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Application of nanoparticles of silver and nanoparticles of titanium dioxide in reinforcement of wood and coating for wood in Costa Rica
2015 - IRG/WP 15-40698
Wood is one of the most widely used materials in last 20 years by society in many applications, with a considerable proportion of this material coming from forest plantations. Plantations usually produce timber with reduced strength properties and low natural durability. On the other hand, nanotechnology applications have the potential to increase wood properties. Likewise, nanotechnology cannot o...
A Berrocal Jiménez, R Moya Roque, A Lucrecia Rodríguez, J R Vega Baudrit


VOC-free remedial treatment agent on organic solvent basis with surface cleaning by photocatalysis using titanium dioxide
2014 - IRG/WP 14-40651
Due to the EU Regulations according to the harmonisation of the European market of biocidal products and the EU Regulations regarding emissions of volatile organic compounds in residential properties a new VOC free yet organic solvent based remedial treatment agent is introduced including a potential method to clean up the wooden surface of remaining biocides after a remedial treatment using photo...
H Ahl, J Fromm, P Jüngel, E Melcher, M Pallaske


Comparative study of the properties of silicate coatings with different mineral pigments (titanium dioxide, iron (III) oxide, copper (II) oxide) on the surface of wood
2022 - IRG/WP 22-40936
Silicate coatings are attractive alternatives to conventional organic-based coatings for wood protection. In this work, silicate coatings were prepared with a potassium silicate binder modified with a methyl siliconate solution, and three types of mineral pigments titanium dioxide, iron (III) oxide and copper (II) oxide. The coatings were applied on beech wood and cured under ambient conditions. T...
A M Cheumani Yona, M Petrič


Respiration methods used to follow the decay of wood and the toximetric evaluation of wood preservatives
1975 - IRG/WP 249
When wood is attacked and decayed by fungi, wood substance and oxygen (02) are consumed, while carbon dioxide (CO2), water and heat are liberated. Early in the 1960's workers from England, Canada and Sweden began studying CO2 evolution, with respect to decay and its control using chemical preservatives, while in Germany and the USA O2 utilization was being similarly examined. Oxygen consu...
R S Smith


Effect of fatty acid removal on treatability of Douglas-fir
1993 - IRG/WP 93-40008
Treatment of Douglas-fir with chromated-copper-arsenate (CCA) poses a major challenge. Several hypotheses based on the anatomical aspects as well as chemical reactivity of the preservative formulations with cell wall constituents and deposits have been proposed. Techniques to prevent pit aspiration or slow fixation reactions have, however, not significantly improved treatment. The presence of high...
S Kumar, J J Morrell


Effects of a formaldehyde and sulphur dioxide treatment on decay and mechanical properties of aspen waferboard
1983 - IRG/WP 3242
Aspen wafers were sequentially treated under vacuum with formaldehyde and sulfur dioxide gas and pressed into waferboard bonded with powdered phenol formaldehyde resin. Decay resistance and strength properties were determined before and after simulated weathering. The water resistance of the phenol bonding system was lost in board made from the gas-treated wafers. This white rot fungus Coriolus ve...
E L Schmidt


Bending properties of TCMTB-treated Southern pine sapwood using supercritical carbon dioxide impregnation process
1997 - IRG/WP 97-40080
The effects of elevated pressure and treatment with thiocyanomethylthiobenzothiazole (TCMTB) on the bending properties of Southern pine sapwood were evaluated at pressures ranging from 1,800 to 3,600 psi. All bending properties were affected to some extent by supercritical fluid treatment. Modulus of elasticity and work to maximum load were not significantly affected by pressure levels. Modulus of...
Gyu-Hyeok Kim, S Kumar, E S Demessie, K L Levien, J J Morrell


Treatment of wood with formaldehyde. Acid catalysis of the reaction between formaldehyde and wood
1980 - IRG/WP 3146
Formaldehyde reacts with the free OH-groups in wood forming cross-linking bonds. The reaction can be brought about without any catalyst but in that case the activation energy is very high and high temperatures and long reaction times are needed. Normally, the reaction is catalysed by different acids. Acid catalysts, however, tend to degrade the cellulose and the wood matrix causing reduction in th...
T Vihavainen, K Piispanen, P Mansikkamäki


