Your search resulted in 563 documents. Displaying 25 entries per page.
Recovery of copper chromium and arsenic from old CCA treated commodities
1998 - IRG/WP 98-50118
Due to the expected increase in spent treated wood over the next several decades, numerous means to reuse and recycle preserved wood have been proposed. Burning this wood for cogeneration or recycling of CCA treated wood into reconstituted composites are possible methods, but they are limited to laboratory scale because of environmental air emission issues and the manufacturing process.
In the av...
D P Kamdem, Wanli Ma, Jun Zhang, J Zyskowski
Removal of copper, chromium and arsenic from CCA treated wood using boron compounds
2005 - IRG/WP 05-50230
This study evaluates the copper (Cu), chromium (Cr) and arsenic (As) removal from CCA treated wood using boron compounds such as boric acid, borax (sodium tetraborate), and Timbor (DOT, disodium octaborate tetrahydrate) at varying (3 and 5%) concentrations. Remediation processes were taken at 1, 5 and 10 day intervals. Metals in remediated chips or sawdust were then analyzed using ICP and XRF. Res...
B Tarakanadha, T Hata, S N Kartal, W J Hwang, Y Imamura
Influence of carboxylic acids on LEACHING of copper amine based preservatives
2005 - IRG/WP 05-30365
The importance of chromium free preservatives is increasing. Leaching of copper from wood preserved with such solutions is still higher compared to leaching from wood impregnated with copper chromium ones. In order to decrease leaching, different carboxylic acids (octanoic, 2-etilheksanoic, decanoic) were added to copper/amine/boron aqueous solutions. Experiment of leaching of copper from Norway s...
M Humar, P Kalan, F Pohleven
Field evaluation of CCA movement in sap-displaced copper chrome arsenic treated softwood poles
1989 - IRG/WP 3539
Commercial sap-displaced UK grown Scots and Corsican pine, and Sitka and Norway spruce poles were exposed in a field site at Dundee, Scotland and radial distribution profiles of CCA monitored prior to implantation and after subsequent field exposure. Results show that groundline levels of all preservative elements were higher after 1 and 2 years field exposure compared with those recorded prior to...
S D Hainey, G M Smith, A Bruce, P D Evans, B King, H J Staines
Performance of preservative-treated wood not in ground contact
1975 - IRG/WP 254
Experimental sash units of Pinus strobus L. and Pinus resinosa Ait. wood were removed from a test fence at Ottawa, Canada after outdoor exposure of over 20 years. The units were superficially treated, prior to painting, with preservatives containing either copper naphthenate, pentachlorophenol or a combination of zinc naphthenate and pentachlorophenol. Results indicated that all treatments were ef...
J K Shields, J Krzyzewski
Laboratory evaluation of the termiticidal effectiveness of TanalithÒ 3485
1995 - IRG/WP 95-10109
The termiticidal effectiveness of the copper azole TANALITH 3485 was evaluated with the benchmark preservative TANALITH C in a laboratory bioassay using two species of subterranean termites, Mastotermes darwiniensis Froggatt and Coptotermes acinaciformis (Froggatt). Retentions of TANALITH 3485 tested were 0.15, 0.24, 0.285 and 0.40% m/m Cu and for TANALITH C 0.025, 0.05, 0.08 and 0.095% m/m Cu. Un...
J W Creffield, J A Drysdale, N Chew, N-K Nguyen
Influence of acidification on decay processes of CCB treated wood
2004 - IRG/WP 04-10514
The phenomenon of copper tolerance by brown rot fungal strains has been known for a long period but the complete mechanism of copper tolerance by these fungi is not understood yet. Copper tolerance has previously been linked to oxalic acid excreted by copper tolerant brown rot fungal strains. This acid reacts with copper in the wood to form an insoluble and therefore less toxic copper oxalate. The...
M Humar, S A Amartey, M Šentjurc, F Pohleven
Laboratory studies of CCA-C-leaching: influence of wood and soil properties on extent of arsenic and copper depletion
2002 - IRG/WP 02-50186
The extent which a wood preservative leaches is important for efficacy studies and environmental concerns. However, little information exists on the effect soil properties have on leaching. This study investigated leaching of stakelets which had been cut from five different southern yellow pine (SYP) sapwood boards then treated with CCA-C to a target retention of 6.4 kgm-3 (0.4 pcf). All stakel...
