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Laboratory Studies on Copper Availability in Wood Treated with Soluble Amine Copper and Micronized Copper Systems
2008 - IRG/WP 08-30489
A laboratory method has been employed to investigate the level of soluble copper in wood treated with various copper-based preservative systems, such as micronized copper (particulate copper) and amine copper solutions. This report describes the methodology and preliminary results on determination of the soluble copper in the treating solutions and the treated wood by these systems, as well as th...
L Jin, P Walcheski, A Preston


Impregnación de durmientes de quebracho blanco (Aspidosperma quebracho blanco) con preservadores cromocuproarsenicales (CCA)
2008 - IRG/WP 08-40428
CCA impregnation of railroad ties is a recent process in Argentina which has not been optimized in a commercial scale. This study analyzed the influence of treatment pressure on final retentions to optimize the impregnation process. Results showed that a 3.2% m/v solution resulted in 10.8 kg/m3 CCA retention. At 1187 kPa (12 kgf/cm2) quebracho blanco wood had an average absorption of 338 l/m3. Als...
D Gherscovic, Z Cataldi, J M Languasco


Interactions between wood and propiconazole in supercritical carbon dioxide
2009 - IRG/WP 09-40461
Understanding the movement and deposition of biocides in wood is a fundamental aspect of the supercritical wood impregnation process and a key issue in developing the process e.g. to handle wood of larger dimensions. Previous research on supercritical wood impregnation frequently reports of a biocide concentration gradient in impregnated samples i.e. a lower concentration of biocides in the core o...
A W Kjellow, O Henriksen


Using plant oils as hydrophobic substances for wood protection
2010 - IRG/WP 10-30550
The increased interest to use oils as hydrophobic agents and the current debate about the further use of creosote emphasises the urgent need of better understanding of plant and other oils as wood protectors. The present study sheds light on the hydrophobic properties and distribution of various plant oils in the anatomical structure of Scots pine sapwood. Oil retentions from approximately 70 to 5...
D Panov, N Terziev, G Daniel


Sorption properties of wood impregnated with aqueous solution of boric acid and montan wax emulsion
2010 - IRG/WP 10-40492
Non-biocidal techniques for wood protection become more and more important, nowadays. One of the possible treatments is use of water repellents. In the present research influence of, one of the possible water repellent, the montan wax emulsion, on the moisturizing and the sorption characteristic of impregnated wood was investigated. To achieve a better protection against wood decay fungi, montan w...
B Lesar, M Humar


Preservative Treatment of simul (Bombax ceiba) Veneers with Hot and Cold Water Solution of borax-boric acid by Soaking Process
2010 - IRG/WP 10-40528
Veneers of simul (Bombax ceiba) were treated with different concentrations of water- borne preservatives borax-boric acid (BB) by soaking process for different time periods. In the case of hot water treatment, it was found that the average retention of preservative chemicals increased gradually with the increasing treatment period from 20 minutes to 60 minutes. Similar trend was observed in the ca...
K Akhter, Md Abul Hashem, S Akhter


Influence of wood swelling agents on penetration and copper leaching of copper-ethanolamine based wood preservatives
2011 - IRG/WP 11-30556
Copper ethanolamine based preservatives are currently the most important solutions for impregnation of wood in ground contact in Europe. One of the issues related to those and similar water based solutions is insufficient penetration to refractory wood species like Norway spruce. In order to elucidate this issue, commercial copper ethanolamine based solution was supplemented with five different wo...
M Humar, N Thaler, B Lesar


The potential of silicone-based formulations to enhance wood properties through industrial treatment for outdoor use
2011 - IRG/WP 11-30578
High hygroscopicity is one of the main weaknesses of wood as far as its susceptibility to biodegradation, and specifically to fungal decay. New wood preservation technologies are constantly entering the wood protection market, competing with traditional, biocide-based preservation. Silicones are commercially used as hydrophobic agents on stones and concrete. They belong to the restricted number of...
F Simon, F Marchal, F Pochon, M Kutnik, I Le Bayon


Effects of nano-silver on brittleness of heat-treated solid woods
2011 - IRG/WP 11-40572
The present study is aimed at the effect of heat-treatment of normal as well as nano-silver-impregnated Populus nigra, Populus deltoides, and Fagus orientalis on brittleness. Specimens were impregnated with 200 ppm water-based solution of nano-silver particles under 3 bars in a pressure vessel using empty-cell process. For heat treatment, both nano-silver-impregnated and normal specimens were kept...
H Reza Taghiyari, B Moradi Malek, A Karimi


