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Microwave modification of Yellow Stringybark (Eucalyptus Muelleriana) posts for impregnation with Copper-Chrom-Arsenic (CCA) preservatives
2000 - IRG/WP 00-40185
Yellow Stringybark posts with diameters ranging from 60-100 mm were microwave conditioned using a 60 kW microwave (MW) generator. A substantial improvement in heartwood penetration of preservatives and relaxation of growth stresses was indicated such that there was no split formation following drying of the posts. High preservative absorption of copper-chrome-arsenic (CCA) was achieved ranging fro...
G Torgovnikov, P Vinden


Modification of solid wood: research and practical potential
1997 - IRG/WP 97-40098
The polymeric structure of the wooden cellwall mainly consists cellulose, hemicellulose and lignin. The most reactive sites on these components are the hydroxyl groups. The cellwall polymers (and its reactive hydroxyl groups) are responsible for most physical and chemical properties of wood. By changing the basic chemistry of the cellwall polymers, it is possible to change different undesirable at...
H Militz, E P J Beckers, W J Homan


Biological degradation resistance of wood acetylated with thioacetic acid
1983 - IRG/WP 3223
Chemically, modification of wood is being considered as an alternative to conventional preservation by toxic chemicals. Acetylated wood has been reported to be quite resistant to most biodegrading organisms at weight percent gains (WPG) around 15-19. The conventional acetylation techniques with acethic anhyrdride result in generation of acetic acid. However, acetylation with thioacetic acid overco...
S Kumar, S C Agarwal


Three years of field tests with "Lignomer" stakes in ground contact
1981 - IRG/WP 3166
The "Lignomer" (Wood Polymer Composite) is a material obtained during the polymerisation of various monomers or its mixtures in wood. As laboratory tests have shown, this material is characterized by a high resistance against biological deteriorating agents. The laboratory investigations on the durability of various materials against biological deterioration are in many instances extended by field...
K Lutomski


Three-year field trials of polymeric formulations which provide a new basis for the invention and design of non-toxic wide-spectrum wood preservatives
1994 - IRG/WP 94-40029
Three types of non-toxic polymeric formulations invented using a new approach to wood preservation were challenged with termites and fungi in three-year ground-contact field trials in the sub-tropical climate of Natal. These formulations were copper soaps of carboxylic acid groups of unsaturated fatty acids of waxes and edible vegetable oils; of resin acids of rosin, and, of synthetic unsaturated ...
A A W Baecker, A Pizzi


Environmental characterisation of retification process by-products (liquid and gaseous wastes)
2005 - IRG/WP 05-50224-10
In order to reduce environmental risks during the service life of the treated wood and to find new alternative developments on the durability of wood, some research and technology development have been made on thermal treatment. The retification process is one of these processes. The retification process induces chemical modification of the lignin and cellulosic components and modifies the intrins...
G Labat, E Bucket, S Legay, C Yriex, P Marchal, E Raphalen, M Vernois, R Guyonnet, H Besset, E Fredon), G Vilarem, L Rigal, C Raynaud


Screening of the technical performance and aquatic toxicity of N-methylolacrylamide treated wood
2000 - IRG/WP 00-40166
In the course of the last decades chemical modification of wood species, with a limited natural durability, has been subjected to intensive research. As a possible alternative and supplementary treatment of non-durable wood in a range of applications it remains one of the major topics in the wood preservation world. Different modification systems have been scaled-up and are now in an industrialisi...
V Rijckaert, S De Geyter, J Van Acker, M Stevens


Effect of fungal degradation on the chemical composition of acetylated beech wood
2003 - IRG/WP 03-40267
This study investigated the impact of fungal attack on the chemical composition of acetylated wood. Beech wood acetylated to different degrees was exposed to decay by the white-rot fungus Trametes versicolor under solid-state fermentation conditions. Laboratory soil-bed assays were also conducted to study the degradation of acetylated wood by soft rot fungi and other soil-inhabiting microorganisms...
H Militz, Dong-won Son, L Gómez-Hernández, R Sierra-Alvarez


