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Synthesis of novelty borate compounds for wood preservatives: Laboratory test of leachability and decay resistance
2010 - IRG/WP 10-30520
A novel series of ammonium tetraphenylborate (ATB) and borate chemical compounds (BBC) were synthesized as wood preservatives. The leaching rates and decay resistance of boron formulations containing ATB and BBC were conducted. The laboratory leaching results showed that boron leaching rate of treated wood by ATB formulations was from 2.1% - 6.7%, while that of BBC formulations from 23.3% -59.0%. ...
Zhiqiang Li, Mingliang Jiang, Xingxia Ma


Adsorption of ACQ components in wood
2010 - IRG/WP 10-30522
To investigate the chemical adsorption capacity of copper-monoethanolamine (Cu-Mea) components on wood, the Na+ cation exchange capacity (CEC) of red pine (Pinus resinosa Ait.) was determined and compared to the adsorption capacity of free Mea and Cu-Mea complexes. The CEC increased with increasing pH. Free Mea adsorption as a function of pH followed the sodium adsorption curve except at pH over 9...
Myung Jae Lee, P Cooper


Biological performance of wood treated with tar-oil recovered during slow pyrolysis of macadamia nut shells
2010 - IRG/WP 10-30523
This study evaluated decay and termite resistance of wood treated with tar oil obtained from a commercial pyrolysis process of macadamia nut shells. Vacuum-treated pine wood specimens were subjected to various brown and white rot fungi based on the soil-block test method specified by the American Wood Protection Association (AWPA) after leaching process. Treated specimens were also subjected to th...
S Nami Kartal, E Terzi, C Kose, J Hofmeyr, Y Imamura


Photostabilization of Wood with Higher Molecular Weight UV Absorbers
2010 - IRG/WP 10-30524
Higher molecular weight UV absorbers were created by reacting the epoxy-functionalized UV absorber 2-hydroxy-4(2,3-epoxypropoxy)-benzophenone (HEPBP) with maleic, phthalic or succinic anhydride. The ability of the UV absorbers to photostabilize wood was then examined. FTIR-spectroscopy confirmed that HEPBP reacted with phthalic anhydride to create a polyester that preserved the UV-absorbing benzop...
P D Evans, M J Chowdhury


Use of Internal Remedial Treatment to Extend Wood Life at the Fort Vancouver National Historic Site
2010 - IRG/WP 10-30525
The condition of wood in a reconstructed fur trading fort was assessed over a 30 year period. Poor initial treatment had resulted in the development of extensive early decay. While supplemental treatment with chloropicrin and methylisothiocyanate had arrested the attack, the results suggested that remedial treatments were unable to completely overcome the initial problems associated with treatmen...
C S Love, C Freitag, J J Morrell


Effects of polyvinyl alcohol on leachability and efficacy of boron wood preservatives against fungal decay and termites attack
2010 - IRG/WP 10-30526
In this study, the use of polyvinyl alcohol (PVA) as boron fixative agent was investigated. Two levels of PVA (2.5 and 4%) were evaluated with disodium octaborate tetrahydrate (DOT) at three concentrations (1, 2 and 4% boric acid equivalent (BAE) using a double vacuum impregnation processes on Scots pine sapwood specimens. Leaching was performed according to a laboratory leaching procedure. Boron ...
A Mohareb, M F Thévenon, E Wozniak, P Gérardin


Effects of Cunninghamia Lanceolata Heartwood Extracts on the Growth of Wood Decay Fungi
2010 - IRG/WP 10-30527
China-fir (Cunninghamia lanceolata) wood is well known for its good durability. This species is native to China and has been extensive planted there. Mainly, extractives are responsible for the wood resistance to decay fungi. In this paper, the extractives of China-fir heartwood were studied for their effects on various wood decay fungi. Sequential extraction of heartwood in hexane, ethyl acet...
Shujun Li, Jing Wang, Jian Li


Antifungal Effect of Bark and Wood Extracts of Condalia hookerii (Rhamnaceae), Ebenopsis ebano (Fabaceae) and Helietta parvifolia (Rutaceae) on Trametes versicolor
2010 - IRG/WP 10-30532
This research detail the growing inhibition effect on Coniophora puteana and Trametes versicolor fungi caused by hot water sawdust and bark extracts of three semi-arid land species Condalia hookerii, Ebenopsis ebano and Helietta parvifolia diluted in malt extract agar medium at 2000 ppm and 10000 ppm. After 12-14 days incubation the inhibition growing effect was measured based on the difference be...
A Carrillo, J G Marmolejo, F Garza, V Bustamante, M Garza


