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Degradation of lignin model compounds with coordinated copper in the presence of peroxide
1998 - IRG/WP 98-10282
A novel diffusible system capable of decomposing lignin model compounds with copper, coordinators and peroxides has been proposed. When pyridine was used as a copper coordinator, two synthetic dyes, Poly-R and RBBR were intensively decolorized with Cu(II) and H2O2 in aqueous solutions at room temperature. Although reactions with Cu(II) and H2O2 produce a strong oxidant, hydroxyl radical, via a Fen...
K Koller, K Messner, T Watanabe


Soft-rot control in hardwoods treated with chromated copper arsenate preservatives. Part 3: Influence of wood substrate and copper loadings
1977 - IRG/WP 2100
The hypothesis is proposed that hardwoods need more chromated copper arsenate (CCA) than softwoods to protect them from soft-rot attack mainly because hardwoods are more readily consumed by soft-rot fungi. Simple model systems, using copper-supplemented agar or groundwood pulp treated with CCA showed that fungi tolerated more toxicant (copper) as more available substrate (malt) was provided. Soft-...
M A Hulme, J A Butcher


Copper storage in the digestive caecae of Limnoria tripunctata and Limnoria quadripunctata (Crustacea: Isopoda) tunnelling in CCA treated and untreated wood in laboratory cultures
1998 - IRG/WP 98-10257
Digestive tract tissues of Limnoria quadripunctata Holthuis and Limnoria tripunctata Menzies, tunnelling untreated and CCA treated Scot's pine sapwood under laboratory conditions were examined using X-ray microanalysis and transmission electron microscopy. Populations of both Limnoria species tunnelling treated and untreated wood stored copper within their digestive caecae in the form of ...
C Wykes, A J Pitman, S M Cragg


Laboratory aquaria evaluation of CDDC (copper dimethyldithiocarbamate) against marine borers
1998 - IRG/WP 98-10262
The performance of CDDC (copper dimethyldithiocarbamate) and CCA (copper chrome arsenic) treated timber blocks was examined in a 1.5 year aquaria bioassay against the marine borers Limnoria tripunctata Menzies and Lyrodus pedicellatus (Quatrefages). Three timbers, southern yellow pine (SYP), Pinus radiata D. Don and Eucalyptus regnans F. Muell were treated with CDDC to retentions of 16, 32, 48 and...
L J Cookson, C R McIntyre, D Scown


Biological detoxification of wood treated with salt preservatives
1992 - IRG/WP 92-3717
The use of microorganisms that are capable to convert chemically fixed inorganic preservative complexes from impregnated wood waste into watersoluble components is investigated. A number of fungi were isolated from deteriorated and initially well-treated wood. They revealed an exceptionally high production of organic acids (pH 2). The fungi were identified and used together with others of the same...
I Stephan, R-D Peek


Remedial ground-line treatment of CCA poles in service. A final report after 60 months' testing
1989 - IRG/WP 3534
Remedial treatment of CCA treated utility poles of Pinus sylvestris with incipient decay was carried out in 1983 and the results of chemical and microbiological analyses 6 months after treatment were reported in Document No: IRG/WP/3388 while microbiological studies 12 and 28 months after treatment as well as chemical analyses of poles treated with boron rods or boric acid paste 28 months after tr...
B Henningsson, H Friis-Hansen, A Käärik, M-L Edlund


Inadequacies in preservative retention and formulation as contributory causes of premature failure of CCA-treated vineyard posts
1984 - IRG/WP 3280
Analyses of severely decayed or failed vineyard posts and examination of stake test data on effectiveness of copper-chrome-arsenate (CCA) preservatives have suggested two contributory causes of premature failure of vineyard posts: 1. Preservative retentions in posts are such that after 15 years' exposure some decay is inevitable. 2. The high arsenic, low chrome formulations with which the...
M E Hedley


Silafluofen, a new insecticide against wood-boring insects and termites
1991 - IRG/WP 3666
Hoe 084498 (proposed common name: Silafluofen) is a new insecticidal compound from Hoechst Aktiengeesellschaft and has been extensively tested to determine its potential use as an insecticide against wood-boring insects and soil termites. Various tests in official institutes indicate a good activity against several wood-boring insects and soil termites. The active ingredient is resistant to weathe...
G Rustenburg, C J Klaver


