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Effects of fixation conditions and seawater on leaching of wood treated with marine retention CCA
1997 - IRG/WP 97-50088
The effect of post-treatment conditioning temperature and humidity on leaching of chromated copper arsenate (CCA) was compared in seawater and deionized water. Southern pine cubes treated to 40 kg/m3 CCA were stored at 2° C and 82% relative humidity (RH), 24° C and 65% RH, or 32° C and 30% RH for 3, 10, or 17 days. Cubes were then leached in deionized water or artificial seawater. The rate of l...
S T Lebow


Determination of absorption, accumulation and transport of copper in mycelium of some wood decay fungi
1999 - IRG/WP 99-10323
Copper compounds are common wood preservatives. However, tolerance of some wood decay fungi to copper compounds has been observed recently. Therefore, we tried to elucidate possible causes of this phenomenon. We investigated uptake, accumulation and secretion of copper in the mycelium of potentially copper tolerant fungi (Antrodia sp.) and non tolerant fungus Trametes versicolor. We observed that ...
F Pohleven, S Breznikar, P Kalan, M Petric


Serpula lacrymans, The Dry Rot Fungus and its Tolerance towards Copper-based Wood Preservatives
2005 - IRG/WP 05-10555
Serpula lacrymans (Wulfen : Fries) Schröter, the dry rot fungus, is considered the most economically important wood decay fungus in temperate regions of the world i.e. northern Europe, Japan and Australia. Previously copper based wood preservatives were the most commonly used preservatives for pressure treatment of wood for building constructions. Because of a suspicion about tolerance toward cop...
A C Steenkjær Hastrup, F Green III, C A Clausen, B Jensen


Leaching characteristics, decay and termite resistance of treated wood with boron compounds, N'-N-(1,8-Naphthalyl) hydroxylamine (NHA-Na), and hydroxynaphthalimide (NHA-H)
2003 - IRG/WP 03-30307
Despite many advantages of boron wood preservatives, boron itself does not adequately protect wood in ground contact and exterior applications because its natural diffusibility and susceptibility to leaching. As a result of previous studies to limit or decrease boron leaching, several fixation systems have been developed. In this study, we evaluated the effects of N'-N-(1, 8-Naphthalyl) h...
S N Kartal, Y Imamura


Selective chromate elimination from the storage-drainage-water of a wood impregnation plant
1980 - IRG/WP 3153
With the Enviro-Chrom-Ex process it is possible to eliminate ecologically and economically hexavalent chromium (chromate) from water selectively. The process which is based on the principle of selective ion exchange works with different chromate concentrations and under the presence of other ions, irrespective of the water hardness. The values of water-offtake reach 0.1 mg CrVI at maximum, causing...
O Wälchli, R Ott, R Hugener, E Graf, B Lieberherr


Relative performance of copper/chrome/boron (CCB) and copper/chrome/arsenate (CCA) in ground contact
1992 - IRG/WP 92-3694
The performance of four retentions each of an oxide CCA formulation and a salt formulation of CCB in radiata pine and European beech was compared after 18 years' field exposure. In radiata pine CCA oxide was more effective (4 failures out of 40) than CCB (9 failures out of 40). However, in European beech CCB was substantially more effective (22 failures) than CCA oxide (all failed). Analy...
M E Hedley


Ability of chitosans to limit wood decay under laboratory conditions.
2004 - IRG/WP 04-30339
Chitosans have recently been explored for controlling a number of plant pathogenic fungi and have shown some promise for controlling stain fungi on wood. The potential for using chitosans either alone or in combination with copper sulfate to protect wood from fungal decay was explored using maple veneers. Chitosan treatment reduce weight losses caused by two brown rot and one white rot fungi, howe...
M Maoz, J J Morrell


An appraisal of methods for environmental testing of leachates from salt-treated wood; part 1
1998 - IRG/WP 98-50115
The magnitude and diversity of leaching tests with salt-treated wood, performed by institutes as well as industry, strongly appeal for harmonisation towards one single method. That procedure should be well-defined, cost- and time-effective and moreover be extended with a clear detection and interpretation scheme. The paper(s) presented here tend to evaluate 2 existing leaching methods, the ENV 12...
G M F Van Eetvelde, M Stevens, F Mahieu, H-W Wegen, A Platen


