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Advances in understanding the mode of action of methylene bisthiocyanate against Sphaeropsis sapinea
2002 - IRG/WP 02-30284
The importance of arresting sapstain pre-infection in radiata pine in New Zealand, to prevent downstream sapstain in both logs and sawn timbers has been clearly demonstrated. Efforts are being made to improve the efficacy of diffusible antisapstain agents through improved understanding wood/fungicide/fungus interactions. The mechanism of action of methylene bisthiocyanate (MBT) was investigated u...
T Singh, R N Wakeling, B Kreber, A Stewart


Preservative treatment of green timber by diffusion
1984 - IRG/WP 3291
The preservative treatment of green timber by diffusion is reviewed together with criteria which influence the economics of the process. New process options are described which should overcome some of the technical and economic disadvantages of double diffusion. These include the use of coagulating agents which increase the viscosity of the preservative solution and facilitate treatment by momenta...
P Vinden


Field evaluation determining the toxic effect and diffusion properties of Impel, Improsol and TBTO-capsules in L-joints (spruce) for pretreatment application
1991 - IRG/WP 3641
Bonded joints (L-joints and T-joints) are especially at risk from water absorption (rain, condensation) over bare, unprotected radial wood surfaces (joggle joints). It is therefore quite certain that lasting protection against fungi attack cannot be guaranteed in the long term if the surface of coating is damaged. Therefore, in a field investigation, using L-joints (spruce) over a total period of ...
R Gründlinger, K Messner, O Janotta


Micromorphology of Schizophyllum commune attack in pine (Pinus sylvestris) wood
1983 - IRG/WP 1184
The decay pattern caused by Schizophyllum commune in pine latewood tracheids was studied using both light and transmission electron microscopy. The attack began as isolated concentric slits within the S2 layer with extensive lamellation and separation of individual wall layers observed in subsequent stages of decay. The slits resulting from attack appeared to be formed in thin, regular concentric ...
T Nilsson, G F Daniel


Diffusion of chromium and fluoride in Rentex treated creosoted pole sections
1991 - IRG/WP 3659
A chromated fluoride preservative was applied by injection to the groundline regions of creosoted distribution pole sections and these were erected at a filed site in Scotland. Wood samples were recovered for chemical analysis at one week, two, five and twelve months after treatment. Small sample mass and destructive nature of the analysis necessitated modification of an alkali fusion technique to...
D C R Sinclair, G M Smith, A Bruce, B King, H J Staines


Diffusion into and bulking of the wood cell wall with polystyrene glycols (PEG)
1991 - IRG/WP 3660
The diffusion and equilibrium distribution of polyethylene glycol (PEG) in the cell walls of red pine (Pinus resinosa) and trembling aspen (Populus tremuloides) were followed by analysing the free lumen solution concentration of vacuum treated wafers at various times after treatment. PEG was more-or-less excluded from the cell walls of wood, depending on the wood species and PEG molecular weight. ...
P A Cooper, Y T Ung, D Alexander, C Holzscherer


Preservative treatment of wood by diffusion processes - Simulation of commercial treatment processes
1988 - IRG/WP 3498
Spruce (Picea abies), Scots pine (Pinus sylvestris) and birch (Betula pendula) were preservative treated by diffusion with mixtures of copper sulphate and arsenic pentoxide. The preservative was fixed after a suitable diffusion storage period by soaking in ammonia solution. A high standard of treatment could be achieved in spruce sapwood. This was attributed to its low wood density, and high wood ...
P Vinden


Movement of borates in a range of timber species at various moisture contents
1998 - IRG/WP 98-30181
Borate-based wood preservatives are used in industrial pre-treatment as well as remedial treatment of timbers in situ. In both of these areas, understanding the mobile nature of these compounds is important in optimizing the main benefits of borates. Considerable work has been conducted on movement of borates in dip-diffusion treatment of freshly felled wood, as well as focusing on subsequent diff...
M W Schoeman, J D Lloyd, M J Manning


