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A comparison of the chemistry of alkaline copper and micronized copper treated wood
2010 - IRG/WP 10-30528
This paper discusses the chemistry of the reaction of alkaline copper and micronized copper with wood. The objective of this study is to examine the copper species produced in wood during the fixation reaction using electron paramagnetic resonance (EPR) spectroscopy. The initial experiments (phases 1 to 2) were designed to confirm the effect of time of treatment and solution concentration on the s...
Wei Xue, P Kennepohl, J N R Ruddick


Treatment of Scots pine wood with oil in water and water in oil emulsion systems: Effects on boron leaching and water absorption
2010 - IRG/WP 10-30535
The aim of this study was to investigate the water absorption and water repellent efficiency of oils and oil water emulsions [oil-in-water (O/W) and water-in-oil (W/O)] and possibilities of reducing the amount of boron leaching from treated wood. Scots pine wood samples treated with waste or sunflower oil and water formulations contained 3%BA. The level of water absorption and water repellent effi...
E D Tomak, Ü C Yildiz, A Can


Copper nanoparticles in southern pine wood treated with a micronised preservative: Can nanoparticles penetrate the cell walls of tracheids and ray parenchyma?
2010 - IRG/WP 10-30547
This study tests the hypothesis that copper nanoparticles can penetrate the cell walls of southern pine wood treated with a micronised preservative. We examined the nanodistribution of particles in tracheid and ray parenchyma cell walls using state-of-the-art HR (High Resolution)-TEM and HR-STEM (Scanning Transmission Electron Microscope)-EDX. These devices are capable of atomic-scale resolution. ...
H Matsunaga, Y Kataoka, M Kiguchi, P Evans


Fungal decay resistance and mechanical properties of plywood panels made from maritime pine (Pinus pinaster) and bonded with cornstarch-quebracho tannin-phenol formaldehyde adhesive
2010 - IRG/WP 10-40490
The aim of this work is to demonstrate the performances of cornstarch-quebracho tannin-based resins designed as adhesive in the plywood production. In this way, the cornstarch and quebracho tannin was introduced in the classic adhesive formulation in order to supply a part of phenol-formaldehyde (PF). In order to evaluate the mechanical performances of optimal cornstarch-quebracho tannin-PF, plywo...
F Charrier, A Moubarik, A Allal, A Pizzi, B Charrier


Biological degradation of acetylated wood after 18 years in ground contact and 10 years in marine water
2010 - IRG/WP 10-40522
This paper addresses the resistance to biological degradation of acetylated wood. Firstly, it presents results from an EN 252 test after 18 years’ exposure. The test is still running in Nordic NWPC test fields, Simlångsdalen in Sweden and Viikki in Finland. Results from this test were presented after 5 years’ exposure ( IRG/WP 97-30139), and showed that the resistance of acetylated wood wit...
P Larsson Brelid, M Westin


Testing of decay resistance of sapwood and heartwood of thermally modified Scots pine and Norway spruce
2010 - IRG/WP 10-40523
Thermal modification at elevated temperatures changes the chemical, biological and physical properties of wood. One of the main targets of thermal modification is to increase the biological durability and decay resistance of wood. Although the effects of thermal modification on wood have been widely studied, the significance of sapwood and heartwood on the resistance of thermally modified wood has...
H Viitanen, S Metsä-Kortelainen


Sample Origin Influencing the Leachability of Wood Preservatives
2011 - IRG/WP 11-20474
The aim of this study is to see if the raw material influences fixation and leachability of wood preservatives. Moving towards more eco-friendly and –concious society, the wood industries must adjust itself to new rules and regulations. Greener solutions in wood protection are being tested and introduced, older systems are being improved, but questions still arise concerning some elements curren...
K Kängsepp. E Larnøy, P Meier


Comparison of rates of wood decay from four different field test protocols following 4-5 years exposure at a site in New Zealand
2011 - IRG/WP 11-30565
The rate of decay of Pinus radiata was evaluated using four different field test protocols at a site near New Plymouth, New Zealand. The average Scheffer index was 86 over the five year period of testing. The field tests were an in-ground stake test (AWPA Std E7-01) and three above ground tests – lap-joint (AWPA Std E16-98), decking (AWPC protocol) and ground proximity tests (AWPA Std E18-06) T...
P Lobb, K Day, A Siraa