D Crawford, R F Fox, D P Kamden, S T Lebow, D D Nicholas, D Pettry, T Schultz, L Sites, R J Ziobro
Water repellency of wood treated with alkylammonium compounds and chromated copper arsenate
2000 - IRG/WP 00-30231
The comparative water sorption properties of southern pine treated with CCA and several alkylammonium compounds was evaluated for freshly treated wood and for wood after exposure in a fungus cellar. It was found that CCA imparts considerable water repellency to wood which is reduced somewhat after exposure to wet soil. With the exception of a long chain (C20 -C22) compound, the alkylammonium compo...
D D Nicholas, A Kabir, A D Williams, A F Preston
Preservative treatment of wood by diffusion processes - Simulation of commercial treatment processes
1988 - IRG/WP 3498
Spruce (Picea abies), Scots pine (Pinus sylvestris) and birch (Betula pendula) were preservative treated by diffusion with mixtures of copper sulphate and arsenic pentoxide. The preservative was fixed after a suitable diffusion storage period by soaking in ammonia solution. A high standard of treatment could be achieved in spruce sapwood. This was attributed to its low wood density, and high wood ...
P Vinden
Performance of copper naphthenate-treated hardwoods
2001 - IRG/WP 01-30269
Copper naphthenate (CuNap) is a historically proven, commercially produced and industry utilized preservative for many wooden commodities including poles, fence posts, lumber, timber and wood shakes/shingles. Historically, most wood preservatives are tested using the sapwood of softwood species like pine (Pinus spp.) and or Douglas-fir (Pseudosuga menziesii) and even though the railroads of the wo...
H M Barnes, T L Amburgey, H M Freeman, J A Brient
Persistance of active ingredients in treated wood
1993 - IRG/WP 93-50001-20
Disposing of chemically protected waste wood implies the distinction between surface and pressure treatment. Considering that barked round-wood merely contains, after 7 months open storage, less than 30 g per ton of bark or 25 mg per ton of sapwood, depending on the type of insecticide, the bark or sapwood shavings may be incinerated normally, according to less severe legal prescriptions than for ...
E Graf, P Manser, S Rezzonico, B Zgraggen
Timber preservatives and corrosion
1983 - IRG/WP 3228
A survey of preservative treated timber commodities has illustrated problems that may be caused by corrosion. After treatment, timber should be compatible with commonly used fasteners. Whilst many corrosion methods have been used in the past, no standardized method is used by workers in timber preservation. The Queensland Department of Forestry is developing laboratory test methods for assessing c...
R I Davis
Leaching of preservative components from pine decking treated with CCA and copper azole, and interactions of leachates with soils
2001 - IRG/WP 01-50171
Radiata pine decking was treated with CCA and copper azole preservatives to Australian H3 retention using conventional and modified Bethel schedules, and air-dried. Treated decking boards and durable hardwood controls were subjected to leaching in weather-exposed decks, and matching 19mm cubes were leached in extended AWPA E11-97 lab tests. Deck runoff and E11 leachate water was analysed after rai...
M J Kennedy, P A Collins
Environmental fate of copper-based wood preservatives in different soil substrates - Part 1: Screening of the metal adsorption potential
1998 - IRG/WP 98-50101-21 a
In treatment plants, spillage of wood preservatives onto soil may be of environmental concern. This potential soil contamination served as an objective for a screening study. Three different mineral soils, a mineral substrate and two horticultural substrates are examined for their sorptive potential of copper through mixing with wood preservative solutions.
Depending on the soil/substrate charact...
G M F Van Eetvelde, J M Mwangi, F Tack, R Hartmann, M Stevens
Efficacy of copper:propiconazole and copper:citrate systems in ground contact exposure at a site with copper tolerant fungi
2003 - IRG/WP 03-30305
Southern yellow pine (SYP) sapwood field stakes were treated with copper alone (ammoniacal copper carbonate, ACC) at four levels, or three levels of copper (1.6, 3.2, or 6.4 kgm-3, as CuO), air-dried, then re-treated with propiconazole in a light organic solvent at 0.07, 0.3, or 0.7 kgm-3 retentions. In a separate study, SYP field stakes were treated with three levels of ACC to give 6.7, 13.4 or ...
D D Nicholas, T Schultz
Accelerated diffusion treatment of sawn Sitka spruce grown in the UK
1986 - IRG/WP 3395
The treatment of 'green' sapwood and heartwood of Sitka spruce by diffusion methods was investigated. Steam/dip treatment processes gave increased solution uptakes and depths of penetration of copper in comparison with a simple dip treatment. Further investigation is required to reduce diffusion gradients with copper based formulations and to improve the penetration of '...
