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Polyesterification of wood using sorbitol and citric acid under aqueous conditions
2018 - IRG/WP 18-40851
The aim of this research is to determine if the polyesterification of sorbitol and citric acid in wood has a future potential as a wood modification process. Pine wood was impregnated with an aqueous solution containing citric acid and sorbitol and was thereafter cured at 103, or 140°C for 18 hours. The dimensional stability and leaching resistance were studied for both modification temperatures....
E Larnøy, A Karaca, L R Gobakken, C A S Hill


Using X-ray scattering to elucidate the mechanisms behind the moisture and fungal decay resistance of epoxybutene modified wood
2019 - IRG/WP 19-40854
Chemical modification of the hydroxyl groups of wood can improve the properties of wood by providing moisture and biological resistance, as well as dimensional stability. Southern pine solid wood was chemically modified to various weight percentage gains (WPG) with epoxybutene (EpB, 8%-38% WPG). After modification, specimens were extracted with a toluene: ethanol (2:1) solution for 2 hours or wate...
R E Ibach, N Plaza


Dimensional stability and decay resistance of montmorillonite- furfuryl alcohol modified wood
2019 - IRG/WP 19-40856
Poplar (Populus cathayana) wood was impregnated successively by organo-montmorillonite (OMMT; in concentration of 2%) and furfuryl alcohol (FA, in concentrations of 15%, 30% and 50%) in a two-step method to prepare OMMT-FA modified wood. The modified wood samples were characterized using X-ray diffraction (XRD) and field emission scanning electron microscopy (FE-SEM). Moreover, wood physical and a...
L Zhang, J Cao


Study on the ability of wood-destroying fungi to grow through chemically modified wood
2019 - IRG/WP 19-40858
Over the last decades, chemical wood modification technologies were developed to increase the resistance against attack by wood-destroying organisms without using biocides. Most of those technologies are based on an impregnation step initially. In most treated wood products, mainly by using solid wood in thicker dimensions as in posts, poles, sleepers, deckings etc. it is known that wood impregnat...
L Emmerich, S Strohbusch, C Brischke, S Bollmus, H Militz


Mineralization of European oak with various ionic salt solutions to achieve an in situ precipitation of calcium oxalate
2019 - IRG/WP 19-40861
Thin specimens of European oak (Quercus spp.) with the dimensions of 4 × 20 × 50 mm3 were treated with various aqueous ionic salt solutions of calcium chloride, potassium oxalate and calcium acetate. Additionally, the oak was treated with combinations of calcium chloride and potassium oxalate, as well as calcium acetate and potassium oxalate with the aim to precipitate in situ the water insolubl...
T Franke, T S Volkmer


An overview of recent studies involving the thermal modification of hardwood species
2019 - IRG/WP 19-40869
This paper outlines recent activities related to the thermal modification of hardwood species, and particularly to tropical hardwood species. Timber demand is ever increasing, but this is being limited by the necessity to protect virgin forest stands. As such, the majority of supply of popular species is being met from juvenile short rotation stands. The limited age from these stands often plays a...
D Jones, M Gaff, F Kacik


Novel approaches for improvement of dimensional, photo- and thermal stability of wood through liquefied wood polyols impregnation
2019 - IRG/WP 19-40884
The major problems encountered in both indoor and outdoor utilization of wood are due photo instability and dimensional instability. The modification of Melia dubia wood for ultraviolet resistance and dimensional stability with liquefied wood has been carried out through impregnation method under solvent free conditions. The level of impregnation in modified wood was estimated by weight perc...
A Kumar, A John, T S Mehra


Towards better integration of wood protection in the forestry wood industry chain - a case study on hybrid poplar
2019 - IRG/WP 19-50359
Wood and wood products are limited in service life as in the forest ecosystem trees at end of their life are degraded to re-enter the bio-geochemical cycle. Humans can select wood species with a level of natural durability fit for an envisaged end use. Mainly those applications that require a long service life under conditions that are similar to those at soil level in a forest ecosystem have been...
J Van Acker


