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Comparison of the inhibitory effects of borate, germanate, tellurate, arsenite and arsenate on 6-phosphogluconate dehydrogenase
1991 - IRG/WP 1508
Sodium borate inhibits the enzymatic activity of many dehydrogenases, and it is thought that this is due to the complexation of the borate anion with the coenzyme nucleotide. It has been suggested in the past that complexation of this type, leading to enzyme inhibition and other biological effects, is responsible for the inhibition of fungal growth and consequently the protection of boron treated ...
J D Lloyd, D J Dickinson


Comments on leaching in view of accelerated testing
1977 - IRG/WP 294
We developed an accelerated test for leaching at elevated temperatures (75-85°C). This test was used for the examination of 11 preservative formulations containing Cu, Zn and As. The data obtained from these experiments were compared with data on some formulations tested by ASTM standard leaching test. The method consists in making a large surface to volume ratio of wood from a treated block by c...
J Rak


A comparison of analytical techniques
1995 - IRG/WP 95-20061
This paper compares carefully-controlled weight retentions and analysis by XRF, ICP, combustion methods and a new extraction procedure for the new preservative, Copper(II) Dimethyldithiocarbamate (CDDC). Various experimental parameters such as particle size and drying conditions were investigated. In general, the correlations between and among the procedures are very high. The extraction-colorimet...
A C Gallacher, C R McIntyre, M H Freeman, D K Stokes, W B Smith


Kerfing and center-boring reduce checking in CCA-treated slash pine posts
1997 - IRG/WP 97-40082
Single and double kerfing, center-boring and incising were applied to green, peeled, slash pine posts. Posts were air dried for ten weeks and assessed for the number of surface drying checks greater than 1.0 mm in width. Posts were then pressure treated with a chromated-copper-arsenate (CCA-C) preservative and exposed outdoors in a horizontal position. The number of surface weathering checks in th...
P D Evans, R Wingate-Hill, R B Cunningham


Preservative treatment of green timber by soaking in ammoniacal copper borate
1984 - IRG/WP 3292
Freshly sawn boards of radiata pine sapwood were preservative treated by soaking in ammoniacal copper borate. Optimum schedules were obtained by partially seasoning the boards for one week prior to treatment. This aided the absorption of preservative and reduced the required soaking time to approximately 2 hours. Complete boron penetration was obtained after one week of block storage under cover a...
P Vinden, A J McQuire


Development of software to automate the quantification of checking occurring in preservative treated wood exposed to weathering
2001 - IRG/WP 01-20228
Surface checking often disfigures the appearance of wood treated with water-borne preservatives and treatments designed to reduce such checking have been receiving increasing attention. Progress in this area has however been slowed by the lack of a method of rapidly and accurately quantifying checking at treated wood surfaces. A software package has therefore been developed which identifies, measu...
A G Christy, P D Evans


Microdistribution of Copper in Copper-Ethanolamine (Cu-EA) Treated Southern Yellow Pine (Pinus spp.) related to density distribution
2004 - IRG/WP 04-40270
The relationship between copper absorption and density distribution in wood cell walls was investigated in this study. The density distribution on layer level was obtained from two approaches: (1) calculation by using data obtained from literature; (2) microdistribution of carbon and oxygen atoms in the wood cell. The microdistribution of carbon and oxygen in untreated southern yellow pine (Pinus ...
Jinzhen Cao, D P Kamdem, E Pasek


Mechanical properties of CCA-treated southern pine after post-treatment kiln drying
1989 - IRG/WP 3543
This report reviews current research dealing with the effects of waterborne preservative treatment and redrying on the mechanical properties of wood. In general, waterborne preservative treatments reduce average mechanical properties. This effect is exaggerated when treated wood is kiln-dried after treatment, especially at elevated temperatures. For lumber, recently completed research at the Missi...
H M Barnes, J E Winandy


Investigation of CCA fixation in wood by sequential extraction. I Determination of CCA component fixation and preliminary extraction results
2002 - IRG/WP 02-50188
The fixation of CCA-C preservative was investigated in sapwood of red pine (Pinus resinosa Ait.), trembling aspen (Populus tremuloides Michx.) and red maple (Populus tremuloides Michx.) at target retentions of 4.0, 6.4, 9.6 and 30.0 kg/m3. Treated wood sawdust was water extracted at close time intervals during the fixation and analyzed for the contents of unfixed hexavalent chromium, total Cr, Cu ...
S Radivojevic, P A Cooper