R J Murphy, D J Dickinson
Microwave digestion of preserved wood for the determination of Cu, Cr, As, B and P in quality control
1991 - IRG/WP 2364
A microwave digestion method for the determination of copper, chromium, arsenic, boron and phosphorus in preserved woods is described. Samples were digested with nitric acid in pressure-relief type teflon PFA vessels by microwave heating in a commercial laboratory microwave oven. Fast, efficient and complete digestion was achieved within 29 min for 12 samples. The digestion time compared favourabl...
N Bernth, L B Sheard
International collaborative laboratory comparison of two wood preservatives against subterranean termites: Second update
1995 - IRG/WP 95-10117
As was agreed by members at the termite workshop at the 24th annual meeting of IRG in Orlando, USA, in May 1993 to initiate an international subterranean termite laboratory bioassay to compare the various preferred termite protocols used by IRG termitologists was initiated. The author was nominated to co-ordinate this comparative laboratory evaluation of two wood preservatives (CCA and Cu-naphthen...
J R J French
The Copper Tolerance of Mycelium vs. Spores for Two Brown Rot Fungi
2002 - IRG/WP 02-10422
The copper tolerance of two brown rot fungi, Gloeophyllum sepiarium and Oligoporus placentus, has been tested using both mycelia and basidiospores as inoculum sources. Mycelial growth of O. placentus on agar medium was shown to be much more tolerant to copper (as copper sulfate) than that of G. sepiarium. However, there was no difference in copper tolerance of basidiospores between the two specie...
S Choi, J N R Ruddick, P I Morris
Dimensional stabilization and decay resistance of wood treated with brown-rotted lignin and copper sulfate
1990 - IRG/WP 3608
The objective of this study was to evaluate the potential usefulness of brown-rotted lignin (BRL) as a dimensional stabilization and copper complexing agent for wood treatment. For dimensional stabilization, aqueous solutions of the lignin extract were combined with either copper sulfate, glyoxal or other additives. Anti-shrink efficiency (ASE) values as high as 42% were obtained with wood treated...
L Jin, D D Nicholas, T Schultz
Laboratory Evaluation and Field Trial of Chlorothalonil and Copper-based Preservatives and Leaching Performance of Copper in Copper Treated Wood
2002 - IRG/WP 02-30279
Soil block test and field trial of some Chinese plantation wood species pine and poplar treated with chlorothalonil formulations and copper-based preservatives such as ACQ-B and copper citrate (CC) were conducted. The results of soil block test indicated that chlorothalonil formulations and ACQ-B as well as CC are very effective for controlling the 2 fungi species Corious versicolor and Poria plac...
Mingliang Jiang, Ping Wang, Chungen Piao, Zhaobang Li, Quan Lu, Lei Liu
Diffusion modeling of inorganic wood preservative leaching in service
2005 - IRG/WP 05-50224-5
To evaluate the potential environmental and health implications of leaching of inorganic wood preservatives in service under different conditions, there is a need for a predictive model that provides estimates of the rate and extent of leaching over a wide range of product dimensions and exposure conditions. In this paper, we show that the leaching behavior of inorganic preservative components fr...
L Waldron, P A Cooper, Y T Ung
Accelerated termicidal performance data for new water-based copper linoleate formulations
1996 - IRG/WP 96-30104
An organic solvent based copper linoleate (Culin) has proved itself as an effective wood preservative in long term field trials in South Africa over a period of 30 years. Whilst the organic solvent based product offers good wood preservative performance, primary industrial interest has been in an emulsified version of the product. The objective of this study was to evaluate the influence of two di...
D Conradie, P Turner
Mechanistic aspects of the reactions of copper complexes with lignin in the presence of hydrogen peroxide and lipid hydroperoxide model compounds as proposed for white rot fungi
2001 - IRG/WP 01-10399
The structural principles and the oxidative reactions of the catalytic system consisting of copper, hydroperoxides, and copper coordination compounds that contain aromatic nitrogen atoms are similar to those of catalytic centers of oxidative enzymes involved in delignification reactions of white rot fungi. The system is capable of selectively degrading lignin and its low molecular weight would all...
K Fackler, P Lamaipis, E Srebotnik, M Humar, C Tavzes, F Pohleven, M Sentjurc, T Watanabe, K Messner