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Chemically modified tannin and tannin-copper complexes as preservatives for wood
2001 - IRG/WP 01-30271
The efficacy of Mimosa tannin, chemically modified tannin, and tannin-copper complexes as wood preservatives was studied. When the tannin-ammonia-CuCl2 solutions were impregnated into wood specimens in a one-step procedure, a large quantity of the tannin-copper complex was fixed in the specimens. Little of the complex was leached from specimens by a weathering treatment, and these specimens showed...
H Yamaguchi


Detoxification of salt impregnated wood by organic acids in a pulping process
1993 - IRG/WP 93-50012
The paper descibes a novel method to detoxify pine wood (Pinus silvestris L.) treated with CCB-, CCF- CC-, and Cu-HDO-type salt preservatives. In the process of biological detoxification organic acids produced by strains of Antrodia vaillantii and other brown rot fungi are used for the dissolution of the previously fixed inorganic compounds. These findings are the basis for applying an acid pulpin...
I Stephan, H H Nimz, R D Peek


Copper based wood preservative - A new approach using fixation with resin acids of rosin
2000 - IRG/WP 00-30249
Copper soaps with carboxylic acid groups of resin acids of rosin were shown to be potential long-term wood preservatives. The principle involved is the attachment of copper to the network formed by the inorganic part of the preservative (rosin) through the -COOH groups. The mechanisms of fixation have been studied, and it has been shown that this association could be obtained : (1) by forming the ...
C Roussel, J P Haluk, A Pizzi, M-F Thévenon


Experiences with environmental risk assessment within the Biocidal Products Directive
2005 - IRG/WP 05-50224-21
The Biocidal Products Directive (98/8/EC, the BPD) aims to authorize biocidal products based on risk assessment for both man and the environment. Active substances for wood preservation products and rodenticides were selected for the first list under the review program (Regulations EC 1896/2000 and EC 2032/2003) because several member states had experience with the evaluation and authorization of ...
P Blancquaert


A spectroscopic investigation of copper ethylenediamine fixation in wood
1999 - IRG/WP 99-20160
The fixation reaction which take place between copper ethylenediamine (Cu-en) solution and wood were expolored using X-ray photoelectron spectroscopy (XPS) and Fourier Transformed Infrared Spectroscopy (FTIR). The FTIR spectra revealed that copper reacts with the carboxylic acid and phenolic groups in wood to form stable complexes. The copper ethylenediamine complexes formed in wood were identifie...
Xiao Jiang, J N R Ruddick


Determination of toxicity data for preservatives against Basidiomycetes by measuring the reduction in compression strength of wood
1988 - IRG/WP 2297
Blocks of Pinus radiata D. Don were treated to 12 retention levels with CCA and NaPCP. These were exposed for 12 weeks in agar jars to the dry rot (brown rot) Serpula lacrymans (Schum. ex Fr.) S.F. Gray. After mass loss determination, the same blocks were tested for reduction in compression strength parallel to the grain. Using both these parameters, together with interpolated 6 week strength loss...
J Wazny, J D Thornton


Wood protecting chemicals for the 21st century
1993 - IRG/WP 93-30018
After assessing the past research with protection chemicals, this paper proposes future avenues for research and development in wood protection. Three scenarios are put forward for consideration. First, more is not better and future systems will emphasize combination formulations which enhance properties while providing biological efficacy. Second, current systems, especially those based on copper...
H M Barnes


The resistance of timbers to impregnation with wood preservatives
1979 - IRG/WP 3137
It is anatomical structure which determines liquid flow rate within different timber species. This cannot be deduced from properties such as density or rate of growth, and can only be found by experiment. A standard test has been in use at the Princes Risborough Laboratory for many years, employing a pressure-impregnation treatment, and a large number of timbers have been studied. The test consist...
Anonymous


Non agricultural biocide directive. Practical proposals of implementation in the case where biocides are wood preservatives
1995 - IRG/WP 95-50040-24
This project of non-agricultural biocide directive has currently an extremely wide scope of pre-marketing authorization of substances and preparations used in numerous applications, other than agricultural. Elaborated on the 86/414/EEC model of the phytopharmaceutical product directive, the "NAB" draft directive aims to cover situations as different as plant or wood protection: in the case of plan...
G Ozanne


