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Diffusion into and bulking of the wood cell wall with polystyrene glycols (PEG)
1991 - IRG/WP 3660
The diffusion and equilibrium distribution of polyethylene glycol (PEG) in the cell walls of red pine (Pinus resinosa) and trembling aspen (Populus tremuloides) were followed by analysing the free lumen solution concentration of vacuum treated wafers at various times after treatment. PEG was more-or-less excluded from the cell walls of wood, depending on the wood species and PEG molecular weight. ...
P A Cooper, Y T Ung, D Alexander, C Holzscherer


Preservative treatment of wood by diffusion processes - Simulation of commercial treatment processes
1988 - IRG/WP 3498
Spruce (Picea abies), Scots pine (Pinus sylvestris) and birch (Betula pendula) were preservative treated by diffusion with mixtures of copper sulphate and arsenic pentoxide. The preservative was fixed after a suitable diffusion storage period by soaking in ammonia solution. A high standard of treatment could be achieved in spruce sapwood. This was attributed to its low wood density, and high wood ...
P Vinden


Movement of borates in a range of timber species at various moisture contents
1998 - IRG/WP 98-30181
Borate-based wood preservatives are used in industrial pre-treatment as well as remedial treatment of timbers in situ. In both of these areas, understanding the mobile nature of these compounds is important in optimizing the main benefits of borates. Considerable work has been conducted on movement of borates in dip-diffusion treatment of freshly felled wood, as well as focusing on subsequent diff...
M W Schoeman, J D Lloyd, M J Manning


Tebuconazole - A new triazole fungicide for wood preservation
1990 - IRG/WP 3629
The main cause of economic damage to timber and millwork worldwide are Basidiomycetes (brown and white rot). After testing a wide range of triazole derivatives for their effectiveness against decay fungi, Tebuconazole, a triazole compound, was selected. The physico-chemical, toxicological and ecotoxicological data of this substance are described. Tebuconazole is unleachable, light-stable, heat-sta...
R Gründlinger, O Exner


Evaluation of the biocide diffusion from treated wood in indoor air. Bibliographic study
1990 - IRG/WP 3584
Within the frame of the risk assessment of the wood preservation products for the Health, the treated wood risk particularly when it is installed in dwellings becomes most important. The European directive "Building materials" (89/106/CEE) mentions the basic requirements with the buildings must comply. Annexe l states in particular that "the building must be conceived and built in order not to bec...
A Pichard


Accelerated diffusion treatment of sawn Sitka spruce grown in the UK
1986 - IRG/WP 3395
The treatment of 'green' sapwood and heartwood of Sitka spruce by diffusion methods was investigated. Steam/dip treatment processes gave increased solution uptakes and depths of penetration of copper in comparison with a simple dip treatment. Further investigation is required to reduce diffusion gradients with copper based formulations and to improve the penetration of '...
R J Murphy, D J Dickinson


Diffusion modeling of inorganic wood preservative leaching in service
2005 - IRG/WP 05-50224-5
To evaluate the potential environmental and health implications of leaching of inorganic wood preservatives in service under different conditions, there is a need for a predictive model that provides estimates of the rate and extent of leaching over a wide range of product dimensions and exposure conditions. In this paper, we show that the leaching behavior of inorganic preservative components fr...
L Waldron, P A Cooper, Y T Ung


Field fencepost test of several species treated with water-borne preservatives by rural methods
1986 - IRG/WP 3385
Fencepost field results in ground-contact treated by rural methods: immersion-diffusion and sap displacement by evaporation are analyzed. Copper-chrome-arsenic and copper-fluor-chrome preservatives were used in two concentrations. The wooden species studied were: Pinus pinaster, Eucalyptus globulus and Quercus rubra. For each of the test units decay index evolution was analyzed after five years ex...
M V Baonza Merino


BG- an easiest preservative paste and its effective diffusibility in timbers for indoors and outdoors uses
2001 - IRG/WP 01-30253
After application of a newly formulated paste "BG-1" on all surfaces of air-dried lumbers, the boron have been found diffused completely in permeable and impermeable hardwoods at the rate of 12 mm radial thickness per week. The new paste may be a solution to protect lumbers being used or to be used under cover where timber is susceptible to termite and borer attack. The new cost effective paste wa...
A K Lahiry