Copper Nanoparticles in Southern Pine Wood Treated with a Micronised Preservative: Nanodistribution of Copper in the Pit Membrane and Border of an Earlywood Bordered Pit
2011 - IRG/WP 11-30566
Copper nanoparticles can penetrate the cell walls of unlignified parenchyma cells in southern pine wood treated with a micronised wood preservative, but they are excluded from lignified tracheid walls. This paper extends these observations to include the cell wall layers of the bordered pit. Focused ion beam and ion milling were used to make an ultra-thin section of the cell wall layers of an earl...
H Matsunaga, Y Kataoka, M Kiguchi, P Evans


Biological and mechanical performances of particleboard panels made from maritime pine (Pinus pinaster) and glued with cornstarch-mimosa tannin-urea formaldehyde adhesive
2011 - IRG/WP 11-40542
The objective of this work was to demonstrate the utility of cornstarch-mimosa tannin-based resins designed for application as an adhesive in the particleboard production. Bond qualities of cornstarch-mimosa tannin- urea formaldehyde (UF) (10:4:86, weight ratios) resins and commercial UF resin were assessed by using an automatic bonding evaluation system, prior to production of particleboard panel...
A Moubarik, F Charrier, A Pizzi, A Allal, B Charrier


Acetylation Properties of Southern Pine and Radiata Pine
2011 - IRG/WP 11-40543
The chemical modification of wood via acetylation with acetic anhydride has been a well investigated technology and is of current commercial interest due to improved properties such as dimensional stability as well as resistance to termites and resistance to rot and decay fungi. Despite this, the acetylation of a board substrate requires further investigation in order to assess board properties a...
J Allen, T Guinn, J Dickerson


Further Studies on the Distribution of Copper in Treated Wood Using an XRF Microscope Technique
2011 - IRG/WP 11-40549
There are two distinct forms of copper in aqueous copper based wood preservative systems that are currently used in the United States for treatment of southern pine lumber. These are systems using either soluble copper (typically amine based) or the more recent particulate or “micronized” copper as the primary biocide. Studies reported last year showed that there were distinct differences in...
A Zahora


Quantification of mobile copper (II) levels in micronized copper treated wood
2011 - IRG/WP 11-40550
The purpose of this study is to quantify the mobile copper(II) levels in micronized copper treated wood using electron paramagnetic resonance (EPR) spectroscopy. A correlation between EPR and EDX intensities on mobile copper levels in a series of copper sulphate treated wood was created as a calibration standard. Laboratory treatments using micronized copper formulations were then carried out and ...
Wei Xue, P Kennepohl J N R Ruddick


Decrease of stiffness properties of degraded wood predicted by means of micromechanical modeling
2011 - IRG/WP 11-40570
Wood exhibits a highly anisotropic mechanical behavior due to its heterogeneous microscopic structure and composition. Its microstructure is organized in a strictly hierarchical manner from a length scale of some nanometers, where the elementary constituents cellulose, hemicelluloses, lignin, and extractives are found, up to a length scale of some millimeters, where growth rings composed of earlyw...
T K Bader, K Hofstetter, G Alfredsen, S Bollmus


Copper Migration from Micronized Copper Preservatives Treated Wood in soil contact:
2011 - IRG/WP 11-50280
Emerging formulations of preservatives made with micronized basic copper carbonates with azoles and/or quat to control copper tolerant fungi have been used to replace formulations containing soluble copper to reduce the leaching of copper and the corrosion of metal in contact with wood. This study proposes to use laboratory soil leaching test AWPA standard (E20-08) to estimate the amount of copper...
Lei Wang, D P Kamdem


Using an accelerated laboratory method to evaluate Aureobasidium pullulans colonization on painted surfaces and underlying wood substrate
2012 - IRG/WP 12-20480
Mold growth on painted surfaces can lead to premature paint film failure and is unsightly. Aureobasidium pullulans has been identified as a major cause of black stain on surfaces painted with acrylic or latex paints. In this study, an accelerated laboratory method developed by Zabel and Horner (1981) was used with modifications to the type of agar used and sample evaluation methods. A study was ...
C Schauwecker, L Burns, A Preston


Accessibility of Wood Cell Walls to Well-defined Platinum Nanoparticles
2012 - IRG/WP 12-20494
Copper nanoparticles are found in the walls of parenchyma cells in southern pine sapwood treated with a micronised wood preservative, but they are absent from tracheid walls. Hence, we hypothesized that small nanoparticles can penetrate the walls of unlignified parenchyma cells, but are excluded from lignified tracheid walls. This paper tests this hypothesis by treating pine sapwood with an aqueou...
H Matsunaga, Y Kataoka, M Kiguchi, P D Evans


