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Tropical In-Ground Durability of CCB-treated Keruing and other Structural Sarawak Timbers after 8 – 10 Years Exposure
2007 - IRG/WP 07-30439
The heartwood of 12 mainly low-durability native timber species of Sarawak [4 Dipterocarpus (Keruing) species, Anisoptera grossivenia (Mersawa kunyit), Canarium apertum (Seladah), Dacryodes incurvata (Seladah laut), Dryobalanops oblongifolia (Kapur kelansau), Mesua macrantha (Mergasing), Podocarpus micropedunculatus (Kayu cina), Shorea compressa (Engkabang langgai), and Pterospermum javanicum (Ba...
A H H Wong, Ling Wang Choon


Natural Weathering of Coated Oil Heat Treated Wood
2007 - IRG/WP 07-30440
Oil heat-treated (thermally modified) pine wood was coated with 9 different types of solvent- or water-borne exterior finishes. The systems with modified wood substrate as well as unpainted and painted non-modified controls were exposed to weathering (EN 927-3) on two locations with sub-alpine and alpine climate. The influence of natural ageing on surface systems was evaluated after one year of ex...
M Petric, B Kricej, M Pavlic, A Rapp


Mold resistance of heat-treated wood
2007 - IRG/WP 07-40358
The resistance of heat-treated sugi sapwood against three mold fungi was evaluated. Wood specimens were first subjected to heat treatments at 180 and 220ºC for 2 and 4 hours. Mold growth on the surface of the specimens was measured 1, 2, 4 and 6 weeks after the inoculation with the fungi in laboratory conditions. Laboratory decay tests were performed using two brown and white-rot fungi along with...
S N Kartal


Micro-Distribution of Metals in Wood Treated with a Nano-Copper Wood Preservative
2007 - IRG/WP 07-40360
The microdistribution of copper in southern pine treated with a newly-developed nano-copper wood preservative was examined to determine if it differed from that reported for wood treated with conventional copper-based wood preservatives. Field Emission Scanning Electron Microscopy (FE-SEM) in combination with x-ray microanalysis (EDX) revealed the presence of nano-sized copper and iron particles i...
H Matsunaga, M Kiguchi, P Evans


Fire, flame resistance and thermal properties of oil thermally-treated wood
2007 - IRG/WP 07-40361
Oil thermal treatment, first developed by German scientists, is a promising technology for improving the durability and dimensional stability of wood for outdoor above-ground residential uses such as siding and shingles. The present authors’ previous research showed that 220ºC is an optimal treatment temperature, with 2 hours’ treatment producing wood with significantly improved moisture and ...
Jieying Wang, P Cooper


Effects of sodium hypochlorite on compression strength and copper retention of spruce wood treated with copper azole and alkaline copper quat
2007 - IRG/WP 07-40362
This work investigates the effects of sodium hypochlorite on compression strength values and copper retention ratios of refractory spruce wood (Picea oriental L.) treated with the waterborne preservative Copper Azole, (CBA-A, Tanalith-E 3492) and alkaline copper quat (ACQ-2200). Before the copper azole and alkaline copper quat treatment, the samples were immersed in 500 ml of sodium hypochlorite s...
S Yildiz, E Dizman, A Temiz, Ü C Yildiz


The effect of additives on copper losses from alkaline copper treated wood
2007 - IRG/WP 07-50246
The replacement of chromated copper arsenate (CCA) by alkaline copper compounds has heightened awareness of the potential impact of copper losses on aquatic organisms. While there remains a healthy debate concerning the actual risk of copper leaching from wood preservatives into aquatic ecosystems, it is clear that reducing these losses will be necessary to avoid continued regulatory actions aga...
J Mitsuhashi, J J Morrell, L Jin, A F Preston


Evaluating the Process of ACQ-Treated Woods with TGAand CEM Analysis
2007 - IRG/WP 07-20374
To provide an understanding of the fundamental thermal behaviour and the disposal-end products of ACQ-treated woods, this study is comprised of two categories of examination. The first is related to the use of TGA under different thermal decomposition conditions (nitrogen or air, and 5 or 40 oC/min), and the use of EDX to examine certain residual elements of the char. The second applies the CEM ...
Han Chien Lin, Tsang-Chyi Shiah, Jung Ting Tsai