Microscopical analysis of formaldehyde-acid modified wood
1981 - IRG/WP 3182
Cross-linking of wood with gaseous formaldehyde improves its hygroscopic and dimensional behaviour, and its resistance against micro-organisms. However, formaldehyde cross-linking reactions take place only in the presence of an acid catalyst, which results in losses in mechanical By optimization of a formaldehyde-sulfur dioxide vapour phase process the reaction conditions were established to limit...
M Stevens, N Parameswaran


Termite Field Tests of Various Timber Species Treated with permethrin using supercritical carbon dioxide
2005 - IRG/WP 05-10560
Termite field tests were conducted on permethrin-treated Eucalyptus obliqua heartwood, Pinus radiata sapwood and P. radiata LVL. The permethrin was impregnated using either supercritical carbon dioxide (scCO2) or light organic solvent preservative (LOSP) systems. Comparative permethrin retentions were most accurately achieved in P. radiata sapwood, where no difference between impregnation systems ...
A Qader, L J Cookson, J W Creffield, D Scown


Cellular and fractural failure after supercritical fluid impregnation of four wood species
2004 - IRG/WP 04-10503
Supercritical fluids (SCFs) have been investigated for delivering biocides into sawn wood. Pressure differentials during treatment may exceed the compressive or tensile strength perpendicular to grain, creating a potential for transverse deformations that exceed elastic strain limits. Wood treated by SCF processing with CO2, a potential biocide carrier, was inspected macroscopically and microscopi...
M E Anderson, R J Leichti, J J Morrell


Applicability of supercritical carbon dioxide to the preservative treatment of wood-based composites
2001 - IRG/WP 01-40199
Treatability of five structural-use wood-based composites (medium density fiberboard, hardwood plywood, softwood plywood, particleboard and oriented strand board) was evaluated when supercritical (SC) carbon dioxide (CO2) was used as a carrier solvent. Treatments were conducted at three temperature 32 levels (25, 35 and 45°C) and two pressure levels [80 kgf/cm2 (7,845 kPa) and 120 kgf/cm2 (11,768...
M Muin, A Adachi, K Tsunoda


Preservative treatment of wood-based composites with a mixture formulation of IPBC-silafluofen using supercritical carbon dioxide as a carrier gas
2003 - IRG/WP 03-40251
Wood-based composites treated with a mixture formulation of a fungicide, 3-iodo-2-propynyl butylcarbamate (IPBC) and a termiticide, silafluofen using supercritical carbon dioxide (SC-CO2) as a carrier solvent were tested for their resistance to decay and termite attack in the laboratory. The treatment solution was prepared by mixing both biocides (IPBC 10 + silafluofen 1) with a co-solvent, ethano...
K Tsunoda, M Muin


Performance of Oriented Strandboard, Medium Density Fiberboard, Plywood, and Particleboard Treated with Tebuconazole in Supercritical Carbon Dioxide
2005 - IRG/WP 05-30364
The performance of oriented strandboard (OSB), medium density fiberboard (MDF), particleboard and plywood treated with tebuconazole using supercritical carbon dioxide was investigated over a 48 month exposure under harsh above ground conditions in Hilo, Hawaii. Samples treated to low retentions (<0.20 kg/m3) tended to experience decay at rates that were only slightly lower than those found wit...
J J Morrell, M N Acda, A R Zahora


Surface protection of wood with titanium, zirconium and manganese compounds
2005 - IRG/WP 05-30376
Thin radiata pine veneers were treated with a range of titanium, zirconium and manganese compounds and exposed to natural weathering. Veneer weight and tensile strength losses were used to assess the protective efficacy of the compounds. The oxidative manganese compounds potassium permanganate and manganic acetate restricted both weight and tensile strength loss of treated wood veneers during weat...
K J Schmalzl, P D Evans


Silver as a Wood Preservative Environmental Requirements and Concerns
2007 - IRG/WP 07-30420
The pesticide uses of silver and its compounds fall under the jurisdiction of the United States Environmental Protection Agency (USEPA) under the US Federal Insecticide Fungicide and Rodenticide Act. In addition, many other national and international organizations maintain close observance of the effects of silver in different environments. The US EPA has also issued a specific announcement that t...
J R Ellis


Development of preservative treatment method using sub and super critical carbon dioxide
2007 - IRG/WP 07-40385
Significant efforts have been devoted for developing biocide impregnation method into wood materials using supercritical fluid. Developing better understandings of fluid phase and its effect on treatment results would facilitate a more rational development of supercritical fluid (SCF) impregnation. In this project, the preservative treatabilities under super- and sub-critical fluid conditions we...
Myeung-Won Cho, Sung-Mo Kang, Gyu-Hyeok Kim


