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Examination of preservative-treated Pinus sylvestris using electron paramagnetic resonance
1992 - IRG/WP 92-3710
EPR is currently being used to help elucidate the nature and extent of the chemical reactions occurring between wood and copper based timber preservatives. In the work reported here treated Scots pine samples were examined at room temperature and in the frozen state. Plots of the electronic parameters A|| vs. g|| were found to be a useful index of the electronic properties of the various formulati...
A S Hughes, R J Murphy, J F Gibson, A J Cornfield


The extraction of boron from treated wood for quantitative analysis: A comparison of procedures
1992 - IRG/WP 92-2414
The extraction of boron preservative from treated rubberwood and scots pine samples was compared using methods based on refluxing and extraction in 1N NaOH or distilled water at 80°C. The extract solutions were analysed by Inductively Coupled Plasma spectroscopy (ICP/AES). A simple extraction procedure based on immersion of wood samples of approximate dimension 2 x 1 x 1 cm³ in distilled water a...
R J Murphy, D J Dickinson, P W McCormack, M K Lung


Experimental variations in the distribution of CCA preservative in lignin and holocellulose as a function of treating conditions (temperature, concentration, pH, species, and time)
1984 - IRG/WP 3277
The exact distributions between lignin and holocellulose and retentions on wood of copper, chromium and arsenic as a function of various sets of conditions in a 3x3x4x2 factorial experiment in which combinations of three temperatures of treatment, three CCA solution concentrations, four pH's of the initial CCA solution and two timber species, namely Pinus radiata and Eucalyptus grandis, a...
A Pizzi, E Orovan, M Singmin, A Jansen, M C Vogel


Effects of boron formulation on specific timber types used in ships of historical importance
1991 - IRG/WP 3676
This paper reports results of preservative treatment and leaching experiments, using borax, polybor and boracol 20, on small wood blocks of English oak and American pitch pine heartwood. Earlier experiments on the performance of various biocides as possible additives to bilgewater to prevent fungal decay of shipping timbers had suggested that some formulations of boron might be associated with phy...
B King, G M Smith, J W Palfreyman, S McCutcheon


Effects of the delay in the beginning of treatment on absorption and distribution of water-soluble salts in posts treated by sap-replacement method
1992 - IRG/WP 92-3719
One of the most important matters in green wood treatments, such as sap-replacement method, is knowing the longest time available for beginning treatment without losing efficacy. In this paper, the influence of this factor on absorptions and distribution of the preservative into the wood is analized. Tree start-up times were first chosen: 3-6 hours, 48 h and 120 h after being cut down. The treatme...
M V Baonza Merino


Time-of-Flight Secondary Ion Mass Spectrometry Analysis of Polyethylene Glycol Penetration into Wood Cell Walls
2006 - IRG/WP 06-20328
Penetration of high molecular weight polyethylene glycol (PEG) into wood cell walls was investigated in red pine. PEG of different molecular weights (1000, 8000 and 20000) was labelled by bromination and treated samples were analyzed on Time-of-Flight Secondary Ion Mass Spectrometry (TOF-SIMS) in dynamic mode. Both negative and positive spectra of the samples were collected in high spatial (bunche...
D Jeremic, P Cooper, P Brodersen


Qualitative and quantitative assessment of chemicals used for wood durability improvement by Near Infrared Spectroscopy
2006 - IRG/WP 06-20349
The Near infrared spectroscopy (NIRS) could be a suitable technique to assess chemicals used for wood durability improvement in the forest products industry. NIRS methodology can be used to obtain results more quickly, less costly and without damaging the wood. In this study, wood samples selected from heartwood and sapwood of Maritime Pine (Pinus pinaster) were prepared to assess the artificial d...
S Zahri, F Charrier, H Baillères, B Charrier


Chemical reactions involved in furfurylation of solid wood - An investigation by ATR-IR spectroscopy
2006 - IRG/WP 06-40347
Wood modification with furfuryl alcohol (FA) has gained renewed interest during the last five to ten years because of advances in process technology and because of increased focus on the environmental hazards of traditional wood impregnation. The reaction mechanisms involved in the furfurylation process are not yet understood in detail. In the work presented here, the chemical reactions and their ...
T Mark Venås, L Garbrecht Thygesen, S Barsberg


