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Modified Wood – Methods, testing and applications: Outcomes of the EU-Thematic Network
2003 - IRG/WP 03-40268
In the last decade, interest in the development of wood modification systems has increased in Europe. Alongside several industrial initiatives for heat treatments, there have also been scaling up and pilot plant projects for chemical wood modification. Between 2000 and 2003, the European Commission funded the "Thematic Network on Wood Modification". This paper will feature the modification process...
D Jones, W Homan, J Van Acker


Determination of the water sorption properties and preliminary results from field tests above ground of thermally modified material from industrial scale processes
2004 - IRG/WP 04-40279
In this study the differences in moisture behavior and durability above ground of heat treated wood originating from different European industrial heat treatment plants by means of the water sorption properties as well as field tests were examined. The manufacturers of heat treated material were: PLATO Hout B.V./Netherlands, Thermo Wood (Premium wood)/ Finland and Menz Holz/ Germany, where Oil-...
C R Welzbacher; A O Rapp


Copper linoleate: A new low toxcity wide spectrum, heavy duty wood preservative
1995 - IRG/WP 95-30082
Copper linoleate, a "fixed" copper soap has been developed and evaluated in South Africa over a 30-year period. The initial product, an organic solvent based preservative has been tested in pine poles against termites and fungi. Results indiate that the product has performed well against existing heavy duty wood preservatives such as CCA and creosote in long term field trials (30 years). The paper...
D Conradie, P Turner, W E Conradie, A J Pendlebury, T Pizzi


Studies on the resistance of DMDHEU treated wood against white-rot and brown-rot fungi
2005 - IRG/WP 05-10566
Beech wood (Fagus sylvatica) modified with the textile finishing agent 1,3 dimethylol-4,5-dihydroxyethylen urea (DMDHEU) has shown to improve durability against the white-rot fungus Trametes versicolor. In a mini-block test, the weight loss over eight weeks of incubation decreased with increasing weight percent gain (WPG) of DMDHEU. At 25% WPG, no significant weight loss was observed, while untrea...
P Verma, C Mai, A Krause, H Militz


Efficacy of anhydrides as wood protection chemicals
1997 - IRG/WP 97-30162
Wood samples treated with anhydrides of various compositions have been examined for their decay resistance and moisture behaviour. For this purpose two brown rot fungi (Coniophora puteana and Gloeophyllum trabeum) and two white rot fungi (Trametes versicolor and Pycnoporus sanguineus) were used in conventional and modified soil block tests. The modified soil block tests conformed to the method as ...
S C Forster, M D C Hale, G R Williams


Development of wood retification process at the industrial stage
1998 - IRG/WP 98-50101-16
Wood is a natural composite material which exhibits outstanding properties from the technical as well as from the ecological point of view. However, it is an anisotropic, hygroscopic material sensitive to biological attacks. We have to stabilise and preserve it if we want to ensure its market shares faced with competing synthetic material, whilst taking the new environmental rules into account. T...
P Gohar, R Guyonnet


Determination of N-cyclohexyl-diazeniumdioxide (HDO) containing compounds in treated wood using GC-MS
2000 - IRG/WP 00-20201
Beside the biological effectiveness the approval of a chemical wood preservative requires also techniques for the analytical determination of active ingredients in different matrices. Fulfilling of the last requirement is particularly difficult in the case of impregnated timber treated with wood preservatives containing organic compounds. This paper describes a procedure for the determination of t...
P Jüngel, J Wittenzellner, E Melcher


The biological effectiveness of wood modified with heptadecenylsuccinic anhydride against two brown rot fungi: Coniophora puteana and Gloeophyllum trabeum
1992 - IRG/WP 92-3705
A modified soil block test was carried out using wood samples reacted with heptadecenylsuccinic anhydride (ASA). This modification gave good resistance to decay brought about by the brown rot fungi Coniophora puteana and Gloeophyllum trabeum during the twelve week exposure period. Results indicated that there was a good correlation between increased loading of modifying reagent and an increase in ...
C Codd, W B Banks, J A Cornfield, G R Williams


