IRG Documents Database and Compendium


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Di-sodium fluorophosphate, a new fluorine containing, water-borne wood preservative
1986 - IRG/WP 3373
The physical, chemical properties of Di-sodiumfluorophosphate (Na2PO3F) are compared with those of a trade-mark SF-salt. The opposition of biological activity and toxicological data showed that Di-sodiumfluorophosphate may be a suitable alternative to SF-salts ( based on MgSiF6)....
D Seepe, W Metzner


Influence of aliphatic acids on spore germination of wood decay fungi
1984 - IRG/WP 2224
Influences of eight saturated fatty acids (C5-C10, C12 and C16) on spores of four isolates of wood decaying basidiomycetes (white rot fungi: Poria tenuis and Trametes hispida; brown rot fungus: Gloeophyllum trabeum [two isolates]) were observed in-vitro. Spore response after 24 hr on malt extract agar containing 10, 10² , or 10³ ppm of each fatty acid included: no effect on normal germination, d...
E L Schmidt


Rates of emission from CCA-treated wood in the marine environment: measurement, modelling and requirements for further research
2001 - IRG/WP 01-50166-12
Accurate estimates of rates of emission of leachate from preservative treated wood are crucial for realistic predictions of the environmental impact of its use in maritime construction. Estimates are available for some commonly used preservatives, but these vary widely. Though variable, these measurements suggest that emission generally decreases exponentially with time. Part of the variation is d...
S M Cragg, C J Brown, R A Albuquerque, R A Eaton


Report on marine borer attack on some timbers treated with CCA wood preservative and exposed for three months in sea-water
1985 - IRG/WP 4112
Destruction of timbers by marine borers has long been a problem for the coastal population of Thailand. The use of heavy durable timbers with frequent maintenance, or total replacement, is the only solution for fishermen with their fishing craft or marine installations, meanwhile wharves or other large scale constructions are usually made by using concrete pilings or concrete casings. In recogniti...
A Rananand, W Yoosukh, U Sittiphuprasert


The use of zirconium as an inert fixative for borates in preservation
2001 - IRG/WP 01-30256
Stand-alone borates have been used in internal protected situations as wood preservatives for about 60 years. They have not been deemed acceptable for external situations because of their leaching characteristics. Work carried out to reduce the leachability of borates has been reviewed briefly here, and a specific fixation agent based on zirconium has been tested in standard leaching and decay tes...
J D Lloyd, J L Fogel, A Vizel


Soil chemistry and wood decay
1978 - IRG/WP 2109
Soil is a most complex biological, chemical and physical material; its study is effectively a separate branch of science but almost entirely in relation to ist ability to grow plants - this paper is intendet just to note some known facets that might have relevance to the decay of wood and the performance of wood preservatives....
E A Hilditch


Autoxidation of beech condensate
2003 - IRG/WP 03-40261
Liquid effluent from steaming beech wood was studied. The effluent contains many phenolic compounds which can present a significant toxicity. The effluent was treated by oxidation was carried out at 250 rpm for 30 min with NaOH. This was followed flocculation with CaCl2 for 30 min. The influence of parameters such as pH, time of autoxidation were studied. Experimental results reveal the electrosta...
M Irmouli, J P Haluk


The Effect of Soil on the pH of Untreated Southern Pine in Ground Contact
2010 - IRG/WP 10-10742
Untreated southern yellow pine samples were subjected to three soils that had been amended to provide acidic, neutral and alkaline conditions. Wood pH was measured prior to, and then one, two, four and eight weeks after being placed in the soil to determine the effect of soil pH on wood pH....
C Vidrine, C Schauwecker, L Jin, A F Preston


The Effect of Soil pH on the pH of Treated Southern Pine in Ground Contact after 12 Months
2011 - IRG/WP 11-50281
Southern pine samples treated with soluble and particulate copper solutions were subjected to three soils that had been amended to provide acidic, neutral and alkaline conditions. Wood pH was measured prior to, and after 6 and 12 months after being placed in the soil to determine the effect of soil pH on wood pH....
L Jin, C Schauwecker, C Vidrine, P Walcheski, A Preston


