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Properties of plywood and Oriented Strand Board manufactured with an organic insecticide incorporated in the adhesive formulation
2000 - IRG/WP 00-40174
The efficacy of Fipronil as an insecticide has been established by laboratory and field experiments and commercial use against a broad range of insect pests for various crops. It can be used by either foliar or soil application. Development is underway for the non-agricultural uses of fipronil. Research is ongoing for the control of ants, cockroaches, fleas, ticks, houseflies, mosquitoes, termites...
D P Kamdem, J H Hope, A Jermannaud


The environmental chemistry of chromium: Science vs. U.S. law
1993 - IRG/WP 93-50014
The cooperation which existed among chromium chemical producers, industrial health laboratories, and governmet agencies was destroyed after 1970 by the advent of environmental activism and regulatory legislation. As prewar plants had been found to pose a serious cancer risk, this fact was the basis of EPA regulations, especially during the term of Joe Califano in HEW under Jimmy Carter. However, a...
W H Hartford


Natural exposure weathering tests: Their role in the assessment of wood preservative efficacy
1993 - IRG/WP 93-20006
Previous work has demonstrated the potential and usefulness of natural ageing procedures in e evaluation of wood preservative efficacy. This results from the combination of physico-chemical influences and microbiological interactions with both substrate and wood preservative. In this paper, results are presented for a range of biocide types. Discussions are centred on the value of natural exposure...
G R Williams, J Brown


Improvement of some technological and biological properties of poplar wood by impregnation with aqueous macromolecular compounds
1992 - IRG/WP 92-3721
Poplars (Populus spp) belong to the most important tree species in afforestation programs of the Netherlands. Due to their rapid growth, the wood quality is usually low. Therefore, studies were performed to elucidate whether some technological properties and the resistance against fungal attack could be improved by impregnation with water-soluble resins. The results showed that swelling and shrink...
R D Peek, H Militz, J J Kettenis


The compatability of tributyltin fungicides and synthetic pyrethroid insecticides as wood preservatives
1987 - IRG/WP 3414
The stability of three synthetic pyrethroids, cypermethrin, deltamethrin and permethrin, to selected tributyltin compounds, Bu3SnX {where X = OSnBu3, Cl, 02CC6H5, O2C (Naphthenyl), OSO2Et}, (Bu3SnO)3PO and {NBu4} {Bu3SnCl2}, in toluene solution was investigated by infra-red spectroscopy over a six month period. It was found that only (Bu3Sn)2O reacted with the pyrethroids and that their order of r...
S J Blunden, R Hill


Contradiction between uptake of preservative in practical situation and laboratory testing
1992 - IRG/WP 92-2392
By brush treatment water- and solvent-based products were applied on boards of Scots pine and Norway spruce to achieve an uptake of 100 and 200 g/ml. In addition the scope of work to achieve the required uptake of preservative was determined under practical conditions for both product groups. EN 113 (RAL-GZ 830) tests were carried out to test the biological efficacy of products. After 18 months ex...
R Gründlinger, O Janotta, M Melzer


The fungal degradation of quaternary ammonium compounds in wood
1998 - IRG/WP 98-10263
This work focuses on the biodegradation of didecyldimethylammonium chloride (DDAC) by the mould fungus Gliocladium roseum within a woody matrix. Three sawdust types, distinguished by their treatment and amount of DDAC retained, were inoculated with the fungus and their DDAC loss was measured over 11 weeks. The rates of degradation varied depending on the sawdust; however, a significant loss of DDA...
J W Dubois, J N R Ruddick


Protection of rubberwood with modified creosote
1998 - IRG/WP 98-30165
Creosote is a renowned wood preservative but has certain disadvantages like obnoxius odour and colour, with its unpaintability and bleeding from wood surface may create environmental hazards. An effort has been made to isolate chemical fractions from creosote to obtain clean odourless preservative formulations by subjecting to steam distillation (SVC). Rubberwood treated with SVC and tested for it...
H C Nagaveni, H S Ananthapadmanabha, G Vijayalakshmi, M N Sharma, K H Shankaranarayana


