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Buffered Amine Oxide Treatment Systems for Ammonical Copper Wood Preservatives
2014 - IRG/WP 14-40685
Wood is the most versatile, practical and sustainable building material in the world. In modern countries, wood is a well-managed renewable resource that has a small carbon footprint. Wood does suffer from a lack of durability against invasive organisms such as insects and fungi. Steel, aluminum and composites have emerged as viable alternative building materials. These sectors market the defi...
R W Clawson Jr


Ammoniacal zinc borate as solid wood preservative
2014 - IRG/WP 14-30659
Zinc borate, well-known for its fungicidal, insecticidal and flame resistant properties, is widely used in manufacture of lignocellulose particle board. This form of borate is the least water soluble form available providing advantages as well as disadvantages for use as a wood preservative. This form does not leach from wood under conditions of high humidity, but it is also very difficult to appl...
C Ibáñez, C Mantero, A Ibarra, M Rabinovich


Buffered Amine Oxide Treatment Systems for Imparting Water Based Azoles/Insecticides in Douglas Fir and Eucalyptus
2015 - IRG/WP 15-40707
In today’s world, wood remains the most versatile, practical and sustainable building material. In contemporary countries, wood is a well-managed renewable resource that has a remarkably small carbon footprint compared to those of steel, aluminium, composites, and concrete. These alternative materials have continued to emerge as viable building materials given the durability issues of untreate...
R W Clawson Jr


Above-ground performance of a buffered amine oxide treatment system against Mastotermes darwiniensis
2016 - IRG/WP 16-10855
Above-ground H2 field tests against Mastotermes darwiniensis were conducted in far north Queensland to assess the efficacy of buffered amine oxide treatments in the softwoods Pinus sylvestris and P. radiata, and the hardwoods Eucalyptus regnans and E. diversicolor. Untreated hardwoods and slash pine bait wood (P. elliottii) were severely attacked or destroyed, while untreated P. sylvestris was mod...
L J Cookson, R W Clawson Jr


Production of reactive oxygen species in the presence of oxidized iron and oxalate under conditions mimicking brown-rot fungal degradation of wood
2016 - IRG/WP 16-10861
The biochemical role of oxalate in the fungal solubilization of iron is well known, but additional information is needed on the role that oxalate plays in the brown-rot decay of lignocellulose. In this study iron sequestration from iron and iron oxide-hydroxides was assessed with regard to the function of a chelator-mediated Fenton (CMF) reaction and the generation of reactive oxygen species (ROS)...
Yuan Zhu, Liangpeng Zhuang, B Goodell, Jinzhen Cao, J Mahaney


Effects of fungal exposure on air and liquid permeability of nanosilver- and nanozincoxide-impregnated Paulownia wood
2016 - IRG/WP 16-30680
Effects of aqueous dispersion of silver and zinc-oxide nano-particles on air and liquid permeability of Paulownia wood exposed to T. versicolor were studied in the present research project. Specimens were also heat-treated at 100 and 150°C and compared with the control specimens. Permeability values were measured when the moisture content of the specimens was 12%. Results showed significant incre...
H R Taghiyari, A Kalantari, M Ghorbani Kookandeh, F Bavaneghi, M Akhtari


Accelerated Weathering Performance of Impregnated Wood Samples Coated with Zinc by Means of Plasma-Assisted Particle Deposition
2016 - IRG/WP 16-30682
Many different methods are currently applied for wood protection against outdoor conditions. The most important of these is the process of impregnation with liquid substances. However, this kind of wood preservatives cannot provide a long-term protection of wooden surfaces. Weathering-resistant surfaces can be obtained by applying UV absorbing agents. In this study, the influence of zinc particles...
A Can, H Sivrikaya


Effect of Nano-Silane on Permeability in MDF as a Result of Susceptibility to Moulds and Fungi
2016 - IRG/WP 16-40716
Effects were studied of vapor chamber on specific gas permeability of nanosilane-treated medium-density fiberboards (MDF). Size range of nanoparticles was 20 – 80 nm. Nano-silane (NS) was used at four consumption levels of 0, 50, 100, and 150 g/kg dry wood fibers. Density of all treatments was kept constant at 0.67 g/cm3. Specimens were kept for 18 weeks in vaporized chamber; their specific gas ...
H R Taghiyari, J Norton, A Moradiyan, M Sadegh Taher Tolou Del, H Siahposht, B Moradi-Malek, M Noferesti


