IRG Documents Database and Compendium


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Addition of boron compounds and octanoic acid for improvement of biocidal properties and copper fixation at copper-ethanolamine based wood preservatives
2006 - IRG/WP 06-30408
Copper-ethanolamine based wood preservatives became important active substance (formulation) for wood protection, novelty. As copper itself can not ensure sufficient protection against wood destroying organisms and fixation in wood we combine it with other biocides like ethanolamine, boron and octanoic acid. This investigates were performance on spruce wood impregnated with different combination o...
F Pohleven, M Humar


Ionic liquids with organic and inorganic anions as highly active wood preservatives
2006 - IRG/WP 06-30411
Quaternary ammonium tetrafluoroborates, nitrates(V), propionates, acetates and formates with alkoxymethyl substituents were prepared and tested on wood destroying and sapstaining fungi. These new compounds are ionic liquids (ILs), which penetrate very well into Scot pine wood. Alkoxymethyldecyldimethylammonium tetrafluoroborates and nitrates(V) show better microbial activity against Coniophor...
J Zabielska-Matejuk, A Skrzypczak


Surface and system treatments of wood for outdoor use
2006 - IRG/WP 06-30412
The project “Surface and system treatment of wood for outdoor use” was initiated the summer 2001. The project evaluates environmentally friendly preservatives and water borne coating systems, to find the best protection for timber indented for outdoor use. The wood species selected as test material were pine and spruce. The different treatments were exposed in several outdoor accelerated tests...
B Jacobsen, F G Evans


Corrosiveness of metal by copper-based preservatives
2006 - IRG/WP 06-40329
The corrosive rates of 4 types of metal as well as epoxy-coated metal by a variety of preservatives derived from different copper source and ingredients were conducted in this paper. The main results shown that: CCA is less corrosive to red brass and Q235A steel than other copper formulations; Copper-based preservatives such as ACQ and copper azole derived from basic cupric carbonate or cupric hyd...
Ying Zhang, Mingliang Jiang


Accelerated assessment tests of new termiticides
2007 - IRG/WP 07-20353
One of the biological agents, which cause major damage to wood in Spain, is the subterranean termites. The systems used for controlling termites don’t eradicate them, and the products presently used to treat wood against them, due to their toxicity and their persistence in the environment, could be prohibited in the near future in Europe as consequence of the 98/8/EC Directive (usually called t...
M T Troya, M J Prieto, D Lorenzo, F Rubio


Current state of world standardization in the toxicometric methods for testing of wood preservatives
2007 - IRG/WP 07-20354
The paper presents an outline of the history of forming standardized toxicometric methods for testing of wood preservatives in the world during last 100 years. Numerous studies resulted in three main methods which are currently used for official and basis assessment of biocides: - agar-block method in Europe (EN 113); - soil-block method in the USA and Pacific countries (ASTM D 1413); - modifi...
J Wazny


Detecting fungal DNA in treated and non-treated wood
2007 - IRG/WP 07-10621
Isolating fungi from wood has long involved culturing on selective media followed by identification using various keys. This process can be cumbersome, costly, and, most importantly, not always capable of detecting all of the fungi present. The recent development of molecular methods for isolation and identification of fungi has created tremendous opportunities for expanding our knowledge of the...
C Freitag, M Freitag, J Morrell


Accelerated Above-ground Testing of Wood Preservatives
2007 - IRG/WP 07-20358
The Canadian wood preservation industry is interested the introduction of new preservative formulations, some of which are intended only for above ground uses. Canada’s Pest Management Regulatory Agency requires data from field tests under Canadian conditions but these can take many years to generate results. Forintek has therefore developed an accelerated above ground test, under contract to a ...
P I Morris, S McFarling


Use of the Digital Refractometer for the On-site Analysis of Copper-based Preservative Systems
2007 - IRG/WP 07-20371
In some counties, there are no on-site chemical analysis methods available for treatment plants to use to determine the key active ingredients in the preservative treatment solutions. The complexity of the sophisticated methodology; cost of analytical instruments and training required for operating these instruments in treating plant level are the reasons for lacking such practice. In this paper...
L Jin, T Cashman, A Preston, J Trompetter, H Trompetter