Water interactions in wood polyesterified with sorbitol and citric acid
2020 - IRG/WP 20-40888
Polyesterifcation of wood with sorbitol and citric acid seems to be a promising chemical wood modification technique that is both low-cost and produced from bio-based chemicals. An interesting aspect of the modification is the interaction of water with the polyesterified wood since the relationship with moisture appears to be unique compared to other wood modification systems. This communication p...
G Beck, A Treu, E Larnøy


Investigations into the use of Maleic Anhydride/Sodium Hypophosphite as a Wood Modification Process
2020 - IRG/WP 20-40891
The formation of crosslinked bonds between wood constituents is believed to be an effective way to stabilize wood against wet conditions. The possibility to use maleic anhydride (MA) combined with sodium hypophosphite (SHP) as crosslinking agents was studied, using Scots pine sapwood and a model compound. The modified wood showed weight gain and bulking effect after treatment and subsequent Soxhle...
I Kim, D Jones, O Karlsson, D Sandberg, O N Antzutkin, F Ullah Shah


Elucidation of reactive sites of wood modified with acetic anhydride: Insights from density functional theory calculations
2020 - IRG/WP 20-40892
Density functional theory (DFT) was employed to investigate the interaction of cellulose and lignin with acetic anhydride for explaining the wood modification process. Atoms in molecules (AIM) and reduced density gradient (RDG) along with non-covalent interaction (NCI) plots were used to analyse the intermolecular bonding characteristics. Cellulose was modelled with a cellobiose unit (dimer of glu...
V Ponnuchamy, A Sandak, J Sandak, R Herrera Diaz


A summary of decay performance with citric acid and sorbitol modification
2020 - IRG/WP 20-40898
Application of wood-based products as construction materials is one piece of the big puzzle to mitigate climate change. Wood is susceptible to biological deterioration. Environmentally motivated legislation is making the use of biocides less attractive from a commercial perspective. Ideally, a wood modification technology should be of low cost, water based and make use of thermal curing. This rese...
G Alfredsen, E Larnøy, G Beck, J Biørnstad, L R Gobakken, C A S Hill, A Treu


Macro biological degradation of wood treated with sorbitol and citric acid – first results from marine environment and termite exposure
2020 - IRG/WP 20-40901
Most European wood species are rapidly and severely degraded in termite-infested areas and the marine environment. There is a need for new solutions, especially in the marine environment, since we lack wood preservatives approved for marine applications in Europe. Several wood modification systems show high resistance against both marine borers and subterranean termites. However, the existing comm...
A Treu, L Nunes, E Larnøy


Thermal spray coatings to protect wood from termites
2020 - IRG/WP 20-40905
Protecting buildings and construction materials against subterranean termites in Europe relies on combined physical and chemical approaches. Buildings can be protected by physical or physico-chemical barriers such as gravel aggregates, steel mesh or plastic films impregnated with insecticides. Wood and wood-based materials are traditionally protected by insecticides applied on the surface or deepl...
L Podgorski, H Myalska, A Dinoirjean, M Kutnik


Plasma treatment of wood - a review of 15 years of research in Göttingen
2021 - IRG/WP 21-40913
Wood is an important renewable resource and can be found omnipresent in everyday life. Its natural properties offer numerous advantages regarding physical, mechanical but also aesthetic aspects, but also challenges that one has to address with various modification methods. Driven by the desire to promote the use of promising new technologies using plasmas, there has been a close research network ...
P Sauerbier, R Köhler, G Avramidis, W Viöl, H Militz


Marine borer resistance of various wood materials in Japan
2021 - IRG/WP 21-10983
Wood resistance against marine borer was intensively studied in the 1940s in Japan, but the research activities on the subject diminished afterward, as the use of wooden marine structures and ships decreased. Today, however, use of wood as a construction material is officially promoted for its environmental benefits. The author started to immerse some wood materials in the seawater pool at PARI ...
M Yamada


Assessing the Performance of Wood-based Materials Exposed to Termite Risk – A New Experimental Approach
2022 - IRG/WP 22-10989
Termites are able to degrade a large number of building materials including wood, wood-based panels, biobased insulation, and polymers. The risk for a material of being degraded by termites depends on its composition, on its accessibility, and also on the behavior and the biology of the termite species considered. Within the EU project Click Design, we investigated the durability, under laboratory...
M Kutnik, I Paulmier, C Brunet, D Ansard, M Montibus