Adsorption of ACQ and CuMEA Wood Preservatives in Red pine
2005 - IRG/WP 05-30374
The rates of stabilization or fixation of ACQ subcomponents (CuO, DDAC and MEA) in red pine (Pinus resinosa) were compared for different solution concentrations (0.75%, 1.5%, 2.25% and 3% ACQ-D) and post treatment conditioning temperatures. Preservative solutions were impregnated into red pine sapwood by a full-cell treatment. Copper and MEA adsorptions from copper monoethanolamine solutions witho...
C Tascioglu, P A Cooper, Y T Ung


X-ray photoelectron spectroscopic analysis of CCA treated wood
1992 - IRG/WP 92-3700
Ponderosa pine and Douglas-fir wood sections were treated with CCA preservative. To elucidate the mechanism of fixation of the CCA, the wood surface was analyzed by X-ray photoelectron spectroscopy (XPS). CCA treatment increased C1 (carbon bonded to carbon and/or hydrogen) and decreased C2 (carbon bonded to one oxygen) in XPS C1s spectra, both in unextracted and pre-extracted sections. This sugges...
J N R Ruddick, K Yamamoto, P C Wong, K A R Mitchell


Tendency of the preservative use for impregnation industries in Japan
1998 - IRG/WP 98-50101-05
In Japan, since 1997, the acceptable limit of the arsenic in the waste water become to 0,1 mg/l and the additional regional severer restriction can be established. In this reason, Japanese wood preservation industries intend to use other than CCA, like DDAC, ACQ, Tanalith CuAz, copper-naphthate and zinc-naphthenate, as replacing from CCA. In Jan-June 1997, the share of CCA preservatives was less t...
K Suzuki


Field performance of novel antisapstain formulations
1997 - IRG/WP 97-30125
The effectiveness as antisapstain formulations of combinations of oxine copper (Cu-8), carbendazim, hexaconazole, cyproconazole, flusilazole, didecyldimethyl ammonium chloride (DDAC), an alkanolamine borate (SB), benzalkonium chloride (BAC), 2-n-octylisothiazolin -3-one (isothiazoline) and p-chlorophenyl-3-iodopropagilformal (CPIPF) was determined for freshly sawn, block-stacked radiata pine in th...
D R Eden, R N Wakeling, C M Chittenden, J G Van der Waals


Fungitoxic effect of the quaternary ammonium compounds preservatives against Basidiomycetes by using agar-plate and agar-block methods
1996 - IRG/WP 96-30118
Results of investigations on the fungitoxic value of three versions of wood preservatives based on the quaternary ammonium compounds (lauryldimethylbenzylammonium chloride, lauryldimethyl-benzylammonium bromide and alkylbenzyldimethylammonium chloride) and borates in relation to the wood destroying fungi have been presented. The agar-plate (screening) and agar-block method were applied. A wide ran...
J Wazny, P Rudniewski


A note on the distribution of copper-chrome-boric (CCB) along the culm length of freshly felled bamboo treated by modified Boucherie process
2005 - IRG/WP 05-40317
Preservative treatment of green and dry bamboo poses severe problems. A number of bamboo/ wood preservatives (Chemical formulations) for the destroying organism like fungi, borers and termites etc. In this paper we reported preliminary results of treatment of fresh green round bamboo attached with baranches by modified Boucheri process. Sample full length of an Indian species of bamboo Dendrocalam...
R Lal, C N Vani


Metal Leaching from Pressure Treated Wood in Sanitary Landfill Leachate
2004 - IRG/WP 04-50220
Pressure treated wood products contain heavy metals to prevent biological decay. Scrap treated wood from construction activities and demolished structures containing treated wood are typically disposed in landfills. To examine the potential mobility of metals from pressure-treated wood disposed in landfills, wood samples were leached using leachate from lined landfills and the concentrations of ar...
B Dubey, T G Townsend, H M Solo-Gabriele


Leaching from CCA-impregnated wood to food, drinking-water and silage
1987 - IRG/WP 3433
During the last years The Norwegian Institute of Wood Technology (NIWT) has analysed different foodstuff for contamination by copper, chrome and arsenic from CCA-impregnated wood. There has been some interest for using CCA-impregnated wood in contact with food and drinking-water. Before giving their permission the Norwegian Health Authorities want results from experiments. NIWT therefore started t...
F G Evans


