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Electrochemical deterioration of wood in sea-water
1981 - IRG/WP 464
In the specialistic literature only few items can be found dealing with the specific kind of wood deterioration called electrochemical corrosion of wood. This deterioration occurs predominantly on marine vessels, yachts, and other marine craft where wood is jointed by means of various metal connectors. Up to date information demonstrates that in wood surrounding copper connectors, when in proximit...
J Raczkowski


Hardwood Field Experiment: Progress Report 1977-1986
1986 - IRG/WP 3391
The international hardwood field experiment was planned in l976 and set up in same 30 different sites around the world. The test stakes include 4 reference species common to each site and in most cases at least 2 species of local importance. It was hoped that a picture of performance of a range of economically important species would be built up and at the same time provide vital background inform...
D J Dickinson, S M Gray


A diffusion and reaction model for the leaching of Cr-VI from unfixed CCA-treated wood
2001 - IRG/WP 01-50169
A physical model applicable to the leaching of any substance undergoing a first-order fixation reaction with wood is presented. Using this model and a laboratory leaching experiment with small wood samples immersed in water, the radial and tangential diffusion coefficients and the reaction rate constants of Cr-VI in unfixed CCA-treated red pine (Pinus resinosa Ait.) are measured. Reaction rate con...
L Waldron, P A Cooper


Leaching from field test stakes. Part 2: The distribution in and leaching from different parts of test stakes
1994 - IRG/WP 94-50026
Field test stakes treated with Boliden K33 (copper, chromium and arsenic) and Cuprinol Tryck (CT86) (copper and N-alkylbenzyldimethylammoniumchloride) respectively were exposed in ground contact at two different test fields in Sweden and rejected due to decay after 2 to 28 years. Stakes treated with the same preservatives were also exposed during 7 years above ground. The test stakes have been ana...
F G Evans, B Nossen, M-L Edlund


The multi-phase pressure (MPP) process. One-stage CCA treatment and accelerated fixation process - The process as a new concept in preservative treatment
1997 - IRG/WP 97-40078
The background to current commercial CCA treatment schedules used in New Zealand and fixation processing is reviewed. The limitations of these conventional practices with respect to treated product quality and CCA solution handling issues are defined. A novel, patented treatment schedule has been developed using a combination of hydraulic and pneumatic pressure phases and hot (~ 75°C) CCA solutio...
K Nasheri, A J Pendlebury, J A Drysdale, H Pearson, M E Hedley


Stake test with ammoniacal copper in combination with different agents started in 1962
1997 - IRG/WP 97-30130
In 1962 a stake test was started with ammoniacal copper in combination with chromium, arsenic, pentachlorophenol, boron, salicylic acid, benzoic acid, sorbic acid, pyridine and tannin. Different concentrations of the copper component were used as well as the added agents. For each concentration and test site, ten stakes of Pinus sylvestris L. sapwood were treated. The stakes were set out at two te...
B Häger, Ö Bergman


Performance of groundline bandage remedial treatments in western US species transmission poles
1993 - IRG/WP 93-30019
Groundline bandages are an important element in remedial treatment strategies for utility poles in the United States. Several bandages containing new or reformulated components have recently been developed but have not been adequately tested. This paper reports on the degree of diffusion of copper naphthenate, boron, and sodium fluoride from groundline bandages into pressuretreated Douglas-fir, po...
P G Forsyth, J J Morrell


Experiences with supervision schemes for treated timber in Denmark
1984 - IRG/WP 3315
Since 1967 a voluntary supervision scheme for vacuum-pressure treatment was established in Denmark. In 1976 the Nordic Wood Preservation Council - NWPC - established a scheme based on wood preservation classes for treated timber as a joint technical standard valid in Denmark, Finland, Norway and Sweden. This paper deals with inspection results over 17 years for CCA treatment within our organizatio...
J Sabroe


Comparison of the inhibitory effects of borate, germanate, tellurate, arsenite and arsenate on 6-phosphogluconate dehydrogenase
1991 - IRG/WP 1508
Sodium borate inhibits the enzymatic activity of many dehydrogenases, and it is thought that this is due to the complexation of the borate anion with the coenzyme nucleotide. It has been suggested in the past that complexation of this type, leading to enzyme inhibition and other biological effects, is responsible for the inhibition of fungal growth and consequently the protection of boron treated ...
J D Lloyd, D J Dickinson