Degradation of Carbon-Based Preservatives by Black-stain Fungi
2010 - IRG/WP 10-30533
Some black-stain fungi are known to exhibit resistance to carbon-based preservatives. However, the cause of this resistance is unclear. The fungi may have mechanisms to tolerate these chemicals, or they may be able to degrade and detoxify them. Fungi capable of degrading carbon-based preservatives are of interest for possible bioremediation of carbon-based preservative-treated wood at the end of i...
R Stirling, P I Morris


Mobility of Copper from MCQ in Shell-Treated Wood Exposed Above Ground
2010 - IRG/WP 10-30534
Most Canadian treated decking in service has been given just a thin shell of preservative treatment but it has still performed very well. This is because copper migrated into checks and prevented germination of basidiospores on the freshly exposed untreated wood. Unlike soluble copper systems, MCQ has its copper primarily in the form of small basic copper carbonate particles. For MCQ to be effecti...
R Stirling, P I Morris


Treatment of Scots pine wood with oil in water and water in oil emulsion systems: Effects on boron leaching and water absorption
2010 - IRG/WP 10-30535
The aim of this study was to investigate the water absorption and water repellent efficiency of oils and oil water emulsions [oil-in-water (O/W) and water-in-oil (W/O)] and possibilities of reducing the amount of boron leaching from treated wood. Scots pine wood samples treated with waste or sunflower oil and water formulations contained 3%BA. The level of water absorption and water repellent effi...
E D Tomak, Ü C Yildiz, A Can


A Comparison of the Performance of Related Copper Based Preservatives against Soft Rot
2010 - IRG/WP 10-30540
The performance of pine and beech wood treated with either a soluble copper + quat (ACQ type D) preservative system or a particulate copper + quat system was evaluated in unsterile soil using the European standard ENV 807 soft rot decay test procedure. In addition, to compare soft rot performance of soluble and particulate copper directly without the influence of co-biocides, beech and pine test...
M Ray, D Dickinson, K Archer


Copper preservative systems: A rapid investigation into effects of co-biocides and used treating solutions
2010 - IRG/WP 10-30541
The efficacy of various micronized and amine copper preservative systems was evaluated using soil block testing with the copper tolerant brown rot fungi, Postia placenta. The American Wood Protection Association E22 protocol was used to compare the relative efficacy of preservatives by monitoring compressive strength losses of the systems in southern pine wood. As information, the weight losses ...
T F Shupe, K Ragon, Q Wu, M H Freeman, C R McIntyre


Application of Nanotechnology in Wood Preservation
2010 - IRG/WP 10-30542
Nanotechnology can enable the development of a wide range of new or enhanced wood-based materials and products that offer cost-effective substitutes for nonrenewable . Wood and other lignocelluloses are heterogeneous natural polymer composites with large variations in physical and chemical properties. These natural materials are composed of cellulose, lignin, and hemicelluloses. The potential use ...
M Akhtari, M Arefkhani


Laboratory evaluation of borate amine: Copper derivatives in wood for fungal decay
2010 - IRG/WP 10-30543
The aims of this study were to evaluate borate: amine: copper derivatives in wood for fungal decay protection as well as the permanence of copper and boron in wood. Wood treated with each of four derivatives of borate:amine:copper prevented fungal decay. Disodium tetraborate ecahydrate (Borax):amine:copper derivatives with retentions of 0.61 to 0.63% after water leaching prevented decay by Gloeo...
G Chen


Natural compounds: A review of their use for wood protection
2010 - IRG/WP 10-30545
A lot of research in the field of wood protection has focused on natural compounds but very few of these have been implemented by industry. This review is an attempt to bring together information from selected area of work: - A brief review of the work done on natural products as organic biocides for wood protection. - Table containing information on natural products, their use as organic biocid...
T Singh, A P Singh