In situ timber treatments by spraying. Distribution of preservative in wood
1991 - IRG/WP 3678
This study was carried out in order to make the Pest Control Operators able to achieve correct treatments and enhance their efficacy. It was carried out in two steps: 1) in laboratory, to learn the influence of various parameters like spraying pressure, use of repeated applications, distance from nozzle to wood; 2) in situ on roof timber of five buildings. In this case, the applications of the pre...
C Defoin, G Dupont, M Lamour, H Sageot, M-M Serment


Studies on the mobility of arsenic, copper and chromium in CCA-contaminated soil
1990 - IRG/WP 3571
CCA contaminated soils from six Swedish preservation plants were investigated primarily to study the mobility of arsenic but also that of copper and chromium in the soils. The soil samples represented average types with different amounts of clay, organic matter, arsenic, copper, chromium and different pH. The total soluble amounts of the elements were measured. The pH dependent solubility and the ...
J Bergholm


Field testing of alkylammonium wood preservatives
1983 - IRG/WP 3248
The field test performance of five alkylammonium wood preservatives is described. The relative effectiveness of three unmodified formulations was determined by calculation of a Performance Index. Of the three, didecyldimethylammonium chloride was found to be superior to octyldecyldimethylammonium chloride, and both were more effective than alkyltrimethylammonium chloride. However, none were consid...
J N R Ruddick


Leaching characteristics, decay and termite resistance of treated wood with boron compounds, N'-N-(1,8-Naphthalyl) hydroxylamine (NHA-Na), and hydroxynaphthalimide (NHA-H)
2003 - IRG/WP 03-30307
Despite many advantages of boron wood preservatives, boron itself does not adequately protect wood in ground contact and exterior applications because its natural diffusibility and susceptibility to leaching. As a result of previous studies to limit or decrease boron leaching, several fixation systems have been developed. In this study, we evaluated the effects of N'-N-(1, 8-Naphthalyl) h...
S N Kartal, Y Imamura


Behaviour of some selective Indian species towards treatment with solvent based water repellent preservative
1984 - IRG/WP 3309
This paper discusses a solvent based preservative using PCP and a water repellent for preserving three species of timber commonly used in India for the manufacture of doors and windows. It examines the method of treatment to achieve desired levels of penetration and retention of the preservative-cum-water repellent, and tests made on these timbers to examine the success of the processing methods a...
V R Sonti, B Chatterjee


Bait box technique for remedial subterranean termite contro
1995 - IRG/WP 95-10115
The bait box technique, as described in this paper, was first used as a method to apply the dust toxicant, arsenic trioxide, to large numbers of aggregated subterranean termites. Over the last twelve years or so the technique has been refined, and in recent years, gained acceptance as an alternative subterranean termite control measure by members of the Australian pest control industry. This baiti...
J R J French, B M Ahmed, D M Ewart


Solvent extraction of CCA-C from out-of-service wood
1998 - IRG/WP 98-50107
Elimination of CCA from decommissioned wood prior to disposal is a major environmental issue. One approach is to extract CCA from treated wood, then reuse the 'clean' (may contain CCA, but below hazardous level) wood materials for manufacturing wood-based composites. In the present paper, we focus on effective leaching processes, selection of leaching agents and optimum leaching ...
K M F Kazi, P A Cooper


Isolation of soil borne bacteria and fungi from treated timber
2001 - IRG/WP 01-50174
Most research in the last few decades has focused on the development of new strategies to control biological attack and the means to quantify this. Comparatively little work has been done to examine the effect that treated timber might have on its surrounding environment. This presentation will describe a methodology that attempts to detect any changes which might occur in the soil microflora foll...
I Stephan, A Stegemann, G Heidrich


Degradation of lignin model compounds with coordinated copper in the presence of peroxide
1998 - IRG/WP 98-10282
A novel diffusible system capable of decomposing lignin model compounds with copper, coordinators and peroxides has been proposed. When pyridine was used as a copper coordinator, two synthetic dyes, Poly-R and RBBR were intensively decolorized with Cu(II) and H2O2 in aqueous solutions at room temperature. Although reactions with Cu(II) and H2O2 produce a strong oxidant, hydroxyl radical, via a Fen...
K Koller, K Messner, T Watanabe