Durability of some alternatives to preservative-treated wood. Progress report 2: Results from field tests after 5 years’exposure
2007 - IRG/WP 07-30442
A number of alternatives to preservative-treated wood have been tested according to EN 252 (stake test) and a specially designed ground-proximity field test, the latter in Sweden as well as in Hawaii, USA. Seven untreated wood species and four alternative wood treatments labelled as environmentally friendly (acetylation, linseed oil, heat treatment, vinyl polymer) were included in the study. Four ...
M-L Edlund, J Jermer


Primary Study on Compressed Preservative-treated Wood (CPW) for Outdoor Applications
2008 - IRG/WP 08-40412
In this study, the compressed wood samples pre-treated with hot water bath or water spraying were immersed in the ammoniacal copper quat –type D (ACQ-D) preservative solution to get compressed preservative-treated wood (CPW). The liquid absorption and the recovery rate of compression deformation of the compressed wood was determined, as well as the surface hardness, the distribution of density a...
Jinzhen Cao, Jia Mao


Termite resistance of DMDHEU-treated wood
2008 - IRG/WP 08-40401
Chemical wood modification with dimethyloldihydroxy-ethyleneurea (DMDHEU) or its derivatives are applicable to both solid lumber and wood-based composites. Advantages of DMDHEU-based modification are an increase of dimensional stability and high durability against white, brown and soft rot fungi. At higher chemical loadings, the hardness of the wood is considerably increased. Due to the durabil...
H Militz, S Schaffert, B C Peters, C J Fitzgerald


Effects of acetic acid and nitric acid pre-treatment on copper content of spruce wood treated with CBA-A and CCA
2008 - IRG/WP 08-40406
This work investigates the effects of nitric acid and acetic acid on compression strength values and copper retention contents of refractory spruce wood (Picea oriental L.) treated with the waterborne preservative Copper azole, (CBA-A, Tanalith-E 3492) and copper / chrom / arsenic (CCA). Before the CBA-A and CCA treatment, the samples were immersed in 500 ml of nitric and acetic acid solutions for...
S Yildiz, E Dizman, Ü C Yildiz


Effect of steam on fixation of Cu-amine preservative treated wood
2008 - IRG/WP 08-50251
The rates of copper fixation in copper amine preservative treated wood were investigated with different fixation conditions (20° with drying and 50° without drying) and post-steaming. We also measured the degree of leaching for other biocide components (azoles, quatz, and Cu-HDO). Treatments conditioned at 20° with drying required 50 days or more to fix in woods. While copper was stabilized i...
Sung-Mo Kang, In-Yong Hwang, Suk-Kuwon Kim


Thermochemical Remediation of Preservative-Treated Wood
2008 - IRG/WP 08-50254
Remediation methods continue to be developed and refined for CCA-treated wood in order to divert this material from landfills and create secondary products from the wood fiber. A two-step thermochemical remediation method was developed to assess the efficiency of metal removal from CCA-treated spruce flakes. Nearly all the metals (As, Cr, and Cu) were thermochemically extracted from chromated copp...
R Sabo, C A Clausen, J E Winandy


Leachability of Arsenic, Chromium and Copper from Weathered Treated Wood
2008 - IRG/WP 08-50255
The objective of this study was to quantify the loss of arsenic, chromium and copper from weathered treated wood under normal field conditions as most residential structures currently in service in the U.S. have been constructed at least 3 years ago. For comparison, leaching from different retention levels of weathered CCA treated wood (low, medium and high) is compared to leaching from new ACQ tr...
A R Hasan, Ligang Hu, H M Solo-Gabriele, Yong Cai, L A Fieber


Laboratory Studies on Copper Availability in Wood Treated with Soluble Amine Copper and Micronized Copper Systems
2008 - IRG/WP 08-30489
A laboratory method has been employed to investigate the level of soluble copper in wood treated with various copper-based preservative systems, such as micronized copper (particulate copper) and amine copper solutions. This report describes the methodology and preliminary results on determination of the soluble copper in the treating solutions and the treated wood by these systems, as well as th...
L Jin, P Walcheski, A Preston


