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The kinetics of anhydride modification reactions of wood. Experimental results and theoretical modelling
1998 - IRG/WP 98-40125
Although the chemical modification of wood remains a fertile area for research, there has been little work performed on the kinetics of the modification process. The reaction kinetics of a series of linear chain and cyclic anhydrides has been studied and activation energies of the reaction determined. The reaction kinetic profiles are determined by the relative rates of reaction of the reagent wit...
C A S Hill, J G Hillier


The relationship between preservative type and surface degrade in Pinus radiata
1980 - IRG/WP 3158
Samples of Pinus radiata D. Don were impregnated with one of two preservative types, a copper chrome arsenic salt and a light organic solvent preservative. The panels were exposed to the weather for 4-5 years at a site near Sydney, Australia. Macroscopic and microscopic examinations showed different rates and patterns of weathering between the samples treated with each preservative and an untreate...
R S Johnstone, R K Bamber


Surface characteristics of wood treated with various AAC, ACQ and CCA formulations after weathering
1991 - IRG/WP 2369
Wood samples treated with various alkylammonium compounds (AACs) as well as ammoniacal copper quat (ACQ) and chromated copper arsenate (CCA) have been studied in accelerated weathering experiments. Microscopic examination of the surfaces of these samples after exposure in a weatherometer revealed several different changes. Samples treated with didecyldimethyl ammonium chloride (DDAC) show consider...
L Jin, K J Archer, A F Preston


Microwave modification of Yellow Stringybark (Eucalyptus Muelleriana) posts for impregnation with Copper-Chrom-Arsenic (CCA) preservatives
2000 - IRG/WP 00-40185
Yellow Stringybark posts with diameters ranging from 60-100 mm were microwave conditioned using a 60 kW microwave (MW) generator. A substantial improvement in heartwood penetration of preservatives and relaxation of growth stresses was indicated such that there was no split formation following drying of the posts. High preservative absorption of copper-chrome-arsenic (CCA) was achieved ranging fro...
G Torgovnikov, P Vinden


Modification of solid wood: research and practical potential
1997 - IRG/WP 97-40098
The polymeric structure of the wooden cellwall mainly consists cellulose, hemicellulose and lignin. The most reactive sites on these components are the hydroxyl groups. The cellwall polymers (and its reactive hydroxyl groups) are responsible for most physical and chemical properties of wood. By changing the basic chemistry of the cellwall polymers, it is possible to change different undesirable at...
H Militz, E P J Beckers, W J Homan


Biological degradation resistance of wood acetylated with thioacetic acid
1983 - IRG/WP 3223
Chemically, modification of wood is being considered as an alternative to conventional preservation by toxic chemicals. Acetylated wood has been reported to be quite resistant to most biodegrading organisms at weight percent gains (WPG) around 15-19. The conventional acetylation techniques with acethic anhyrdride result in generation of acetic acid. However, acetylation with thioacetic acid overco...
S Kumar, S C Agarwal


Three years of field tests with "Lignomer" stakes in ground contact
1981 - IRG/WP 3166
The "Lignomer" (Wood Polymer Composite) is a material obtained during the polymerisation of various monomers or its mixtures in wood. As laboratory tests have shown, this material is characterized by a high resistance against biological deteriorating agents. The laboratory investigations on the durability of various materials against biological deterioration are in many instances extended by field...
K Lutomski


Moisture distribution in coated wooden panels. Studies of moisture dynamics by computerized axial tomography
1992 - IRG/WP 92-2413
Certain modern coatings have been held responsible for the rot damages in wood sidings, which have, during the past few years, appeared at an increasing extent in Scandinavia and which have occurred rather soon after the application of the coating. In this study, the moisture excluding effect of different coating systems intended for sidings have been studied with the help of an X-ray technique, c...
J Ekstedt, L O Lindgren, S Grundberg