Dip diffusion treatments in the tropics. A preliminary report
1973 - IRG/WP 316
Diffusion treatments based on the use of boric acid alone or in combination with other preservatives are widely used in Australasia (see IRG/WP/310). As part of a general survey covering both temperate and tropical countries, a survey of diffusion treatments in South East Asia, Southern Asia and the South Pacific was carried out, and the results of this survey are reported here. The survey is far ...
C R Levy


Diffusion and interaction of components of water-borne preservatives in the wood cell wall
1988 - IRG/WP 3474
This study investigates the rates of diffusion and ultimate distributions of copper and arsenate components of wood preservatives in wood cell walls following vacuum treatment. Adsorption studies of copper on red pine (Pinus resinosa) and trembling aspen (Populus tremuloides) wood confirm the importance of cation exchange reactions on the ultimate distribution of copper in the wood substance and i...
P A Cooper


A novel chemical barrier system, KORDON® TMB, for the protection of buildings against subterranean termites using a synthetic matrix as carrier for the chemical
1998 - IRG/WP 98-10264
Kordon TMB is a new chemical barrier system for installation beneath concrete slab-on-ground constructions using a matrix other than soil as carrier for the termiticide. The product consists of a synthetic foraminous web (blanket) carrying the synthetic pyrethroid deltamethrin. The blanket is laminated on the upper side to a standard 0.2mm thick moisture vapour membrane of low density polyethylene...
M Lenz, P Morrow, S Runko


Gaseous boron treatments of wood and wood products
1992 - IRG/WP 92-3691
Treatment of wood and wood products by gaseous organoborates has now been under study for about 5 years. This technique has potential for boron treatment of a wide range of substrates from solid wood through to wood composite materials such as particleboard or wet and dry formed fibreboards. The vapour treatment technique is proving to be very flexible in that it can be adapted to integrate into a...
A J Bergervoet, R Burton, K Nasheri, D R Page, P Vinden


Ammoniacal wood preservatives for use in non-pressure treatment of spruce and aspen poplar. Part 2
1984 - IRG/WP 3274
A series of thermal diffusion treatments were carried out on unseasoned white spruce (Picea glauca (Moench) Voss) lumber and air dry aspen poplar (Populus tremuloides Michx.) timbers using an ammoniacal copper arsenate wood preservative. Under the specific conditions described, certain charges of lumber met the present Canadian Standards Association Wood Preservation Committee's requireme...
C D Ralph, J K Shields


Comparison of Temporal Changes in Metal Leaching and Aquatic Toxicity from Wood Treated with CCA and Alternative Preservatives
2005 - IRG/WP 05-50236
This study compares the temporal variation of chemical leaching and aquatic toxicity of wood treated with chromated copper arsenate (CCA) and other copper-based wood preservatives (alkaline copper quaternary (ACQ), copper boron azole (CBA), copper citrate (CC) and copper dimethyldithiocarbamate (CDDC)). Treated wood blocks were leached for 21 days and the leachate collected was analyzed for prese...
B Dubey, T G Townsend, G Bitton, H M Solo-Gabriele


A diffusion and reaction model for the leaching of Cr-VI from unfixed CCA-treated wood
2001 - IRG/WP 01-50169
A physical model applicable to the leaching of any substance undergoing a first-order fixation reaction with wood is presented. Using this model and a laboratory leaching experiment with small wood samples immersed in water, the radial and tangential diffusion coefficients and the reaction rate constants of Cr-VI in unfixed CCA-treated red pine (Pinus resinosa Ait.) are measured. Reaction rate con...
L Waldron, P A Cooper