Methods to determine the efficacy of three water repellent additives in waterborne preservatives
1997 - IRG/WP 97-30142
The paper describes the methods used to determine the efficacy of three different water repellent additives in waterborne preservatives. The wooden samples used are pine (Pinus sylvestris) and spruce (Picea abies) that are treated with 9 different waterborne preservatives in retention for hazard class 3 (above ground commodities). There are two sample sizes exposed, cladding boards (19 x 148 mm) w...
F G Evans, B Nossen, K M Jenssen, L R Wilhelmsen, G Fuglum


Penetration and absorption of water-borne preservatives in conifers from the Western United States: A preliminary report
1988 - IRG/WP 3475
The treatment of most softwoods from the western United States with waterborne chemicals poses a major challenge. Although many of these species are commercially treated with waterbornes, there is considerable debate about their treatability. At present, there is little or no information on the treatability of western wood species with waterborne chemicals. The lack of accurate treatability inform...
S Kumar, J J Morrell


Less pollution due to technical approaches on accelerated steam fixation of chromated wood preservatives
1988 - IRG/WP 3487
Steaming of freshly treated wood at 100°C to 120°C initiates a spontaneous fixation of copper-chromate-containing wood preservatives. For the performance, a suitable anticorrosive equipment is necessary. Good results can be achieved using a separate steaming equipment which allows a rapid heating of the wood. While warming-up, in the wood some preservative solution extends and can be partly extr...
H Willeitner, R-D Peek


Depletion of preservatives from treated wood: Results from laboratory, fungus cellar and field test
1993 - IRG/WP 93-50001-07
This paper compares results of preservative component losses using a range of test procedures with several different water-borne preservatives. The data shows that laboratory leaching tests are in some cases comparable to, but in other cases significantly underestimate preservative component losses when compared with field or fungus cellar depletion tests. The results also suggest that preservativ...
L Jin, A F Preston


Effectiveness of wood preservatives and treatments against marine borers in Philippine waters
1976 - IRG/WP 416
A 5-year exposure test was conducted on the effectiveness of wood preservatives and treatments against marine borers in Philippine waters. Air-dried heartwood samples of apitong (Dipterocarpus grandiflorus) 76.2 x 88.9 x 609.6 mm³ (3 x 3.5 x 24 in³) in size were pressure treated with coal tar creosote and two types of CCA (copper/chrome/arsenic) and CuCZA (copperized chromated zinc arsenate) wat...
F R Siriban, M G Laxamana, P G Mata


IRG/COIPM INTERNATIONAL MARINE TEST - To determine the effect of timber substrate on the efectiveness of different preservatives in sea-water: Coding scheme
1976 - IRG/WP 420
It was agreed in Wildhaus on 15 May 1976 that preparations for the test detailed in Document No: IRG/WP/414 should commence immediately, but that initially only two water-borne preservatives should be used - a copper/chrome/arsenic (CCA) and a copper/chrome/boron (CCB) formulation respectively. PRL, England (R Cockcroft) would be responsible for supplying only the reference species treated with th...
Anonymous


Leaching Characteristics of Alder Wood Treated with Copper Based Wood Preservatives
2005 - IRG/WP 05-50225
In this study, it was designed for determining leaching characteristics of CCA and alternatives wood preservatives. Alder wood blocks were treated with CCA (1 % and 2 %), ACQ-1900 (2 % and 3 %), ACQ-2200 (1 % and 2 %), Tanalith E 3491 (2 % and 2.8 %), Wolmanit CX-8 (% 1 and 2 %). Leaching studies were conducted according to AWPA E11-97. Copper analyses of leachate were determined Atomic absorption...
A Temiz, Ü C Yildiz, E D Gezer, S Yildiz, E Dizman


