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Amine copper reaction with wood components: acidity versus copper adsorption
1997 - IRG/WP 97-30161
The bonding sites for copper in wood from CCA, as well as ammoniacal/amine based systems, has long been a topic of investigation. Both phenolic and carboxylic functional groups have been discussed as potential bonding sites for copper. However, no consensus on the adsorption mechanism has been realized. Thus, the selective adsorption of copper in southern yellow pine from ethanolamine-copper solut...
S M Thomason, E A Pasek


Examination of preservative-treated Pinus sylvestris using electron paramagnetic resonance
1992 - IRG/WP 92-3710
EPR is currently being used to help elucidate the nature and extent of the chemical reactions occurring between wood and copper based timber preservatives. In the work reported here treated Scots pine samples were examined at room temperature and in the frozen state. Plots of the electronic parameters A|| vs. g|| were found to be a useful index of the electronic properties of the various formulati...
A S Hughes, R J Murphy, J F Gibson, A J Cornfield


Determination of thermal degradation of isothiazolone treated wood
1997 - IRG/WP 97-30154
Wood treated with 4,5-dichloro-2-n-octyl-4-isothiazolin-3-one was the subject of thermal degradation study. The study included burning isothiazolone treated wood under various temperatures with and without oxygen. The result showed that no harmful combustion products, such as polychlorinated dibenzo-p-dioxins, polychlorinated dibenzo-p-furans and polychlorinated biphenyls, were detected. These fin...
Bing Yu


Comparative study of lignocellulolytic activities of Pleurotus spp. and white rot and brown-rot fungi
1997 - IRG/WP 97-10209
Field and fungal cellar trials have been set up to assess the biocontrol potential of a selected Trichoderma viride isolate in a situation representative of the end use of treated timber in ground contact situations. These trials are designed to give information about the efficacy of biological control as well as the suitability of existing chemical treatment methods for use with biocontrol fungi....
H L Brown, A Bruce


High-energy multiple impact (HEMI)-test – Part 2: A mechanical test for the detection of fungal decay
2006 - IRG/WP 06-20339
The suitability of the high-energy multiple impact (HEMI)-test for detection of early fungal decay was examined. The HEMI – test characterizes the treatment quality of thermally modified wood by stressing the treated material by thousands of impacts of pounding steel balls. This method differentiates between heat treatment intensities, which are expressed by structural changes of the wood. Simil...
C R Welzbacher, C Brischke, A O Rapp


High-energy multiple impact (HEMI)-test – Part 1: A new tool for quality control of thermally modified timber
2006 - IRG/WP 06-20346
Thermal modification processes improve durability and dimensional stability of wood, but the strength properties, especially the dynamic ones, are compromised and need to be considered with respect to industrial quality control. Results from standard dynamic strength testing, such as impact bending tests, suffer from high variability, and therefore require a high number of replicates. To overcome ...
C Brischke, A O Rapp, C R Welzbacher


The commercialisation of ThermoWood® products
2006 - IRG/WP 06-40339
The concept of thermally modifying timber is well established, which has achieved a limited market breakthrough to date. Commercial application has mainly occurred within Finland, though recent years has seen market gain in several other European countries. This paper reviews the known properties of ThermoWood® timber, based on the combined work of the Finnish ThermoWood® Association, alongside ...
D Jones, E Suttie, J Ala-Viikari, N Bergstrom, D Mayes


The Effect of Flavonoids on Colour and Spectral Changes of the Wood Surface Caused by Heat Treatment or Ultra-violet Irradiation
2006 - IRG/WP 06-40341
Both heat treatment and UV irradiation can cause discolouration and change in the spectral properties of wood surface. Some of the characteristic flavonols have significant role on colour and spectral changes, despite of their relative small quantities in wood. Colour changes and spectral properties of natural and extracted black locust (Robinia pseudoacacia L.) and poplar (Populus nigra L.) were...
R Csonka-Rákosa, L Molnár-Hamvas, E Börcsök, J Molnár, K Németh


Chemical reactions involved in furfurylation of solid wood - An investigation by ATR-IR spectroscopy
2006 - IRG/WP 06-40347
Wood modification with furfuryl alcohol (FA) has gained renewed interest during the last five to ten years because of advances in process technology and because of increased focus on the environmental hazards of traditional wood impregnation. The reaction mechanisms involved in the furfurylation process are not yet understood in detail. In the work presented here, the chemical reactions and their ...
T Mark Venås, L Garbrecht Thygesen, S Barsberg