Observations on the performance of copper-based wood preservatives in fungal cellar (soil-bed) tests
1994 - IRG/WP 94-20047
Fungal cellar (soil-bed) tests are considered to be an important tool for the evaluation of the performance of ground contact wood preservatives. Facilities of this type have been established world wide although caution has been exercised in their introduction into standard testing methods for the approval of wood preservatives. This is the result of concerns over the variability in the biological...
G R Williams, D Rudolph, M E Hedley, J A Drysdale, R F Fox


Description of a trial with wood preservatives against marine wood boring organisms
1975 - IRG/WP 412
Wood situated in sea water along the Atlantic coasts of the Nordic countries is attacked by marine wood boring organisms. Timber constructions in these waters therefore must be preservative treated. In order to evaluate the effect of various preservatives against marine wood borers, the Nordic Wood Preservation Council (NWPC) organized a rather extensive trial in 1972. In the absence of and while ...
E Norman, B Henningsson


On-site test for indicative determination of leaching of components of preservatives from treated timber
1993 - IRG/WP 93-50001-12
In the late eighties the environmental concern about treated timber increased and it is still a hot issue in the Netherlands. From the environmental point of view three phases in the timbers life cycle can be distinguished: - the production phase - the service life - the waste phase. In the Netherlands at this moment much emphasis is laid on the production phase. In 1992 this has led to a new legi...
W J Homan, H Militz


A marine borer test with water-borne preservatives
1980 - IRG/WP 452
The use of preservative treated timber in sea-water where marine borers are active is of great economic importance, since untreated wood immediately will be damaged. Vacuum/pressure treated timber has been tested in several marine exposure trials on the Swedish west coast since the 1930s (Hager 1941, Hultman 1949, Sandstrom 1951, Nylinder-Norman et al. 1974). Since new interesting materials or pre...
B Henningsson, E Norman


Equilibrium distribution of toxic elements in the burning of impregnated wood
2001 - IRG/WP 01-50172
The current work focuses on predicting the behavior of arsenic, chromium, and copper in the burning of impregnated wood. A theoretical method is used to study the chemistry of the system, with special interest directed towards the vaporization tendency of the potentially toxic elements. The core of the study is the global equilibrium analysis that simultaneously takes into consideration all chemic...
K Sandelin, R Backman


Preservation of robinia wood (Robinia pseudoacacia L.) stakes by vintners
1982 - IRG/WP 3194
This work discusses decay resistance of robinia wood to fungi Trametes versicolor (L.ex Fr.) Pil. and Coniophora puteana (Schum. ex Fr.) Karst., and also the possibility of influencing its resistance by means of chemical protection. The results showed that natural resistance of robinia wood to these two different agents of wood decay is not the same. It is much less resistant to the fungus Conioph...
R Benko


Remedial ground-line treatment of CCA poles in service. Results of chemical and microbiological analyses 6 months after treatment
1986 - IRG/WP 3388
CCA-treated poles in service with incipient internal soft rot were remedially treated by inserting borate rods, brushing with a boron/glycol solution and injecting boric acid paste, copper/creosote paste or a commercial product (DFCK paste). The spread of active chemicals in the treated zone as well as the change in microflora have been studied with time. After six months chemicals had spread to m...
B Henningsson, H Friis-Hansen, A Käärik, M-L Edlund


Determination of ethanolamine in impregnated wood
2000 - IRG/WP 00-20198
Leaching of copper based preservatives from wood is usually prevented by adding chromium compounds to copper containing formulations. It seems that suitable substitutes for chromium fixation agents may be amines. In this paper, we report our results on interactions between copper(II) octanoate and ethanolamine (C2H7NO, 2-aminoethanole) with wood or its components. A part of ethanolamine from a woo...
M Humar, M Petric


Recycling of treated timber by copper smelter
1994 - IRG/WP 94-50030
A preliminary trial was carried out to see whether copper smelting process is able to recycle CCA treated timber. As a result of the first trial almost a full recovery of both copper and arsenic was achieved. Recovered metals were utilized in manufacturing CCA preservatives. The energy bound in wood is utilized in the flash smelting process and the burning gases are fed to the sulphuric acid plant...
A J Nurmi, L Lindroos