Comments on leaching in view of accelerated testing
1977 - IRG/WP 294
We developed an accelerated test for leaching at elevated temperatures (75-85°C). This test was used for the examination of 11 preservative formulations containing Cu, Zn and As. The data obtained from these experiments were compared with data on some formulations tested by ASTM standard leaching test. The method consists in making a large surface to volume ratio of wood from a treated block by c...
J Rak


A comparison of analytical techniques
1995 - IRG/WP 95-20061
This paper compares carefully-controlled weight retentions and analysis by XRF, ICP, combustion methods and a new extraction procedure for the new preservative, Copper(II) Dimethyldithiocarbamate (CDDC). Various experimental parameters such as particle size and drying conditions were investigated. In general, the correlations between and among the procedures are very high. The extraction-colorimet...
A C Gallacher, C R McIntyre, M H Freeman, D K Stokes, W B Smith


Kerfing and center-boring reduce checking in CCA-treated slash pine posts
1997 - IRG/WP 97-40082
Single and double kerfing, center-boring and incising were applied to green, peeled, slash pine posts. Posts were air dried for ten weeks and assessed for the number of surface drying checks greater than 1.0 mm in width. Posts were then pressure treated with a chromated-copper-arsenate (CCA-C) preservative and exposed outdoors in a horizontal position. The number of surface weathering checks in th...
P D Evans, R Wingate-Hill, R B Cunningham


Preservative treatment of green timber by soaking in ammoniacal copper borate
1984 - IRG/WP 3292
Freshly sawn boards of radiata pine sapwood were preservative treated by soaking in ammoniacal copper borate. Optimum schedules were obtained by partially seasoning the boards for one week prior to treatment. This aided the absorption of preservative and reduced the required soaking time to approximately 2 hours. Complete boron penetration was obtained after one week of block storage under cover a...
P Vinden, A J McQuire


Development of software to automate the quantification of checking occurring in preservative treated wood exposed to weathering
2001 - IRG/WP 01-20228
Surface checking often disfigures the appearance of wood treated with water-borne preservatives and treatments designed to reduce such checking have been receiving increasing attention. Progress in this area has however been slowed by the lack of a method of rapidly and accurately quantifying checking at treated wood surfaces. A software package has therefore been developed which identifies, measu...
A G Christy, P D Evans


Microdistribution of Copper in Copper-Ethanolamine (Cu-EA) Treated Southern Yellow Pine (Pinus spp.) related to density distribution
2004 - IRG/WP 04-40270
The relationship between copper absorption and density distribution in wood cell walls was investigated in this study. The density distribution on layer level was obtained from two approaches: (1) calculation by using data obtained from literature; (2) microdistribution of carbon and oxygen atoms in the wood cell. The microdistribution of carbon and oxygen in untreated southern yellow pine (Pinus ...
Jinzhen Cao, D P Kamdem, E Pasek


Mechanical properties of CCA-treated southern pine after post-treatment kiln drying
1989 - IRG/WP 3543
This report reviews current research dealing with the effects of waterborne preservative treatment and redrying on the mechanical properties of wood. In general, waterborne preservative treatments reduce average mechanical properties. This effect is exaggerated when treated wood is kiln-dried after treatment, especially at elevated temperatures. For lumber, recently completed research at the Missi...
H M Barnes, J E Winandy


Investigation of CCA fixation in wood by sequential extraction. I Determination of CCA component fixation and preliminary extraction results
2002 - IRG/WP 02-50188
The fixation of CCA-C preservative was investigated in sapwood of red pine (Pinus resinosa Ait.), trembling aspen (Populus tremuloides Michx.) and red maple (Populus tremuloides Michx.) at target retentions of 4.0, 6.4, 9.6 and 30.0 kg/m3. Treated wood sawdust was water extracted at close time intervals during the fixation and analyzed for the contents of unfixed hexavalent chromium, total Cr, Cu ...
S Radivojevic, P A Cooper