Thermal decomposition behavior of CCA-treated wood for safe disposal and the safe recovery of heavy metals through pyrolysis
2006 - IRG/WP 06-50238
If we could estimate the chemical changes in heavy metals by temperature in chromated copper arsenate (CCA)-treated wood during pyrolysis, it is expected that we could solve the environmental problems of heavy metals, which may occur during pyrolysis, and therefore, the thermal decomposition behavior of effective elements of CCA-treated wood was examined to find a safe disposal method. First, CCA-...
Dong Won Son, Dong-heub Lee, Sun-hae Cheon, Myung Jae Lee


Wood decay fungi from New Zealand ‘leaky’ buildings: PCR identification and laboratory decay tests of wood preservative-treated Pinus radiata (Part 1)
2007 - IRG/WP 07-10620
Fungi colonising Pinus radiata D. Don framing timber of ‘leaky’ New Zealand buildings were isolated to produce pure cultures. Mycelia from these cultures on agar media were collected to extract DNA. To identify the fungi to the species level, polymerase chain reaction (PCR) with primer pairs ITS1-F and ITS4 were performed followed by sequencing of the internal transcribed spacer (ITS) region. ...
D Stahlhut, R L Farrell, R Wakeling, M Hedley


Photo-degradation of modified and non-modified wood, coated with water borne acrylic coatings during artificial light exposure
2007 - IRG/WP 07-30416
A series of experiments were carried out to investigate photo-degradation of thermally modified (at 210oC and – 0.9 bars for two hours) and non-modified spruce wood (Picea abies L (Karst)), coated with transparent and semitransparent (with 3% pigment content) acrylic coatings during artificial UV light irradiation for 200 hours. Photo-degradation was evaluated in terms of colour changes througho...
M Deka, M Tomažic, M Petric


Effects of heat treatments on decay resistance and material properties of ponderosa pine and yellow poplar
2007 - IRG/WP 07-40374
The potential for using heat treatment to improve the properties of North American fenestration species was evaluated on ponderosa pine (Pinus ponderosa L) and yellow poplar (Liriodendron tulipifera L) treated using the ThermoWood process at various treatment temperatures and times. Soil block tests using Gloeophyllum trabeum, Postia placenta, or Trametes versicolor showed that durability was enh...
C Vidrine, C Freitag, J Nicholson, J J Morrell


Fire, flame resistance and thermal properties of oil thermally-treated wood
2007 - IRG/WP 07-40361
Oil thermal treatment, first developed by German scientists, is a promising technology for improving the durability and dimensional stability of wood for outdoor above-ground residential uses such as siding and shingles. The present authors’ previous research showed that 220ºC is an optimal treatment temperature, with 2 hours’ treatment producing wood with significantly improved moisture and ...
Jieying Wang, P Cooper


Wood decay fungi from New Zealand leaky buildings – PCR identification (Part 2) and aerial spore trapping
2008 - IRG/WP 08-10649
Prior to this study, it was not know which species of decay fungi caused decay in New Zealand leaky buildings. Use of molecular biology methodology, polymerase chain reaction (PCR), and subsequent DNA sequencing, as well as classical mycological techniques based on morphology, has enabled identification of decay fungi and has provided insight into their relative importance based on isolation frequ...
D Stahlhut, R L Farrell, R Wakeling, M Hedley


A step towards a better understanding of fungal colonization of modified wood - QRT-PCR studies
2008 - IRG/WP 08-10653
The area of wood protection is in a period of change. New wood protection systems have been developed while their mode of action remains insufficiently understood. The development of molecular methods provides potential tools to investigate the interaction between modified wood and decay fungi. One small step to tackle some of the unsolved questions about the mode of action of modified wood is tak...
G Alfredsen, A Pilgård, A Hietala


Preliminary investigation of biological resistance, water absorption and swelling of thermally compressed pine wood panels
2008 - IRG/WP 08-40396
Wood can be modified by compressive, thermal and chemical treatments. Compression of wood under thermal conditions is resulted in densification of wood. This study evaluated decay and termite resistance of thermally compressed pine wood panels at either 5 or 7 MPa and at either 120 or 150?C for one hour. The process caused increases in density and decreases in thickness of the panels; however, lab...
Ö Ünsal, S N Kartal, Z Candan, R Arango, C A Clausen, F Green III