The course of fixation of Cu-Cr-As wood preservatives
1972 - IRG/WP 307
Copper-chrome-arsenic (CCA) preservatives in contact with wood result in an instant extensive increase of pH, because of ion-exchange and adsorption reactions with the wood. During precipitation of the active elements the pH continuously increases but reaches a maximum, when all chrome is consumed. Some of the early reaction products are unstable and slowly convert via dissolution into stable comp...
S-E Dahlgren


Practical consequences of the clarification of the chemical mechanism of CCA fixation to wood
1983 - IRG/WP 3220
Practical consequences derived from the chemical investigation of the mechanism of fixation of CCA to the wood constituents are discussed. Among these, formulas for the calculation of the time of hexavalent chrome fixation are presented. Furthermore, three parameters are shown to be important to the long-term effectiveness of CCA-treated timber: (i) the temperature of treatment, (ii) the initial p...
A Pizzi


Kiln drying of CCA-treated wood - Some safety and environmental considerations
1987 - IRG/WP 3443
Vapours and condensate from a condenser kiln in which CCA-treated wood was being dried have been collected and analysed. The concentrations of arsenic, copper and chromium found in the vapours from the drying process were well below Swedish threshold limit values. The contents of arsenic and chromium were also low in the condensate, although the copper content was fairly high. The latter result wa...
J Jermer, B Lundberg


Selective chromate elimination from the storage-drainage-water of a wood impregnation plant
1980 - IRG/WP 3153
With the Enviro-Chrom-Ex process it is possible to eliminate ecologically and economically hexavalent chromium (chromate) from water selectively. The process which is based on the principle of selective ion exchange works with different chromate concentrations and under the presence of other ions, irrespective of the water hardness. The values of water-offtake reach 0.1 mg CrVI at maximum, causing...
O Wälchli, R Ott, R Hugener, E Graf, B Lieberherr


Biochemical relationships between biodegradation of cellulose and formation of oxalic acid in brown-rot wood decay
1991 - IRG/WP 1472
Non-enzymic hydrolysis of cellulose with low concentrations of oxalic acid was examined. The incubation of pine wood pulp with 1% oxalic acid (pH 1.3) at 35°C for 4 weeks reduced the original viscosity to 60%. Reducing sugars were liberated from various cellulosic samples by the oxalic acid treatment. However, crystallinities of cellulose in those samples did not change before and after the treat...
M Shimada, Y Akamatsu, A Ohta, M Takahashi


Discoloration of pressure impregnated wood caused by Amorphotheca resinae
1990 - IRG/WP 1438
Amorphotheca resinae Parbery with the anamorph Cladosporium resinae (Lindau) von Arx & de Vries is a cosmopolitan fungus known from aviation kerosene, hydrocarbon contaminated soil and creosoted timbers. In Denmark it causes heavy discoloration on wood treated with waterborne chromate-containing preservatives e.g. CCA-oxide type. The teleomorph produces small spherical fruitbodies widespread o...
F Rune, A P Koch


Kinetics and mechanism of fixation of Cu-Cr-As wood preservatives. Part 6: The length of the primary precipitation period
1975 - IRG/WP 359
The end of the primary precipitation fixation period of CCA preservatives coincides with the first peak in pH versus time. This offers a simple way of estimating the duration of the period. The duration is determined by a number of factors and their interactions, the most important of which are: wood species (anatomy, natural pH, accessibility of reducing agents), preservative type, preservative c...
S-E Dahlgren


Chemical Remediation of Beech Condensates
2004 - IRG/WP 04-50221
In the present work, The beech wood condensate are subsequently separated from the aqueous phase. Experimental results reveal the electrostatic interaction between the oppositely charged wood extracts after oxidation and Ca(OH)2. The influence of parameters such as pH, oxidation were studied. The increase in aqueous phase pH resulted in enhanced removal of wood extracts from water. The effect of p...
M Irmouli, J P Haluk