Smart hydrogels from low molecular weight amphiphilic compounds: toward a solution to decrease leachability and increase efficacy of boron preservatives?
2012 - IRG/WP 12-30589
A new catanionic system associating amphiphilic carnosine (AlaHisC8) and lauric acid forms supramolecular hydrogel at very low concentration. This gel was investigated and we have checked the validity of the concept of hydrogels utilization to reduce boron leachability and to develop new wood protection treatments. Impregnation with 5% aqueous borax solution (w/w) and 0.3% gelator agent (...
F Obounou Akong, P Gérardin, C Gérardin-Charbonnier


Supercritical impregnation of wood with siloxane
2012 - IRG/WP 12-30595
This paper describes the effect of supercritical impregnation with siloxane on the water repellency of Scots pine (Pinus sylvestris) sapwood samples. Samples were impregnated with a low amount of siloxane dissolved in supercritical carbon dioxide using isopropanol as a co-solvent. Siloxane retention (i.e. weight percent gain (WPG)) of the treated samples was 1.3 % (w/w) as found by mass balance. T...
A Kjellow, F Imsgard, J Fernandes, O Henriksen, E Klaassen, R Wagner, J Delis


Study on the Effect of Combined Nanosilver-Hygrothermal Treatment on Wood Properties
2012 - IRG/WP 12-40581
In this study, the impregnation process with nanosilver solution, before hygrothermal treatment was carried out to investigate its effect on some physical and mechanical properties of Iranian beech (Fagus orientalis Lipsky) and Russian imported spruce (Picea abies). Wood specimens were impregnated with nanosilver solution (400ppm) in an impregnation tank under pressure of 0.25 Mpa, for 20 minutes....
G Rassam, H Reza Taghiyari, A Karimi, B Jamnani, M Ebrahimi


Effects of nano-wollastonite impregnation on fire resistance and dimensional stability of Poplar wood
2012 - IRG/WP 12-40595
The fire-retardant properties of Nano-Wollastonite (NW) in poplar wood (Populus nigra) were determined in this study. Some physical properties such as water absorption, volumetric swelling and Anti-Swelling Efficiency (ASE) were also measured. Specimens were prepared according to the ISO 11925 standard for the fire-retarding properties, and ASTM D4446-2002 standard for the physical properties. Imp...
A Karimi, A Haghighi Poshtir, H Reza Taghiyari, Y Hamzeh, A Akbar Enayati


The Effects of Industrial-Scale Heat Treatment and Impregnation with Boron Compounds on Water Uptake and Tangential Swelling of Some Wood Species
2012 - IRG/WP 12-40599
This study evaluated the effects of boron impregnation and heat treatment on water uptake and tangential swelling of spruce (Picea orientalis), pine (Pinus nigra), beech (Fagus orientalis) and poplar (Populus deltoides) wood species. The samples (10 x 5 x 40 - tangential x radial x longitudinal cm) were impregnated with 4 % boric acid and 4 % borax according to the ASTM D-1413 standard method. Aft...
A Can, S Yildiz, Ü C Yildiz


Environmental safeness of 60% and 72% concentrated CCA-C solution and paste for wood treatment
2012 - IRG/WP 12-50284
In this study 30-years practical and observational experience of the present author about using of 72% concentrated CCA-C paste for preparing treating solutions and for treating wooden poles, anchor logs and cross arms has revealed that the 60% concentrated CCA-C solution is superior to the 72% concentrated CCA-C paste regarding solubility, homogeneity, cleanliness, treatability, sludge formation,...
A K Lahiry


Study on the Effect of Combined Nanosilver-Hygrothermal Treatment on Wood Properties
2012 - IRG/WP 12-40581
In this study, the impregnation process with nanosilver solution, before hygrothermal treatment was carried out to investigate its effect on some physical and mechanical properties of Iranian beech (Fagus orientalis Lipsky) and imported Russian spruce (Picea abies). Wood specimens were impregnated with nanosilver solution (400ppm) in an impregnation tank under pressure of 0.25 Mpa, for 20 minutes....
G Rassam, H Reza Taghiyari, A Karimi, B Jamnani, M Ebrahimi


Hydrogels: a solution to reduce boron leachability without reduction of its biodisponibility to wood decaying fungi?
2012 - IRG/WP 12-30602
Products used today for wood protection must fulfill to more and more environmental constraints, such as being of low toxicity in answer to the Biocidal Product Directory, but also to involve waterborne treatments to limit rejection of volatile organic compounds in the atmosphere. Boron preservatives have been described as valuable alternatives for wood protection for non-ground contact applicatio...
F Obounou Akong, P Gérardin, M-F Thévenon, S Parant, C Gérardin-Charbonnier


