Your search resulted in 396 documents. Displaying 25 entries per page.
Detoxification of salt impregnated wood by organic acids in a pulping process
1993 - IRG/WP 93-50012
The paper descibes a novel method to detoxify pine wood (Pinus silvestris L.) treated with CCB-, CCF- CC-, and Cu-HDO-type salt preservatives. In the process of biological detoxification organic acids produced by strains of Antrodia vaillantii and other brown rot fungi are used for the dissolution of the previously fixed inorganic compounds. These findings are the basis for applying an acid pulpin...
I Stephan, H H Nimz, R D Peek
Copper based wood preservative - A new approach using fixation with resin acids of rosin
2000 - IRG/WP 00-30249
Copper soaps with carboxylic acid groups of resin acids of rosin were shown to be potential long-term wood preservatives. The principle involved is the attachment of copper to the network formed by the inorganic part of the preservative (rosin) through the -COOH groups. The mechanisms of fixation have been studied, and it has been shown that this association could be obtained : (1) by forming the ...
C Roussel, J P Haluk, A Pizzi, M-F Thévenon
Studies in an accelerated soil bed facility on the decay susceptibility of U.K. grown spruce and pine poles treated with copper/chrome/arsenic (CCA) by pressurised sap-displacement. Part 1: Setting up of soil beds and initial soft rot results
1990 - IRG/WP 2344
The paper describes the methodology used in the construction and early operation of an accelerated soil bed facility used to examine the decay susceptibility of U.K. grown Scots and Corsican pine and Sitka and Norway spruce treated with C.C.A. by high pressure sap-displacememt. The design and control of the facility as well as the preparation, soil exposure and soft rot decay analysis of quarter p...
A Bruce, S D Hainey, G M Smith, B King, P D Evans
A spectroscopic investigation of copper ethylenediamine fixation in wood
1999 - IRG/WP 99-20160
The fixation reaction which take place between copper ethylenediamine (Cu-en) solution and wood were expolored using X-ray photoelectron spectroscopy (XPS) and Fourier Transformed Infrared Spectroscopy (FTIR). The FTIR spectra revealed that copper reacts with the carboxylic acid and phenolic groups in wood to form stable complexes. The copper ethylenediamine complexes formed in wood were identifie...
Xiao Jiang, J N R Ruddick
The fixation of copper in Pinus sylvestris using the sodium salts of two polyhydroxycarboxylic acids
1992 - IRG/WP 92-3706
As part of the research concerned with the development of fixed, copper based preservatives, the salts of polyhydroxycarboxyIic acids, have been used in copper sequestration studies and fixation trials in Pinus sylvestris splinters. Selected compounds have been shown to be effective sequestrants at low concentrations allowing alkaline solutions to be formulated. Leaching trials following a 48 hour...
M Bacon, J A Cornfield
Free radical process controlled by manganese peroxidase and lipid-related metabolites produced by Ceriporiopsis subvermispora
2001 - IRG/WP 01-10412
Ceriporiopsis subvermispora, a specific lignin-degrading fungus produced free unsaturated fatty acids (USFAs) including 9,12-octadecaienoic asid, together with saturated fatty acids (SFAs) at an incipient stage of cultivation on wood meal cultures. In prolonged cultivation period after two weeks, the amount of intact fatty acids decreased with increasing in organic hydroperoxide and TBARS producti...
T Watanabe, M Enoki, S Sato, Y Honda, M Kuwahara, N Shirai, K Messner
Effect of leaching temperature and water acidity on the loss of metal elements from CCA treated timber in aquatic applications. Part 1: Laboratory scale investigation
1995 - IRG/WP 95-50046
In order to investigate the applicability of current prestandard leaching test methods, a series of experiments has been performed on CCA impregnated wood dealing with the influence of pH, temperature and agitation of the surrounding water. The leaching method used in this first part of the investigation is the European prestandard drafted by CEN/TC38/WG11, a short term dynamic leaching test under...
G M F Van Eetvelde, R J Orsler, G E Holland, M Stevens
Examination of preservative-treated Pinus sylvestris using electron paramagnetic resonance
1992 - IRG/WP 92-3710
EPR is currently being used to help elucidate the nature and extent of the chemical reactions occurring between wood and copper based timber preservatives. In the work reported here treated Scots pine samples were examined at room temperature and in the frozen state. Plots of the electronic parameters A|| vs. g|| were found to be a useful index of the electronic properties of the various formulati...
