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Comparative investigations between thermal and microwave assisted digestion as a novel tool for the chemical analysis of inorganic wood preservative components
2011 - IRG/WP 11-20461
The correct chemical impregnation of wood requires an internal as well as external quality control of the treated wood. The active is located in a solid matrix, therefore it is often difficult to analyse such material since most analytical procedures are based on liquid systems. Because of this quite a number of methods – like extraction or thermal digestion - were developed in order to transfer...
H Ahl, J Fromm, E Melcher


Thermally modified timber (TMT) for decking applications – determination of relevant surface properties
2011 - IRG/WP 11-40544
In recent years thermally modified timber (TMT) entered various market segments. It is used for facades, horticultural equipment, garden furniture, and also for kitchen and bathroom cabinets. However, flooring turned out to be the most important application for TMT, either as interior parquet or as exterior decking. Besides durability and dimensional stability, which had been the initial target pr...
L Meyer, C Brischke, C R Welzbacher


Limited variability in biological durability of thermally modified timber using vacuum based technology
2011 - IRG/WP 11-40567
The SmartHeat® thermal timber treatment is a new technology based on the process parameters being steered very precisely mainly due to the vacuum applied and heating system involved. Timber treated with this technology shows a potential for less variability of biological durability in one batch. Several batch treatments were sampled and assessed on statistical variability of decay resistance agai...
J Van Acker, S Michon, J Van den Bulcke, I De Windt, B Van Swaay, M Stevens


Mold Control for Treated Lumber in Block-Stack Storage Conditions
2012 - IRG/WP 12-30588
The mold development and control for freshly treated and block-stacked wood have been evaluated using a green house mold testing method. The results for the mold resistance of several commonly used water boron preservative treatment systems, such as ACQ, Copper Azole, and borates with and without inclusion of mold inhibitors are presented. The data suggest that the different preservative treatme...
L Jin, P Walcheski, A Preston


Effects of oil types and treatment temperature on the properties of wood subjected to thermal modification in oil medium
2012 - IRG/WP 12-40574
The effect of the use of oil as a medium of heat transfer during thermal modification of different species of wood has been widely investigated with different results accruing with regards to the various end-use properties of the materials. However very little have been done on the effect of oil types as well as its interaction with treatment temperature on the resultant properties of the material...
L Awoyemi, M M Apetogbor, A A Oteng-Amoako


Influence of heat treatment intensity on the structural integrity of 14 timber species
2012 - IRG/WP 12-40586
Thermally modified timber (TMT) is characterized by improved durability and dimensionally stability, but strength properties, especially the dynamic ones, are compromised at the same time. Because dynamic standard tests require high efforts and time, the high-energy multiple impact (HEMI) –test was developed for the fast and reliable characterisation of the structural integrity of TMT, showing a...
C R Welzbacher, C Brischke, G Maier


Utilization of thermodesorption coupled to GC-MS to characterize volatiles formation kinetics during wood thermodegradation
2012 - IRG/WP 12-40587
Identification of volatile degradation products produced during wood mild pyrolysis is important to have better insight on thermodegradation mechanisms. Previous studies have shown that thermodesorption coupled to GC-MS is an attractive tool to characterize and quantify products formed during wood thermodegradation indicating an higher susceptibility of hardwoods to thermodegradation compare to so...
K Candelier, S Dumarçay, A Pétrissans, M Pétrissans, P Kamdem, P Gérardin


Corrosion of fasteners in heat-treated wood – progress report after nine years’ exposure outdoors
2012 - IRG/WP 12-40601
The corrosion of common fastener materials now in use - mild steel, zinc-coated steel, aluminium and Sanbond Z-coated steel – has been evaluated after nine years’ exposure outdoors in untreated and heat-treated (thermally modified) spruce (Picea abies). Spruce from south-western Sweden was used. The heat-treatment was carried out in Finland by Stora-Enso Oy according to the ThermoWood process ...
J Jermer, B-L Andersson


Improvement of the biological performance and dimensional stability of two tropical woods by thermal modification
2012 - IRG/WP 12-40605
Pink cedar wood and rubberwood were thermally modified at 230°C in air for 4 h or for 8 h, and then subjected to bending, compression and hardness tests to evaluate the effect of the treatment on these mechanical properties. The biological performance of the modified wood was also determined, according to EN113, and the dimensional stability measured by means of the anti-swelling efficiency. The ...
M M González-Peña