Interactions between wood and propiconazole in supercritical carbon dioxide
2009 - IRG/WP 09-40461
Understanding the movement and deposition of biocides in wood is a fundamental aspect of the supercritical wood impregnation process and a key issue in developing the process e.g. to handle wood of larger dimensions. Previous research on supercritical wood impregnation frequently reports of a biocide concentration gradient in impregnated samples i.e. a lower concentration of biocides in the core o...
A W Kjellow, O Henriksen


Copper nanoparticles in southern pine wood treated with a micronised preservative: Can nanoparticles penetrate the cell walls of tracheids and ray parenchyma?
2010 - IRG/WP 10-30547
This study tests the hypothesis that copper nanoparticles can penetrate the cell walls of southern pine wood treated with a micronised preservative. We examined the nanodistribution of particles in tracheid and ray parenchyma cell walls using state-of-the-art HR (High Resolution)-TEM and HR-STEM (Scanning Transmission Electron Microscope)-EDX. These devices are capable of atomic-scale resolution. ...
H Matsunaga, Y Kataoka, M Kiguchi, P Evans


Preliminary Observations of the Photostabilization of Wood Surfaces with Cerium Oxide Nanoparticles
2010 - IRG/WP 10-40504
Reactive transition metal compounds, wood modification and grafting of UV absorbers have all been used to photostabilize wood. Some of these approaches are promising, but the toxicity of certain reactive transition metal compounds and the cost of wood modification and grafting have restricted their commercial applications. Hence, more cost-effective and environmentally friendly methods of protecti...
Chunling Liu, A Ahniyaz, P Evans


Riverbed Construction Technology using Thinned Timbers for Carbon Dioxide Sink in Korea
2010 - IRG/WP 10-50271
The Climatic Change Convention is a big burden in limiting the energy usage like the blood of economy. The certification standard about the carbon storage of timbers after harvesting them is expected to be an important role in setting the goal for future reduction of the green house gas(CO2). The extension of a timber's life span through its preservation is one of technologies for carbon sink...
Dong-heub Lee, Won-Joung Hwang


The decontamination of a historical xylotheque with liquid carbon dioxide
2011 - IRG/WP 11-10757
The pharmacist Johann Heinrich Linck senior (1674-1734) created the xylotheque (collection of wood species) in Leipzig, Saxony (Germany). His son, Johann Heinrich Linck junior (1734-1807), continued the valuable and unique collection, which now belongs to the Museum Waldenburg near Dresden, Germany. In the past the cupboard, including the wood specimens, was impregnated with a wood preservative co...
S Zoppke, A Unger, J Mankiewicz, M Eisbein


Copper Nanoparticles in Southern Pine Wood Treated with a Micronised Preservative: Nanodistribution of Copper in the Pit Membrane and Border of an Earlywood Bordered Pit
2011 - IRG/WP 11-30566
Copper nanoparticles can penetrate the cell walls of unlignified parenchyma cells in southern pine wood treated with a micronised wood preservative, but they are excluded from lignified tracheid walls. This paper extends these observations to include the cell wall layers of the bordered pit. Focused ion beam and ion milling were used to make an ultra-thin section of the cell wall layers of an earl...
H Matsunaga, Y Kataoka, M Kiguchi, P Evans


The potential for using CuO nanoparticles as a wood preservative
2011 - IRG/WP 11-30569
The potential for using nano-copper particles for wood protection was investigated using mini-agar slant and wood block tests with Gloeophyllum trabeum or Trametes versicolor. Nano-copper was more effective against G. trabeum than T. versicolor, although neither of these fungi would be considered copper tolerant. Nano-copper solutions were stable over a 17 week storage period, but precipitated w...
I S Weitz, K Knani, M Maoz, C Freitag, J J Morrell


Accessibility of Wood Cell Walls to Well-defined Platinum Nanoparticles
2012 - IRG/WP 12-20494
Copper nanoparticles are found in the walls of parenchyma cells in southern pine sapwood treated with a micronised wood preservative, but they are absent from tracheid walls. Hence, we hypothesized that small nanoparticles can penetrate the walls of unlignified parenchyma cells, but are excluded from lignified tracheid walls. This paper tests this hypothesis by treating pine sapwood with an aqueou...
H Matsunaga, Y Kataoka, M Kiguchi, P D Evans


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