Heat treatment, thermal treatment, thermal degradation of wood, carbon nanotubes and Damascus steel swords. What do they all have in common?
2008 - IRG/WP 08-40399
Thermal degradation of wood is a well known phenomenon. Yet heat-treatment of wood can also provide protection for wood against certain environmental hazards. This paper explores some of the aspects of thermal degradation of wood fiber at relatively low temperatures with a surprising result. Carbon nanotubes (CNTs) were produced when a specific heating regime was used to carbonize the wood fiber. ...
Xinfeng Xie, B Goodell, Yuhui Qian, G Daniel


Thermal treatment of Nigerian-grown Albizzia zygia and Funtumia elastica wood in soy oil medium.
2008 - IRG/WP 08-40413
Thermal treatment in soy oil medium is one of the techniques used as a substitute to the chemical treatment in wood preservation. However, the effects of this technique vary from one species to another and hence the need to investigate the response of individual species to it. Thermal treatment of air-dried Nigerian-grown Albizzia zygia and Funtumia elastica wood was carried out in a vessel contai...
L Awoyemi


Bi-oleothermal treatment of wood at atmospheric pressure: resistance to fungi and insects, resistance to weathering and reaction to fire results
2008 - IRG/WP 08-40418
Bi-oleothermal process is a simple treatment which has been developped by CIRAD in cooperation with FCBA. It allows a deep impregnation of wood with hydrophobic products using cheap facilities. The process includes two steps at atmospheric pressure. The first one is a dipping of wood samples in a hot oil bath (between 110 °C and 200°C) which creates an overpressure inside the wood. The second on...
L Podgorski, I Le Bayon, I Paulmier, J-D Lanvin, V Georges, D Grenier, H Baillères, J-M Méot


High Temperature Treated Wood
2008 - IRG/WP 08-40429
High temperature can modify internal structure and physic-chemical properties of wood by a controlled pyrolysis process. Such treatment, among other changes in properties, modifies the wood color in a way that resembles exotic species, increasing its market value. The main objective of this work is to determine the changes in wood properties caused by the effect of temperature and time, in order t...
C C Borges, A L Barbosa, R Faber de Campos, S T Targas


Degradation of wood veneers by Fenton’s reagents: effects of low molecular weight phenolic compounds on hydrogen peroxide decay and tensile strength loss
2009 - IRG/WP 09-20400
Pine wood (Pinus sylvestris) veneers strips were incubated in acetate buffer containing hydrogen peroxide and iron to mimic mechanisms of brown rot decay and assess the degradation of cellulose through analysis of the tensile properties of the decayed wood. The tensile properties of thin wood strips treated with Fenton system reagents or precursors were determined and correlated to weight loss as ...
Yanjun Xie, R Well, Zefang Xiao, B Goodell, J Jellison, H Militz, C Mai


Thermal behavior of zinc borate-treated wood
2009 - IRG/WP 09-30511
The objective of this study was to investigate the thermal behavior of zinc borate (ZnB)-treated solid wood by thermal analysis (TA). Thermogravimetry (TG) and differential thermogravimetry (DTG) curves obtained from TA showed that ZnB-treated wood specimens had higher char yields and lower maximum thermal decomposition temperature than untreated wood specimens. Reducing thermal decomposition temp...
E Terzi, H Sutcu, S N Kartal


Differential response of wood to dry air thermal treatment (DATT) and soy oil thermal treatment (SOTT)
2009 - IRG/WP 09-40446
Thermal treatment is an alternative to chemical modification method which has been used to some extent in improving timber quality. In order to get the maximum benefits possible without compromising the various end-use quality requirements of timber, several possibilities have been and are still being investigated in relation to this technique. Clear wood samples (19 x 19 x 150mm) of kiln-dried re...
L Awoyemi


Wettability and bonding strength of wood thermally-treated with different combinations of soy oil and chemical additives
2009 - IRG/WP 09-40454
Thermal treatment is a method which has gained wider acceptability as an alternative to the chemical treatment in wood preservation. In order to maximize the benefits of this technique several options have been adopted including the use of soy oil in transferring the heat to the wood. Available information on thermal treatment in general and the oil method in particular show that there are still n...
L Awoyemi, P A Cooper, T Ung


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