Effect of boron compounds-furfuryl alcohol treatment of wood on dimensional stability, termite resistance and boron leachability
2001 - IRG/WP 01-40195
Sapwood blocks of Japanese cedar (Cryptomeria japonica) and Caribbean pitch pine (Pinus caribaea) measuring 20 (tangential) x 20 (radial) x 10 (longitudinal) mm were impregnated with furfuryl alcohol (FFA) by a vacuum-diffusion process followed by curing under heating. Boron compounds (boric acid, ammonium borate and ammonium biborate) were mixed in the impregnation solution of FFA. Anti- swelling...
S K Ozaki, M K Yalinkilic, Y Imamura, M F Souza


Fungitoxic effect of the quaternary ammonium compounds preservatives against Basidiomycetes by using agar-plate and agar-block methods
1996 - IRG/WP 96-30118
Results of investigations on the fungitoxic value of three versions of wood preservatives based on the quaternary ammonium compounds (lauryldimethylbenzylammonium chloride, lauryldimethyl-benzylammonium bromide and alkylbenzyldimethylammonium chloride) and borates in relation to the wood destroying fungi have been presented. The agar-plate (screening) and agar-block method were applied. A wide ran...
J Wazny, P Rudniewski


Extracellular hydrogen peroxide producing and hydrogen peroxide reducing compounds of wood decay fungi
1991 - IRG/WP 1516
Extracellular H2O2-producing and H2O2-reducing compounds were isolated from wood-containing cultures of all the white-rot and brown-rot fungi and Ascomycetes which well degraded wood, but were not detected in the culture of the fungi which degraded little wood. The compounds are glycopeptides with a low molecular weight, require H2O2 for one-electron oxidation, catalyze the redox reaction between ...
A Enoki, G Fuse, H Tanaka


An evaluation of the synthetic pyrethroid cypermethrin in organic solvent and emulsion formulations
1984 - IRG/WP 3290
The studies reported indicate that cypermethrin (NRDC 149) has considerable potential as an insecticide for wood preservatives. Cypermethrin appears to be about twice as effective as permethrin. The effectiveness of cypermethrin compared with g-HCH varies depending on the insect species, the phase of the life cycle and size of larva: for example, against mature Anobium larvae cypermethrin is appro...
S J Read, R W Berry


Toxic value estimation of wood preservatives by using the probit analysis
1990 - IRG/WP 2348
As it was assumed from previous experiments, the probit analysis appears to be the most suitable method of all used to estimate the toxic value of wood preservatives. With the help of the classical agar-block method the probit analysis was tested for its suitability in: 1) fungitoxic value estimation of the WR-3 preservative (quaternary ammonium compound + borate), as compared to different test fu...
J Wazny, K J Krajewski


Incomplete fixation of chromium in the pre-treated wood with a solution of copper and arsenic compounds
1995 - IRG/WP 95-50052
Ponderosa pine wood thin sections were treated with a combination of chromium, copper, and arsenic chemicals. The wood sections was analyzed by electron spin resonance spectrometry (ESR) and X-ray photoelectron spectrometry (XPS) to elucidate the mechanism of fixation of the chromated-copper preservatives. The wood subjected to the two-step treatment with copper and arsenic followed by chromium ex...
J N R Ruddick, K Yamamoto, F G Herring, P C Wong, K A R Mitchell


Evaluating the potential of amine chemicals for use as wood protecting agents. Part 1: Investigation of cation components of quaternary ammonium compounds
1994 - IRG/WP 94-30049
Quaternary ammonium compounds (quats) have shown a great potential as more environmentally acceptable wood preservatives. In order to identify chemicals possessing the wood protecting potential, an evaluation was carried out of a range of commercially available 'quats', using a modified soil block test. Ponderosa pine sapwood blocks were treated with selected 'quat&a...
Hang Tang, J N R Ruddick


Tests with ammoniacal copper and alkyl ammonium compounds as wood preservatives
1984 - IRG/WP 3299
Formulations based on copper and alkyl ammonium compounds in ammonia solution have been tested in a fungus cellar on Pinus radiata and Fagus sylvatica. This type of products gives promising results as wood preservatives, especially on hardwood and are safe to destroy by e.g. combustion. The best results were achieved with a dialkyl ammonium compound, Cu/octyldecyl dimethyl ammonium chloride (NH3)....
C-E Sundman


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