Modification of wood by graft treatment
2003 - IRG/WP 03-40257
New water-repellent systems for wood are needed to improve the weathering characteristics. This study found that treatment of wood with chemical grafting systems imparted substantial water repellency. Different direct oxidative grafting systems were examined. Specifically, KMnO4, Fe(NH4)(SO4)2·12H2O, Fe2(SO4)3·5H2O, and (NH4)2Ce(NO3)6 were used as initiators and styrene as the monomer. All the...
M M Morshed, D D Nicholas, C Pittman Jr, T Schultz


Investigation of the suitability of silver fir (Abies alba Mill.) for thermal modification
2004 - IRG/WP 04-40275
In this study the suitability of silver fir (Abies alba Mill.) was examined for thermal modification. Comparative experimental investigations were performed with silver fir and Norway spruce (Picea abies Karst.) after thermal treatments. Besides properties, which characterize the quality of heat treatments, like dimensional stability and resistance against fungal attack, strength properties of the...
C Brischke, A O Rapp


Durability aspects of (hydro)thermal treated wood
2000 - IRG/WP 00-40160
Samples of several wood species were treated in a two steps process, subsequently hydrothermal and dry heat-treated, by the so-called PLATO-process and analysed for their resistance against fungal attack. Both PLATO-treated and dry heat-treated specimen were prepared and analysed, in order to study the influence of moisture during hydrothermal treatment of wood. The resistance against all of the s...
B F Tjeerdsma, M Stevens, H Militz


Effect of some resin treatments on fungal degradation reactions
1999 - IRG/WP 99-10318
The effect of impregnation of wood with vegetable oil, tall oil and two water soluble on fungal degradation reactions was assessed by hydrolysis and enzyme activity measurements. The experiments were carried out by using isolated enzyme preparations and a living brown-rot fungus Poria placenta. The results indicate that the inhibitory effect of treatments was clearly directec towards the enzymatic...
A-C Ritschkoff, M Rättö, A J Nurmi, H Kokko, A O Rapp, H Militz


The identification of organic compounds in wood using thermal desorption GC-MS - possibilities and limitations
2001 - IRG/WP 01-20224
There is a clear need for the analytical characterisation and identification of organic compounds and their derivatives in different phases especially in timber. In this context the paper describes a rapid and powerful gas chromatographic method for the determination of insecticides, biocides and "other" organic substances in treated and/or modified wood. The main advantage of this procedure is th...
P Jüngel, E Melcher


The Effect on Biological and Moisture Resistance of Epichlorohydrin Chemically Modified Wood
2002 - IRG/WP 02-40224
Southern pine solid wood and fiber were chemically modified with epichlorohydrin to help in understanding the role of moisture in the mechanism of biological effectiveness of chemically modified wood. The solid wood had weight gains from 11% to 34%, while the fiber had weight gains from 9% to 75%. After modification, part of the specimens were water leached for 2 weeks or extracted for 2 hours ...
R E Ibach, B-G Lee


Microwave modification of wood properties - Improvements in wood permeability
2000 - IRG/WP 00-40181
A new method of microwave (MW) wood modification is described. Microwave irradiation of timber provides an improvement in wood permeability mainly in the radial and longitudinal directions. This is achieved by physically modifying ray cells and forming a large number of cavities in the radial - longitudinal planes. More extensive MW irradiation of different species transforms the wood into a new m...
G Torgovnikov, P Vinden


Dimensional stability and decay resistance of wood upon modification with some new type chemical reactants
1994 - IRG/WP 94-40028
Solid wood of home grown species can be upgraded by chemical modification with environmentally acceptable chemicals. The best kwown example of modification reaction is acetylation with acetic anhydride. A continued search for reactive chemicals other than acetic anhydride is ongoing, aiming at the improvement of technical properties of wood. This contribution deals with the results of a screening ...
P Goethals, M Stevens


Assessing the bioresistance conferred to solid wood by chemical modification
1997 - IRG/WP 97-40099
The chemical modification of wood using straight chain alkyl anhydrides can considerably enhance its durability. This paper presents an assessment of the effectiveness of these modifiers in improving the biological resistance of a susceptible softwood when exposed to four different basidiomycete fungi, soft rots and the larvae of the house longhorn beetle (Hylotrupes bajulus). It was clear that so...
E D Suttie, C A S Hill, D Jones, R J Orsler