Study of modulus of rupture, circumference taper, sapwood thickness and CCA treatment of Norwegian origin Pinus sylvestris poles
1994 - IRG/WP 94-20054
Nondestructive strength testing with Pilodyn (6J) of Norwegian Pinus sylvestris poles revealed effective modulus of rupture (MOR) of 54.39 N/mm² at wet conditions after CCA-C treatment and circumference measurement revealed circumference taper of 0.021 m/n. Sapwood thickness or penetration of CCA-C study revealed that 77% poles were with sapwood thickness equivalent to 39.6% of radius of poles an...
A K Lahiry, S Begum, G N M Ilias, M A B Fakir, R U Hafiz


Effect of post-treatment drying schedule on the modulus of elasticity of CCA-treated southern pine dimension stock using nondestructive methods
1987 - IRG/WP 3413
This paper describes the results from the nondestructive testing for modulus of elasticity (MOE) of southern pine (Pinus sp.) 2 x 6's treated with chromated copper arsenate and redried using three commercial kiln schedules. The data indicate that redrying CCA-treated southern pine dimension stock treated to above-ground retentions (4 kg/m³) has no deleterious effect on the MOE, regardles...
H M Barnes, S Moore


Evaluation of impact of CCA-treated wood on the marine environment
1995 - IRG/WP 95-50040-15
This paper reviews the literature relating to the potential of CCA-treated wood to affect the marine environment and outlines the compounds required for a model which could be used to predict the environemental impact of maritime construction using such timber. Marine pilings require high loadings of CCA to provide protection from marine borers. Though loadings of 32-48 kg/m³ provide long-term pr...
R M Albuquerque, S M Cragg


Evaluating the performance of wood preservatives against fungi
1974 - IRG/WP 247
A compilation is made of results published by various workers for agar/block laboratory tests of the effectiveness of wood preservatives against 11 species of wood destroying Basidiomycetes and one species of soft rot fungus. Preservatives include creosote, boron, metal/arsenic mixtures, metallic naphthenates, chlorinated naphthalene, chlorinated phenols and tri-n-butyl tin oxide. The results are ...
R Cockcroft


The Disposal of CCA-Treated Wood in Simulated Landfills: Potential Impacts
2003 - IRG/WP 03-50198
Landfills are typically where CCA-treated wood is currently disposed, and will likely continue to be the primary form of management in the future. It has been shown that arsenic, copper and chromium leach from CCA-treated wood in certain situations; however, the impact of the disposal of CCA-treated wood on landfill leachate is currently unknown. The objective of this research is to examine the po...
J Jambeck, T G Townsend, H M Solo-Gabriele


IRG/COIPM INTERNATIONAL MARINE TEST - to determine the effect of timber substrate on the effectiveness of water-borne salt preservatives in sea-water. Progress Report 11: Report of fourth inspection (3 years) in Italy
1981 - IRG/WP 471
The wood samples of Alstonia scholaris, Fagus sylvatica, Pinus sylvestris were submerged in the sea at Follonica, Italy, in Apri1 1977. Follonica, latitude 42°55' North and longitude 10°45' East, is situated on the Tyrrhenian coast. The recorded temperature varies from 13°C td 25°C, salinity 37- 38%. and pH about 8. The inspections were carried out after 6 months (10/1977), 1...
A Gambetta, E Orlandi


Environmental situations on wood preservation industries in Japan
1995 - IRG/WP 95-50040-21
Because of environmental civil oppinions, Ministry of Agriculture, Forestry and Fisheries in Japan, reviesed "the standards for sawn lumber" in 1994. For the possibilities of the use of preservatives out of CCA, by the using of the hazard levels, new products like ACQ, DDAC and emulsified zinc-naphthenate can be used in the standards. Since 1994, the permitable limit of the arsenic in the waste wa...
K Suzuki


Reappraisal of some fungicides by the amended JWPA method
1992 - IRG/WP 92-3689
Organoiodine compounds which have been commercialized these years in Japan poorly performed as fungicides in the amended JWPA decay test (Standard 1, 1989) when applied to superficial treatment of timber. Because some parts of active ingredients seemed to disappear from the treated timber surface mainly due to the severe leaching cycles. This was prominently true for beech (Fagus crenata Blume) sa...
K Tsunoda