Synthesis of boric acid ammonium oleate salt for wood preservation: Leachability and termite resistance test
2007 - IRG/WP 07-30435
A new chemical compound coupling boric acid and oleic acid through a joint of ammonium salt has been produced and its synthesis followed and validated by Fourier Transformed Infra Red (FTIR). This compound named ammonium borate oleate (BAO) combining biocidal properties of boron and water repellence of fatty acids has then been studied as a wood preservative. Synthesis of BAO involved different...
F Lyon, A Pizzi, Y Imamura, M F Thevenon, S N Kartal, J Gril


Bamboo Protection Research: Contributions from India
2007 - IRG/WP 07-40355
Bamboo preservation has become more important in India because of Government’s directions to develop bamboo resources and adopt their rational utilization to conserve natural forests. This paper traces the development of various processes for treatment of bamboo and their effectiveness. Results obtained by various workers since 1947 when systematic work on bamboo protection was first published. ...
S Kumar


Water repellency and dimensional stabilIty of wodd treated with waterborne resin acids/TOR
2007 - IRG/WP 07-40364
Wood used in above ground applications such as decking undergoes undesired dimensional changes leading to the lumber warping, cupping, splitting, etc. This is a major concern to consumers but it can be reduced by treating lumber with a water repellent. The ability of resin acids, hydrophobic compounds naturally present in southern yellow pines, was examined as a possible water repellent. A wate...
T P Schultz, D D Nicholas, J Shi


Refinement of emission values for preserved wood in the ‘Storage Scenario’, for use in the environmental risk assessment of Wood Preservatives under the Biocidal Products Directive
2007 - IRG/WP 07-50244
The evaluation of an active substance or a biocidal product under the Biocidal Products Directive (BPD) requires that an environmental risk assessment is carried out. The risk assessment for wood preservatives includes a scenario for the treated wood in storage after treatment, in which the predicted environmental concentration (PEC) in soil, surface water and groundwater is calculated, using emis...
E F Baines


Evaluatiang the potency of cinnamaldehyde as a natural wood preservatives
2007 - IRG/WP 07-30444
Since cinnamaldehyde, the major constituent of leaf essential oil from Cinnamomum osmophloeum, has significant antifungal and antitermitic activities, it is worthy of understanding whether cinnamaldehyde has potential to be used as a natural preservative for improving the durability of wood. In this study, the fungi and termite resistance of cinnamaldehyde-treated wood (CTW) were evaluated accordi...
Chun-Ya Lin, Chi-Lin Wu, Shang-Tzen Chang


Evaluation and identification of extractives from Iranian walnut (Juglans regia L.) by GC/MS technique for protection of non-decay resistant species
2008 - IRG/WP 08-10670
The use of walnut extractives is interest as environment friendly wood preservatives in the wood preservation industry. In this study, organic solvents were used to remove extractives from Iranian walnut heartwood samples. The solvent was removed by rotoevaporation, and Identification of chemical compounds in the Walnut extractives was done by using GC/MS technique. The toxicity of various extract...
S K H Hashemi, D Parsapajouh, H Khademi Eslam


Validity of above ground testing according to ENV 12037
2008 - IRG/WP 08-20379
The standard ENV 12037 for testing of treated and untreated wood (lap-joint) exposed above ground was issued in 1996 by The European Committee for Standardization. A draft for the development of the standard was presented by CEN-TC 38/WG 25/DOC N 076 in 2002. For a test to become valid the median rating of decay for untreated control replicates (Scots pine sapwood) must be equal or greater than ...
Ö Bergman, U Råberg, N Terziev


Development of a Weatherometer to Accelerate the Surface Checking of Wood
2008 - IRG/WP 08-20388
There is significant interest in developing preservatives that are better at preventing wood from checking. Currently, however, there is no accepted test methodology for accelerating the development of checks in wood samples so information on the effectiveness of treatments at restricting checking can be obtained more quickly. This paper describes the development of a new type of weatherometer (Ac...
R Ratu, P D Evans