Effect of nutrient regimes, temperature, pH, and wood sterilization method on performance of selected bioprotectants against wood staining fungi
1992 - IRG/WP 92-1551
The effect of nutrient regimes, incubation temperature, media pH, and wood sterilization method on performance of four potential bioprotectants (Pseudomonas putida, Pseudomonas cepacia, Bacillus subtilis, and Trichoderma harzianum) against wood staining fungi were evaluated using small ponderosa pine samples over a four week period. Incubation at 32°C resulted in slight increases in the degree of...
J J Morrell, C M Secton


Chitosan for wood protection - state of the art
2005 - IRG/WP 05-30378
The aim of this paper was to give a state of the art description of chitosan as a wood protecting agent. Chitosan is a metal free natural compound derived from crustacean shells and is under evaluation as an environmentally benign wood protecting agent. Information from journals states that chitosan may act both fungistatically and at higher concentrations, as fungitoxic, but the mode of action is...
M Eikenes, G Alfredsen, E Larnøy, H Militz, B Kreber, C Chittenden


Differences in pH, electrical resistance, cation composition and NIR spectra of red spruce wood during early stages of brown rot degradation
2002 - IRG/WP 02-10449
Red spruce sapwood was exposed to degradation by the brown rot fungi Coniophora puteana, Postia placenta, Gloeophyllum trabeum and Serpula lacrymans for 0, 1, 2 or 3 weeks using a modified soil block assay design. Average weight losses over time ranged from 0-8.9% during this time period. Detectable changes in pH, electrical resistance and cation compostion were observed in the wood as early as 1 ...
J Jellison, S Kelley, B Goodell, D Hui, A Ostrofsky


Site characteristics impacting historic waterlogged wood: A review
2000 - IRG/WP 00-10344
Survival of waterlogged wood from hundreds and in rare cases millions of years presents scientists with a unique opportunity to examine wood specimens which, due to select properties of the wood itself and/or the depostional environment, have not been completely degraded. Although degradation patterns of various types of microbial wood decay have been studied in detail, the site parameters of the ...
B A Jordan, E L Schmidt


Extracellular mucilage (ECM) in wood decay basidiomycetes
2002 - IRG/WP 02-10439
The ability of wood decay basidiomycetes to produce extracellular mucilage (ECM) and its relationship with total biomass production is being investigated. Growth and ECM production by the brown-rot fungus Gloeophyllum trabeum (FPRL 108 N) and the white-rot fungus Coriolus versicolor (CTB 863 A) was assessed in liquid culture under different conditions and in the presence of the fungicide cyprocona...
D Vesentini, D J Dickinson, R J Murphy


Cation analysis of wood degraded by white and brown rot fungi
1992 - IRG/WP 92-1552
Changes in the concentrations and composition of cations within wood colonized by the brown-rot fungi Postia placenta and Gloeophyllum trabeum and the white-rot fungi Trametes versicolor and Phanaerochaete chrysosporium were analyzed using plasma emission and atomic absorption spectrophotometry. In degraded poplar wood significant decreases in pH and electrical resistance readings were observed as...
J Jellison, K C Smith, W T Shortle


Chemically modified tannin and tannin-copper complexes as preservatives for wood
2001 - IRG/WP 01-30271
The efficacy of Mimosa tannin, chemically modified tannin, and tannin-copper complexes as wood preservatives was studied. When the tannin-ammonia-CuCl2 solutions were impregnated into wood specimens in a one-step procedure, a large quantity of the tannin-copper complex was fixed in the specimens. Little of the complex was leached from specimens by a weathering treatment, and these specimens showed...
H Yamaguchi


Exclusion of anions from the wood cell wall
1991 - IRG/WP 3661
Anionic components of wood preservatives and fire retardants such, as arsenates and phosphates, equilibrate at much lower concentrations in the cell wall bound water than in the free solution in the cell lumens. A degree of anion exclusion is expected in wood, due to the Donnan membrane effect. Fixed anions in the wood cell wall, produced by pH-dependent dissociation of the weak acid groups in woo...
P A Cooper


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