Surface energy characterization of thermally modified wood using inverse gas chromatography
2013 - IRG/WP 13-20532
The objective of this work is to characterize surface energetics of thermally modified wood. Such information may be useful for a better understanding and predictions of adhesion properties between the modified wood and other material systems, e.g. coatings, adhesives or matrices in composites. Inverse gas chromatography (IGC) was used to study the surface energy characteristics of thermally modif...
S Källbom, K Segerholm, D Jones, M Wålinder


Copper Coating on Wood: a New Way of Protecting Wood
2013 - IRG/WP 13-30617
Thermal spray metal coating technology was used to apply a thin layer of copper on the surfaces of a number of wood species. The adhesion of metal coating to mahogany, oak, soft maple, spruce, white pine and medium density fibreboard (MDF) was evaluated by pull off adhesion test. The resistance of copper coated wood samples to mildew were assessed in the lab. Also, the decay resitance and water re...
M Nejad, R Shafaghi, L Pershin, J Mostaghimi, P Cooper


Decay resistance of thermally modified Scots pine after 6 years’ exposure above ground
2013 - IRG/WP 13-40624
In the present study the performance of boards treated by ThermoWood process were studied above ground and the results given are based on a “modified” horizontal double- layer test. The base layer of boards was in direct contact with ground and the conditions were much harder than in the standard method. After six years’ exposure clear differences were found between untreated Scots pine and ...
H Viitanen, S Metsä-Kortelainen, A Nurmi, S Jämsä


Effect of the nature of the inert atmosphere used during thermal treatment on chemical composition, decay durability and mechanical properties of wood
2013 - IRG/WP 13-40625
Wood heat treatment is an attractive alternative to improve decay resistance of low natural durability wood species. Nowadays, several types of thermal treatments of wood exist. These treatments differ mainly by the nature of the inert atmosphere used to avoid wood combustion which may correspond to: nitrogen, vacuum, steam or oil. Decay resistances as well as mechanical properties are strongly co...
K Candelier, S Dumarçay, A Pétrissans, M Pétrissans, P Gérardin


Utilization of TG-DSC to study thermal degradation of beech and silver fir
2013 - IRG/WP 13-40628
Thermal treatment of wood is, besides other wood modification system, used to improve the decay resistance and dimensional stability. However, the chemical changes that are caused by treatment process are still difficult to quantify, characterize and control. Previous studies have shown that thermodesorption coupled to GC-MS is an attractive tool to characterize and quantify products formed during...
K Candelier, A Treu, J Dibdiakova, E Larnøy, A Petrissans, S Dumarçay, M Pétrissans, P Gérardin


Combined effects of thermal modification and ACQ-D impregnation on properties of southern yellow pine wood
2013 - IRG/WP 13-40637
In this study, samples of southern yellow pine sapwood were first thermally modified and then treated by the alkaline copper quat-type D (ACQ-D) wood preservative. Two heating temperature (180℃ and 220℃) and two concentrations of ACQ-D solution (0.9% and 1.35%) were used in the experiments. The combined effects of thermal modification and ACQ-D on leaching performance, mechanical prope...
Wang Wang, Yuan Zhu, Jinzhen Cao


COST Action FP0904 – Increasing the Understanding of Thermo-Hydro-Mechanical Wood Behaviour and Processing
2013 - IRG/WP 13-40646
The polymeric components of wood and its porous structure allow its properties to be modified under the combined effects of temperature, moisture and mechanical action – so-called Thermo-Hydro-Mechanical (THM) treatments. Various types of processing techniques, including high temperature steam with or without an applied mechanical force, can be utilised to enhance wood properties, to produce eco...
D Jones, P Navi


Durability of alternatives to CCA-treated wood - Results from field tests after 11 years exposure
2013 - IRG/WP 13-30633
The present study was initiated as a consequence of restrictions against the use of CCA-type wood preservatives in Sweden in the 1990s. New copper-based formulations were introduced on the market and to some extent, also alternatives to preservative-treated wood, such as thermally and chemically modified and linseed oil treated wood as well as heartwood of non-tropical naturally durable wood s...
P Larsson Brelid, M-L Edlund