Semi-Solid State Bioremediation of CCA-Treated Wood Using Malted Barley as a Nutrient Source
2002 - IRG/WP 02-50184
Bioremediation processes for recovery and reuse of CCA-treated wood invariably increase the cost of any secondary products manufactured from the remediated fiber. Microbial remediation using either bacteria or fungi has been shown to remove heavy metals from CCA-treated southern yellow pine (SYP). In a two-step remediation process utilizing oxalic acid extraction and the metal-tolerant bacterium...
C A Clausen


Chitosan for wood protection - state of the art
2005 - IRG/WP 05-30378
The aim of this paper was to give a state of the art description of chitosan as a wood protecting agent. Chitosan is a metal free natural compound derived from crustacean shells and is under evaluation as an environmentally benign wood protecting agent. Information from journals states that chitosan may act both fungistatically and at higher concentrations, as fungitoxic, but the mode of action is...
M Eikenes, G Alfredsen, E Larnøy, H Militz, B Kreber, C Chittenden


Evaluation of the biocide diffusion from treated wood in indoor air. Bibliographic study
1990 - IRG/WP 3584
Within the frame of the risk assessment of the wood preservation products for the Health, the treated wood risk particularly when it is installed in dwellings becomes most important. The European directive "Building materials" (89/106/CEE) mentions the basic requirements with the buildings must comply. Annexe l states in particular that "the building must be conceived and built in order not to bec...
A Pichard


Accelerated diffusion treatment of sawn Sitka spruce grown in the UK
1986 - IRG/WP 3395
The treatment of 'green' sapwood and heartwood of Sitka spruce by diffusion methods was investigated. Steam/dip treatment processes gave increased solution uptakes and depths of penetration of copper in comparison with a simple dip treatment. Further investigation is required to reduce diffusion gradients with copper based formulations and to improve the penetration of '...
R J Murphy, D J Dickinson


Diffusion modeling of inorganic wood preservative leaching in service
2005 - IRG/WP 05-50224-5
To evaluate the potential environmental and health implications of leaching of inorganic wood preservatives in service under different conditions, there is a need for a predictive model that provides estimates of the rate and extent of leaching over a wide range of product dimensions and exposure conditions. In this paper, we show that the leaching behavior of inorganic preservative components fr...
L Waldron, P A Cooper, Y T Ung


Field fencepost test of several species treated with water-borne preservatives by rural methods
1986 - IRG/WP 3385
Fencepost field results in ground-contact treated by rural methods: immersion-diffusion and sap displacement by evaporation are analyzed. Copper-chrome-arsenic and copper-fluor-chrome preservatives were used in two concentrations. The wooden species studied were: Pinus pinaster, Eucalyptus globulus and Quercus rubra. For each of the test units decay index evolution was analyzed after five years ex...
M V Baonza Merino


Electricity pole treatments - Wedding Bells State Forest. Inspection September 1983
1985 - IRG/WP 3334
A survey to study the extent of soft rot in hardwood poles in N.S.W. was commenced in 1975. The results of the survey, published in 1982, indicated that a number of factors contributed towards soft rot attack on poles in service. A detailed rest on pole treatments and maintenance procedures was established in 1976, at a site in Wedding Bells State Forest near Coffs Harbour. The site selected was k...
R S Johnstone, R H Eldridge


BG- an easiest preservative paste and its effective diffusibility in timbers for indoors and outdoors uses
2001 - IRG/WP 01-30253
After application of a newly formulated paste "BG-1" on all surfaces of air-dried lumbers, the boron have been found diffused completely in permeable and impermeable hardwoods at the rate of 12 mm radial thickness per week. The new paste may be a solution to protect lumbers being used or to be used under cover where timber is susceptible to termite and borer attack. The new cost effective paste wa...
A K Lahiry


Preliminary evaluation of the answers to the 2nd IRG/WP-questionnaire on the state of pollution control in the field of wood preservation
1982 - IRG/WP 3209
This preliminary evaluation of the answers to the 2nd IRG/WP-Questionnaire only gives a general survey on those questionnaires which the author received until April 30th, 1982. Details, such as correlations between importance of wood preservation and pollution control, as well as a comparison of the answers with those to the first questionnaire (Doc. IRG/WP/369), could not be considered due to lac...
H Willeitner


