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Effect of P/F ratio, PF concentration and treating method on boron leaching from wood treated with PF modified boron compounds
2011 - IRG/WP 11-30559
In order to immobilize boron in wood, three kinds of resol-type phenol-formaldehyde (PF) resin with different P/F ratios were synthesized in laboratory and incorporated with three types of boron compounds to treat wood. The used boron compounds included boric acid (BA), borax (BX) and disodium octaborate tetrahydrate (DOT). The leaching test of boron from wood blocks was performed according to the...
Liping Yu, Jinzhen Cao


Tannin resin-boron for outdoor wood protection and fire retardancy
2011 - IRG/WP 11-30567
Boron in the form of boric acid is well known for its efficacy against wood destroying organisms, as well as for its high leachability from treated wood when in outside exposure. Moreover, due to the European directive 2008/58/EC, boric acid is only authorized at low levels. In order to keep considering boric acid as an interesting active ingredient for wood protection, the issue is now to fix it ...
M-F Thévenon, G Tondi, N Leménager, S Wieland, A Pizzi


Use of X-Ray Micro-Computed Tomography to Visualize Copper in Preservative Treated Wood
2012 - IRG/WP 12-20488
This study tests the hypothesis that X-ray micro-computed tomography will be able to visualize the distribution of copper in wood treated with a micronized wood preservative containing copper carbonate. A small wood block measuring 12 x 12 x 19 mm was cut from a 2.4 m x 51 mm x 51 mm southern pine batten that had been treated with a micronized wood preservative. Tomograms of the wood block were ob...
P D Evans, A Limaye, H Averdunk, M Turner, T J Senden, M A Knackstedt


Tannin resin-boron associations: Leaching and biological resistance
2012 - IRG/WP 12-30587
The easy leaching of boron in wood preservation formulations has allowed to use this fungicide only for short term applications. The recently discovered adduct with flavonoids allows boron to resist longer periods of time within wood and consequently extend its life. Two different leaching treatments were compared and the fungal and termite decay was examined. The biological tests have shown extre...
G Tondi, S Wieland, N Lemenager, A Petutschnigg, A Pizzi, M-F Thevenon


Comparison of exterior performance of two coating systems based polyurethane applied Pinus sylvestris L. and Picea orientalis L. wood
2012 - IRG/WP 12-40588
Some surface changes in sapwood and heartwood of two species before applying clear-coating were characterized after accelerated weathering time. Wood specimens covered with two types polyurethane (PU) films were also observed in accelerated weathering exposure. In this study, changes on the wood surface were compared of between wood specimens covered with two types polyurethane (PU) films after ir...
Ö Özgenç, Û Cafer Yıldız


Termite resistance of wood impregnated with phenol-formaldehyde (PF) modified boron compounds
2012 - IRG/WP 12-30604
In order to investigate the effect of phenol-formaldehyde (PF) modified boron compounds on termite resistance of two main plantation-grown wood species, namely, Masson pine (Pinus massoniana Lamb.) and Chinese fir (Cunninghamia lanceolata (Lamb.) Hook.), laboratory termite tests and field tests were carried out according to AWPA standard E1-97 and AWPC protocols/2007. Different concentrations of b...
Jinzhen CAO, Liping YU, Xuexiang HE


Curing kinetics of nano cupric oxide (CuO) modified PF resin as wood adhesive: Effect of surfactant
2013 - IRG/WP 13-40620
The effect of nano cupric oxide (CuO) in combination with surfactants on the curing kinetics of phenol formaldehyde (PF) resin, as well as the bonding strength of plywood prepared using the modified resin were investigated in this study using dynamic and isothermal differential scanning calorimetry (DSC). The result showed that the incorporation of nano CuO along with alkane surfactant made in the...
Wei Gao, Guanben Du


Study of UV resistance and natural weathering of coatings on chemically modified wood
2013 - IRG/WP 13-40629
In this study, UV resistance and weathering performance of rubberwood (Hevea brasiliensis) and radiata pine (Pinus radiata) modified with benzoyl chloride and acetic anhydride was studied. Performance of polyurethane based wood coatings on modified wood was also evaluated. Unmodified and chemically modified specimens were exposed to accelerated and natural weathering. Modified and unmodified woo...
K K Pandey, K Srinivas


