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A laboratory study on effect of coating materials on leaching of copper from CCA treated wood
2001 - IRG/WP 01-50176
Components of CCA preservatives can leach into surrounding soil and water and have some effect on germination and growth of some plants. In this report, the effect of coating materials in reducing chemical concentration in the leachate were evaluated. Rubber wood blocks (Hevea brasiliensis) treated with CCA were fixed at room temperature at high humidity. After air dried, they were painted with co...
A Veenin, T Veenin


Rainfall simulation to assess CCA permanence
1991 - IRG/WP 2373
During experimental work on accelerated fixation of chromium containing preservatives a method has been developed which compares the degree of preservative levels of contamination of simulated preservative fixation in timber with the levels of simulated rainfall. This method uses commercial sized wood sections wetted in a way that simulates actual rainfall and relates the associated run-off contam...
P Warburton, J A Cornfield


The effect of composition on the effectiveness and fixation of CCA and copper/chrome preservatives. Part 1: Effectiveness. Part 2: Selective absorption and fixation
1973 - IRG/WP 324
A preliminary study of a wide range of copper-chrome-arsenic formulations indicates that the most effective are in the region, CuSO4 · 5H2O - 35 to 45 per cent; K2Cr2O7 - 40 per cent and above; As2O5 · 2H2O - 25 to 15 per cent or less. Effectiveness appears to depend more on the copper content than the copper - arsenic. Observations on selective absorption and leaching suggest that the chromium ...
D N R Smith, A I Williams


The relationship between the electrical resistance and fixation of water-borne CCA salts and pressure-treated wood
1991 - IRG/WP 3657
Two investigations at 22°C and 30°C have been carried out. The electrical resistance in the treated wood and chemical analyses of the remaining amount of unfixed copper, chromium and arsenic were investigated. Samples impregnated with water were used as references. To hold the samples moist during the investigation, each sample was wrapped in a polyethylene plastic foil immediately after impregn...
F G Evans, B Nossen


Leachability of didecyldimethylammonium chloride (a quaternary ammonium compound) from four wood species
1982 - IRG/WP 3204
Sapwood blocks prepared from red pine, ponderosa pine, southern yellow pine and hem-fir (a commercial mixture of western hemlock and amabilis fir) were treated with didecyldimethylammonium chloride, (an alkylammonium compound, AAC). After oven drying the blocks were vacuum impregnated with distilled water and subjected to a static leach cycle for 48 hours. The leachate was analyzed and the amount ...
J N R Ruddick, A R H Sam


Effect of water repellents on leaching of CCA from treated fence and deck units - An update
1997 - IRG/WP 97-50086
In an earlier study, it was shown that CCA leaching losses could be reduced over an accelerated leaching and short term natural weathering exposures by post treatment application of a commercial water repellent. In this report, the effects of this coating and two commercial CCA solution water repellent additives are evaluated after two years of natural weathering. Wood boards were pressure treated...
P A Cooper, Y T Ung, R M Vicar


Susceptibility of CCA treated North American hardwoods to Chaetomium globosum decay
1998 - IRG/WP 98-10278
Seven species of hardwood, Beech (Fagus grandifolia), Basswood (Tilia americana), Maple (Acer rubrum), Oak (Quercus rubra), Trembling Aspen (Populus tremuloides), White birch (Betula papyrifera) and Yellow poplar (Liriodendron tulipifera) were vacuum or pressure impregnated with CCA, at four retention levels. The CCA was allowed to fix in the wood at 35°C. Red pine (Pinus resinosa) was also inclu...
U Srinivasan, Y T Ung, P A Cooper


Waterborne preservative treatability of tamarack (Larix laricina (Du Roi) K.Koch)
1998 - IRG/WP 98-40112
Eastern larch or tamarack (Larix laricina (Du Roi) K.Koch) lumber from New Brunswick, Canada was evaluated for preservative treatability with chromated copper arsenate (CCA-C) and ammoniacal copper arsenate (ACA). The fixation and leaching characteristics of CCA-C treated tamarack sapwood and heartwood were also evaluated. CCA-C penetration into both sapwood and heartwood was poor. ACA fully penet...
A Taylor, Y T Ung, P A Cooper