Study of modulus of rupture, circumference taper, sapwood thickness and CCA treatment of Norwegian origin Pinus sylvestris poles
1994 - IRG/WP 94-20054
Nondestructive strength testing with Pilodyn (6J) of Norwegian Pinus sylvestris poles revealed effective modulus of rupture (MOR) of 54.39 N/mm² at wet conditions after CCA-C treatment and circumference measurement revealed circumference taper of 0.021 m/n. Sapwood thickness or penetration of CCA-C study revealed that 77% poles were with sapwood thickness equivalent to 39.6% of radius of poles an...
A K Lahiry, S Begum, G N M Ilias, M A B Fakir, R U Hafiz


Effect of post-treatment drying schedule on the modulus of elasticity of CCA-treated southern pine dimension stock using nondestructive methods
1987 - IRG/WP 3413
This paper describes the results from the nondestructive testing for modulus of elasticity (MOE) of southern pine (Pinus sp.) 2 x 6's treated with chromated copper arsenate and redried using three commercial kiln schedules. The data indicate that redrying CCA-treated southern pine dimension stock treated to above-ground retentions (4 kg/m³) has no deleterious effect on the MOE, regardles...
H M Barnes, S Moore


Evaluation of impact of CCA-treated wood on the marine environment
1995 - IRG/WP 95-50040-15
This paper reviews the literature relating to the potential of CCA-treated wood to affect the marine environment and outlines the compounds required for a model which could be used to predict the environemental impact of maritime construction using such timber. Marine pilings require high loadings of CCA to provide protection from marine borers. Though loadings of 32-48 kg/m³ provide long-term pr...
R M Albuquerque, S M Cragg


Evaluating the performance of wood preservatives against fungi
1974 - IRG/WP 247
A compilation is made of results published by various workers for agar/block laboratory tests of the effectiveness of wood preservatives against 11 species of wood destroying Basidiomycetes and one species of soft rot fungus. Preservatives include creosote, boron, metal/arsenic mixtures, metallic naphthenates, chlorinated naphthalene, chlorinated phenols and tri-n-butyl tin oxide. The results are ...
R Cockcroft


CCFZ, a new type of water-borne wood preservative for vacuum pressure impregnation
1991 - IRG/WP 3643
By combination of CCF-Salt types with zinchexafluorosilicate a remarkable improvement of efficacy is achieved. In the same time the ecotoxicoligical data become more save. As well as the efficacy against wood-destroying organisms (Basidiomycetes, Soft rot and Long horn beetle) the basic data to evaluate the ecotoxicological behaviour of a CCFZ-Salt are described and compared with the properties of...
W Metzner, D Seepe, H-W Wegen


The Disposal of CCA-Treated Wood in Simulated Landfills: Potential Impacts
2003 - IRG/WP 03-50198
Landfills are typically where CCA-treated wood is currently disposed, and will likely continue to be the primary form of management in the future. It has been shown that arsenic, copper and chromium leach from CCA-treated wood in certain situations; however, the impact of the disposal of CCA-treated wood on landfill leachate is currently unknown. The objective of this research is to examine the po...
J Jambeck, T G Townsend, H M Solo-Gabriele


IRG/COIPM INTERNATIONAL MARINE TEST - to determine the effect of timber substrate on the effectiveness of water-borne salt preservatives in sea-water. Progress Report 11: Report of fourth inspection (3 years) in Italy
1981 - IRG/WP 471
The wood samples of Alstonia scholaris, Fagus sylvatica, Pinus sylvestris were submerged in the sea at Follonica, Italy, in Apri1 1977. Follonica, latitude 42°55' North and longitude 10°45' East, is situated on the Tyrrhenian coast. The recorded temperature varies from 13°C td 25°C, salinity 37- 38%. and pH about 8. The inspections were carried out after 6 months (10/1977), 1...
A Gambetta, E Orlandi


Variable chlordane residues in soil surrounding houses in Louisiana
1989 - IRG/WP 1404
Eight soil samples from each of 30 houses in greater New Orleans, Louisiana were collected in October, 1986 and analyzed for chlordane residues (ppm). All houses had reportedly been treated in the late 1960's or early 1970's. Chlordane occurred in all samples, and the overall mean (+ SEM) was 870.6 + 96.5 ppm. Residue levels were unaffected by construction type (slab, crawl, craw...
J P La Fage, K S Delaplane


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