Wood modification reduces the feeding rate of the wood boring crustacean, Limnoria quadripunctata
2022 - IRG/WP 22-10993
Adult Adult Limnoria search for new wood once their current piece disintegrates from tunnelling. During this time, they do not have access to wood so experience a period of starvation and must feed again once settled. Wood modification offers protection to marine structures by reducing the feeding rate of Limnoria and therefore can reduce recruitment of adults from distant pieces of wood. Chemical...
L S Martin, S Lande, M Westin, S M Cragg


Results of the resistance of acetylated wood against marine borers at three Italian sites after five years of sea immersion
2022 - IRG/WP 22-10994
The aim of this research was the determination of resistance of acetylated wood against marine decay in use class 5 (EN 335) in temperate sea waters. The resistance of acetylated Pinus radiata (radiate pine) in solid and medium density fibreboard (MDF) panels is compared with that of the untreated Scots pine, radiata pine and other untreated wood of European species such as Fagus sylvatica (Europe...
S Palanti, F Stefani, M Andrenacci, M Faimali, I Guarneri, M Sigovini, D Tagliapietra


Significance of the thermal design and the sorption isotherm shape in hygroscopic wood moisture dynamics and service life
2022 - IRG/WP 22-20682
Moisture dynamics are considered important for predicting the service performance of wood in exterior applications. Above a critical moisture content, water acts a softener on the structural polymer matrix of the wood cell wall, enabling the necessary diffusion of molecular species involved in the fungal degradation mechanism of wood. Water may enter solid wood in either liquid form or in vapor fo...
W Willems


Analysis of wooden shingles after seven years of exposure
2022 - IRG/WP 22-20690
Wood is a traditional roofing material in the Alpine regions. In the 17th century, wooden roofing was typically used on more important buildings. Still, today it is predominately used on huts and houses in the hilly regions of northern and north-western Slovenia. Because wooden roofing is expensive, we investigated the possibility of extending the service life of the roofing through impregnation a...
M Humar, B Lesar, D Kržišnik, E Keržič, B Jemec


Green approach in wood mineralization for improvement of fire properties
2022 - IRG/WP 22-30769
Various treatments have been developed in order to improve fire properties of wood. Because the use of some flame retardants can release toxic compounds in the event of a fire, leading to poisoning or even death of people from smoke inhalation, the use of no-toxic and more ecologically acceptable flame retardants is preferable. Mineralization of wood with the incorporation of carbonates has proven...
A Pondelak, R Repič, L Škrlep, N Knez, F Knez, A S Škapin


A novel wood preservation technology improving durability and water-related properties
2022 - IRG/WP 22-40926
A newly developed silicone oil (Archroma Management GmbH, Switzerland) was tested for wood modification purposes. Scots pine sapwood was treated with aqueous solutions of this silicone oil and showed a penetration of the modification agent into the wood cell wall. Both, biological durability and moisture-related properties, experienced significant improvements by the modification. Besides, the mod...
L Emmerich, H Militz, M Vila


Durability against fungal decay of sorbitol and citric acid (SorCA) modified wood
2022 - IRG/WP 22-40928
Most European-grown wood species are susceptible to biological degradation, specifically, they suffer from a poor resistance against wood-destroying fungi. Therefore, prior to outdoor exposure, wood has to be treated either by applying a protective coating on its surface or by full-volume impregnation with antifungal chemicals. However, due to environmental and health concerns, the most frequently...
K Kurkowiak, L Emmerich, H Militz


Environmentally Friendly Wood Modification based on Tannin-Furfuryl alcohol - Effect on stabilisation, mechanical properties and decay durability
2022 - IRG/WP 22-40929
Furfurylation is a well-known wood modification technology. This paper studied the effect of tannin addition on the wood furfurylation. Three kinds of dicarboxylic acids, adipic acid, succinic acid, and tartaric acid, as well as glyoxal as a comparing agent, were used to catalyse the polymerisation of furanic or tannin-furanic solutions during wood modification. Impregnation of furanic or tannin-f...
M Mubarok, E Azadeh, F O Akong, S Dumarçay, A Pizzi, C Charbonnier-Gérardin, P Gérardin


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