Kinetics and mechanism of fixation of Cu-Cr-As wood preservatives. Part 6: The length of the primary precipitation period
1975 - IRG/WP 359
The end of the primary precipitation fixation period of CCA preservatives coincides with the first peak in pH versus time. This offers a simple way of estimating the duration of the period. The duration is determined by a number of factors and their interactions, the most important of which are: wood species (anatomy, natural pH, accessibility of reducing agents), preservative type, preservative c...
S-E Dahlgren


Chromium in wood preservation: Health and environmental aspects
1978 - IRG/WP 3120
The majority of water-borne salts in current use contain hexavalent chromium, usually as dichromate or chromium trioxide. In about 1913 it was suggested that chromates, phosphates or borates could be added to the sodium fluoride and dinitrophenol mixtures then in use in order to inhibit corrosion. Dichromates were found to be most suitable and the resulting mixture known as Thriolith and later Tri...
T R G Cox, B A Richardson


Heat transfer and wood moisture effects in moderate temperature fixation of CCA treated wood
1994 - IRG/WP 94-40022
Practical aspects of heat transfer and fixation of wood exposed to drying conditions after CCA treatment are considered. The rates of heat transfer and CCA fixation are substantially influenced by the cooling effect of water evaporating from the wood surface when drying occurs during fixation. At least in the early stages of fixation, the wood temperature approaches the wet bulb temperature, rathe...
J Chen, M Kaldas, Y T Ung, P A Cooper


Difference of CCA efficacy among coniferous wood species
1990 - IRG/WP 3601
Wood blocks of Cryptomeria japonica, Tsuga heterophylla, and Pinus radiata successively extracted with n-hexane, ether, and methanol were treated with various concentrations of CCA type 3, which were subjected to the decay by Tyromyces palustris. The weight loss were different among species and kinds of extraction. Cryptomeria japonica treated with CCA had higher fungal resistance than Tsuga heter...
K Yamamoto, M Inoue


Fundamentals on steam fixation of chromated wood preservatives
1988 - IRG/WP 3483
Weathering of treated wood directly after impregnation leaches up to 2% of copper-chromate-containing wood preservatives. Almost total fixation of Cr+6 is achieved by steaming the treated wood at 100°C to 120°C, preferably 110°C. To initiate such spontaneous fixation 85°C to 90°C inside the wood are essential, which requires heating times ranging from 20 to 80 min, depending on timber species...
R-D Peek, H Willeitner


Termite resistance of Malaysian and exotic woods with plantation potential: Field evaluation
1998 - IRG/WP 98-10289
An in-ground resistance of selected Malaysian and exotic timbers to attack by a representative aggressive subterranean Coptotermes termite was evaluated as part of an on-going collaborative research between the Forest Research Institute of Malaysia and the University of Hawaii on termite control of building timbers under humid tropical conditions. A test site at FRIM, highly susceptible to the sub...
A H H Wong, J K Grace, L H Kirton


Leachabilty and efficacy of fatty acid derived boron esters as wood preservatives - leachability and efficacy of fatty acid derived boron esters as wood preservatives
2004 - IRG/WP 04-30351
Borates have many advantages as wood preservatives. However, boron is susceptible to depletion under humid conditions and this restricts its outdoor use. In order to reduce boron leachability in treated wood, one of the anticipative approaches is to use organic fixed boron-based preservatives. This study investigated the leachability of six boron ester compounds as potential preservatives. Scots p...
A Mohareb, J Van Acker, M Stevens


Performance of Two Imidacloprid-Treated Malaysian Hardwoods in an Accelerated Aboveground Termite Test
2005 - IRG/WP 05-30389
The performance of the chloronicotinyl insecticide imidacloprid as a wood protecting termiticide, under a simulated Malaysian biological hazard class H2 (exposure aboveground indoors against termites and wood borers), was evaluated by a novel termite field test protocol. Replicate end-grain sealed air dried test blocks (20 x 20 x 20 mm) of two Malaysian hardwoods, Kembang Semangkok (Scaphium spp.)...
A H H Wong


Leaching of preservative components from pine decking treated with CCA and copper azole, and interactions of leachates with soils
2001 - IRG/WP 01-50171
Radiata pine decking was treated with CCA and copper azole preservatives to Australian H3 retention using conventional and modified Bethel schedules, and air-dried. Treated decking boards and durable hardwood controls were subjected to leaching in weather-exposed decks, and matching 19mm cubes were leached in extended AWPA E11-97 lab tests. Deck runoff and E11 leachate water was analysed after rai...
M J Kennedy, P A Collins