Ammoniacal wood preservatives for use in non-pressure treatment of spruce and aspen poplar. Part 2
1984 - IRG/WP 3274
A series of thermal diffusion treatments were carried out on unseasoned white spruce (Picea glauca (Moench) Voss) lumber and air dry aspen poplar (Populus tremuloides Michx.) timbers using an ammoniacal copper arsenate wood preservative. Under the specific conditions described, certain charges of lumber met the present Canadian Standards Association Wood Preservation Committee's requireme...
C D Ralph, J K Shields


The quantitative determination of N-cyclohexyl-diazeniumdioxide (HDO) containing compounds in treated wood using TD-GC-MS
2001 - IRG/WP 01-20223
Last year we presented the paper (IRG/WP/00-20201) "Determination of N-cyclohexyl-diazeniumdioxide (HDO) containing compounds in treated wood using GC-MS". Based on the intensive discussion at the meeting, the first experiences made with the calibration of the system for this application will be reported. For the quantitative determination of N-cyclohexyl-diazeniumdioxide in treated wood, milled m...
P Jüngel, J Wittenzellner, E Melcher


Bending properties of wood after its decay with Coniophora puteana and subsequent modification with selected chemicals
1999 - IRG/WP 99-40146
Mechanical properties of wood are often decreased due to decay processes caused by biotic and/or abiotic factors. Damaged wooden elements (e.g. historical structures) can be reinforced by more methods, including their modification with convenient chemicals. This paper presents influences of selected chemicals on basic bending properties (modulus of elasticity - MOE, modulus of rupture - MOR) of so...
L Reinprecht, S Varinska


The kinetics of anhydride modification reactions of wood. Experimental results and theoretical modelling
1998 - IRG/WP 98-40125
Although the chemical modification of wood remains a fertile area for research, there has been little work performed on the kinetics of the modification process. The reaction kinetics of a series of linear chain and cyclic anhydrides has been studied and activation energies of the reaction determined. The reaction kinetic profiles are determined by the relative rates of reaction of the reagent wit...
C A S Hill, J G Hillier


Modification of solid wood: research and practical potential
1997 - IRG/WP 97-40098
The polymeric structure of the wooden cellwall mainly consists cellulose, hemicellulose and lignin. The most reactive sites on these components are the hydroxyl groups. The cellwall polymers (and its reactive hydroxyl groups) are responsible for most physical and chemical properties of wood. By changing the basic chemistry of the cellwall polymers, it is possible to change different undesirable at...
H Militz, E P J Beckers, W J Homan


Biological degradation resistance of wood acetylated with thioacetic acid
1983 - IRG/WP 3223
Chemically, modification of wood is being considered as an alternative to conventional preservation by toxic chemicals. Acetylated wood has been reported to be quite resistant to most biodegrading organisms at weight percent gains (WPG) around 15-19. The conventional acetylation techniques with acethic anhyrdride result in generation of acetic acid. However, acetylation with thioacetic acid overco...
S Kumar, S C Agarwal


Three-year field trials of polymeric formulations which provide a new basis for the invention and design of non-toxic wide-spectrum wood preservatives
1994 - IRG/WP 94-40029
Three types of non-toxic polymeric formulations invented using a new approach to wood preservation were challenged with termites and fungi in three-year ground-contact field trials in the sub-tropical climate of Natal. These formulations were copper soaps of carboxylic acid groups of unsaturated fatty acids of waxes and edible vegetable oils; of resin acids of rosin, and, of synthetic unsaturated ...
A A W Baecker, A Pizzi


Environmental characterisation of retification process by-products (liquid and gaseous wastes)
2005 - IRG/WP 05-50224-10
In order to reduce environmental risks during the service life of the treated wood and to find new alternative developments on the durability of wood, some research and technology development have been made on thermal treatment. The retification process is one of these processes. The retification process induces chemical modification of the lignin and cellulosic components and modifies the intrins...
G Labat, E Bucket, S Legay, C Yriex, P Marchal, E Raphalen, M Vernois, R Guyonnet, H Besset, E Fredon), G Vilarem, L Rigal, C Raynaud


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