Incorporation of raw boron minerals to protect particleboard against decay and mold fungi, termites and insects
2016 - IRG/WP 16-40729
This paper evaluated the biological performance of particleboards incorporated with the raw boron minerals ulexite and colemanite against decay, mold fungi, termites and insect larvae in comparison with that of particleboards with zinc borate, or boric acid plus a borax mixture. The results showed that ulexite and colemanite were highly effective against the decay fungi and termite attack in labor...
S N Kartal, E Terzi, P Gerardin, C M Ibanez, T Yoshimura


Decay Resistance of MDF Manufactured with Huntite- Hydromagnesite and Zinc borate
2017 - IRG/WP 17-30710
The objective of this study was to evaluate the effectiveness of some mineral based fire retardants on decay resistance of Medium density fiberboard (MDF). Two mineral based chemicals containing (Huntite/Hydromagnesite) and zinc borate (ZB) were used at two different concentrations for panel manufacturing. Decay test of samples was performed according to EN 113 standard method. At the end of the t...
U E Başer, D Ustaömer, Ö Özgenç


Effects of Nano-Wollastonite Impregnation on Fire Properties of Some Thermally-Treated Solid Wood Species
2017 - IRG/WP 17-40771
The effects of nano-wollastonite (NW) suspension impregnation on the fire-retarding properties of heat-treated solid wood of three species (beech, poplar, fir) were studied. Heat treatment was performed at two temperatures of 180 °C and 200 °C. Impregnation was carried out at a pressure of 3 bars for 30 min. The fire properties included ignition time, glowing time, back-darkening, back-splitting...
H R Taghiyari, R Hossinpourpia, S Adamopoulos, A Jahangiri, D Rabie


Five-year evaluation of a field trial of Eucalyptus grandis poles treated with zinc and boron
2017 - IRG/WP 17-30721
Round Eucalyptus wood treatment in sequential stages with inorganic borates and metal salts (zinc sulfate and boric acid+borax) was studied; the aims were to form an insoluble precipitate of zinc borate inside wood and to reduce treatment costs by performing the first treatment by simple ascent and diffusion of the preservative, at the same time as it was sought to impregnate the heartwood. The se...
C Ibáñez, A Camargo, C Mantero, M Rabinovich


Termite resistance of wood-plastic composites made with acetylated wood flour, coupling agent or zinc borate
2018 - IRG/WP 18-10917
There is little published scientific literature on the laboratory or field testing of wood-plastic composites (WPC) against termite attack. Therefore, the objective of this research was to investigate termite resistance (both laboratory and field) of 5 different extruded WPC blends of 50% western pine wood flour (WF) and high-density polyethylene (HDPE), and untreated pine solid wood. The study in...
R E Ibach, Y S Hadi, C M Clemons, S Yusuf


Mechanism of nano metal fluorides against fungi
2018 - IRG/WP 18-30730
Metal fluoride nanoparticles are promising because of their low water solubility, which reduces the need for fixatives required in widely used active ingredient in wood preservatives such as copper and boron. Wood specimens treated with fluoride sols of MgF2 and CaF2 have been tested against brown-rot fungi (Coniophora puteana and Rhodonia placenta) in accordance with EN 113 and against termites (...
S M Usmani, K Klutzny, I Stephan, T Hübert, E Kemnitz


Biocidic effect of nano metal fluorides against brown-rot fungi
2019 - IRG/WP 19-30732
Metal fluoride nanoparticles are promising because of their low water solubility, which reduces the need for fixatives required in widely used active ingredients in wood preservatives such as copper and boron. The effectiveness of nano metal fluorides was compared to sodium fluoride treated wood samples. Wood specimens treated with homo-dispersed sols of MgF2 and CaF2 were tested against brown-rot...
S M Usmani, K Klutzny, I Stephan, E Kemnitz


Application of nano metal fluorides against termites
2019 - IRG/WP 19-30733
Recent research has shown that fluorides such as NaF have potential as a wood preservative against termite attack (Pan and Wang, 2015). However, NaF has high leaching susceptibility because of its solubility (40 g/l ) which can reduce its efficacy over long term. Metal fluoride nanoparticles such as MgF2 and CaF2 present a viable alternative to water soluble fluoride-based wood preservatives as th...
S M Usmani, K Klutzny, Y de Laval, R Plarre, D McMahon, I Stephan, T Hübert, E Kemnitz


Boron dual-treatments for Douglas-fir utility poles: Tracking boron migration over time
2019 - IRG/WP 19-30739
The potential for using boron pressure-treatment prior to over-treatment with conventional, heavy-duty wood preservatives to limit internal decay in-service was investigated in two field tests on Douglas-fir utility poles. Pole sections were pressure-treated with disodium octaborate tetrahydrate (DOT) and then over-treated with either pentachlorophenol or copper naphthenate in oil. Alternatively, ...
J Cappellazzi, M J Konkler, J J Morrell