Three-year field trials of polymeric formulations which provide a new basis for the invention and design of non-toxic wide-spectrum wood preservatives
1994 - IRG/WP 94-40029
Three types of non-toxic polymeric formulations invented using a new approach to wood preservation were challenged with termites and fungi in three-year ground-contact field trials in the sub-tropical climate of Natal. These formulations were copper soaps of carboxylic acid groups of unsaturated fatty acids of waxes and edible vegetable oils; of resin acids of rosin, and, of synthetic unsaturated ...
A A W Baecker, A Pizzi


Surface checking of CCA-treated radiata pine decking timber exposed to natural weathering
2000 - IRG/WP 00-40165
A field trial was established at four locations in Australia to assess the effect of CCA and CCA-wax treatment on the checking (cracking) of radiata pine decking timber exposed to natural weathering. Untreated decking timber and timber that had been pressure treated with water acted as controls. After 1 year's exposure the number and sizes of checks occurring in treated timber and control...
P D Evans, P J Beutel, C F Donnelly, R B Cunningham


Potential toxicants for controlling soft rot in preservative treated hardwoods. Part 2: Laboratory screening tests using sawdust
1977 - IRG/WP 2101
A technique is described for the rapid screening of toxicants against microorganisms, represented by the brown rot, Gloeophyllum trabeum, and a natural inoculum from soft rotted wood. Sawdust, in this case from sapwood of Eucalyptus maculata, is pretreated with the candidate formulation and moistened before inoculation. Visual scoring of growth can be used to discriminate suitable candidates as ea...
J D Thornton


Surface Barriers for Protection of Culture and Heritage Wooden Objects from Insect Attack
2004 - IRG/WP 04-40286
Anoxic treatment is an environment friendly procedure for eradication of wood boring insects in wooden objects of cultural and historical heritage. However, after the anoxic treatment, wooden antiques remain susceptible to further insect attacks. Possible protection against insects could be provided by the so-called post-repression protective barriers. Potential coating materials for such barriers...
M Petric, M Pavlic, B Kricej, M Humar, F Pohleven


Screening of the technical performance and aquatic toxicity of N-methylolacrylamide treated wood
2000 - IRG/WP 00-40166
In the course of the last decades chemical modification of wood species, with a limited natural durability, has been subjected to intensive research. As a possible alternative and supplementary treatment of non-durable wood in a range of applications it remains one of the major topics in the wood preservation world. Different modification systems have been scaled-up and are now in an industrialisi...
V Rijckaert, S De Geyter, J Van Acker, M Stevens


Surface protection of wood with titanium, zirconium and manganese compounds
2005 - IRG/WP 05-30376
Thin radiata pine veneers were treated with a range of titanium, zirconium and manganese compounds and exposed to natural weathering. Veneer weight and tensile strength losses were used to assess the protective efficacy of the compounds. The oxidative manganese compounds potassium permanganate and manganic acetate restricted both weight and tensile strength loss of treated wood veneers during weat...
K J Schmalzl, P D Evans


Characteristics of thermally modified wood in vacuum
2004 - IRG/WP 04-40287
In commercial thermal wood modification processes nitrogen, steam or oil has been used for the reduction of oxygen content in the reactor atmosphere. In present study no special heating medium, but an initial vacuuming step has been used for this purpose. Mass loss, resistance to fungal decay, dimensional stability, bending strength and modulus of elasticity of heat treated wood were evaluated and...
G Rep, F Pohleven, B Bucar


The degradation of wood surfaces by dilute acids
1985 - IRG/WP 3326
Thin radial/longitudinal sections(~100 µ) of Corsican Pine (Pinus nigra) and Lime (Tilia vulgaris), were exposed to Sulphuric, Sulphurous, nitric, acetic, and formic acid at 40°C in the pH range 2-6. After about 3 months exposure to Sulphuric, nitric, acetic and formic acid at pH 2.0 Pine lost some 20-25% of its tensile strength. Losses in tensile strength due to sulphurous acid were greater bei...
P D Evans, W B Banks


Permeability measurements on surface layers for detecting wood with abnormally high permeability
1988 - IRG/WP 2298
Wet storage of timber during the warm period of the year may lead to an increased permeability of the wood, an undesirable phenomenon for several wood industries and also for many end-uses. Neither before nor after drying, such wood with "wet storage damage" can be visually distinguished from wood with a normal permeability. A non-destructive method for inspecting the permeability of surface layer...
J B Boutelje, G Hägglund


