IRG Documents Database and Compendium


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Factors affecting sodium hypochlorite extraction of CCA preservative components from out of service treated wood for recycling
2009 - IRG/WP 09-50263
Significant amounts of chromated copper arsenate (CCA) treated wood products such as utility poles and residential constructions remain in service. There is an increasing public concern about environmental contamination from CCA treated wood when it is removed from service for reuse or recycling, placed in landfills or burned in commercial incinerators. In this paper, we investigate the effects of...
E D Gezer, P A Cooper


The natural durability and preservative treatability of 11 bamboo species
2010 - IRG/WP 10-10708
Tests on the natural durability and preservative treatability of 11 common bamboo species were conducted. The results showed that there was a linear relation between bamboo density and its preservative retention by mass, and the preservative retention of bamboo reduced while its density increased. The test also showed that there were significant differences in the natural durability of bamboos, bu...
Chen Lifang, Su Haitao, Zhang Yanjun, Wang Yuxia, He Xuexiang, Ma Hongxia, Xie Guijun


Seasonal shifts of fungal community structure at the interface of treated or untreated wood and soil
2010 - IRG/WP 10-10721
Many wood species are degraded rapidly in soil by the fungal community. In order to preserve wood and structures in which it is used, chemical preservatives are used. Little is known about the interaction of treated wood and the surrounding soil fungal community. For this work, presented at IRG 41, wooden specimens (Pinus sylvestris sapwood, sizes 25 mm x 50 mm x 500 mm (longitudinal)) were treate...
M Noll, I Stephan


Mould growth on wood-based materials – a comparative study
2010 - IRG/WP 10-20455
Ten different wood-based materials - preservative-treated wood, fire retardant-treated wood, modified wood, WPCs and untreated references of pine sapwood and spruce - were tested for mould growth according to SP method 2899 during 42 days at 90% RH and 22°C. Even though the results must be interpreted carefully, they indicate significant differences in mould resistance between the materials tes...
P Johansson, J Jermer


The use of thermal desorption and pyrolysis combined with a semiconductor VOC detector for the on-site detection of preservative-treated wood
2010 - IRG/WP 10-20456
The purpose of this study was twofold; to identify possible marker molecules released from preservative-treated wood upon heat treatment and then develop a prototype detector for this marker. Two methods for heating the samples were used: Pyrolysis combined with Gas-Chromatography with IR-detection and Thermal Desorption combined with Gas-Chromatography with mass detection. A first prototype detec...
I Svensson, A Gonzalez, L Irusta, Mª J Fernandez-Berridi, O Munné


A comparison of the chemistry of alkaline copper and micronized copper treated wood
2010 - IRG/WP 10-30528
This paper discusses the chemistry of the reaction of alkaline copper and micronized copper with wood. The objective of this study is to examine the copper species produced in wood during the fixation reaction using electron paramagnetic resonance (EPR) spectroscopy. The initial experiments (phases 1 to 2) were designed to confirm the effect of time of treatment and solution concentration on the s...
Wei Xue, P Kennepohl, J N R Ruddick


Distribution and availability of preservative components in ACQ treated wood - effects of coatings and weathering
2010 - IRG/WP 10-30537
Copper and quaternary ammonium compound (quat) distributions across lumber (gradients) and availability, as measured by amount removed by intensive leaching of wood flour, were measured in ACQ treated southern pine lumber. Samples were evaluated just after treatment and stabilization, or after 3 years of laboratory storage, or after 3 years of natural weathering exposure. The objective was to in...
T Ung, M Nejad, P Cooper


Copper nanoparticles in southern pine wood treated with a micronised preservative: Can nanoparticles penetrate the cell walls of tracheids and ray parenchyma?
2010 - IRG/WP 10-30547
This study tests the hypothesis that copper nanoparticles can penetrate the cell walls of southern pine wood treated with a micronised preservative. We examined the nanodistribution of particles in tracheid and ray parenchyma cell walls using state-of-the-art HR (High Resolution)-TEM and HR-STEM (Scanning Transmission Electron Microscope)-EDX. These devices are capable of atomic-scale resolution. ...
H Matsunaga, Y Kataoka, M Kiguchi, P Evans