Test methods for modifies wood: The EU-Thematic network approach
2002 - IRG/WP 02-20255
The last decade wood modification systems have become new wood treatment methods in Europe. Alongside several industrial initiatives for heat treatments also scaling up and pilot plant projects for chemical wood modification have recently been carried out. In 2000 an initiative to create a network related to these new developments was supported by the European Commission. Within the work proposed ...
J Van Acker, D Jones


Melamine resins as preservatives results of biological testing
1996 - IRG/WP 96-40061
Based on previous work of the authors on resins, the upgrading of wood with a true solution of a methanol etherificated melamine resin in low aqueous concentration was performed. For the relative assessment of the biological resistance against brown and white-rot fungi were used not only untreated controls of pine sapwood (Pinus sylvestris L.), but also heartwood of European larch (Larix decidua M...
A O Rapp, R-D Peek


Characterization of wood decay enzymes by MALDI-MS for post-translational modification and gene identification
2002 - IRG/WP 02-10442
The recent sequencing of the Phanerochaete chrysosporium genome presents many opportunities, including the possibility of rapidly correlating specific wood decay proteins of the fungus with the corresponding gene sequences. Here we compare mass fragments of trypsin digests, determined by MALDI-MS (Matrix Assisted Laser Desorption Ionization-Mass Spectrometry), with predicted mass fragments derive...
T H de Koker, P J Kersten


Determination of thermal degradation of isothiazolone treated wood
1997 - IRG/WP 97-30154
Wood treated with 4,5-dichloro-2-n-octyl-4-isothiazolin-3-one was the subject of thermal degradation study. The study included burning isothiazolone treated wood under various temperatures with and without oxygen. The result showed that no harmful combustion products, such as polychlorinated dibenzo-p-dioxins, polychlorinated dibenzo-p-furans and polychlorinated biphenyls, were detected. These fin...
Bing Yu


Effects of the sulfuric acid modification of CCA treating solution
1987 - IRG/WP 3415
Sulfuric acid modification of CCA treating solution is often used to control the formation of sludges and undesirable deposits on the surface of treated wood. The consequences of sulfuric acid addition are examined in this work and negative effects are shown to far outweigh any benefits. Major risks include the loss of copper due to leaching from treated wood and the accelerated corrosion of treat...
R F Fox, H J Fry, E A Pasek, A S Ross


Blue Staining of Coated Modified and Unmodified Wood
2006 - IRG/WP 06-10589
We investigated resistance of unmodified, DMDHEU modified and oil heat treated uncoated and coated Scots pine wood against blue stain fungi. Both EN 152-1 and the reverse exposure tests showed excellent resistance of DMDHEU and especially of oil heat treated wood against blue staining. It is not needed to add any additional protective coating layers to prevent modified wood from staining. However,...
M Petric, M Pavlic, M Humar, M Tomažic


Further discussion of biological durability assessments of acetylated wood from several European institutes
2006 - IRG/WP 06-40340
In the last decade, interest in the development of wood modification systems has increased in Europe. Alongside several industrial initiatives for heat treatments, there have also been scaling up and pilot plant projects for chemical wood modification. Between 2000-03, the European Commission funded the "Thematic Network on Wood Modification". This paper features a re-evaluation of work undertaken...
D Jones, W Homan, F Bongers


The Effect of Flavonoids on Colour and Spectral Changes of the Wood Surface Caused by Heat Treatment or Ultra-violet Irradiation
2006 - IRG/WP 06-40341
Both heat treatment and UV irradiation can cause discolouration and change in the spectral properties of wood surface. Some of the characteristic flavonols have significant role on colour and spectral changes, despite of their relative small quantities in wood. Colour changes and spectral properties of natural and extracted black locust (Robinia pseudoacacia L.) and poplar (Populus nigra L.) were...
R Csonka-Rákosa, L Molnár-Hamvas, E Börcsök, J Molnár, K Németh


Thermal decomposition behavior of CCA-treated wood for safe disposal and the safe recovery of heavy metals through pyrolysis
2006 - IRG/WP 06-50238
If we could estimate the chemical changes in heavy metals by temperature in chromated copper arsenate (CCA)-treated wood during pyrolysis, it is expected that we could solve the environmental problems of heavy metals, which may occur during pyrolysis, and therefore, the thermal decomposition behavior of effective elements of CCA-treated wood was examined to find a safe disposal method. First, CCA-...
Dong Won Son, Dong-heub Lee, Sun-hae Cheon, Myung Jae Lee


