preservatives in different soil substrates - Part 1: Screening of the metal adsorption potential
1998 - IRG/WP 98-50101-21 a
In treatment plants, spillage of wood preservatives onto soil may be of environmental concern. This potential soil contamination served as an objective for a screening study. Three different mineral soils, a mineral substrate and two horticultural substrates are examined for their sorptive potential of copper through mixing with wood preservative solutions. Depending on the soil/substrate charact...
G M F Van Eetvelde, J M Mwangi, F Tack, R Hartmann, M Stevens


Efficacy of copper:propiconazole and copper:citrate systems in ground contact exposure at a site with copper tolerant fungi
2003 - IRG/WP 03-30305
Southern yellow pine (SYP) sapwood field stakes were treated with copper alone (ammoniacal copper carbonate, ACC) at four levels, or three levels of copper (1.6, 3.2, or 6.4 kgm-3, as CuO), air-dried, then re-treated with propiconazole in a light organic solvent at 0.07, 0.3, or 0.7 kgm-3 retentions. In a separate study, SYP field stakes were treated with three levels of ACC to give 6.7, 13.4 or ...
D D Nicholas, T Schultz


Interactions between water-borne preservatives and emulsion additives that influence the water repellency of wood
1991 - IRG/WP 2374
Incorporation of non-polar additives into water-borne treatments through of emulsion technology can greatly improve the physical characteristics of wood in service. Of specific interest with these emulsions is their effectiveness in reducing the rate of wood swelling. We have observed that the presence or absence of preservatives can often significantly influence the resultant effectiveness of the...
A R Zahora


Reduction of preservatives leaching from wood by the application of animal proteins
2005 - IRG/WP 05-30387
The investigations consisted in the estimation of the effectiveness of protein borates and protein propionates in wood preservation against Coniophora puteana. The estimation was made on the basis of mass losses caused by the test fungus action against treated wood which was subjected to leaching with water. The investigations were performed for Scots pine wood (Pinus sylvestris L.) treated with p...
B Mazela, I Ratajczak, M Bartkowiak


Leaching of active components from preservative-treated timber. Stages 2 & 3: Laboratory testing and comparison with semi-field testing
2004 - IRG/WP 04-20303
This part of the project is focussed on leaching from preservative-treated wood obtained by the laboratory test method CEN/OECD draft guideline, February 2003 ”OECD guideline for the testing of chemicals proposal for new guideline XXX. Estimation of Emissions from Preservative-treated Wood to the Environment: Laboratory Method for wood held in the storage yard after treatment and for wooden comm...
N Morsing, B Lindegaard


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