Molecular methods as a tool within the field of wood protection – available methods and new possibilities
2007 - IRG/WP 07-20361
The area of wood protection is in a period of change. New tools are needed to understand the mode of action, and to further improve the new wood protection systems. A set of useful tools are found among the molecular methods. This paper presents an overview of some of the tools available, and the methods are exemplified by papers within the frame of wood protection issues. However, there is stil...
G Alfredsen, A M Hietala, C G Fossdal, H Solheim


Quantitative Determination of Cyproconazole in Wood treated with Tanalith CY
2007 - IRG/WP 07-20369
The HPLC method has been widely applied to quantitative determination of cyproconazole in preservative solutions. However, HPLC assay has not been successfully employed to determine cyproconazole content in treated wood. Some extractives from treated wood hinder cyproconazole determination because they have a similar retention time to that of cyproconazole on an HPLC chromatogram. In addition, ...
I Momohara, T Miyauchi, M Mori


Amine Oxides for Use in Wood Protection: II: Water Repellent Agents for Wood
2007 - IRG/WP 07-30426
Wood treated with cetyl and stearyl amine oxides was evaluated to determine its long term water repellency. Comparative water uptake data, generated during two years of outdoor exposure, illustrated that Lonza’s products, Barlox® 18S (N-octadecyl-N, N-dimethylamine oxide) and Barlox® 16S (N-hexadecyl-N, N-dimethylamine oxide), were effective water repellent agents, imparting lasting water res...
Xiao Jiang, L Walker


Quantitative and qualitative losses in wood of oriental spruce, Picea orientalis (L.) Link., induced by insects from forest to utility
2008 - IRG/WP 08-10647
In this study, some quantitative and qualitative losses in wood of oriental spruce, Picea orientalis (L.) Link., induced by insects from forest to utility were evaluated. In experimental plots, volume of trees damaged by Dendroctonus micans (Kug.) was 34% of the volume of total standing spruce trees in the oriental spruce forests of Turkey. The volume of standing trees that D. micans damaged was ...
H A Akinci, M Eroglu, G E Özcan, Ü C Yildiz


Bi-oleothermal treatment of wood at atmospheric pressure: resistance to fungi and insects, resistance to weathering and reaction to fire results
2008 - IRG/WP 08-40418
Bi-oleothermal process is a simple treatment which has been developped by CIRAD in cooperation with FCBA. It allows a deep impregnation of wood with hydrophobic products using cheap facilities. The process includes two steps at atmospheric pressure. The first one is a dipping of wood samples in a hot oil bath (between 110 °C and 200°C) which creates an overpressure inside the wood. The second on...
L Podgorski, I Le Bayon, I Paulmier, J-D Lanvin, V Georges, D Grenier, H Baillères, J-M Méot


Degradation of wood veneers by Fenton’s reagents: effects of low molecular weight phenolic compounds on hydrogen peroxide decay and tensile strength loss
2009 - IRG/WP 09-20400
Pine wood (Pinus sylvestris) veneers strips were incubated in acetate buffer containing hydrogen peroxide and iron to mimic mechanisms of brown rot decay and assess the degradation of cellulose through analysis of the tensile properties of the decayed wood. The tensile properties of thin wood strips treated with Fenton system reagents or precursors were determined and correlated to weight loss as ...
Yanjun Xie, R Well, Zefang Xiao, B Goodell, J Jellison, H Militz, C Mai


Analysis on dynamics of basidiomycetes in decayed wood by a method using non-specific amplification of DNA
2009 - IRG/WP 09-20426
A combination of non-specific amplification of DNA by Phi29 DNA polymerase and specific amplification of the internal transcribed spacer (ITS) region of ribosomal DNA (rDNA) by polymerase chain reaction (PCR) was applied to elucidate the ratio of basidiomycete species inhabiting decayed wood from an outdoor bench. After more than 8 hours incubation with Phi29 DNA polymerase, concentration of DNA ...
T Wada, K Igarashi, M Samejima


Qualitative - Quantitative Analysis of Wood-Inhabiting Fungi in External Wooden Structures of the Latvian Cultural Heritage
2010 - IRG/WP 10-10728
The frequency and diversity of wood inhabiting fungi in the exterior wood were established in the Araishi lake fortress, the Lielvarde wooden castle, the Latvian Ethnographic Open-Air Museum, Riga, and twelve wooden heritage objects in the Eastern part of Latvia (Latgale). The inspected wooden structures of the external woodwork included windows, stairs, walls, floorings, roofs, fences, and benche...
I Irbe, M Karadelev, B Andersons