Effect of damage to polyurea coatings on metal losses from ammoniacal copper zinc arsenate treated Douglas-fir pile sections
2019 - IRG/WP 19-40867
Metal-based preservatives remain the most widely used treatments for protecting wood in soil or water contact. While these treatments are highly effective, one drawback is a tendency for small amounts of metal to migrate into the surrounding environment. The greatest risk in this regard is copper because many organisms are highly sensitive to this metal. While post treatment practices can reduce ...
M J Konkler, J J Morrell


Wood Protection Using Nano Metal Oxides in Propylene Glycol
2022 - IRG/WP 22-30760
Metals and metal oxides are known to have properties that can protect wood from degradation. Nanoparticles, due to its unique physical and chemical properties can enhance the protection to a much greater extent. Major constraints in dealing with nanoparticle dispersion can only be resolved by identifying a proper dispersive medium. Studies were carried out by preparing nanodispersion of four metal...
S Nair, G B Nagarajappa, K K Pandey


Comparative study of the properties of silicate coatings with different mineral pigments (titanium dioxide, iron (III) oxide, copper (II) oxide) on the surface of wood
2022 - IRG/WP 22-40936
Silicate coatings are attractive alternatives to conventional organic-based coatings for wood protection. In this work, silicate coatings were prepared with a potassium silicate binder modified with a methyl siliconate solution, and three types of mineral pigments titanium dioxide, iron (III) oxide and copper (II) oxide. The coatings were applied on beech wood and cured under ambient conditions. T...
A M Cheumani Yona, M Petrič


Optimized composition of alkyd emulsion with nanoparticles of iron oxide for enhancing protection of thermally modified wood
2022 - IRG/WP 22-40940
Thermal treatment is acknowledged as an environmentally friendly method to improve durability of wood and some of its properties, such as biological resistance, dimensional stability, reduced hygroscopy. Despite these improvements, when used outdoors, also thermally treated wood is subjected to the action of environmental factors, like solar radiation, moisture, precipitations, temperature, etc., ...
E Sansonetti, D Cīrule, I Andersone, B Andersons, E Kuka


Effect of nano-particle characteristics and concentration on UV protection of timber: A field exposure test
2022 - IRG/WP 22-40941
Wood has a well-known susceptibility to ultra-violet light degradation, leading to premature replacement. A variety of products have been developed to protect against this damage, but most provide less than 12 months of protection and must be regularly reapplied. Developing improved coatings would help reduce wood losses and reduce maintenance costs. Nano-particles have a variety of attractive pro...
T Yi, J J Morrell


Assessing changes in hardness of furfurylated wood on a nano-scale to mimic levels experienced by the marine wood-boring crustacean, Limnoria
2023 - IRG/WP 23-11016
Wood-boring crustaceans and bivalves can cause severe damage to wooden structures in the marine environment, warranting the need for novel protection systems, such as chemical modifications. Furfurylation increases mechanical properties and resistance of timber species that would usually be susceptible to biodegradation by these borers, such as pine. In rapid laboratory and field testing, furfuryl...
L Martin, J Zekonyte, S Lande, M Westin, S Cragg


Evaluation of the efficacy of silver nanoparticles and chitosan oligomer composites as poplar wood protective treatments against termites
2023 - IRG/WP 23-40963
Populus × euramericana ‘I-214’ (poplar) is a fast-growing species widely distributed throughout the world, and in the Castile-Leon region of Spain it accounts for more than 50% of all plantations. Its wood is becoming increasingly appreciated, yet its low durability against xylophagous agents —termites being one of the most aggressive and destructive in warm climates— continues to be a li...
E Spavento, M T Troya, M Casado-Sanz, J Martín-Gil, P Matín-Ramos, L Robertson, L Acuña-Rello


Effectivity of zinc borate in medium density fiberboard (MDF) for ground proximity testing
2024 - IRG/WP 24-20723
Medium-density fiberboard (MDF) is one of the most used and versatile wood composites. Most of its use has been focused on interior applications. Adhesives such as p-MDI (polymeric methyl diphenyl diisocyanate) provide MDF with a better performance against moisture, but resistance against decay is also required for outdoor use. A mix of wood fibers, p-MDI, and 0.75%-1.5% of ZB was made to produce ...
S M Vega Gutierrez, T Olivadoti


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