Copper naphthenate-treated Southern Pine pole stubs in field exposure: - Part 1: Gradient & biodeterioration analysis 12 years after treatment
2000 - IRG/WP 00-30242
Naphthenates have been used for the preservation of timber and cellulose since their original identification in Russia in the early 1880's as part of a series of petroleum characterizations. Later work in the development of copper naphthenate as a heavy-duty preservative for poles led to the development of various treating cycles similar to other oil-borne systems. Recent work concerning ...
H M Barnes, M H Freeman


Environmental fate of copper-based wood preservatives in different soil substrates - Part 2: Study of the metal sorption and migration potential under simulated rainfall
1998 - IRG/WP 98-50101-21 b
In order to examine the potential environmental impact of spillages of the saltborne wood preservative CCA in treatment plants, four large scale experiments are set-up so as to follow the water transport and ion mobility in various field soils. A plastic container is filled with a sand, silt, clay and potting soil, made up at their respective bulk density and wetted to a given moisture content. U...
G M F Van Eetvelde, R Hartmann, J M Mwangi, H S Öztürk, M Stevens


Marine trial progress report
1980 - IRG/WP 453
In May 1977 and May 1978, tests of new chemical formulations for the protection of timber in the sea were installed in Mt. Maunganui Harbour. Investigation into new preservatives for such usage was urgently required since it had been found that there was progressive leaching of copper from copper-chrome-arsenate treated marine piles which could lead to a reduction in their service life. Hochmann (...
A F Preston, C M Chittenden


Report on the co-operative leaching tests
1975 - IRG/WP 246
The Work reported here was undertaken at the request of CEN to see (1) whether the standard beaker leaching method under discussion at CEN, and based on the German DIN could be made less labour intensive; and (2) whether the leaching parameters could be expressed in more general terms so that alternative procedures could be used. A co-operative experiment was set up in which the amount of leaching...
J W W Morgan


Respiratory response of the wood boring teredinid, Lyrodus pedicellatus (Quatrefages) to copper stress
2004 - IRG/WP 04-10528
Wood boring teredinid molluscs engulf most of the wooden particles scrapped by them while actively boring into wood, obtaining nourishment for their metabolic activities. In order to protect the wooden structures from the biodeteriorating activity of such organisms, the wood is treated with different chemical formulations to prolong their service life. Copper chrome arsenic (CCA) is one such woo...
V Kuppusamy, M Balaji, M V Rao, K S Rao


IRG/COIPM INTERNATIONAL MARINE TEST - to determine the effect of timber substrate on the effectiveness of water-borne salt preservatives in sea-water. Progress Report 21: Report of eighth inspection (7 years) in Australia
1985 - IRG/WP 4119
This report tabulates the seven year (86 month) inspection results, obtained on 28 Fabruary l985, of the IRG/COIPM International Marine Test at Goat Island, Australia. This test was installed in December 1977. The results are given in Tables 1-6. Table 7 lists the number of marine borers identified from blocks (2 cm and 6 cm long respectively) cut from the ends of specimens removed at the previous...
L J Cookson, J E Barnacle


Chlorothalonil: A new ground contact wood preservative
1992 - IRG/WP 92-3712
Extensive investigations have been conducted in recent years on the performance of chlorothalonil (tetrachloroisophthalonitrile) as a ground contact wood preservative. Efficacy information is presented on a soil block test with 11 Basidiomycetes, a fungus cellar evaluation, above-ground field testing against termites in Australia and Hawaii, and ground-contact field stakes installed in Florida (9 ...
P E Laks, T L Woods


Microbial decomposition of salt treated wood
1993 - IRG/WP 93-50001-22
Specialized microorganisms which are able to convert fixed inorganic preservatives from treated wood into water soluble components are investigated. A number of brown rot fungi like Antrodia vaillantii have been isolated from cases of damage and examined under unsterile conditions with CCA-, CCB-, CCF- and CC-treated wood at retention levels of at least 50% higher than recommended for wood in grou...
R-D Peek, I Stephan, H Leithoff


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