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Dimensional Stability of Melamine Formaldehyde-Treated Southern Pine
2017 - IRG/WP 17-40774
The objective of this preliminary study was to evaluate the influence of different levels of melamine formaldehyde (MF) and curing cycle on the dimensional properties of southern pine. Thirty samples for each combination of treatment and curing regimen plus untreated controls and controls subjected to the same curing regimen were tested. Shrinkage/swelling coefficients showed that up to 60% ASE c...
H M Barnes, L S Sites, T S F A França, M G Sanders, F J N França


Effect of Particle Size on Wax Distribution in Paraffin Wax Emulsion Impregnated Wood
2017 - IRG/WP 17-40779
Paraffin wax emulsion impregnation has been a common eco-friendly approach for improving water repellency of wood. In this study, southern pine (Pinus spp.) and Scots pine (Pinus sylvesteris L.) samples were impregnated with paraffin wax emulsions of different solid contents and particle sizes, and then the time domain nuclear magnetic resonance (TD-NMR) was used to elucidate the influence of part...
Wang Wang, Jinzhen Cao, Yiheng Huang


Accessibility of hydroxyl groups in anhydride modified wood as measured by deuterium exchange
2017 - IRG/WP 17-40784
Acetylated wood shows improved properties largely due to the reduced amount of water in the acetylated cell wall. However, the exact mechanism by which water is excluded in acetylated wood remains unclear. Acetylation reduces hydroxyl content by substitution of hydroxyl groups in wood polymers but may also hinder access to unmodified hydroxyls by physical bulking. This work assesses hydroxyl acces...
G Beck, S Strohbusch, E Larnøy, H Militz, C Hill


The potential and the challenges of acetylated wood in timber bridges - experiences from an ongoing project
2017 - IRG/WP 17-40792
Acetylated wood is known to be a durable and dimensional stable alternative for high performance materials, and has high potential for exterior timber structures. Research has shown that acetylated wood can be effectively bonded by various adhesive types. However, one of the most common used adhesives for timber constructions, Melamine Urea Formaldehyde (MUF), shows a high degree of delamination o...
A Treu, R Bredesen, F Bongers


Surface Protection of Wood with Metal Acetylacetonates
2017 - IRG/WP 17-40802
Metal acetylacetonates are coordination complexes of metal ions and the acetylacetonate anion. They have diverse uses as catalysts, cross-linking and curing agents and adhesion promotors. Some metal acetylacetonates can photostabilise polymers whereas others are photocatalysts. We hypothesise that the ability of metal acetylacetonates to photostabilise wood will vary depending on the metal in the ...
Yuner Zhu, P D Evans


Studying Weathering Performance of Coatings on Thermally Modified Wood
2017 - IRG/WP 17-40805
Thermal modification and degree of improved properties depends on wood species and treatment parameters. Southern pine and spruce are the two common wood species for decking, fences and siding in North America. This study was the first to evaluate coating performance when applied on oil-heat-treated southern pine and spruce wood samples. Water uptake, colour and gloss changes of samples were analy...
M Nejad, M Dadbin, P Cooper


Impact of heat treatment on physico-mechanical properties of torrefied Antholceistha djalonensis wood
2017 - IRG/WP 17-40811
Thermal modification at relatively high temperatures is an effective method to improve the dimensional stability and mechanical properties of wood. This study was carried out to investigate the impact of heat treatment on the physic-mechanical properties of torrefied Anthocleistha djalonensis wood. Thirty nine defect-free specimens of dimensions 20 mm × 20 mm × 60 were prepared for the determina...
E A Iyiola, B Olufemi, J A Fuwape, J M Owoyemi


Influence of hygro-thermal treatment temperature and duration on dimensional stabilisation of wood modified with poly(butylene succinate)
2017 - IRG/WP 17-40813
To improve wood properties, especially dimensional stability, a treatment based on poly(butylene succinate) oligomers (OBS) was experimented. After impregnation in wood, a further hygro-thermal treatment (HTT) was carried out in a pressurized reactor at 100% relative humidity (RH) at differing temperatures for differing durations. The aim of HTT is to induce partial swelling of wood cell walls so ...
C Grosse, M Noël, L Rautkari, P Gérardin