Field trials of wood preservatives in UC3 retention. Part 1. Durability results after 13 years in and above ground
2010 - IRG/WP 10-30548
In 1996 an extensive field trial program was set up in order to obtain more data on wood treated with chromium and arsenic free preservatives in Use Class 3 retention. Apart from durability in and above ground, other features were also assessed, e.g. discoloration by staining fungi, depletion of active ingredients, weathering and corrosion of fasteners in con¬tact with the treated wood. Wood spec...
M Westin, J Jermer, M-L Edlund, P Larsson Brelid, I Johansson


Studies on Effect of pH on Copper Availability in Copper-Based Preservatives
2010 - IRG/WP 10-30549
Laboratory methods have been employed to investigate the pH effect on the copper solubility of basic copper carbonate. The pH was controlled using two different approaches. One was with the adjustment of pH of the solutions by acid or base using sulfuric acid or sodium hydroxide until the solution equilibriums were obtained for each defined pH. A second approach was to control pH with buffer sol...
L Jin, P Walcheski, A F Preston


Using plant oils as hydrophobic substances for wood protection
2010 - IRG/WP 10-30550
The increased interest to use oils as hydrophobic agents and the current debate about the further use of creosote emphasises the urgent need of better understanding of plant and other oils as wood protectors. The present study sheds light on the hydrophobic properties and distribution of various plant oils in the anatomical structure of Scots pine sapwood. Oil retentions from approximately 70 to 5...
D Panov, N Terziev, G Daniel


Accelerated L-joint performance testing of organosilicon treated wood
2010 - IRG/WP 10-30551
In this research Scots pine sapwood L-joints were treated with organosilicons and organosilicons in combination with biocides. These L-joints were prepared and exposed according to the accelerated L-joint method. They were inspected each season for fungal discolouration and removed from the rack after three years outdoor exposure. Subsequently the moisture content, mass loss and decaline uptake we...
L De Vetter, J Van Acker


The Effects of Natural Weathering on the Properties of Heat Treated Alder Wood
2010 - IRG/WP 10-40484
Heat treatment is an effective method to improve the dimensional stability and biological durability of wood. The heat treatment technology and the heat treated wood products were recently introduced to Turkey. However, only a few studies have been reported on the effect of natural weathering on the properties of heat treated wood in both Turkey and the world. In this study, heat treated alder (Al...
S Yildiz, Ü C Yildiz, E D Tomak


Repairing of wooden elements by beta-method using carbon, steel or beech rods
2010 - IRG/WP 10-40488
Presented paper is focused on repairing of wooden elements by Beta joints reinforced with carbon, steel or beech rods, and on comparing the efficiency of these joints with traditional carpentry joints. In model laboratory experiments have been determined the bending strength (fm) and the modulus of elasticity (E) of control or original elements (fm-Control; Eo) from Norway spruce (Picea abies Kars...
L Reinprecht


Fungal decay resistance and mechanical properties of plywood panels made from maritime pine (Pinus pinaster) and bonded with cornstarch-quebracho tannin-phenol formaldehyde adhesive
2010 - IRG/WP 10-40490
The aim of this work is to demonstrate the performances of cornstarch-quebracho tannin-based resins designed as adhesive in the plywood production. In this way, the cornstarch and quebracho tannin was introduced in the classic adhesive formulation in order to supply a part of phenol-formaldehyde (PF). In order to evaluate the mechanical performances of optimal cornstarch-quebracho tannin-PF, plywo...
F Charrier, A Moubarik, A Allal, A Pizzi, B Charrier


Sorption properties of wood impregnated with aqueous solution of boric acid and montan wax emulsion
2010 - IRG/WP 10-40492
Non-biocidal techniques for wood protection become more and more important, nowadays. One of the possible treatments is use of water repellents. In the present research influence of, one of the possible water repellent, the montan wax emulsion, on the moisturizing and the sorption characteristic of impregnated wood was investigated. To achieve a better protection against wood decay fungi, montan w...
B Lesar, M Humar


Hydrothermal modification for upgrading the durability properties of soft deciduous wood
2010 - IRG/WP 10-40494
To extend the application potentialities of soft deciduous wood, upgrading the durability properties, hydrothermal modification (HTM) of aspen alder and birch wood was investigated. The treatment was conducted in a multifunctional laboratory device WTT. In the previous cases it has been found that the treatment at 160oC improves the durability insufficiently. The modification at 180oC ensured a hi...
B Andersons, I Andersone, V Biziks, I Irbe, J Chirkova, E Sansonetti, J Grinins, H Militz


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