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Copper to quat ratio in alkaline copper quat (ACQ) wood preservative - Effects on fixation and leaching of preservative components in red pine
2009 - IRG/WP 09-30496
This study investigates the effect of the relative proportion of copper oxide (CuO) to didecy dimethyl ammonium carbonate (DDACb) in an alkaline copper quat (ACQ) formulation on the rate of copper fixation or stabilization and the resistance of treated wood to leaching of copper and quat (DDACb). Red pine samples were treated with ACQ, having CuO to DDACb ratios of 2:1 (the normal ratio for ACQ-D...
S Pankras, P A Cooper, T Ung, L Awoyemi


Thermal behavior of zinc borate-treated wood
2009 - IRG/WP 09-30511
The objective of this study was to investigate the thermal behavior of zinc borate (ZnB)-treated solid wood by thermal analysis (TA). Thermogravimetry (TG) and differential thermogravimetry (DTG) curves obtained from TA showed that ZnB-treated wood specimens had higher char yields and lower maximum thermal decomposition temperature than untreated wood specimens. Reducing thermal decomposition temp...
E Terzi, H Sutcu, S N Kartal


Micronized Copper Preservative Systems: Observations on the Release of Cupric ion (Cu2+) from Treated Wood and Performance against Wood Decay Fungi
2009 - IRG/WP 09-30519
In an attempt to address the mechanism of action of micronized copper preservatives, a 20-week continuous water leaching study was conducted. The leaching results indicated that, once impregnated in wood, micronized copper preservatives continuously release cupric ion, and the levels of cupric ion released from micronized copper treated wood are higher than those released from CCA treated wood, a...
J Zhang, R Ziobro


Environmental Emission of Wood Preservatives: Interpretation of Data Relevant to BPD Risk Assessments
2009 - IRG/WP 09-50259
The risk assessments for the use of wood preservatives proposed by the OECD and used under the Biocidal Products Directive (BPD) (98/8/EC) require the derivation of leaching rates for active substances. These rates are to be used as input data in to agreed exposure scenarios. The leaching rates can be derived from laboratory testing and from field testing. The relationship between laboratory and f...
D G Cantrell


Leaching of the copper component from full scale decking boards during one summer season
2009 - IRG/WP 09-50260
The leaching of copper has been tested in laboratory and in outside exposure for freshly treated pine sapwood samples with three different copper preservatives, Cu HDO, copper quat and copper triazoles. We found in the laboratory leaching test that a fixation with warming to 60 °C (140 °F) for 48 hours without drying and then drying in the laboratory in room temperature gave the lowest leaching of copper. We also found that surface treatments with wood oils reduced the leaching, and that washing of the surface before testing had no effect. Full scale decking board samples (0.25 m2) were then exposed outdoors for rain. The rain water was collected and analysed for copper. After one summer season (about 600 mm rain) we found that the leaching differ for the three preservatives. All samples with a water borne surface treatment had the lowest leaching, about half the amount of untreated.
F G Evans


Factors affecting sodium hypochlorite extraction of CCA preservative components from out of service treated wood for recycling
2009 - IRG/WP 09-50263
Significant amounts of chromated copper arsenate (CCA) treated wood products such as utility poles and residential constructions remain in service. There is an increasing public concern about environmental contamination from CCA treated wood when it is removed from service for reuse or recycling, placed in landfills or burned in commercial incinerators. In this paper, we investigate the effects of...
E D Gezer, P A Cooper


Life Cycle Assessment of treated timber: methodological aspects and first results
2009 - IRG/WP 09-50264
Environmental information on products is more and more required as a key to the market, and the building sector in Europe is certainly advanced in that direction. In France, Environmental Product Declarations are becoming very common for construction products. Therefore, the CTB P+ and CTB B+ certification comity as commissioned FCBA to perform the Life Cycle Analysis of treated timber in order to...
E Vial, M Bertrand, C Cornillier, G Deroubaix


Microwave Surface Modification of Radiata Pine Peeler Cores for Preservative Treatment
2009 - IRG/WP 09-40453
Radiata pine peeler cores are classified as a by-product derived from the cores of logs left over after the veneer peeling process. The core can be potentially developed for value added solid wood products as it is abundantly available and has a constant diameter. However, the core needs to be preservative treated because of low durability in ground contact. An additional problem is that the wood ...
K Sugiyanto, G Torgovnikov, P Vinden