Effect of fungal degradation on the chemical composition of acetylated beech wood
2003 - IRG/WP 03-40267
This study investigated the impact of fungal attack on the chemical composition of acetylated wood. Beech wood acetylated to different degrees was exposed to decay by the white-rot fungus Trametes versicolor under solid-state fermentation conditions. Laboratory soil-bed assays were also conducted to study the degradation of acetylated wood by soft rot fungi and other soil-inhabiting microorganisms...
H Militz, Dong-won Son, L Gómez-Hernández, R Sierra-Alvarez


Quantification of creosote migration down wooden poles and the prevention of its depletion during flood irrigation
1994 - IRG/WP 94-50032
Polyethylene field liners heat-shrunk onto soil-contact surfaces prevented decay of creosote-treated Eucalyptus grandis vineyard poles under flood-irrigation. The present work quantified losses of creosote from these poles after six and 24 months' service. After six months' service the mean creosote retention of unlined poles above the ground line was 12.62% (m/m dry wood), with ...
M Behr, A A W Baecker


Less pollution due to technical approaches on accelerated steam fixation of chromated wood preservatives
1988 - IRG/WP 3487
Steaming of freshly treated wood at 100°C to 120°C initiates a spontaneous fixation of copper-chromate-containing wood preservatives. For the performance, a suitable anticorrosive equipment is necessary. Good results can be achieved using a separate steaming equipment which allows a rapid heating of the wood. While warming-up, in the wood some preservative solution extends and can be partly extr...
H Willeitner, R-D Peek


Preliminary observations of the effect of growth ring orientation on the surface checking of flat sawn Southern pine decking
2005 - IRG/WP 05-20313
Checking in decking timber is a serious defect and methods of reducing its severity are required to ensure that wood can compete with alternative decking materials. The first aim of this research was to test the hypothesis that flat sawn Southern pine decking boards with growth rings oriented concave to the exposed surface will develop less severe checking when exposed outdoors than similarly expo...
K Urban, P D Evans


Test methods for modifies wood: The EU-Thematic network approach
2002 - IRG/WP 02-20255
The last decade wood modification systems have become new wood treatment methods in Europe. Alongside several industrial initiatives for heat treatments also scaling up and pilot plant projects for chemical wood modification have recently been carried out. In 2000 an initiative to create a network related to these new developments was supported by the European Commission. Within the work proposed ...
J Van Acker, D Jones


Melamine resins as preservatives results of biological testing
1996 - IRG/WP 96-40061
Based on previous work of the authors on resins, the upgrading of wood with a true solution of a methanol etherificated melamine resin in low aqueous concentration was performed. For the relative assessment of the biological resistance against brown and white-rot fungi were used not only untreated controls of pine sapwood (Pinus sylvestris L.), but also heartwood of European larch (Larix decidua M...
A O Rapp, R-D Peek


Characterization of wood decay enzymes by MALDI-MS for post-translational modification and gene identification
2002 - IRG/WP 02-10442
The recent sequencing of the Phanerochaete chrysosporium genome presents many opportunities, including the possibility of rapidly correlating specific wood decay proteins of the fungus with the corresponding gene sequences. Here we compare mass fragments of trypsin digests, determined by MALDI-MS (Matrix Assisted Laser Desorption Ionization-Mass Spectrometry), with predicted mass fragments derive...
T H de Koker, P J Kersten


Effects of the sulfuric acid modification of CCA treating solution
1987 - IRG/WP 3415
Sulfuric acid modification of CCA treating solution is often used to control the formation of sludges and undesirable deposits on the surface of treated wood. The consequences of sulfuric acid addition are examined in this work and negative effects are shown to far outweigh any benefits. Major risks include the loss of copper due to leaching from treated wood and the accelerated corrosion of treat...
R F Fox, H J Fry, E A Pasek, A S Ross


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