Bibliography on the use of boron compounds for the preservation of wood
1973 - IRG/WP 315
This bibliography is based on an earlier literature survey prepared by J. Thornton and Wm. E. Bruce (O.E.C.D. Document No. 27/DAS/CSI/M/91) which was enlarged and revised for a meeting in Paris in October 1968 (Document 27/DAS/CSI/M554) by Professor W. Bavendamm of Reinbek. The latter (1968) document with its 166 references has now been extended and brought up to date. Acknowledgments are due to B...
R Cockcroft, J F Levy


Restrictions on the use of chlorosilanes as potential wood preservatives
1985 - IRG/WP 3345
The biological protection of wood by chemical modification with different types of chlorosilanes has been investigated. The impregnation of wood has been carried out by means of liquid phase and vapor phase treatments using pure silane and silane-solvent systems. The biological efficacy against wood rotting fungi, molds and staining fungi was determined in a number of screening trials, subsequentl...
M Stevens


The influence of drilling patterns on the distribution of toxicants from Polesaver Rods in hardwood poles
1994 - IRG/WP 94-30051
Polesaver Rods are solid rods of wood preservative that are used as a groundline maintenance treatment to control biodeterioration in hardwood transmission poles in Australia. The rods are inserted in holes that are drilled in a prescribed manner to distribute the toxicants into the critical groundline region of the poles. To determine the influence of drilling patterns on the distribution of toxi...
W D Gardner, C N McEvoy


Preservative treatment of green timber by soaking in ammoniacal copper borate
1984 - IRG/WP 3292
Freshly sawn boards of radiata pine sapwood were preservative treated by soaking in ammoniacal copper borate. Optimum schedules were obtained by partially seasoning the boards for one week prior to treatment. This aided the absorption of preservative and reduced the required soaking time to approximately 2 hours. Complete boron penetration was obtained after one week of block storage under cover a...
P Vinden, A J McQuire


Field fencepost tests of several species treated with water-borne preservatives by rural methods
1986 - IRG/WP 3385 E
Fencepost field results in ground-contact treated by rural methods: immersion-diffusion and sap displacement by evaporation are analyzed. Copper-chrome-arsenic and copper-fluor-chrome preservatives were used in two concentrations. The wooden species studied were: Pinus pinaster, Eucalyptus globulus and Quercus rubra. For each of the test units decay index evolution was analyzed after five years ex...
M V Baonza Merino


The kinetics of anhydride modification reactions of wood. Experimental results and theoretical modelling
1998 - IRG/WP 98-40125
Although the chemical modification of wood remains a fertile area for research, there has been little work performed on the kinetics of the modification process. The reaction kinetics of a series of linear chain and cyclic anhydrides has been studied and activation energies of the reaction determined. The reaction kinetic profiles are determined by the relative rates of reaction of the reagent wit...
C A S Hill, J G Hillier


Borates as wood preserving compounds: The status of research in the United States
1989 - IRG/WP 3542
This paper describes the extensive, on-going cooperative research effort among government and university research laboratories and industry to fully evaluate the potential for borates as wood preservatives in the United States. Research is discussed in terms of laboratory evaluations, field testing and mill trials, pilot plant pressure treatment studies, and remedial treatments. Future research pl...
H M Barnes, T L Amburgey, L H Williams, J J Morrell


A comparison of the diffusion of boron from two types of solid preservative rods into the heartwood of 3 Eucalypt pole species
2000 - IRG/WP 00-30227
The ability of boron to diffuse from polyborate and boron/fluoride rods through the heartwood of three eucalypt pole species (blackbutt, red ironbark and spotted gum) was examined. The aim was simply to determine the effects of rod type, wood species and time on the longitudinal diffusion of boron in eucalypt heartwood. Rapid diffusion of boron from polyborate or boron/fluoride preservative rods o...
P J Beutel, P D Evans


Ten year performance of l-joints made from borate diffusion treated wood
2000 - IRG/WP 00-30225
While there are decades of experience with borate-treated wood in coated, exterior applications in New Zealand and the UK, other countries have been more reluctant to use this process. As part of a research program on the potential use of borates by the Canadian wood products industry, Forintek set up, in 1990, an L-joint test of untreated and borate-diffusion treated hem-fir (western hemlock and ...
P I Morris


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