Effect of preservative treatment on mechanical performance of round and square poles made of small diameter Scots pine
2012 - IRG/WP 12-40612
A growing proportion of harvested Scots pine (Pinus sylvestris L.) timber originates from the first or second commercial thinning stands. There is a need to find economically viable and high quality wood products that can be manufactured from this raw material. Small log volume means not only demands of increased efficiency for material handling in logistics and manufacturing processes, but also c...
V Möttönen, R Stöd, K Heikkilä, H Heräjärvi


Water absorption and desorption of non treated, pressure impregnated, and pine oil treated glulam made of small diameter Scots pine and Norway spruce
2012 - IRG/WP 12-40616
A growing proportion of harvested timber originates from the first or second commercial thinning stands in Finland, which means smaller average log volumes in comparison to final felling stands. Smaller log volume means challenging wood properties such as higher proportion of juvenile wood and sapwood. Due to these facts, products made of small diameter logs are prone to twist and check, and have ...
H Heräjärvi, V Möttönen, R Stöd


Developing Analytical Methods for Determination of Quaternary Ammonium Compounds (DDAC) using HPLC and HPLC-MS (Application to treating solution and preservatives treated wood)
2013 - IRG/WP 13-20516
Korea preservative treating industry has mainly used alkaline copper quaternary (ACQ) expected over 80% of market share in Korea. ACQ employs dodecyl dimethyl ammonium chloride (DDAC) and benzyl dimethyl dodecyl ammonium chloride (DBAC) for active ingredient along with copper. The strongly increasing domestic applications for wood preservatives require developing accurate and reproducible analytic...
Sung-Mo Kang, Kwon-Min Kim, Won-Mo Koo, Myeong-Won Cho


The effects of impregnation with secondary metabolite extracted from Ipe on durability of Japanese cedar and beech wood
2013 - IRG/WP 13-30618
Ipe wood is known for its high durability; it has been widely used in exterior structures that are exposed to the weather. In this paper, to increase the durability of less durable wood, Japanese cedar and beech specimens were impregnated with a secondary metabolite from Ipe. In a previous study, secondary metabolites extracted by a Soxhlet extraction method showed antifungal properties. Therefore...
T Iida, R Konuma, K Kawarada


Hygroscopicity of wood after polyethylene glycol (PEG) impregnation and/or heat treatment
2013 - IRG/WP 13-40623
The hygroscopicity of wood after polyethylene glycol (PEG) impregnation and/or heat treatment was investigated by testing the water uptake, equilibrium moisture content (EMC) at various relative humidity levels, and contact angle of the poplar wood surface. The results showed that: (1) At the first moment, the heat treatment at temperatures lower than 160 ℃ did not reduce the water uptake be...
Weiyue Xu Yuan Zhu, Jinzhen Cao


Field performance of wood impregnated with siloxanes using supercritical carbon dioxide
2013 - IRG/WP 13-40632
This paper presents preliminary results from a 13-month field test containing pine sapwood samples (Pinus sylvestris) impregnated with a mixture of siloxane and organic biocides using supercritical carbon dioxide as carrier. Samples were exposed above ground at a Danish field test site using matched non-treated sapwood controls for every treated sample. All samples were painted before exposure. Pi...
A Kjellow, F Imsgard, J Fernandes, R Wagner, J Delis


Combined effects of thermal modification and ACQ-D impregnation on properties of southern yellow pine wood
2013 - IRG/WP 13-40637
In this study, samples of southern yellow pine sapwood were first thermally modified and then treated by the alkaline copper quat-type D (ACQ-D) wood preservative. Two heating temperature (180℃ and 220℃) and two concentrations of ACQ-D solution (0.9% and 1.35%) were used in the experiments. The combined effects of thermal modification and ACQ-D on leaching performance, mechanical prope...
Wang Wang, Yuan Zhu, Jinzhen Cao


Effect of bio-resin from cashew nut shell liquid (CNSL) on decay resistance properties of wood
2013 - IRG/WP 13-40649
This study assesses the decay resistance properties of bio-resin modified wood against decay fungi of the Basidiomycota according to the EN 113 protocol. A bio-resin system was developed by ozonolysis process from cashew nut shell liquid (CNSL), a naturally occurring mixture of phenolics. Small wood blocks from sapwood of Scots pine (Pinus sylvestris), Obeche (Triplochiton scleroxylon) and Gmelina...
M Ashaduzzaman, M D Hale, V Tverezovskiy, G A Ormondroyd


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