Quantification of creosote and fluoride in remedially-treated poles
1997 - IRG/WP 97-40097
Three creosoted transmission poles were put into service in 1961 and they were subsequently remedially-treated with a proprietary fluoride remedial paste formulation in 1981. The poles were removed from service in 1996 and their ground-contact regions were analysed for creosote and fluoride contents. It was found that the poles were undecayed. Creosote retentions decreased down the profiles of the...
B P Hill


The future for chromium in wood preservation
1985 - IRG/WP 3332
Most water-borne preservatives contain CrVI compounds, originally to reduce corrosion although now also to improve toxicant fixation. Chromium contributes to preservation and this is recognised in, for example, New Zealand and USA where chromium contents are included in calculations of overall preservative activity of CCA formulations, but chromium may also have anti-stain and joinery (millwork) p...
B A Richardson, T R G Cox


Melamine resins as preservatives results of biological testing
1996 - IRG/WP 96-40061
Based on previous work of the authors on resins, the upgrading of wood with a true solution of a methanol etherificated melamine resin in low aqueous concentration was performed. For the relative assessment of the biological resistance against brown and white-rot fungi were used not only untreated controls of pine sapwood (Pinus sylvestris L.), but also heartwood of European larch (Larix decidua M...
A O Rapp, R-D Peek


The effect of oil-borne preservative treatments on the shear strength of FRP/wood composite adhesive bonds
2003 - IRG/WP 03-40265
Reinforcement of structural wood components with Fiber Reinforced Polymer (FRP) will enhance the beam’s strength, but actual data on long-term durability is sparse, not well documented or not readily accessible. In this study, bond properties of FRP-wood composite materials were investigated following treatment with creosote or copper naphthenate preservatives. The properties investigated inclu...
B Herzog, B Goodell, R Lopez-Anido


Uptake by grape plants of preservatives from pressure-treated posts not detected
1975 - IRG/WP 350
Leaf and stem tissue and fruit of grape plants (Vitis rotundifolia Michx. cv. Magnolia) were analyzed for copper, chromium, and arsenic, 1, 2, and 3 years after planting 3 inches from copper-chrome-arsenate or fluor-chrome-arsenate-dinitrophenol-treated southern pine posts. Quantities of copper in leaf and stem tissue and fruit of plants next to posts treated with copper-containing preservatives r...
M P Levi, D Huisingh, W B Nesbitt


A review of the current status of the estimation of emissions from preserved wood and their use in the environmental risk assessment of wood preservatives under the Biocidal Products Directive
2005 - IRG/WP 05-50224-7
A review and update of the status of the issues concerning the estimation of emissions from preserved wood (e.g. amendments to the proposed ‘OECD Guidelines’), and the environmental risk assessment of wood preservatives under the Biocidal Products Directive (e.g. compartmental sizes, emissate ecotoxicity testing)....
E F Baines


The use of organic wood preservatives in ground contact and the suitability of laboratory test procedures to determine their efficacy
1999 - IRG/WP 99-20175
Organic fungicides, such as propiconazole, have proven to be highly effective when used as a co-biocide in recently developed wood preservative formulations. They have however been ineffective when used as a stand alone preservative, particularly when used in ground contact (European Hazard class 4). Previous research, using the test methods of ENV 807 (1993), provided conflicting evidence regardi...
I J Herring, D J Dickinson


Leaching of components from CCF treated timber in ground contact
1998 - IRG/WP 98-50108
In order to investigate the depletion of different CCF-salts during service small stakes (10*10*450mm³) were treated with five water-borne wood preservatives and after fixation brought into ground contact for several years. After failing some of the broken down stakes were used to determine the remaining concentration of relevant ions and their distribution in different segments of the stakes. A...
E Melcher


The extraction of boron from treated wood for quantitative analysis: A comparison of procedures
1992 - IRG/WP 92-2414
The extraction of boron preservative from treated rubberwood and scots pine samples was compared using methods based on refluxing and extraction in 1N NaOH or distilled water at 80°C. The extract solutions were analysed by Inductively Coupled Plasma spectroscopy (ICP/AES). A simple extraction procedure based on immersion of wood samples of approximate dimension 2 x 1 x 1 cm³ in distilled water a...
R J Murphy, D J Dickinson, P W McCormack, M K Lung


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