A survey of the incidence of decay in copper-chrome-arsenate treated trellis support posts used in horticulture in New Zealand
1984 - IRG/WP 1225
Copper-chrom-arsenate treated softwood posts used as trellis support structures in 5 major horticultural districts of New Zealand were systematically examined for presence of decay. Principal crops on properties examined were grapes and kiwifruit; a minority of properties grew hops, boysenberries, and dwarf apples. Occurrence and severity of decay were variable within specific age classes of posts...
M E Hedley, J A Drysdale


Kinetics and mechanism of fixation of Cu-Cr-As wood preservatives. Part 5: Effect of wood species and preservative composition on the leaching during storage
1975 - IRG/WP 354
Conversion reactions during storage of CCA treated wood take place even at and below the fiber saturation point as long as ion transport is possible. Increase in drying temperature increases the final pH of the treated wood and the leachability of Cu and decreases slightly the leachability of Cr, while the leachability of As is not affected. This temperature effect is considered to be of no techni...
S-E Dahlgren


Preservative treatment of different thatching materials for low cost housing
1999 - IRG/WP 99-40144
Preservative treatment were made in seven different roofing materials with Copper-Chrome-Boron (CCB) at different concentration by soaking process. These were paddy straw, wheat straw, jute stick, sungrass, ulu grass, sugercane leaf and Nipa fruticans. It was observed that retention of preservative chemicals varies from species to species at the same concentration. From the service test it was obs...
K Akhter, M Younusuzzaman, M H Chowdhury


International collaborative laboratory comparison of two wood preservatives against subterranean termites: Update
1994 - IRG/WP 94-20032
It was agreed by members at the termite workshop at the 24th annual meeting of IRG in Orlando, USA, in May 1993 to initiate an international subterranean termite laboratory bioassay to compare the various preferred termite protocols used by IRG termitologists. The author was nominated to co-ordinate this comparative laboratory evaluation of two wood preservatives (CCA and Cu-naphthenate) against t...
J R J French


An example of media response to perceived environmental problems with CCA-treated wood
1990 - IRG/WP 3564
A recent study suggested that CCA-treated wood exposed to acidic precipitation could lose significant amounts of copper chromium and arsenic resulting in loss of efficacy and possible environmental contamination. The study received wide newspaper and radio coverage in Canada, thereby heightening public concern about CCA use. Subsequent studies in our laboratory confirmed that the high losses were ...
P A Cooper


Performance of preservative-treated timber against biodeterioration in Indian waters
1984 - IRG/WP 4106
Results on the investigation on the durability of panels of 32 timber species, pressure-treated with various preservatives and exposed along the Indian coast for varying periods upto a maximum of 15 years, are summarised. Panels of even non-durable timber gave excellent results against biodeterioration after treatment. Their life was comparable to that of treated durable timber. The preservative t...
L N Santhakumaran, J C Jain, M C Tewari


Preservative treatment of Golpata (Nypa fruticans) using CCA (Chromated Copper Boric Acid)
1999 - IRG/WP 99-40131
Golpata (Nypa fruticans) leaves provide a cheap but practical source of roof thatches. This study was carried out to determine whether the life span of Golpata could be extended by using CCB (Chromated Copper Boric Acid) treatment. Both leaves and midribs of Golpata , with different moisture contents ranging 16.63% to 70.67%, at the start of the experiment were treated with four different concentr...
G N M Ilias, F Abdullah, M O Hannan, S M Feroz


Oxine copper (NYTEK® GD) for the control of mould and sapstain on lumber in North America
1989 - IRG/WP 3517
NYTEK® GD is a new, water-based, micro-dispersible formulation of oxine copper registered in the United States and Canada for control of mold and sapstain-causing fungi. NYTEK GD is noncorrosive and of low hazard to applicators and people handling treated lumber, when used according to the label. The product is an effective wood protectant applied as a dip or spray treatment at concentrations of ...
D F Myers, J M Fyler, C H Palmer, G D Rosebery


Future Directions Regarding Research on the Environmental Impacts of Preservative-Treated Wood: Environmental Impacts of Preservative-Treated Wood. February 8-11, 2004, FL, USA Workshop – Research Needs
2004 - IRG/WP 04-50222
This paper presents a series of documents that focus on research needs for potential future work focusing on the environmental impacts of preservative-treated wood. These documents were developed through a conference sponsored by the Florida Center for Environmental Solutions (FCES), located in Gainesville, Florida. The conference was held in Orlando, Florida, February 8 – 11, 2004 and the tit...
H M Solo-Gabriele, J D Schert, T G Townsend


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