The natural durability and preservative treatability of 11 bamboo species
2010 - IRG/WP 10-10708
Tests on the natural durability and preservative treatability of 11 common bamboo species were conducted. The results showed that there was a linear relation between bamboo density and its preservative retention by mass, and the preservative retention of bamboo reduced while its density increased. The test also showed that there were significant differences in the natural durability of bamboos, bu...
Chen Lifang, Su Haitao, Zhang Yanjun, Wang Yuxia, He Xuexiang, Ma Hongxia, Xie Guijun


Microscopy evaluation of microbial decay patterns in wood stakes after 6 years in soil contact
2010 - IRG/WP 10-10715
Most studies on wood modification have so far been concerned with service life predictions rather than investigating the decay protection mechanism. Very little is known about the mode of action of these new treatments and about the strategies used by wood degraders in order to utilize the wood material despite a treatment. Access to such knowledge would allow further modification and improvement ...
A Pilgård, C G Björdal


Seasonal shifts of fungal community structure at the interface of treated or untreated wood and soil
2010 - IRG/WP 10-10721
Many wood species are degraded rapidly in soil by the fungal community. In order to preserve wood and structures in which it is used, chemical preservatives are used. Little is known about the interaction of treated wood and the surrounding soil fungal community. For this work, presented at IRG 41, wooden specimens (Pinus sylvestris sapwood, sizes 25 mm x 50 mm x 500 mm (longitudinal)) were treate...
M Noll, I Stephan


Qualitative - Quantitative Analysis of Wood-Inhabiting Fungi in External Wooden Structures of the Latvian Cultural Heritage
2010 - IRG/WP 10-10728
The frequency and diversity of wood inhabiting fungi in the exterior wood were established in the Araishi lake fortress, the Lielvarde wooden castle, the Latvian Ethnographic Open-Air Museum, Riga, and twelve wooden heritage objects in the Eastern part of Latvia (Latgale). The inspected wooden structures of the external woodwork included windows, stairs, walls, floorings, roofs, fences, and benche...
I Irbe, M Karadelev, B Andersons


Towards Understanding the Biology of Wood Decay
2010 - IRG/WP 10-10739
Our previous research has focused primarily on ways to identify the wood decay fungi and microbial community. We continue to explore this complex and dynamic community and its interactions through microbial community ecology studies, gene expression interactions and proteomics. However, in order to better understand the mechanisms of fungal decay, we have sequenced the genome of a copper tolerant...
J Tang, K Jenkins, L Parker, S V Diehl


The Relative Performance of an Organic Preservative System under UC3A and UC3B Conditions using Two Test Methods
2010 - IRG/WP 10-20429
Coated L-joints have been used for decades to evaluate the performance of wood preservatives in protected environments. This study was conducted using matched coated and uncoated L-joints to simulate above ground protected and unprotect exposures. When exposed to constant moisture in a greenhouse environment, coated and uncoated L-joints give very similar performance results. In contrast, exposi...
C F Schauwecker, A Zahora, A F Preston


Determination of a fixation time of wood preservatives: A discussion paper
2010 - IRG/WP 10-20436
The intention of that paper is to initiate a discussion on the basis of a French method in combination with a German approach regarding the need of a method for the determination of a fixation time and especially to obtain input as well as ideas concerning a possible test design. Since no harmonised European approach exists up to now concerning the determination of a fixation time, CEN TC 38 (2009...
E Raphalen, E Melcher


Stress wave and visual analysis of treated and non treated fence posts after 15 years in field test
2010 - IRG/WP 10-20449
Wood preservation may play an important role in protecting tropical rain forest. Basically, it can reduce pressure on natural resources by increasing wood durability. Field tests are conducted to simulate final use of woods under different environmental conditions. Visual analysis, non destructive testing, and non destructive evaluation techniques were applied to assess wood resistance and chemica...
A Florian da Costa, R Faustino Teles, J Costa Gonçalves


Mould growth on wood-based materials – a comparative study
2010 - IRG/WP 10-20455
Ten different wood-based materials - preservative-treated wood, fire retardant-treated wood, modified wood, WPCs and untreated references of pine sapwood and spruce - were tested for mould growth according to SP method 2899 during 42 days at 90% RH and 22°C. Even though the results must be interpreted carefully, they indicate significant differences in mould resistance between the materials tes...
P Johansson, J Jermer