A S Hughes, R J Murphy, J F Gibson, A J Cornfield
Accelerated testing for out of ground contact using natural biological preconditioning: Part 2
1997 - IRG/WP 97-20108
Small blocks of scots pine sapwood were treated, buried in vermiculite and exposed to natural microbial colonisation during outdoor exposure prior to laboratory decay testing. An EN 84-type leach trial was carried out on unexposed samples. Periodic microbial isolations, moisture content, permeability and weight loss tests were also conducted. The experiment ran for 12 months. The colonisation of t...
S Molnar, D J Dickinson, R J Murphy
Influence of water soluble extractives on CCA fixation and leaching performance of red maple and red oak
1997 - IRG/WP 97-30133
We have observed several peculiarities in relation to CCA fixation in red maple and red oak woods such as high variability in fixation rates and leaching performance in maple and precipitate formation in solutions expressed from CCA treated red oak wood blocks at different stages of fixation. We have postulated that the extractives could be the factor of influence, as this has already been reporte...
T Stevanovic-Janezic, P A Cooper, Y T Ung
Preservative leaching from copper-chrome-arsenic treated timber: Towards an international standard for environmental monitoring
1996 - IRG/WP 96-50076
A review of standards and legislative requirements around the world relating to environmental contamination from copper-chrome-arsenic wood preservative indicates a plethora of methodologies for expressing and determining contamination levels. The imposition of arbitrary quarantine periods for treated timber, or special fixation processes, appear to be applied without a rational analysis of what l...
S Walley, P R S Cobham, P Vinden
Efficacy of Avermectin B1 dust and bait formulations in new simulated and accelerated field tests
1985 - IRG/WP 1257
Avermectin B1 on a silica carrier dust was used in dust and bait formulations whose efficacy against Reticulitermes flavipes was assessed in new simulated and accelerated field tests. A 0.5 mg avermectin/mg dust and a bait with 50 ppm avermectin in paper pulp sandwiched between pieces of corrugated boxboard caused nearly complete mortality in bioassays and suppression of foraging in field tests. T...
G R Esenther
Effects of pre-harvest girdling on selected properties of red pine, red maple and Eastern larch
1999 - IRG/WP 99-40137
Trees of three species - tamarack (Larix laricina), soft maple (Acer rubrum) and red pine (Pinus resinosa) - were girdled immediately below the crown,one to two years before felling. The wood from these trees was compared with wood taken from un-girdled control trees felled at the same. Sapwood and heartwood, from the controls, and from above and below the girdle of treated trees, were examined fo...
A Taylor, P A Cooper
A substantively bonded water repellent treatment based on chromium carboxylates
1985 - IRG/WP 3344
Chromium carboxylates soluble in toluene have been synthesised and applied to Scots pine (Pinus sylvestris) sapwood. Without any further treatment, the compounds may be readily leached from wood surfaces with toluene. After a period of heating however, they become fixed to the cell wall, substantial amounts being resistant to leaching even under reflux conditions for several hours. Treatment of wo...
J K Wright, W B Banks, W J Eilbeck
The effect of oil-borne preservative treatments on the shear strength of FRP/wood composite adhesive bonds
2003 - IRG/WP 03-40265
Reinforcement of structural wood components with Fiber Reinforced Polymer (FRP) will enhance the beam’s strength, but actual data on long-term durability is sparse, not well documented or not readily accessible. In this study, bond properties of FRP-wood composite materials were investigated following treatment with creosote or copper naphthenate preservatives. The properties investigated inclu...
B Herzog, B Goodell, R Lopez-Anido
The risk assessment process. Point of view of a biocide manufacturer [Évaluation du risque. Point de vue d'un fabricant de biocide]
1990 - IRG/WP 3568
Risk assessment is an inherent part of our everyday lives. The risk assessment equation combines Hazards and Exposure. For the Wood Preservation Industry, the hazards may be characterised by the toxicity a the ecotoxicity of chemicals and the exposure by the identification of exposed people, of the exposure routes and exposure frequency. To quantify the exposure, good co-operation is required betw...