Influence of Copper Preservative Type on Earlywood and Latewood Distribution of Copper in Treated Wood
2010 - IRG/WP 10-40507
Some of the new water based copper containing wood preservative systems use particulate “micronized” copper as the primary biocide instead of the more traditional soluble amine copper based systems. Studies were conducted to investigate how this difference in the type of copper system might impact both initial and post drying distribution of the preservatives in wood. Of specific interest wa...
A Zahora


A comparison of the corrosion of alkaline copper and micronized copper treated wood
2010 - IRG/WP 10-40515
With the replacement of chromate copper arsenate (CCA) by alkaline copper wood preservatives, there have been reports of increasing corrosion of metal fasteners and connectors in contact with treated wood. This may be explained by the presence of more mobile copper in the treated wood. One novel industrial response has been to develop a wood preservative based on an aqueous solution containing sus...
M Kofoed, J N R Ruddick


Metal Migration from Douglas-fir Poles Treated with Ammoniacal Copper Zinc Arsenate According to Best Management Practices
2010 - IRG/WP 10-50272
The potential for migration of metal components from ammoniacal copper zinc arsenate treated (ACZA) poles was examined using pole sections treated using Best Management Practices. Copper and zinc levels were highest in runoff collected following the first rainfall events, then declined. Copper and zinc levels in runoff averaged 20 ppm and 5 pm respectively. The metal levels were then used to pr...
J J Morrell, C S Love, C Freitag


Copper Nanoparticles in Southern Pine Wood Treated with a Micronised Preservative: Nanodistribution of Copper in the Pit Membrane and Border of an Earlywood Bordered Pit
2011 - IRG/WP 11-30566
Copper nanoparticles can penetrate the cell walls of unlignified parenchyma cells in southern pine wood treated with a micronised wood preservative, but they are excluded from lignified tracheid walls. This paper extends these observations to include the cell wall layers of the bordered pit. Focused ion beam and ion milling were used to make an ultra-thin section of the cell wall layers of an earl...
H Matsunaga, Y Kataoka, M Kiguchi, P Evans


Quantification of mobile copper (II) levels in micronized copper treated wood
2011 - IRG/WP 11-40550
The purpose of this study is to quantify the mobile copper(II) levels in micronized copper treated wood using electron paramagnetic resonance (EPR) spectroscopy. A correlation between EPR and EDX intensities on mobile copper levels in a series of copper sulphate treated wood was created as a calibration standard. Laboratory treatments using micronized copper formulations were then carried out and ...
Wei Xue, P Kennepohl J N R Ruddick


Utilization of thermodesorption coupled to GC-MS to study kinetics of thermodegradation of different wood species
2011 - IRG/WP 11-40559
Thermdesorption coupled to Gas Chromatography coupled to Mass Spectroscopy (TD-GC-MS) has been investigated to identify volatile degradation products generated during wood heat treatment by mild pyrolysis. For this purpose, wood samples of different softwood and hardwood species have been heat treated under nitrogen for different temperatures comprised between 180 and 230°C during 15 min. in the ...
K Candelier, M Chaouch, S Dumarçay, A Pétrissans, M Pétrissans, P Gérardin


Characterizing long term leaching behaviour of copper from preservative treated wood in a practical exposure scenario
2011 - IRG/WP 11-50278
To investigate the prediction of the long term emission of copper from preservative treated wood in a Use Class Class 3 scenario, treated boards were exposed vertically above ground to natural weather conditions. The study included two products; an amine copper ACQ-type formulation, air-dried after treatment to a 22 kg/m3 retention, and the same formulation which was hot oil vacuum dried after tre...
T Mark Venås, M Klamer


TRU-CORE Process for Treatment of Refractory Species and Engineered Wood Products
2011 - IRG/WP 11-40573
The TRU-CORE Process is a novel, chemically-based technology for rapidly delivering globally accepted wood preservatives and insecticides deep into the core of wood and wood-based composites in a waterborne carrier. Protectant materials which can be utilized with the TRU-CORE Process include a variety of carbon-based fungicides and insecticides. An important feature of the TRU-CORE Process is it...
A S Ross


Long term durability of the heartwood of seven common softwood species in above ground conditions
2012 - IRG/WP 12-10771
The natural durability for wood in above ground use has been evaluated based on results after 11 years of exposure in a test site situated at the Danish Technological Institute in Taastrup, Denmark. Selected results for seven common softwood species exposed horizontally are reported. The test results cover samples with direct rain exposure (use class 3 of the European standard EN335-1:2006) and sa...
E Tang Engelund, M Klamer, T Mark Venås, B Lindegaard