Aesthetic changes of coated thermally modified wood after artificial weathering
2017 - IRG/WP 17-40819
The thermal modification process affects the chemical configuration of the wood matrix improving some physical properties and durability. In addition, the distinctive dark tones of thermally modified timber increase the economic value of several light-coloured species. However, heat-treatment alters the substrates and it could influence in the application of coating products, necessaries to mainta...
R Herrera, J Sandak, E Robles, J Labidi


Understanding of the effect of ancestral and natural saltwater treatment on durability, fibers densification and chemical modification of palm wood
2018 - IRG/WP 18-10921
The palm-tree sector plays a very important role on both the socioeconomic and ecological levels, in Tunisia. There are three million trees in Tunisian palm plantations, ensuring a potential significant wood production, mainly in the craft and furniture industries. In the past, Date Palm wood (Phoenix dactylifera L.,) was also used as structural material. Its low natural durability and its low m...
M T Elaieb, A Namsi, M Tella, M-F Thévenon, K Chandelier


FTIR-ATR monitoring of chemical changes of thermo-chemically modified beech wood degraded by brown-rot fungus
2018 - IRG/WP 18-40823
Wood chemical modification with lactic acid oligomers (OLA) has been reported to confer promising properties for wood outdoors applications. To better understand the lactic acid interaction with wood, chemical changes following biological degradation have been characterized with a battery of tests. Fourier transform infrared (FTIR) spectroscopy has been proved to be a valuable tool for studying fu...
C Grosse, M Noël, M-F Thevenon, P Gérardin


Resistance of modified wood to termite attack assessed in laboratory and field testing: A review of internal research
2018 - IRG/WP 18-40824
Within the past decades, new wood modification technologies have been investigated in order to improve certain wood characteristics and enable the use of timber products for outdoor applications. Some of these non-biocidal technologies have been developed and commercialized recently. Thus, various material properties were studied intensively and shown to be improved. To a great extent, previous re...
L Emmerich, P Gascón-Garrido, H Militz


Long-term performance of DMDHEU-treated wood exposed in ground, above ground and in the marine environment
2018 - IRG/WP 18-40825
Chemical wood modification with N-methylol compounds such as 1.3-dimethylol-4.5-dihydroxyethyleneurea (DMDHEU) has been studied intensively since the 1990s. Research of the past years focused on treatment of Scots pine (Pinus sylvestris L.) and European beech wood (Fagus sylvatica L.) and was shown to be applicable to improve specific material properties. A high resistance against wood-destroying ...
L Emmerich, H Militz, C Brischke


Multiscale modification on water resistance and dimensional stability of Populus cathayana by alkali lignin combined with heat treatment
2018 - IRG/WP 18-40826
The aim of this study was to enhance the water resistance and dimensional stability of fast growing wood by alkali lignin combined with heat treatment. Poplar (Populus cathayana) samples were first impregnated with alkali lignin solution and then subjected to heat treatment at 140, 160, and 180°C respectively for 2h. Properties of leachability, moisture adsorption and water absorption, contact an...
H Zhou, J Li, E Ma


Thermodynamic properties of furfurylated wood during moisture adsorption process
2018 - IRG/WP 18-40828
Furfurylation of wood seems a promising wood modification method considering the wide raw material source of furfuryl alcohol (FA) and overall performance of FA modified wood. However, the modification mechanism of furfurylation is still not clear and needs further investigation. In this study, poplar (Populus cathayana Rehd.) samples with the size of 1(R) mm × Ф4 mm, were impregnated with ...
J Wang, J Cao, T Yang, E Ma, W Wang


An examination of the potential for the use of the Maillard reaction to modify wood
2018 - IRG/WP 18-40829
Finding efficient ways to decrease wood decay caused by fungi and increasing its dimensional stability is an important issue in the timber construction. A possible way to avoid wood decay by fungi is by reducing the water content of wood, since water is a primary condition for fungal growth. Bulking of the wood cell wall by chemical reagents occupies the space where water normally occurs. At the s...
K Peeters, E Larnøy, A Kutnar, Č Tavzes, C A S Hill


Visual appearance of unpainted wooden claddings during the first year of outdoor exposure: Evaluation of surface mould growth, lightness (L*) and wasp attack
2018 - IRG/WP 18-40841
This study addresses changes in visual appearance of unpainted wood materials exposed outdoors. Specimens of Norway spruce (Picea abies) Scots pine (Pinus sylvestris), aspen (Populus tremula), acetylated Radiata pine (Pinus radiata) and DMDHEU-modified Scots pine sapwood were exposed facing south in Ås, Norway for 60 weeks. During this period, surface mould growth development and wasp attack were...
S Karlsen Lie, L Ross Gobakken, G I Vestøl, O Høibø