Determination of bis-(N-cyclohexyl-diazeniumdioxy)-copper in different matrices by photometer, thermal energy analyzer and HPLC
1999 - IRG/WP 99-20179
For the quantitative analysis of bis (N-cyclohexyl-diazeniumdioxy)-copper (Cu-HDO) three analytical methods are used. The employment of the different methods depends on the matrices involved. For several years now, the colorimetric determination of Cu-HDO by photometer has been applied to solutions and concentrates of wood preservatives. In principle, the technique consists of a quantitative conve...
J Wittenzellner, W Hettler, M Maier


Plant uptake of CCA components from contaminated soil
1995 - IRG/WP 95-50043
The above ground portions of lettuce and rye grass grown in CCA contaminated soil collected at the base of CCA-C treated poles in service did not absorb appreciable amounts of copper, chromium and arsenic, even at soil concentrations above the recommended levels for soil remediation for agricultural uses. At high soil arsenic levels whole radish plants absorbed more As, but not the other elements....
P A Cooper, E Jasonek, J-P Aucoin


Untersuchungen zur Prüfung mit Moderfäulepilzen im Vermiculit-Eingrabe-Verfahren
1972 - IRG/WP 214
Im Hinblick auf die Entwicklung eines Prüfverfahrens für die Bestimmung der moderfäulewidrigen Wirksamkeit von Holzschutzmitteln wurden Versuche mit Reinzuchten von Pilzen und mit Vermiculit als Trägersubstanz sowohl mit unbehandelten als auch mit Schutzmittelgetränkten Holzproben durchgeführt. Dabei wurde die Eignung von handelsüblichen, eintachen Einweg-Kunststoffbechern anstelle der bish...
W Kerner-Gang, M Gersonde


Field fencepost tests of several species treated with water-borne preservatives by rural methods
1986 - IRG/WP 3385 E
Fencepost field results in ground-contact treated by rural methods: immersion-diffusion and sap displacement by evaporation are analyzed. Copper-chrome-arsenic and copper-fluor-chrome preservatives were used in two concentrations. The wooden species studied were: Pinus pinaster, Eucalyptus globulus and Quercus rubra. For each of the test units decay index evolution was analyzed after five years ex...
M V Baonza Merino


Occurrence and importance of various types of fungal and bacterial decay in CCA-treated horticultural pine posts in New Zealand
1984 - IRG/WP 1234
A detailed microscopical examination has been carried out on samples taken from CCA-treated pine posts exposed in horticultural soils. The following decay types were observed: white rot, brown rot, soft rot, tunnelling bacteria, cavitation bacteria, and bacterial erosion. The occurrence and importance of the various decay types between different regions, and plots within a specific region, varied ...
T Nilsson


The effect of concrete embedment on CCA treated hardwood and softwood timbers
1985 - IRG/WP 3340
Small size stakes of Eucalyptus maculata and Pinus elliottii were treated with CCA to various retentions and embedded in concrete collars containing varying amounts of a fungicide additive. During the 30 month trial period stakes were removed after 12, 18, 24 and 30 months and assessed for residual strength. Stakes which showed significant strength reductions were microscopically examined for the ...
L E Leightley, G A Willoughby


IRG test of preservative-treated hardwoods with particular reference to soft rot. Report on condition of specimens installed in Victoria, Australia
1984 - IRG/WP 3318
Over a third of the treated stakes involved in this test have been mechanically damaged. As many of these stakes broke off at or near groundline they could not be reinstalled. So they have been removed from the study despite most exhibiting little or no decay. Because of the mechanical damage to a substantial number of the treated stakes, we propose to terminate the CSIRO part of this study after ...
G C Johnson, J D Thornton


International comparison of three field methods for assessing the in-ground resistance of preservative-treated and untreated wood to termites and fungal decay – Summary of observations after five years
2003 - IRG/WP 03-20261
Results are presented from a five-year study conducted in five locations in Australia, Thailand and the USA. Three methods of exposure were assessed (below-ground, graveyard and ground contact) for evaluating the in-ground termite and decay resistance of Pinus radiata D. Don sapwood stakes that had been vacuum pressure impregnated with CCA (Type C) and ACQ (Type D) each at two nominal retentions (...
M Lenz, J W Creffield, T A Evans, B M Kard, C Vongkaluang, Y Sornnuwat, A F Preston


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