Field Stake Tests with Copper-based Preservatives
2008 - IRG/WP 08-30459
The performance of field test stakes derived from commercially produced ground contact retention copper quat preservatives based on either soluble copper complexed with ethanolamine, or from a water-based suspension of particulate micronized copper compounds, as well as untreated southern yellow pine controls, is compared at two decay test sites. After less than one year in field test some of t...
A Preston, L Jin, D Nicholas, A Zahora, P Walcheski, K Archer, T Schultz


Effect of amphiphilic antioxidant alkyl ammonium ascorbate on inhibition of fungal growth: Application to wood preservatives formulation
2008 - IRG/WP 08-30466
Amphiphilic surfactants were synthesized from ascorbic acid and different fatty amines and evaluated for formulation of wood preservation products. Characterization of physicochemical properties of the new compounds indicated classical behavior of cationic surfactants. Antioxidant properties, estimated using methyl linoleate oxidation inhibition method, were similar to that of ascorbic acid teste...
C Gérardin , T Koumbi Mounanga, P Gérardin


The role of chromium in wood preservatives under BPD - a review and the current situation in Europe
2008 - IRG/WP 08-30468
Already during the IRG-meeting in Trømso a paper was presented to give an overview regarding the situation on chromium (JÜNGEL et al. 2006). Already in that year there was an increased attempt to achieve a science-based correct and harmonised solution in Europe regarding the chromium-question by the European Commission. Nevertheless the competent authorities (CAs) and the industry were similarly...
P Jüngel, S Hellkamp


The Comparison of Fixation and Leachability of Bark, Fruit and Leaf Tannin Extracts with Boron Minerals
2008 - IRG/WP 08-30473
Tannins extracted from several plants have natural durability properties. Due to these properties, some of the researchers have studied them for protecting wood. In this study, Scots pine (Pinus sylvestris) and beech (Fagus orientalis) wood samples were treated with bark, fruit, and leaf extracts as well as water-based wood preservative salts at various concentrations to increase fixation. The pen...
S Sen, C Tascioglu, K Tirak


Near infrared spectroscopy for the quantification of wood preservatives
2008 - IRG/WP 08-20391
Near infrared (NIR) spectroscopy is a rapid, flexible, inexpensive and non-destructive technology that has many applications, including the evaluation of many wood properties. Initial studies have indicated the potential to apply NIRS for the quantification of wood preservatives. However, further evaluation with borate and azole preservative systems has revealed that NIRS technology is challenged ...
A M Taylor, Seung H Baek, Myong K Jeong, J D Lloyd, J J Morrell


Field Stake Performance of Parallel Strand Lumber Treated with Waterborne Copper Naphthenate
2008 - IRG/WP 08-40435
Wood and wood products have been considered a premium building material for residential and industrial structures for many centuries. More recently, structural composite lumber (SCL) products have played an increasing role in satisfying the needs of the building industry. However, both wood and wood composites are naturally biodegradable materials which require enhanced durability when used in ce...
G P Merrick, M H Freeman, J A Brient


Wood preservative obtained by recycling – preliminary selection of leaching inhibitor
2008 - IRG/WP 08-50252
Based on recycling of used household batteries, a process was developed to enable the recovery of major manufacturing components, leading to a solution of zinc (32 g.l-1) and manganese (15 g.l-1) salts, free of heavy metals. The potential use of the above solution as wood preservative was demonstrated by means of assays both of fungicidal activity -using white and brown rot fungi- and of insectici...
C Ibáñez, C Mantero, G Cecchetto, M Rabinovich, M Cerdeiras


Comparison of laboratory and natural exposure leaching of copper from wood treated with three wood preservatives
2008 - IRG/WP 08-50258
Standard and non-standard laboratory and field leaching tests were used to compare copper leaching from wood treated to above ground and ground contact specified retentions for three wood preservative systems, CCA-C, ACQ-D and a micronized copper formulation with quat DDAC as co-biocide. Copper leaching was highest for the ACQ formulation. Percent leaching was lowest for the micronized copper sy...
P A Cooper, Y T Ung


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