Supercritical impregnation of wood with siloxane
2012 - IRG/WP 12-30595
This paper describes the effect of supercritical impregnation with siloxane on the water repellency of Scots pine (Pinus sylvestris) sapwood samples. Samples were impregnated with a low amount of siloxane dissolved in supercritical carbon dioxide using isopropanol as a co-solvent. Siloxane retention (i.e. weight percent gain (WPG)) of the treated samples was 1.3 % (w/w) as found by mass balance. T...
A Kjellow, F Imsgard, J Fernandes, O Henriksen, E Klaassen, R Wagner, J Delis


Stabilization of IPBC in wood through the use of organosilicon compounds
2012 - IRG/WP 12-30597
The aim of the research was to increase durability of wood treated with 3-Iodo-2-propynyl butylcarbamate (IPBC). The study used a blend of silanes. Biological examination against microfungi was performed to determine resistance of Scots pine wood treated with the tested formulations. Chemical analysis by the Electrospray Ionization Mass Spectrometry (ESI-MS) of water extracts from the leaching per...
B Mazela, W Perdoch


Correlation of %Acetyl and Fiber Saturation in Acetylated Southern Pine Boards
2012 - IRG/WP 12-40598
Wood acetylation represents a chemical modification that increases the hydrophobicity of wood. The level of acetylation in the wood structure determines the extent of hydrophocity with higher levels providing reduced moisture affinity. Due to the reduced hygroscopic nature of acetylated wood, performance features such as dimensional stability, resistance to termites, and resistance to rot and de...
J Dickerson, E Cwirko, J Allen


Efficiency of the Amazon Forest Oils as Preservatives to the Attack of cellulolytic fungi in Pine Wood
2012 - IRG/WP 12-30599
The bobbins of wood are used for storage and field installation of cables from the electricity and telecommunications sectors. There are legal requirements governing the Brazilian ways of treating the wood used in these sectors, aimed at preventing pollution and protecting nature. When exposed to severe environmental conditions in Brazil these products are degraded and occurs many operational prob...
S Silveira, I M S Mendes, R S Paiva, J E Volponi, R C G Comar, R S Cruz


Tar-oil uptake vs time in immersion treatment of short pine posts: A simple technique applicable to rural communities of Papua New Guinea
2012 - IRG/WP 12-40608
Pinus caribaea and Araucaria cunninghamii logs ca. 100 mm in diameter were shortened to lengths 25-30 cm, conditioned to at/below fibre saturation point (FSP) for immersion/dip treatment using a hot- and- cold bath open- tank process. Before oven-drying and subsequent treatment, individual test specimens were numbered, their green weights and volumes, and dry weights recorded for basic density, vo...
B K Gusamo, R Tulo


Surface moulds and staining fungi on acetylated wood – effect of increasing acetyl content
2013 - IRG/WP 13-10797
Wood used in outside applications is susceptible to weathering and photo degradation, which often leads to surface discoloration, loss of brightness and surface deterioration. Research has shown that acetylated wood is more resistant against brown rot, white rot and soft rot, and more dimensionally stable than untreated wood. However, acetylated wood seems still to be disfigured by surface moulds ...
L Ross Gobakken, S Bardage, C J Long II


The assessment by visual grading, change of color and ergosterol content ratings, the resistance to mould fungi of treated with wood preservative Scots pine sapwood
2013 - IRG/WP 13-20514
The filamentous (mould) fungi belonging to Ascomycetes, Deuteromycetes group are an cosmopolitan organisms which attacks wooden elements disfiguring them, dropping their value and causing environmental and health hazard. The fungi in a short time cause mainly disfigurement of wood does not effect on strength properties of wood, but with strong prolongation of duration of conditions favourable for ...
A Fojutowski, A Koziróg, A Kropacz


Extraction and analysis of DNA from green and seasoned timber as basic methods for determination of wood species and origin
2013 - IRG/WP 13-20523
Against the background of the European timber trade regulation EUTR, commenced to law by March 2013, the determination of wood species and tracing of its origin is getting a great importance. A promising approach for establishing fast and reliable tracking systems for wood products is DNA analysis. A critical point is the extraction of analysable DNA from the wood and its lignified cell walls. Thu...
K Jacobs, H Mende, W Scheiding


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