Molecular methods as a tool within the field of wood protection – available methods and new possibilities
2007 - IRG/WP 07-20361
The area of wood protection is in a period of change. New tools are needed to understand the mode of action, and to further improve the new wood protection systems. A set of useful tools are found among the molecular methods. This paper presents an overview of some of the tools available, and the methods are exemplified by papers within the frame of wood protection issues. However, there is stil...
G Alfredsen, A M Hietala, C G Fossdal, H Solheim


Microwave curing of furfuryl alcohol modified wood
2007 - IRG/WP 07-40371
Furfurylated wood has shown to have promising properties for a wood modification agent during the last years. In this paper, an alternative curing method for furfuryl alcohol modified pine sapwood by means of microwave radiation was investigated. Different process parameters of microwave treatment such as output power, exposure time to microwave radiation, initial wood moisture content and evapor...
A Treu, E Larnøy, H Militz


Wood furfurylation process development. Part 2: Lowry impregnation trials
2007 - IRG/WP 07-40377
The objective was to evaluate whether Lowry-impregnation of Scots pine with FA100-mix, instead of the FA40-mix, would lead to similar or slightly higher WPGs and to investigate any potential changes in penetration pattern. The results indicate that the penetration was better, also penetrating the outer zone of the heartwood. Furthermore, it was possible to reduce the WPG-levels for pine down to 50...
M Westin, E Larnøy, S Lande


Protection of wood for above ground application through modification with a fatty acid modified N-methylol/paraffin formulation
2007 - IRG/WP 07-40378
Hydrophobic chemical modification can be regarded as an alternative approach to conventional wood preservation using biocides in order to protect wood in hazard class 3 according the European Standard EN 335-1. A formulation containing fatty acid modified N-methylol/paraffin and an aluminium salt catalyst was used to change the material properties of wood in order to protect wood from fungal dec...
Nguyen Hong Minh, H Militz, C Mai


Natural Weathering of Coated Oil Heat Treated Wood
2007 - IRG/WP 07-30440
Oil heat-treated (thermally modified) pine wood was coated with 9 different types of solvent- or water-borne exterior finishes. The systems with modified wood substrate as well as unpainted and painted non-modified controls were exposed to weathering (EN 927-3) on two locations with sub-alpine and alpine climate. The influence of natural ageing on surface systems was evaluated after one year of ex...
M Petric, B Kricej, M Pavlic, A Rapp


Fire, flame resistance and thermal properties of oil thermally-treated wood
2007 - IRG/WP 07-40361
Oil thermal treatment, first developed by German scientists, is a promising technology for improving the durability and dimensional stability of wood for outdoor above-ground residential uses such as siding and shingles. The present authors’ previous research showed that 220ºC is an optimal treatment temperature, with 2 hours’ treatment producing wood with significantly improved moisture and ...
Jieying Wang, P Cooper


The effects of chemical modification on the biological properties of alder and spruce particleboards
2007 - IRG/WP 07-40363
This study is evaluated by measuring the weight loss, and the ability of white and brown-rot fungi to attack unmodified and modified particleboards manufactured using spruce (Picea orientalis (L.) Link.) and alder (Alnus glutinosa) chips. The chips were reacted with acetic, succinic, maleic and phthalic anhydride at constant temperature for 3 hours then, hot pressed at 150 °C by using phenol for...
Ü C Yildiz, E Dizman, S Yildiz, A Temiz, M Aslan, E D Gezer


Resistance against basidiomycetes of 1,3-dimethylol-4,5-dihydroxy ethylene urea (DMDHEU)-modified plywood of Pinus sylvestris
2008 - IRG/WP 08-40398
Plywood produced with rotary-cut veneers of Pinus sylvestris impregnated with a solution of 1.3 M 1.3-dimethylol-4.5-dihydroxyethyleneurea (DMDHEU) and glued with a phenolic resin (Prefere 4976 DYNEA) were inoculated with Coniophora puteana, Coriolus versicolor and Pleurotus ostreatus, following the European standard ENV 12038. The specimens were leached following European standard EN 84. The re...
A Dieste, A Pfeffer, S Bollmus, H Militz


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