Changes in fat and moisture contents, and nitrogen fixation in laboratory maintained termites
1984 - IRG/WP 1242
Orphaned groups of termites of Coptotermes acinaciformis and Mastotermes darwiniensis were maintained in the laboratory for several months on two dietary regimes, and changes in their fat contents, moisture contents and nitrogen fixation rates were examined. There were no significant feed or feed time effects for either species. For Coptotermes acinaciformis, there was a highly significant time ef...
J R J French, P J Robinson, L G Turner, P J Pahl


Leaching of active components from preservative-treated timber. Stages 2 & 3: Laboratory testing and comparison with semi-field testing
2004 - IRG/WP 04-20303
This part of the project is focussed on leaching from preservative-treated wood obtained by the laboratory test method CEN/OECD draft guideline, February 2003 ”OECD guideline for the testing of chemicals proposal for new guideline XXX. Estimation of Emissions from Preservative-treated Wood to the Environment: Laboratory Method for wood held in the storage yard after treatment and for wooden comm...
N Morsing, B Lindegaard


Accelerated diffusion treatment of sawn Sitka spruce grown in the UK
1986 - IRG/WP 3395
The treatment of 'green' sapwood and heartwood of Sitka spruce by diffusion methods was investigated. Steam/dip treatment processes gave increased solution uptakes and depths of penetration of copper in comparison with a simple dip treatment. Further investigation is required to reduce diffusion gradients with copper based formulations and to improve the penetration of '...
R J Murphy, D J Dickinson


Window test. Direct testing of wood resistance to decay: A study of its fitness, its reliability and its accelerating factor
1984 - IRG/WP 2219
This is the results of an experiment using the window-test specimens, exposing the specimens to three different types of testing procedure: 1. Natural infestation in the open air; 2. Artificial infestation and exposure in the open air; 3. Artificial infestation in a green-house. The results show good similiraties of the three parallel tests in term of decay, and assess the reliability of the windo...
G R Y Déon, L N Trong


Dimensional stabilization and decay resistance of wood treated with brown-rotted lignin and copper sulfate
1990 - IRG/WP 3608
The objective of this study was to evaluate the potential usefulness of brown-rotted lignin (BRL) as a dimensional stabilization and copper complexing agent for wood treatment. For dimensional stabilization, aqueous solutions of the lignin extract were combined with either copper sulfate, glyoxal or other additives. Anti-shrink efficiency (ASE) values as high as 42% were obtained with wood treated...
L Jin, D D Nicholas, T Schultz


Laboratory Evaluation and Field Trial of Chlorothalonil and Copper-based Preservatives and Leaching Performance of Copper in Copper Treated Wood
2002 - IRG/WP 02-30279
Soil block test and field trial of some Chinese plantation wood species pine and poplar treated with chlorothalonil formulations and copper-based preservatives such as ACQ-B and copper citrate (CC) were conducted. The results of soil block test indicated that chlorothalonil formulations and ACQ-B as well as CC are very effective for controlling the 2 fungi species Corious versicolor and Poria plac...
Mingliang Jiang, Ping Wang, Chungen Piao, Zhaobang Li, Quan Lu, Lei Liu


Accelerated termicidal performance data for new water-based copper linoleate formulations
1996 - IRG/WP 96-30104
An organic solvent based copper linoleate (Culin) has proved itself as an effective wood preservative in long term field trials in South Africa over a period of 30 years. Whilst the organic solvent based product offers good wood preservative performance, primary industrial interest has been in an emulsified version of the product. The objective of this study was to evaluate the influence of two di...
D Conradie, P Turner


Cyclic delamination analysis of preservative-treated wood/FRP interfaces
2002 - IRG/WP 02-40244
Wood preservative chemicals can interfere with adhesive properties when bonding wood laminates or wood/FRP (Fiber Reinforced Polymer) laminate composites. In this work we studied the effects of various wood preservative treatments, and pre- and post-treatment on wood/wood and wood/FRP bond durability using a severe cyclic delamination test (ASTM D-2559). Pre-treatment of individual laminates with ...
C Tascioglu, B Goodell, R Lopez-Anido


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