Visualization of Copper in the Voids and Cell Walls of Treated Wood using X-Ray Micro-Computed Tomography
2013 - IRG/WP 13-40640
This study extends our observations of the distribution of copper in treated wood. A small wood block was cut from a southern pine batten that had been treated with a particulate-copper preservative and similar sized block was cut from a batten that had been treated with a copper-amine preservative. Both blocks were imaged using X-ray micro-computed tomography. We obtained tomograms of each treate...
P D Evans, A Limaye, H Averdunk, M Turner, T J Senden


Study on Fire Resistance of Lightweight Panels Made of Honeycomb and Polyurethane Cores
2013 - IRG/WP 13-40645
In response to the increasing demand of lightweight and durable materials in furniture manufacture, potential of different skin types and cores were investigated to make proper lightweight panel. Fire resistance of panels made of different skins and cores were studied to elucidate the board’s behavior exposed to fire. Skins were MDF (3, 6 and 8 mm), particle board, plywood (3 and 5 layers) and c...
A Talaei, M Ghofrani, S Pishan


Effect of bio-resin from cashew nut shell liquid (CNSL) on decay resistance properties of wood
2013 - IRG/WP 13-40649
This study assesses the decay resistance properties of bio-resin modified wood against decay fungi of the Basidiomycota according to the EN 113 protocol. A bio-resin system was developed by ozonolysis process from cashew nut shell liquid (CNSL), a naturally occurring mixture of phenolics. Small wood blocks from sapwood of Scots pine (Pinus sylvestris), Obeche (Triplochiton scleroxylon) and Gmelina...
M Ashaduzzaman, M D Hale, V Tverezovskiy, G A Ormondroyd


Bio-based thermoset resins for bonding and eco-friendly preservation in the wood industry
2013 - IRG/WP 13-40650
Yellow dextrins and tannins were used in wood adhesives formulation to substitute resins based on formaldehyde. Several formulations were carried out in alkaline aqueous media by varying the weight fraction of two compounds from 10% to 30%. The cross-linking was performed using epichlorohydrin as a reticulant agent. Rheological behaviours and initial adhesion of three liquid formulations, before r...
C Motillon, A Allal, A Visse, F Charrier, B Charrier, A Baldé


Dynamic mechanical analysis (DMA) of nano cupric oxide (CuO) modified aqueous phenol formaldehyde (PF) resin
2014 - IRG/WP 14-40654
Phenol formaldehyde (PF) resins, modified by nano CuO incorporating alkane surfactant and polyvinyl alcohol (PVA) 17-99, were analyzed by dynamic mechanical analysis (DMA). The mechanical properties of its bonded plywood including tensile strength, modulus of rupture (MOR), modulus of elasticity (MOE) and shear strength under five test conditions were evaluated. Results indicated that the incorpor...
Wei Gao, Guanben Du


The effect of UV irradiation on some technological properties of different polyurethane varnishes coated plywood panels from veneers dried at different temperatures
2014 - IRG/WP 14-40661
In this study, the effect of UV irradiation on some technological properties of three different polyurethane varnishes coated plywood panels produced from Scots pine (Pinus sylvestris L.) and Maritime pine (Pinus pinaster L.) veneers manuactured and dried at different temperatures was studied. Accordingly, 32°C log peeling temperature and three different veneer drying temperatures (110, 140 and ...
Ö Özgenç, C Demirkir, Ü C Yildiz, G Çolakoğlu


Performance of some wood modification treatments against marine borers
2014 - IRG/WP 14-40668
Since some years, new treatment technology to protect wood against wood destroying fungi is introduced. Limited knowledge on their resistance to water organisms is available. Therefore, the resistance of chemically modified wood was assessed in a field test according to the European Standard EN 275 over a period of 3 resp. 5 years at sites in the North Sea and the Baltic Sea. Scots pine (Pinus syl...
A Klüppel, C Mai, H Militz, S Cragg


Penetration of phenol formaldehyde (PF) resin into beech wood studied by light microscopy
2015 - IRG/WP 15-20558
In this study, we examined the distribution and penetration depth of phenol-formaldehyde (PF) resin into wood specimens by light microscopy (LM). Two PF resins from different producers, of concentrations 9, 18 and 27 wt % in water, were vacuum impregnated into European beech wood (Fagus sylvatica) blocks of 15x25x50 mm³. The presence of chemical agent in the wood was carried out by way of their i...
V Biziks, S Bicke, H Militz