Performance of dip and pressure treated wood in termite ground proximity exposures in Hilo, HI, and Colombia
2008 - IRG/WP 08-30491
A number of preservative systems were evaluated for their ability to control termite attack when applied as both dip and pressure treatments. With dip treatments, better performance was observed with southern pine than spruce-pine-fir using the same solution strength treatment, probably as a result of the about 50% greater uptake with southern pine and associated deeper preservative penetration. B...
P Walcheski, A Zahora


Alkaline copper treated wood for use in residential decking
2008 - IRG/WP 08-30490
Alkaline copper quaternary ammonium compound (ACQ) treated decking was exposed in a field experiment and the mobile copper assessed based on that collected in the leachate. The amount of copper which leached was modeled after 4 years. The results showed that boards which leached most chemical initially provided the greatest loss over four years. The reduction in the mobility of copper with time wa...
J N R Ruddick


High Temperature Treated Wood
2008 - IRG/WP 08-40429
High temperature can modify internal structure and physic-chemical properties of wood by a controlled pyrolysis process. Such treatment, among other changes in properties, modifies the wood color in a way that resembles exotic species, increasing its market value. The main objective of this work is to determine the changes in wood properties caused by the effect of temperature and time, in order t...
C C Borges, A L Barbosa, R Faber de Campos, S T Targas


Corrosion of fastener and connector in contact with alkaline copper treated wood – it is a problem
2008 - IRG/WP 08-40437
For many decades, chromated copper arsenate (CCA) was the most common wood preservative used in North America for residential and industrial applications. Since December 31, 2003, the use of CCA for residential application was voluntarily terminated. One of the most widely accepted alternative wood preservatives in Western Canada is Alkaline Copper Quaternary Compound (ACQ). This paper will compar...
J N R Ruddick


Comparison of laboratory and natural exposure leaching of copper from wood treated with three wood preservatives
2008 - IRG/WP 08-50258
Standard and non-standard laboratory and field leaching tests were used to compare copper leaching from wood treated to above ground and ground contact specified retentions for three wood preservative systems, CCA-C, ACQ-D and a micronized copper formulation with quat DDAC as co-biocide. Copper leaching was highest for the ACQ formulation. Percent leaching was lowest for the micronized copper sy...
P A Cooper, Y T Ung


Evaluation of Water Repellency of Treated Wood Using Several Alternative Methods
2009 - IRG/WP 09-20419
In this study, the results of water repellency testing using a digital swellometer method for water-borne organic-preservative systems with water repellent additives are reported. The findings suggest that the traditional method of using matched untreated controls as a reference developed from historic solvent-based treatments for determination anti-swelling efficacy (ASE) may underestimate the a...
L Jin, A F Preston


Leaching performance, decay and termite resistance of wood treated with boron compounds incorporated with phenol-formaldehyde resin
2009 - IRG/WP 09-30503
A resol-type phenol-formaldehyde (PF) resin was synthesized and designed to penetrate wood incorporated with boron compounds in order to immobilize boron in wood. The leaching performance, decay and termite resistance of treated wood was investigated. Three kinds of boron compounds, that is, boric acid (BA), borax (BX) and disodium octaborate tetrahydrate (DOT), were selected to mix with PF and tw...
Liping Yu, Jinzhen Cao


Resistance to decay fungi of ammonium borate oleate treated wood
2009 - IRG/WP 09-30505
Ammonium borate oleate molecule (ABO) produced from reaction between boric acid, ammonia and oleic acid was tested as wood preservative treatment against brown and white rot fungi according to European standards. This compound was prepared according to a previous study which has proved existence of synthesis reaction and effectiveness against termites (Lyon et al. 2007b). Four solutions of ABO in ...
F Lyon, M-F Thevenon, A Pizzi, J Gril


Re-Distribution of Copper in the Cell Walls of Wood Treated with Micronized Copper Quat
2009 - IRG/WP 09-30506
Wood treated with copper-based preservatives to be used in ground contact may fail to inhibit soft rot fungi if penetration of copper into the cell wall is insufficient. Preservatives containing soluble copper are known to penetrate the cell wall; however, it is not known whether preservatives containing particulate copper will also migrate into the cell wall in sufficient quantities to control so...
R Stirling, J Drummond


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