Use of X-Ray Micro-Computed Tomography to Visualize Copper in Preservative Treated Wood
2012 - IRG/WP 12-20488
This study tests the hypothesis that X-ray micro-computed tomography will be able to visualize the distribution of copper in wood treated with a micronized wood preservative containing copper carbonate. A small wood block measuring 12 x 12 x 19 mm was cut from a 2.4 m x 51 mm x 51 mm southern pine batten that had been treated with a micronized wood preservative. Tomograms of the wood block were ob...
P D Evans, A Limaye, H Averdunk, M Turner, T J Senden, M A Knackstedt


Mobilized copper(II) concentrations in earlywood and latewood of micronized copper treated red pine
2012 - IRG/WP 12-30596
Electron paramagnetic resonance (EPR) was used in conjunction with energy dispersive x-ray spectroscopy (EDX) to quantify total copper and mobilized copper retentions in MCQ and MCA treated red pine. The MCQ treated red pine was found to have higher copper retention than that of the MCA treated one. Earlywood in general had higher total copper content than latewood. The mobilized and complexed cop...
Wei Xue, P Kennepohl, J N R Ruddick


Effect of preservative treatment on dimensional stability of plywood made of treated simul (Bombax ceiba) veneer
2012 - IRG/WP 12-40575
The dimensional stability such as thickness swelling and water absorption of plywood made of treated simul (Bombax ceiba) veneers were investigated after 2 hours and 24 hours soaking under water. The veneers were treated with hot water and cold water solution of borax-boric acid (1:1), neem leaves and mahogany seeds of different concentration (1:10, 1:20, and 1:40) at different treatment duration....
K Akhter, M Mahabubur Rahaman, A Ara


Effects Of Wood Preservative On Mechanical Properties Of Glulam Manufactured From Lower Density Malaysian Tropical Timber
2012 - IRG/WP 12-40590
This study is to investigate the effect of wood preservative on the mechanical properties of glulam timbers made from low density Malaysian hardwood timbers. Utilization of lower density Malaysian tropical timber for structural applications have not exploited extensively due to their inferior strength. By converting into treated glued laminated (glulam) timbers it could offer the possibility of th...
L Francis, Z Ahmad


Relationships between heat treatment intensity and some conferred properties of different European softwood and hardwood species
2012 - IRG/WP 12-40593
Effect of treatment intensity on conferred properties like elemental composition, durability, anti swelling efficiency (ASE) and equilibrium moisture content (EMC) of different European softwood and hardwood species subjected to mild pyrolysis at 230°C under nitrogen for different durations has been investigated. Independently of the wood species studied, elemental composition is strongly correl...
M Chaouch, S Dumarçay, A Pétrissans, M Pétrissans, P Gérardin


Scale-up of a chemical process for copper-based preservative-treated wood wastes recycling
2012 - IRG/WP 12-50286
In recent years, the development of appropriate wood waste disposal options has been encouraged by severe regulations and expensive fees associated with wastes landfilling or burning. An efficient and economically attractive leaching process was developed at laboratory scale (200 mL) for CCA-, ACQ- and CA-treated wood wastes recycling. This leaching process consisted of three leaching steps of 2 h...
L Coudert, L Gastonguay, J F Blais, G Mercier, P Cooper, P Morris, A Janin, N Reynier


Mould growth on wood-based materials – a simulated in-service study
2012 - IRG/WP 12-20503
Ten different wood-based materials including preservative-treated wood, fire retardant-treated wood, modified wood, WPCs and untreated references of pine sapwood and spruce were placed in three different environments (an attic and two crawl spaces) for a period of 26 months. Mould growth was analysed at five to seven month intervals in an effort to map the growth development. The relative humidit...
G Bok, P Johansson, J Jermer


An assessment of soft rot in preservative-treated poles in two test sites and two network areas in New South Wales
2013 - IRG/WP 13-10801
This document presents an extended summary of recent investigations into soft rot attack of preservative treated power poles from the re-inspection of samples selected from two field sites and two in-service trials located in New South Wales, Australia. The in-ground sapwood of selected poles was assessed by probing and, after core sampling, by microscopy to determine the severity and extent of s...
W D Gardner, M A Powell, C Kirton


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