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The effect of additives on copper losses from alkaline copper treated wood
2007 - IRG/WP 07-50246
The replacement of chromated copper arsenate (CCA) by alkaline copper compounds has heightened awareness of the potential impact of copper losses on aquatic organisms. While there remains a healthy debate concerning the actual risk of copper leaching from wood preservatives into aquatic ecosystems, it is clear that reducing these losses will be necessary to avoid continued regulatory actions aga...
J Mitsuhashi, J J Morrell, L Jin, A F Preston


Quercetin - a potential compound of Azadirachta indica A. Juss. (Neem) leaves exhibiting activity against wood decaying fungi and termites
2008 - IRG/WP 08-30463
Azadirachta indica A.Juss. is widely recognized for its medicinal, insecticidal, pesticidal and anti-microbial property. Methanol extract of neem leaves revealed marked anti-fungal activity when subjected to malt-agar and soil block bioassay against wood destroying brown (Oligoporus placentus) and white rot (Trametes versicolor). The extract also revealed marked termicidal property when subjected ...
S Dhyani, S Tripathi


Effect of amphiphilic antioxidant alkyl ammonium ascorbate on inhibition of fungal growth: Application to wood preservatives formulation
2008 - IRG/WP 08-30466
Amphiphilic surfactants were synthesized from ascorbic acid and different fatty amines and evaluated for formulation of wood preservation products. Characterization of physicochemical properties of the new compounds indicated classical behavior of cationic surfactants. Antioxidant properties, estimated using methyl linoleate oxidation inhibition method, were similar to that of ascorbic acid teste...
C Gérardin , T Koumbi Mounanga, P Gérardin


Resistance to decay fungi of ammonium borate oleate treated wood
2009 - IRG/WP 09-30505
Ammonium borate oleate molecule (ABO) produced from reaction between boric acid, ammonia and oleic acid was tested as wood preservative treatment against brown and white rot fungi according to European standards. This compound was prepared according to a previous study which has proved existence of synthesis reaction and effectiveness against termites (Lyon et al. 2007b). Four solutions of ABO in ...
F Lyon, M-F Thevenon, A Pizzi, J Gril


Modification of Wood by a Water-Repellent Compound Used in the Textile Industry: Boron Release and Termite Resistance
2009 - IRG/WP 09-40447
In the study, wood specimens were treated with disodium octoborate tetrahydrate (DOT) and a commercial water and oil repellent compound, FORGUARD M®, a weak cationic emulsion containing dipropylene glycol monomethylether, water and solids in its formulation and used in the textile industry. There were two different processes for preservative treatments: double and single treatments. The leaching ...
S N Kartal, E Terzi, B Erilkun, Y Imamura


Properties of strand board bonded with ammonium pentaborate (APB) modified phenol formaldehyde resin
2009 - IRG/WP 09-40455
Ammonium pentaborate (APB) is combined with phenol formaldehyde (PF) resin in this study to develop a high-performance wood-based composite. The effect of APB and its combination with polyethylene glycol (PEG) on the physical, mechanical properties as well as formaldehyde emission of strand board were tested and compared with disodium octaborate tetrahydrateand (DOT) and zinc borate (ZB). The resu...
Wei Gao, Jinzhen Cao


Weathering of Wood Modified with the N-Methylol Compound 1,3‑dimethylol-4,5-dihydroxyethyleneurea (DMDHEU)
2009 - IRG/WP 09-40467
Scots pine (Pinus sylvestris L.) sapwood boards were treated with a methylated 1,3‑dimethylol-4,5-dihydroxyethyleneurea (mDMDHEU) causing weight gains of approx. 25% and exposed to weathering for 18 months. Compared to untreated boards, treatment with mDMDHEU reduced surface discoloration mainly caused by staining fungi. Boards treated with mDMDHEU exhibited clearly lower moisture content th...
C Mai, Yanjun Xie, A Krause, K Urban, P D Evans, K Richter, H Militz


Synthesis of novelty borate compounds for wood preservatives: Laboratory test of leachability and decay resistance
2010 - IRG/WP 10-30520
A novel series of ammonium tetraphenylborate (ATB) and borate chemical compounds (BBC) were synthesized as wood preservatives. The leaching rates and decay resistance of boron formulations containing ATB and BBC were conducted. The laboratory leaching results showed that boron leaching rate of treated wood by ATB formulations was from 2.1% - 6.7%, while that of BBC formulations from 23.3% -59.0%. ...
Zhiqiang Li, Mingliang Jiang, Xingxia Ma


Three-year field test of preservative-treated Canadian species in Korea
2014 - IRG/WP 14-30646
The purpose of this study was to generate field performance data in Korea on Canadian softwood species preservative-treated to Canadian standards. Two field tests of preservative-treated Canadian softwood species, one in ground contact and one above ground, were installed in Jinju, Korea in November 2010. Western hemlock and white spruce were incised and pressure-treated with alkaline copper quate...
Jieying Wang, Jong Bum Ra, P I Morris


A Green and Novel Technology for Recovering Copper and Wood from Treated Waste - Part I
2015 - IRG/WP 15-50309
Preservative treatment of wood extends its service life. The US consumes about 70 million pounds of copper and produces about 7 billion board feet of treated wood annually. Burning and reusing CCA and copper treated wood wastes are disallowed by US EPA due to health and environmental concerns. Millions of pounds of copper and wood are disposed by landfill annually. The objective of this study was...
S Chen


A Green and Novel Technology for Recovering Copper and Wood from Treated Wood Waste – Part II: Optimization, copper metal recovery, and process design
2017 - IRG/WP 17-50326
The US consumes 70 million pounds of copper and produces 580 million cubic feet treated wood annually. The EPA disallows burning and reusing treated wood waste due to health/environmental concerns. Vast quantities of copper and wood are landfilled. Two safe and low cost extraction systems, citric acid and ammonium citrate, were identified in Part I of this study. In Part II of the study, effects o...
S Chen, R Patel


Bio-preservative properties of technical lignins from South African pulp mills: An investigation towards a conceptualized development of natural compound-based wood preservatives
2018 - IRG/WP 18-30724
The depletion of naturally durable timber and the risk posed by some of the conventional wood preservatives to human health and the environment continue to drive research efforts towards developing new formulations that are benign. Furthermore, the global concept of environmental sustainability aims at optimal use of resources and to comprehensively include conversion of waste to value added produ...
A Alade, L Tyhoda, M Meincken


Comparison of copper leaching from alkaline copper quat and copper compound nanosol-based wood preservative treated wood
2024 - IRG/WP 24-20726
To improve the leaching resistance of copper ion-based wood preservatives, copper compound nanosol-based wood preservatives were developed and its copper leaching characteristics were evaluated. Three types of preservatives (DC1, DC2, DC3) were prepared with different crystallinity and dispersant types of copper compound nanosol, and the copper concentration was adjusted to be the same as that of ...
Y-S Choi, S-M Yoon, J O Kim, J-G Kang, J-G Park


A new wood preservative system based on basic copper compound nanosols
2024 - IRG/WP 24-20728
A bottom-up process was established to synthesize insoluble basic copper compound nanoparticles and simultaneously form a stable nanosol by dropping a neutralizing agent solution into an aqueous solution of a copper compound to which an appropriate dispersant system was added. The main ingredient of MCA (Micronized Copper Azole), the leading copper-based wood preservative in the current world mark...
J O Kim, J-G Kang, Y-S Choi, S-M Yoon, H-M Lee, J-G Park


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