Solid state NMR study on pine wood degraded by brown rot fungus Gloeophyllum trabeum
1994 - IRG/WP 94-10067
Blocks of Pinus koraiensis wood were degraded by Gloeophyllum trabeum and examined by solid-state 13C NMR spectroscopy. Chemical compositions were estimated from relative signal aras. There was no evidence for preferential degradation of the noncrystalline cellulose which accounted for about 4% by weight of the wood. Loss of partly ordered cellulose on crystal surfaces exceeded the loss of crystal...
Yoon Soo Kim, R Newman


Dip diffusion treatments in the tropics. A preliminary report
1973 - IRG/WP 316
Diffusion treatments based on the use of boric acid alone or in combination with other preservatives are widely used in Australasia (see IRG/WP/310). As part of a general survey covering both temperate and tropical countries, a survey of diffusion treatments in South East Asia, Southern Asia and the South Pacific was carried out, and the results of this survey are reported here. The survey is far ...
C R Levy


Diffusion and interaction of components of water-borne preservatives in the wood cell wall
1988 - IRG/WP 3474
This study investigates the rates of diffusion and ultimate distributions of copper and arsenate components of wood preservatives in wood cell walls following vacuum treatment. Adsorption studies of copper on red pine (Pinus resinosa) and trembling aspen (Populus tremuloides) wood confirm the importance of cation exchange reactions on the ultimate distribution of copper in the wood substance and i...
P A Cooper


Ammoniacal wood preservatives for use in non-pressure treatment of spruce and aspen poplar. Part 2
1984 - IRG/WP 3274
A series of thermal diffusion treatments were carried out on unseasoned white spruce (Picea glauca (Moench) Voss) lumber and air dry aspen poplar (Populus tremuloides Michx.) timbers using an ammoniacal copper arsenate wood preservative. Under the specific conditions described, certain charges of lumber met the present Canadian Standards Association Wood Preservation Committee's requireme...
C D Ralph, J K Shields


Comparison of Temporal Changes in Metal Leaching and Aquatic Toxicity from Wood Treated with CCA and Alternative Preservatives
2005 - IRG/WP 05-50236
This study compares the temporal variation of chemical leaching and aquatic toxicity of wood treated with chromated copper arsenate (CCA) and other copper-based wood preservatives (alkaline copper quaternary (ACQ), copper boron azole (CBA), copper citrate (CC) and copper dimethyldithiocarbamate (CDDC)). Treated wood blocks were leached for 21 days and the leachate collected was analyzed for prese...
B Dubey, T G Townsend, G Bitton, H M Solo-Gabriele


A diffusion and reaction model for the leaching of Cr-VI from unfixed CCA-treated wood
2001 - IRG/WP 01-50169
A physical model applicable to the leaching of any substance undergoing a first-order fixation reaction with wood is presented. Using this model and a laboratory leaching experiment with small wood samples immersed in water, the radial and tangential diffusion coefficients and the reaction rate constants of Cr-VI in unfixed CCA-treated red pine (Pinus resinosa Ait.) are measured. Reaction rate con...
L Waldron, P A Cooper


Bibliography on the use of boron compounds for the preservation of wood
1973 - IRG/WP 315
This bibliography is based on an earlier literature survey prepared by J. Thornton and Wm. E. Bruce (O.E.C.D. Document No. 27/DAS/CSI/M/91) which was enlarged and revised for a meeting in Paris in October 1968 (Document 27/DAS/CSI/M554) by Professor W. Bavendamm of Reinbek. The latter (1968) document with its 166 references has now been extended and brought up to date. Acknowledgments are due to B...
R Cockcroft, J F Levy


Wood preservatives. The state of French legislation (June 1977)
1977 - IRG/WP 3106
There does not exist any special legislation for preservatives but general laws may intervene at three levels:-Manufacture -Transport -Selling. In every case, it is based on a poisonous substances classification, an official classification provided by a para-governmental organisation which includes toxicologists. This legislation may refer to other texts: categories of danger for transport (the Eu...
M Romeis, P Guéneau


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