Decay resistance of beech wood and plywood treated with different type of phenol-formaldehyde (PF) resins
2016 - IRG/WP 16-40717
In this study treatment of beech and poplar wood veneers with (PF) resin industrial scale and screening tests of nine different phenol-formaldehyde (PF) resins were made. Specifically, the effect of different phenol-formaldehyde (PF) resin types on the resistance of beech wood against brown- and white-rot fungi was evaluated. Criteria for selection of optimal (PF) resin were based on minimum WPG ...
V Biziks, S Bicke, H Militz


Marine Borer Resistance of Acetylated and Furfurylated Wood – Results from up to 16 years of Field Exposure
2016 - IRG/WP 16-40756
Furfurylated and acetylated Scots pine sapwood has been tested since 1999 in a marine field with high marine borer activity. In 2004, two test groups with acetylated southern yellow pine (product later known as Perennial Wood™) were put out and over the whole test period differently furfurylated wood (later marketed as Kebony®) test groups have been started. Furthermore, some combinations of mo...
M Westin, P Larsson Brelid, T Nilsson, A O Rapp, J P Dickerson, S Lande, S Cragg


Improvement of wood properties by impregnation with liquefied spruce bark based resins
2016 - IRG/WP 16-40761
In this paper, biobased phenolic thermosetting resins are designed to be used as wood stabilization treatment. The originality of the study stands in substituting part of phenol by spruce (picea abies) bark: this is achieved by a liquefaction process in phenol in the presence of sulfuric acid as catalyst. Next, thermosetting resins are synthetized from liquefied bark by condensation on formaldehy...
X Duret, E Fredon, E Masson, P Gérardin


Lignin-Based Adhesive for Engineered Wood Products
2016 - IRG/WP 16-50319
Lignin as a naturally occurring polyphenolic compound has an excellent potential to replace petroleum-based phenol in formulation of phenol-formaldehyde adhesive that are used in manufacturing of engineered wood products. However, there are three major obstacles in application of polymeric lignin as phenol replacement: 1) low reactivity toward phenol, 2) high molecular weight, and 3) high polydisp...
I Kalami, M Arefmanesh, E Master, M Nejad


Weathering protection of European hardwoods through double modification
2017 - IRG/WP 17-30715
Beech and poplar were thermally modified, treated with melamine resin and both treatments were combined. The weathering performance (cracks and general appearance) of modified beech and poplar was assessed in natural weathering and correlated to material properties such as work in bending (WB) and Brinell hardness. In addition, the equilibrium moisture content after exposure of 12 months and subse...
G Behr, A Gellerich, S Bollmus, H Militz


Dimensional Stability of Melamine Formaldehyde-Treated Southern Pine
2017 - IRG/WP 17-40774
The objective of this preliminary study was to evaluate the influence of different levels of melamine formaldehyde (MF) and curing cycle on the dimensional properties of southern pine. Thirty samples for each combination of treatment and curing regimen plus untreated controls and controls subjected to the same curing regimen were tested. Shrinkage/swelling coefficients showed that up to 60% ASE c...
H M Barnes, L S Sites, T S F A França, M G Sanders, F J N França


The Comparison of Weathering Resistance of New Generation Wood-Coating Systems
2017 - IRG/WP 17-40789
In this study, the performance of wood-coating systems containing different UV absorbers was evaluated in artificial weathering conditions. Acrylic-based resin containing three different UV absorbers was applied on oriental beech and scots pine surfaces. Weathering conditions were sustained for 84 days. After the weathering test, the change of color and roughness on the wood surface was measured t...
Ö Özgenç, S Durmaz


The Study of the Preparation of Overlaid MDF with the Flame Retardant Impregnated Paper
2018 - IRG/WP 18-40848
The preparation of overlaid medium density fiberboard (MDF) was studied. The flame retardant impregnated papers (FRIP) were overlaid on the surface of the MDF for the fire protection. The results showed that: 1) The production of the FRIP was based on the technology of melamine-impregnated paper, which required the viscosity of the impregnated resin lower than 20s. However, with the addition of th...
W Qu, M Wu, Y-Z Wu


Thermally modified timber treated with methacrylate
2018 - IRG/WP 18-40849
Thermally modified timber (TMT) from Scots pine sapwood similar to Thermo-D quality was impregnated with methacrylate resin by the hot-and-cold method and subsequently cured at elevated temperatures. The results showed that methacrylate resin could be used to reduce colouring of painted TMT wood during accelerated weathering probably by hindering the migration of extractives. The resin itself did ...
O Karlsson, O Myronycheva, DJones, D Elustondo, D Sandberg


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