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Vinyl Benzoate Photostabilizes Wood Whereas Vinyl Cinnamate and Vinyl 4-T-butylbenzoate are Less Effective
2009 - IRG/WP 09-40452
Thin wood veneers were esterified to different weight gains with three different aromatic vinyl esters, vinyl benzoate, vinyl cinnamate and vinyl 4-T-butylbenzoate and the photostability of the modified wood was examined. There was a linear relationship between the level of esterification of wood with vinyl benzoate and the photostability of the modified veneers exposed to natural weathering. Viny...
M Jebrane, G Sèbe, I Cullis P Evans


Fire resistance of Alder wood treated with some chemicals. Part II. Effect of Other Chemicals on the Combustion Properties
2002 - IRG/WP 02-40235
Samples from alder wood (Alnus glutinosa (L.) Gaertn. subsp. barbata (C.A.Mey) Yalt.) were impregnated according to ASTM D 1413-88 with boron compounds (boric acid, borax, sodium perborate), vinyl monomers (styrene, methyl methacrylate), Tanalith-CBC, Phosphoric acid, Vacsol, Immersol, Polyethylene glycole (PEG-400) and their mixed solutions of chemicals in order to determine their combustion pro...
A Temiz, Ü C Yildiz


Treatment of wood-based panel products with volatile borate
1990 - IRG/WP 3616
The paper presents recent developments in the use of volatile borate esters for the preservative treatment of wood based board materials. Several advances on previous reports are discussed. In laboratory studies, treatment times of approximately ten minutes at 20°C on boards at equilibrium moisture content provided full penetration and retentions of 1% wt/wt boric acid. Biological tests have been...
P Turner, R J Murphy, D J Dickinson


Pentachlorophenol, its salts and esters; UK review of its uses in wood preservation and surface biocides
1995 - IRG/WP 95-50040-27
The review on pentachlorophenol was undertaken by the Health and Safety Executive on behalf of the independent Advisory Committee on Pesticides in response to the 9th Amendment to the Marketing and Use Directive. The high toxicity to man and the environment was noted and the associated risks were assessed. The Cornmittee concluded that the potential carcinogenicity was probably via a non-genotoxic...
M Fitzpatrick, C Mackie


Physical and mechanical properties of wood-polymer composites prepared from alder wood (Alnus glutinosa (l.) gaertn. subsp. barbata (c.a.mey.) yalt)
2001 - IRG/WP 01-40201
In this study, the physical mechanical properties of wood-polymer composites prepared from alder (Alnus glutinosa (L.) Gaertn. subsp. barbata (C.A.Mey.) Yalt) wood were investigated. Three different monomers styrene, methyl methacrylate and styrene/methyl methacrylate (70/30) mixtures and two loading levels were used in preparation of wood-polymer composites. Of physical properties, the oven-dry s...
A Temiz, Ü C Yildiz, E D Gezer


Leachabilty and efficacy of fatty acid derived boron esters as wood preservatives - leachability and efficacy of fatty acid derived boron esters as wood preservatives
2004 - IRG/WP 04-30351
Borates have many advantages as wood preservatives. However, boron is susceptible to depletion under humid conditions and this restricts its outdoor use. In order to reduce boron leachability in treated wood, one of the anticipative approaches is to use organic fixed boron-based preservatives. This study investigated the leachability of six boron ester compounds as potential preservatives. Scots p...
A Mohareb, J Van Acker, M Stevens


Modification of solid wood: research and practical potential
1997 - IRG/WP 97-40098
The polymeric structure of the wooden cellwall mainly consists cellulose, hemicellulose and lignin. The most reactive sites on these components are the hydroxyl groups. The cellwall polymers (and its reactive hydroxyl groups) are responsible for most physical and chemical properties of wood. By changing the basic chemistry of the cellwall polymers, it is possible to change different undesirable at...
H Militz, E P J Beckers, W J Homan


Treatment of wood with boron esters
1995 - IRG/WP 95-30087
The treatment of wood and wood products with boron esters is reviewed. The physical and chemical characteristics of boron esters affecting the treatability of wood are discussed, in particular thermal decomposition and rates of hydrolysis. The uses and methods applying boron esters as wood preservatives include: (i) Solutions of boron esters for remedial and diffusible treatment of wood; (ii) soli...
J Romero, P Vinden, J A Drysdale


A new process for in situ polymerization of vinyl monomers in wood to delay boron leaching
1998 - IRG/WP 98-40110
Efforts were accelerated on effective use of boron compounds in wood preservation owing to their environmentally safe characteristics and relatively low costs in addition to their well-known high bioactivity and fire resistant properties. Although having these unique favorable properties, they are readily leachable from treated wood at humid conditions. Therefore, they had limited market for exter...
M K Yalinkilic, W Dwianto, Y Imamura, M Takahashi


Chemical modification of Scots Pine Sawdust by mixed anhydrides
2008 - IRG/WP 08-40439
By making react mixtures containing acetic-fatty anhydrides on Scots pine sawdust (SPS) without any solvent or catalyst; we synthesized mixed acetic-fatty esters of SPS. Such mixtures were synthesized by reaction between a carboxylic acid and acetic anhydride. These mixtures were obtained after reaction of acetic anhydride and a fatty acid that yields at equilibrium a mixture of five compounds: ac...
J Peydecastaing, E Borredon, S El Kasmi


Effects of intumescent formulation of vinyl acetate-based coating on flame-retardancy of thin painted red lauan (Parashorea spp.) plywood
2011 - IRG/WP 10-40537
Using intumescent coatings on wood-based materials is an effective method for fire safety. The intumescent coatings consist of four major components: (1) binder resin (BR), (2) carbonizing substance (CS), (3) foam producing substance (FPS) and (4) dehydrating agent (DA). Previous studies have demonstrated that the formulation of the four components strongly influences the performance of coatings. ...
Chih-Shen Chuang, Kuang-Chung Tsai, Te-Hsin Yang, Ming-Kuang Wang, Chun-Han Ko


Preliminary testing of spiroborate esters as wood preservatives
2013 - IRG/WP 13-30614
Fungicide and insecticide properties of boric acid are known since 30’s of the last century, but high solubility and leachability of inorganic borates limit their use for only applications not directly exposed to liquid water. A number of attempts were made to fixate borate salts into the wood structure but this research topic is still up to date and undiscovered. Water insoluble organoboron est...
D Panov, N Terziev