Improvement of short rotation teak wood properties through thermal modification
2018 - IRG/WP 18-40842
Teak (Tectona grandis L.f) is one of the most popular tropical timber species. Nowadays, the source of long rotation teak is limited in the availability. Many wood processing industries use short rotation teak, which has lower quality especially in durability and dimensional stability. Heat treatment is an eco-friendly method improving dimensional stability and durability of wood. The objectives o...
L A Pratiwi, I W Darmawan, B George, A Merlin, C Gérardin, S Dumarçay, T Priadi, P Gérardin


Developments within COST Action FP1303 related to the modification of wood
2018 - IRG/WP 18-40847
COST Action FP 1303 (Performance of bio-based building materials) was established in 2013 with the main aim to improve the knowledge on the performance of bio-based materials used as building products and the assessment of factors influencing these, with the aim of increasing their service life. This Action has helped in understanding the interlinked relationships between durability, product aesth...
D Jones


Polyesterification of wood using sorbitol and citric acid under aqueous conditions
2018 - IRG/WP 18-40851
The aim of this research is to determine if the polyesterification of sorbitol and citric acid in wood has a future potential as a wood modification process. Pine wood was impregnated with an aqueous solution containing citric acid and sorbitol and was thereafter cured at 103, or 140°C for 18 hours. The dimensional stability and leaching resistance were studied for both modification temperatures....
E Larnøy, A Karaca, L R Gobakken, C A S Hill


The use of bicine and tricine as possible Maillard reagents in a combined thermal/chemical modification of beech
2019 - IRG/WP 19-40852
The effects of thermal modification have been well established, particularly in terms of reductions in mechanical performance. In recent years, there has been an increase in studies related to the Maillard reaction. More commonly associated with food chemistry, it involves the reaction of amines and reducing sugars during cooking procedures. This paper has attempted to combine the use of amines an...
D Jones, C-M Popescu, D Krzisnik, M Hocevar, M Humar, M-C Popescu


Using X-ray scattering to elucidate the mechanisms behind the moisture and fungal decay resistance of epoxybutene modified wood
2019 - IRG/WP 19-40854
Chemical modification of the hydroxyl groups of wood can improve the properties of wood by providing moisture and biological resistance, as well as dimensional stability. Southern pine solid wood was chemically modified to various weight percentage gains (WPG) with epoxybutene (EpB, 8%-38% WPG). After modification, specimens were extracted with a toluene: ethanol (2:1) solution for 2 hours or wate...
R E Ibach, N Plaza


Development of beech wood thermo-chemical modification treatments based on different vinylic derivatives of glycerol and polyglycerol
2019 - IRG/WP 19-40855
In this study, a combination between chemical and thermal wood modification has been investigated. Seven types of a low concentration of 10% aqueous additive solution of vinylicglycerol [glycerol-maleic anhydride (Gly-MA), glycidyl methacrylate (GM), and Glycerol methacrylate-maleic anhydride (GM/MA(2eq))], vinylicpolyglycerol [polyglycerol-maleic anhydride (PG-MA), polyglycerol methacrylate (PGM...
M Mubarok, S Dumarcay, H Militz, K Candelier, M-F Thevenon, P Gerardin


Dimensional stability and decay resistance of montmorillonite- furfuryl alcohol modified wood
2019 - IRG/WP 19-40856
Poplar (Populus cathayana) wood was impregnated successively by organo-montmorillonite (OMMT; in concentration of 2%) and furfuryl alcohol (FA, in concentrations of 15%, 30% and 50%) in a two-step method to prepare OMMT-FA modified wood. The modified wood samples were characterized using X-ray diffraction (XRD) and field emission scanning electron microscopy (FE-SEM). Moreover, wood physical and a...
L Zhang, J Cao


Study on the ability of wood-destroying fungi to grow through chemically modified wood
2019 - IRG/WP 19-40858
Over the last decades, chemical wood modification technologies were developed to increase the resistance against attack by wood-destroying organisms without using biocides. Most of those technologies are based on an impregnation step initially. In most treated wood products, mainly by using solid wood in thicker dimensions as in posts, poles, sleepers, deckings etc. it is known that wood impregnat...
L Emmerich, S Strohbusch, C Brischke, S Bollmus, H Militz


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