The Chelator Mediated Fenton System in the Brown Rot Fungi: Details of the Mechanism, and Reasons Why it has Been Ineffective as a Biomimetic Treatment in some Biomass Applications – a Review
2014 - IRG/WP 14-10828
The chelator-mediated Fenton (CMF) reaction requires the action of two types of chelating compounds. The first chelator, oxalate, solubilizes and then sequesters iron, and the second chelator reduces iron. Iron reduction must be controlled near the fungal hyphae to prevent damaging Fenton chemistry from occurring in that location. Similarly, iron reduction must be promoted within the wood/plant ce...
B S Goodell, M Nakamura, J Jellison


Changes in mechanical and chemical properties of wood exposed outdoors
2014 - IRG/WP 14-20550
The aim of this study was to investigate differences in certain mechanical and chemical properties of three different wood species (common beach (Fagus sylvatica), Norway spruce (Picea abies), and copper-ethanolamine (CuE) impregnated Norway spruce (Picea abies)) that were exposed in use class 3 (CEN, 2006) for periods between 4 and 30 months. The results show, that changes in the investigated me...
N Thaler, C Brischke, D Žlindra, V Vek, M Humar


Migration of copper from copper naphthenate treated Douglas-fir poles during storage
2014 - IRG/WP 14-50302
Preservative migration from treated wood products has raised concerns among regulators, especially when the biocides move into surface waters. In most cases, chemical levels are well below the acceptable minimum level, but can become a concern if large quantities of treated wood are stored in one location. One such case would be a location where utility poles are stored for use in emergency repai...
C S Love, C M Freitag, J J Morrell


Effect of silver nanoparticles on the rate of heat transfer to the core of the medium-density fiberboard mat
2014 - IRG/WP 14-40653
Effect of silver nanoparticles on the rate of heat transferred to the core section of medium-density fiberboard (MDF) mat was studied here. A 400 ppm aqueous nanosilver suspension was used at three consumption levels of 100, 150, and 200 mL/kg based on the weight of dry wood fibers; the results were then compared with the control MDF panels. The size range of silver nanoparticles was 30-80 nm. Res...
H Reza Taghiyari, O Schmidt, E Bari, P M Tahir, A Karimi, P Nouri, A Jahangiri


Thermal durability and biodegradation of tannin lignin adhesives
2014 - IRG/WP 14-40657
Mimosa tannins and lignosulfonates were used in wood adhesives formulation to substitute resins based on formaldehyde. Mimosa tannins were mixed with either glyoxalated sodium lignosulfonates or glyoxalated ammonium lignosulfonates. The ratios of mimosa tannins and sodium lignosulfonates varied from 20% tannins to 60% tannins. The thermal durability of the adhesives were analysed by thermogravimet...
L Chupin, B Charrier, A Pizzi, F Charrier


Effects of thermal modification on properties of Douglas-fir heartwood
2014 - IRG/WP 14-40663
The flexural properties and mass losses of thermal modified Douglas-fir pretreated with boron or glycerol were examined. Pretreatments were associated with slight, but not significant, reductions in modulus of rupture (MOR) and modulus of elasticity (MOE)of Douglas-fir at different thermal treatment levels. Boron pretreatment had the greatest effect on MOR. MOR of non-pretreated and ...
Li Yan, J J Morrell


Improving dimensional stability of thermally treated wood by secondary modification – potential and limitations
2014 - IRG/WP 14-40664
The potential of treating thermally modified wood with melamine resin to improve the dimensional stabilization is tested in this research. Two different boards of poplar (Populus ssp.) were cut into two halves. One half of each board was thermally modified (T1 and T2) in a commercial process, the other half was used as untreated reference material. The material was thermally modified using the vac...
G Behr, K-C Mahnert, S Bollmus, H Militz


Development of new wood treatments combining boron impregnation and thermo modification - Effect on decay and termites durability
2014 - IRG/WP 14-40666
Environmental pressures appeared in most European countries during the last decade has lead to the development of more environmentally acceptable preservation methods. In this context, wood heat treatment has been one of the most investigated alternative methods during the last years. Treated at temperatures ranging between 180 and 220°C, wood components undergo more or less important chemical mo...
S Salman, A Pétrissans, M-F Thévenon, S Dumarçay, B Pollier, P Gérardin


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