Chemical mediated depolymerization of cotton cellulose for the understanding of non-enzymatic fungal decay
2010 - IRG/WP 10-10731
Small, low molecular weight non-enzymatic compounds have been linked to the early stages of brown rot decay as the enzymes involved with holocellulose degradation are found to be too large to penetrate the S3 layer of intact wood cells. The most pronounced of these which were analyzed in this study are hydrogen peroxide, iron, and oxalic. The compounds related to the Fenton reaction: the combinati...
A C Steenkjær Hastrup, B Jensen, F Green III


The Use of Micro-Tensile Testing to Assess Weathering Decay and Oxidative Degradation of Wooden Items
2010 - IRG/WP 10-20433
This paper presents a method to study the weathering performance of wooden items and to assess the oxidative degradation of wood via the Fenton reaction. Weathering resistance and photo-stability of wood was tested using pine wood (Pinus sylvestris) veneer strips measuring approximately 60 µm in thickness. The veneer strips were treated using a reactive chemical to impart surface protection. The ...
C Mai, Yanjun Xie, Zefang Xiao, P D Evans, H Militz


Determination of a fixation time of wood preservatives: A discussion paper
2010 - IRG/WP 10-20436
The intention of that paper is to initiate a discussion on the basis of a French method in combination with a German approach regarding the need of a method for the determination of a fixation time and especially to obtain input as well as ideas concerning a possible test design. Since no harmonised European approach exists up to now concerning the determination of a fixation time, CEN TC 38 (2009...
E Raphalen, E Melcher


Service life prediction of wooden components – Part 1: Determination of dose-response functions for above ground decay
2010 - IRG/WP 10-20439
Scots pine sapwood (Pinus sylvestris L.) and Douglas fir heartwood (Pseudotsuga menziesii Franco) specimens were exposed in double layer field trials at 24 different European test sites under different exposure conditions (in total 28 test sets). The material climate in terms of wood moisture content (MC) and wood temperature was automatically recorded over a period of up to eight years and compar...
C Brischke, A O Rapp


DNA-based tools for rapidly detecting, quantifying and monitoring ophiostomatoid fungi on beetles, in trees and wood products
2010 - IRG/WP 10-20450
Approximately half of the trees harvested for commercial purposes are lost because of native or introduced insects or insect-vectored microorganisms. Ophiostomatoid fungi, which are well adapted to dissemination by insects, include ~140 species of saprobes and pathogens. They are present worldwide, have high economical impact and many are subject to quarantine regulation. Thus, it is necessary to ...
L Khadempour, Young Woon Lim, S Massoumi Alamouti, C Breuil


Molecular investigation of Postia placenta growing in modified wood
2011 - IRG/WP 11-10756
Brown rot is the most common and destructive type of fungal decay for wood in service. These fungi depolymerize preferentially the structural carbohydrates, cellulose and hemicellulose in the cell wall leaving oxidized lignin behind. Modified wood can provide protection against a variety of wood deteriorating organisms, including decay fungi. However, there is still little known about the mode of ...
B Schmöllerl, G Alfredsen, C G Fossdal, M Westin, A Steitz


Quantitative design guideline for wood outdoors above ground applications
2011 - IRG/WP 11-20465
This paper describes the background and principles behind an engineering design guideline for wood in outdoor above ground applications, i.e. use class 3 according to EN 335. The guideline has been developed in the European research project WoodExter and can be seen as a first prototype for a quantitative design tool in the area of wood durability. It is based on a defined limit state for onset of...
S Thelandersson, T Isaksson, E Suttie, E Frühwald, T Toratti, G Grüll, H Viitanen, J Jermer


Methods of field data evaluation - time versus reliability
2011 - IRG/WP 11-20466
Field testing of wood and wood-based products is so far the most reliable way to get information on performance with respect to durability and expected service life. However, field trials are extremely time and cost consuming. The main objective of the present study was to investigate possible correlations between early stages of decay, preferably during the first 5 years, and the actual service l...
P Larsson Brelid, C Brischke, A O Rapp, M Hansson, M Westin, J Jermer, A Pilgård


Performances of Douglas fir in real outdoor use conditions
2011 - IRG/WP 11-20472
The European standard EN 350-2 classifies Douglas fir as moderately resistant to fungal decay on the basis of standardized laboratory and field tests. However, the lifespan expectancy of outdoor structures such as cladding, decking and elements of wood construction carpentry may also vary according to environmental conditions (climate, exposure to weathering), maintenance and design. An investigat...
M Kutnik, S Lepetit, S Le Nevé


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