The use of thermal desorption and pyrolysis combined with a semiconductor VOC detector for the on-site detection of preservative-treated wood
2010 - IRG/WP 10-20456
The purpose of this study was twofold; to identify possible marker molecules released from preservative-treated wood upon heat treatment and then develop a prototype detector for this marker. Two methods for heating the samples were used: Pyrolysis combined with Gas-Chromatography with IR-detection and Thermal Desorption combined with Gas-Chromatography with mass detection. A first prototype detec...
I Svensson, A Gonzalez, L Irusta, Mª J Fernandez-Berridi, O Munné


Improved analysis of field test data related to service life prediction of tropical wood species
2010 - IRG/WP 10-20458
Long field trials of wood in ground contact give valuable data on the natural durability of the material. The European Standard EN 350 gives guidance on how to perform these durability classification, but is limited to the use of averages of in-service life of a set of specimens compared to a reference set. Starting from a database of visual assessment of field stake testing, it is possible to obt...
J Van den Bulcke, A Wong, Ling Wang Choon, Yoon Soo Kim, J Van Acker


A comparison of the chemistry of alkaline copper and micronized copper treated wood
2010 - IRG/WP 10-30528
This paper discusses the chemistry of the reaction of alkaline copper and micronized copper with wood. The objective of this study is to examine the copper species produced in wood during the fixation reaction using electron paramagnetic resonance (EPR) spectroscopy. The initial experiments (phases 1 to 2) were designed to confirm the effect of time of treatment and solution concentration on the s...
Wei Xue, P Kennepohl, J N R Ruddick


Distribution and availability of preservative components in ACQ treated wood - effects of coatings and weathering
2010 - IRG/WP 10-30537
Copper and quaternary ammonium compound (quat) distributions across lumber (gradients) and availability, as measured by amount removed by intensive leaching of wood flour, were measured in ACQ treated southern pine lumber. Samples were evaluated just after treatment and stabilization, or after 3 years of laboratory storage, or after 3 years of natural weathering exposure. The objective was to in...
T Ung, M Nejad, P Cooper


Copper preservative systems: A rapid investigation into effects of co-biocides and used treating solutions
2010 - IRG/WP 10-30541
The efficacy of various micronized and amine copper preservative systems was evaluated using soil block testing with the copper tolerant brown rot fungi, Postia placenta. The American Wood Protection Association E22 protocol was used to compare the relative efficacy of preservatives by monitoring compressive strength losses of the systems in southern pine wood. As information, the weight losses ...
T F Shupe, K Ragon, Q Wu, M H Freeman, C R McIntyre


Antifungal and wood preservative efficacy of IPBC is enhanced by α - aminoisobutyric acid
2010 - IRG/WP 10-30544
There is currently a need to reduce the biocide content of wood preservatives, without decreasing efficacy. The nonmetabolised amino acid analogue α-aminoisobutyric acid (AIB) acts as a translocated inhibitor of mycelial spread in basidiomycete wood decay fungi, although it does not kill the organism. Factorial combinations of AIB with either the azole fungicide tebuconazole, or 3-iodo-2-...
P Bota, E Baines, A Mead, S C Watkinson


Analysis of phenolic extractives from various Tunisian species trees -Study of its potential valorisation
2010 - IRG/WP 10-30552
Phenol extractives are naturally synthesized compounds taken from several trees. It is well demonstrated that the presence of phenol compounds is positively correlated with the durability of wood. This property is very interesting for outdoor uses of wood with a limited treatment. Phenol compounds may also be used in the formulation of glue. In the aim to improve the knowledge on Mediterranean tr...
I Oueslati, F Charrier, K Seffah, A Moubarik, N Ayed, A Zerizer, B Charrier


Influence of Copper Preservative Type on Earlywood and Latewood Distribution of Copper in Treated Wood
2010 - IRG/WP 10-40507
Some of the new water based copper containing wood preservative systems use particulate “micronized” copper as the primary biocide instead of the more traditional soluble amine copper based systems. Studies were conducted to investigate how this difference in the type of copper system might impact both initial and post drying distribution of the preservatives in wood. Of specific interest wa...
A Zahora


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