D Baur
Relating CCA fixation to leaching of CCA components from treated products
1995 - IRG/WP 95-50045
The relationship between chromium fixation in CCA-C treated wood, as determined by CrVI analysis of solution expressed from treated wood and the leaching of Cu, Cr, As and CrVI in a simulated rain test are evaluated for dimension lumber (2"x6") and pole sections. Leachate concentrations after 2 hour exposure to a misting spray (about 300 mm cumulative rainfall) decrease rapidly with increased degr...
P A Cooper, R MacVicar, Y T Ung
A new process for in situ polymerization of vinyl monomers in wood to delay boron leaching
1998 - IRG/WP 98-40110
Efforts were accelerated on effective use of boron compounds in wood preservation owing to their environmentally safe characteristics and relatively low costs in addition to their well-known high bioactivity and fire resistant properties. Although having these unique favorable properties, they are readily leachable from treated wood at humid conditions. Therefore, they had limited market for exter...
M K Yalinkilic, W Dwianto, Y Imamura, M Takahashi
Creosote for wood preservation. (Reissued from earlier OECD draft)
1970 - IRG/WP III 1A
The literature on this subject is extensive and, to some extent, repetitive so that for pratical reference purposes it is essential that selective surveys and bibliographies be prepared. Many of these exist and, as an example, the reports issued by The Coal Tar Research Association (Numbers 0156, 0292 and 0396) may be quoted. The following bibliography, listing the more important sources of inform...
Anonymous
Kinetics and mechanism of fixation of Cu-Cr-As wood preservatives. Part 4: Conversion reactions during storage
1974 - IRG/WP 332
Precipitates simulating those produced in wood by preservative fixation reactions were prepared by the reduction of Boliden K 33 and Celcure AP solutions with hydrogen peroxide and hydrazine. The pH changes on aging at 20 and 50°C were studied and related to the chemistry of fixation previously described. Hydrolysis of copper arsenates may render arsenic acid temporarily water soluble pending pre...
S-E Dahlgren
Fixation of chromated wood preservatives through technical drying
1990 - IRG/WP 3623
Twin samples of sawn timber of Pinus sylvestris and Picea sp. were treated with copper-chromate-containing wood preservatives and subsequently kiln resp. air dried. After drying, the distribution of preservative and rate of fixation were determined. Drying of freshly treated wood in a condenser type kiln at temperatures of 60°C and 80°C and in a vacuum type kiln at 55°C with a pressure of about...
R-D Peek, H Klipp
Penetration of oil-borne preservatives in American elm
1975 - IRG/WP 355
Pressure treatment of elm posts and cants by Rueping schedules resulted in erratic penetration. Instead of the expected gradual decrease in retention from surface inward in posts, inner zones frequently contained more preservative than the surface quarter inch. Heartwood was found penetrated when sapwood was not. There were numerous skips in treated zones. The prevalence and possible causes were i...
E A Behr
Experimental variations in the distribution of CCA preservative in lignin and holocellulose as a function of treating conditions (temperature, concentration, pH, species, and time)
1984 - IRG/WP 3277
The exact distributions between lignin and holocellulose and retentions on wood of copper, chromium and arsenic as a function of various sets of conditions in a 3x3x4x2 factorial experiment in which combinations of three temperatures of treatment, three CCA solution concentrations, four pH's of the initial CCA solution and two timber species, namely Pinus radiata and Eucalyptus grandis, a...
A Pizzi, E Orovan, M Singmin, A Jansen, M C Vogel
Fixation and leaching characteristics of Douglas-fir treated with CCA-C
2004 - IRG/WP 04-50213
Fixation and leaching characteristics of CCA-treated Douglas-fir was evaluated using the expressate method and the AWPA E11-97 leaching procedure. CCA fixation, as monitored by the chromium reduction, was much faster in heartwood than in sapwood; however, copper and arsenic fixation in heartwood appeared to be incomplete regardless of the extension of fixation time. This poor fixation of copper a...
Gyu-Hyeok Kim, Yun-Sang Song, Dong-heub Lee
The effects of accelerated drying of green Pinus radiata on its attractiveness to Anobium punctatum as an egg-laying site
1984 - IRG/WP 1199
The methods and results are given for a series of experiments in drying Pinus radiata sapwood under a variety of conditions, then exposing the material to Anobium punctatum egg-laying. The results showed very clearly that the attractiveness of the wood to gravid females was drastically reduced when dried from green at temperatures much above 35°C. Both simple oven drying and steam kilning produce...
D J Cross